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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 25,
  • Issue 4,
  • pp. 460-465
  • (1971)

ΔMs= ±2 Transitions of Benzophenone and Derivatives in the Phosphorescent Triplet State Via Fast-Scan Flash-Synchronized ESR

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Abstract

Δ<i>M</i><sub>s</sub> = ±2 transitions of benzophenone, <i>p</i>-hydroxybenzophenone, <i>p</i>-methyl-benzophenone, <i>p</i>-aminobenzophenone, benzyl, xanthane-9-one, fluorene-9-one, and thio-xanthane-9-one in EPA glass at 77 K were observed with a fast-scan flash-synchronized X-band ESR spectrometer. Instrumentation which may be useful in the observation of Δ<i>M</i><sub>s</sub> = ±2 transitions in similar short-lived <i>S</i>≠<i>O</i> molecules is discussed.

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