Dispersion of Carbon Dioxide*

J. G. Old; K. L. Gentili; E. R. Peck

doi:10.1364/JOSA.61.000089

Dispersion of Carbon Dioxide

J. G. Old, K. L. Gentili, and E. R. Peck

Journal of the Optical Society of America
Vol. 61,
Issue 1,
pp. 89-90
(1971)
•https://doi.org/10.1364/JOSA.61.000089

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J. G. Old, K. L. Gentili, and E. R. Peck, "Dispersion of Carbon Dioxide*," J. Opt. Soc. Am. 61, 89-90 (1971)

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History
- Original Manuscript: June 29, 1970
- Published: January 1, 1971

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Abstract

The refractivity of carbon dioxide has been measured at vacuum wavelengths from 0.4801260 to 1.8172 (μm). The data were fitted to a Sellmeier curve having three terms. The refractivity reduced to 1 atm at 0°C for 0.5462 μm is (n − 1) 10⁷ = 4505.0±0.6. By use of the dispersion formula, quantities related to dispersion were also found: absorption, oscillator strengths, dielectric constant, Verdet constant, and Rayleigh-scattering coefficient.

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Vacuum wavelength (μm)	(n−1)10⁷ Experimental	(n−1)10⁷ Predicted	Difference
1.8172285	4362.699	4362.704	−0.005
1.6945208	4373.838	4373.836	+0.002
1.5293544	4387.443	4387.414	+0.029
1.4756503	4391.562	4391.573	−0.011
1.3722327	4399.414	4399.361	+0.053
1.3507884	4400.854	4400.953	−0.099
1.2960201	4405.031	4405.005	+0.026
1.0142573	4427.044	4427.037	+0.007
0.9660434	4431.376	4431.391	−0.015
0.9227030	4435.584	4434.595	−0.011
0.9125471	4436.630	4436.628	+0.002
0.8931145	4438.662	4438.662	−0.000
0.8777160	4440.321	4440.310	+0.011
0.8266794	4446.330	4446.302	+0.028
0.7440946	4457.856	4457.846	+0.010
0.7247163	4460.979	4461.004	−0.025
0.5462258	4505.000	4505.007	−0.007
0.5087242	4520.165	4520.158	+0.007
0.4801260	4534.159	4534.160	−0.001

Wavelength	Predicted “S”
0.3635 (μm)	0.532
0.4000	0.535
0.4360	0.533
0.4500	0.533
0.5460	0.525
0.5500	0.524
0.5780	0.521
0.5893	0.518
0.6000	0.515
0.6500	0.500
0.7000	0.483
0.7500	0.463
0.8000	0.400
0.8500	0.416
0.9000	0.366
0.9875	0.357

Vacuum wavelength (μm)	(n−1)10⁷ Experimental	(n−1)10⁷ Predicted	Difference
1.8172285	4362.699	4362.704	−0.005
1.6945208	4373.838	4373.836	+0.002
1.5293544	4387.443	4387.414	+0.029
1.4756503	4391.562	4391.573	−0.011
1.3722327	4399.414	4399.361	+0.053
1.3507884	4400.854	4400.953	−0.099
1.2960201	4405.031	4405.005	+0.026
1.0142573	4427.044	4427.037	+0.007
0.9660434	4431.376	4431.391	−0.015
0.9227030	4435.584	4434.595	−0.011
0.9125471	4436.630	4436.628	+0.002
0.8931145	4438.662	4438.662	−0.000
0.8777160	4440.321	4440.310	+0.011
0.8266794	4446.330	4446.302	+0.028
0.7440946	4457.856	4457.846	+0.010
0.7247163	4460.979	4461.004	−0.025
0.5462258	4505.000	4505.007	−0.007
0.5087242	4520.165	4520.158	+0.007
0.4801260	4534.159	4534.160	−0.001

Wavelength	Predicted “S”
0.3635 (μm)	0.532
0.4000	0.535
0.4360	0.533
0.4500	0.533
0.5460	0.525
0.5500	0.524
0.5780	0.521
0.5893	0.518
0.6000	0.515
0.6500	0.500
0.7000	0.483
0.7500	0.463
0.8000	0.400
0.8500	0.416
0.9000	0.366
0.9875	0.357

Abstract

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Tables (2)

Equations (7)

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