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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 57,
  • Issue 7,
  • pp. 729-732
  • (2003)

Laser-Enhanced Ionization with Avalanche Amplification: Detection of Cesium at fg/mL Levels

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Abstract

The avalanche amplification of the laser-enhanced ionization signal of Cs atoms in a flame has been studied. Ionization of Cs atoms, enhanced by two-step excitation, was detected in hydrogen and propane flames. By employing the effect of avalanche amplification of electrons, high signal-to-noise ratio (~10<sup>4</sup>) was obtained for a 100 ppt Cs solution. The extrapolated limit of detection was 30 fg/mL (ppq).

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