Abstract
This study probes the basic dynamics and energy transfer mechanisms by which laser-stimulated surface reactions proceed. We photofragment surface molecules by exciting internally repulsive states and analyze the velocities of fragments ejected away from the surface. We present a UHV study of photofragmentation CH3Br physisorbed on LiF.1 The expected Chemical, electronic, and optical inertness of LiF was desired for simplicity. Also recent resulta In another labora- tory2 showed a completely unexpected and poorly understood molecular photodesorption.
© 1986 Optical Society of America
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TuA1 Microphysics of Surfaces, Beams, and Adsorbates (MSBA) 1985
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