Abstract

The linearity of diffuse transmittance spectra was considered on the basis of the Kubelka–Munk theory. The sub-linear dependence of –logT on the component concentration was determined and a linearisation method is suggested. The main point of linearisation is solving a cubic equation with absorbance to be linearised as an unknown variable and with the equation coefficients being power functions of the sample scattering capacity. The performance of the method is tested by employing the spectra of adsorbed water in the 1796–2004 nm range. The cellulose sheet was a matrix for adsorbed water molecules. Seventeen water content values from 0.6% to 22.7% (w/w) were prepared for calibration–prediction procedures. Raw spectra and linearised spectra were analysed by principal component analysis and partial least squares (PLS) regression. PLS cross-validation shows the 2.85-fold decrease of the prediction error after linearisation.

© 2004 NIR Publications

Reflectance and Transmittance of Inhomogeneous Diffusing Layers

Åke S:son Stenius
J. Opt. Soc. Am. 44(10) 804-805 (1954)

Atmospheric diffuse transmittance of the linear polarization component of water-leaving radiation

Tianfeng Pan, Xianqiang He, Yan Bai, Jia Liu, Qiankun Zhu, Fang Gong, Teng Li, and Xuchen Jin
Opt. Express 30(15) 27196-27213 (2022)

Spectral reflectance and transmittance of stacks of nonscattering films printed with halftone colors

Mathieu Hébert and Jacques Machizaud
J. Opt. Soc. Am. A 29(11) 2498-2508 (2012)

Total Reflectances of Opaque Diffusers

W. R. Blevin and W. J. Brown
J. Opt. Soc. Am. 52(11) 1250-1255 (1962)

Goniometric Spectrometer for the Measurement of Diffuse Reflectance and Transmittance of Skin in the Infrared Spectral Region

Carl Clark, Ralph Vinegar, and James D. Hardy
J. Opt. Soc. Am. 43(11) 993-998 (1953)