Abstract

We present chemical kinetics and environmental monitoring applications in the long-wavelength mid-infrared (LW-MIR) region using a new diagnostic that exploits a widely tunable light source emitting in the LW-MIR. The custom-designed laser source is based on a difference-frequency generation (DFG) process in a nonlinear orientation-patterned GaAs crystal. The pump laser, an external-cavity quantum cascade laser, is tuned in a continuous-wave (cw) mode, while the signal laser, a ${{\rm{CO}}_2}$ gas laser, is operated in a pulsed mode with a kilohertz repetition rate. The idler wavelength can be tuned between 11.58 (${863.56}\;{\rm{c}}{{\rm{m}}^{- 1}}$) and 15.00 µm (${666.67}\;{\rm{c}}{{\rm{m}}^{- 1}}$) in a quasi-cw manner. We discuss the unique prospective applications offered by probing the LW-MIR region for chemical kinetics and environment-monitoring applications. We showcase the potential of the DFG laser source by some representative applications.

© 2023 Optica Publishing Group

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