Abstract
An unambiguous comparison has been made of the spatial features of a 27.12 and a 40.68 MHz inductively coupled plasma. Experiments were carried out with a switchable-frequency, solid-state radio-frequency generator from the Leco 2000 system. Several features of analytical significance have been evaluated in a spatially resolved fashion. Results from optimization of the magnesium ion-to-atom (Mg II/Mg I) line-intensity ratio have been compared. The volume of the two discharges was estimated from molecular nitrogen-ion emission, and a spatially resolved map of the Fe(I) excitation temperature was determined by means of a Boltzmann analysis at each spatial location. Calcium and magnesium ion-to-atom line-intensity ratios have been calculated throughout both plasmas. Finally, limits of detection are presented. The results indicate that the plasma operated at 40.68 MHz provides slightly better figures of merit, although fundamental parameters suggest a lower degree of analyte excitation. This difference is explained by examining the results of a simulation of plasmas operated at 27.12 and 40.68 MHz.
PDF Article
More Like This
Multielemental analysis of prehistoric animal teeth by laser-induced breakdown spectroscopy and laser ablation inductively coupled plasma mass spectrometry
Michaela Galiová, Jozef Kaiser, Francisco J. Fortes, Karel Novotný, Radomír Malina, Lubomír Prokeš, Aleš Hrdlička, Tomáš Vaculovič, Miriam Nývltová Fišáková, Jiří Svoboda, Viktor Kanický, and Javier J. Laserna
Appl. Opt. 49(13) C191-C199 (2010)
Propagation characteristics of terahertz wave in inductively coupled plasma
Jinhai Sun, Yan Zheng, Jielin Shi, Yarui Zhao, Yu Li, Ding Wu, He Cai, Xutao Zhang, Xianli Zhu, Yongqiang Liu, Xinxue Sun, Zengming Chao, Hongcheng Yin, Wenqi Lu, and Hongbin Ding
Opt. Express 29(22) 35837-35847 (2021)
Cited By
You do not have subscription access to this journal. Cited by links are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.
Contact your librarian or system administrator
or
Login to access Optica Member Subscription