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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 55,
  • Issue 12,
  • pp. 1618-1621
  • (2001)

Global Phase Angle Description of Generalized Two-Dimensional Correlation Spectroscopy: 1. Theory and its Simulation for Practical Use

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Abstract

The concept of a global phase map derived from generalized two-dimensional synchronous and asynchronous correlation spectra is introduced to extract the purely correlational information by intentionally canceling amplitude information. For the practical usage of a global 2D phase map, a filtering method based on the standard deviation spectrum obtained from the time series intensity profiles is proposed to remove the effect of small amplitude noise. A simulation created with the use of three synthesized bands with exponential decay has clearly detected the only difference in the <i>characteristic rate constant</i> of the decay process in the global 2D phase map, although the three bands have different initial values of the peak intensity <i>amplitudes</i>.

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