Abstract
Mixed-valent transition metal dimers have become key systems for understanding many fundamental aspects of electron transfer dynamics.1 We have been interested in the mixed-valent dimer [(NC)5RuIICNRum(NH3)5]1- for which optical excitation into the metal-metal charge transfer (MMCT) band produces a state which is highly unstable with respect to back electron transfer.
© 1992 The Author(s)
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