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Conferences > QELS > 1992 > QThF > QThF2
  • Quantum Electronics and Laser Science Conference
  • OSA Technical Digest (Optica Publishing Group, 1992),
  • paper QThF2

Resonance Raman and absorption studies of ultrafast polyene photophysics

Anne B. Myers, Xiaopei Ci, David L. Phillips, Jon-Marc Rodier, and Curtis Westerfield

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Abstract

Substituted ethylenes and polyenes are simple representatives of a large class of molecules that can undergo rapid photoinduced cis-trans isomerization. We are employing a combination of steady-state uv resonance Raman and picosecond time-resolved absorption and Raman spectroscopies to probe the dynamics of photo isomerization and electronic and vibrational relaxation in cisstilbene, butadiene, and hexatriene, with particular emphasis on the solvent dependence of the photophysics.

© 1992 Optical Society of America

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