Abstract
Trace-level ammonia gas in air was analyzed using a fiber-based compact cavity ring-down spectrometer (CRDS). For the compact spectrometer, a 20 cm linear cavity with two high reflectivity (${\gt}{99.999}\%$) mirrors was employed. The laser frequency was locked to the cavity resonance by using frequency shifted (160 MHz) optical feedback. For ${{\rm{NH}}_3}$ detection, a strong absorption band at 1513.98 nm with an absorption cross section of ${{3}.{3\cdot1}}{{{0}}^{- 21}}\;{\rm{cm}}/{\rm{molecule}}$ was used. As a result, a detection sensitivity of ${\sim}{0.1}\;{\rm{ppb}}$ (${{3 {\text -}}}\sigma$) was achieved for ${{\rm{NH}}_3}$ within 10 s.
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