Raman spectroscopy of gases with a Fourier transform spectrometer: the spectrum of D₂

Comparison of Raman and Infrared Line Positions (cm⁻¹) for H₂

a Measurements at 600 Torr corrected to zero pressure (zero shift for υ = 0−0, 0.002-cm⁻¹ shift for υ = 1−0; see Ref. 12).
b Infrared line frequencies are from Jennings and Brault 1983 (for υ = 0−0) and Bragg et al. 1982 (for υ = 1−0).
c Errors in parentheses are one standard deviation in units of the least significant digit.

Measured Line Positions (cm⁻¹) for D₂

a Measurements at 600 Torr corrected to zero pressure (zero shift for υ = 0−0, 0.001-cm⁻¹ shift for υ = 1−0; see Refs. 16, 18, and 19).
b Errors in parentheses are one standard deviation in units of the least significant digit.

Dunham Coefficients for D₂

a These values were found from our measurements listed on Table II. The weighted standard error of the fit was 9.0 × 10⁻⁴ cm⁻¹.
b Errors in parentheses are one standard deviation in units of the least significant digit.

Table I

Comparison of Raman and Infrared Line Positions (cm⁻¹) for H₂

a Measurements at 600 Torr corrected to zero pressure (zero shift for υ = 0−0, 0.002-cm⁻¹ shift for υ = 1−0; see Ref. 12).
b Infrared line frequencies are from Jennings and Brault 1983 (for υ = 0−0) and Bragg et al. 1982 (for υ = 1−0).
c Errors in parentheses are one standard deviation in units of the least significant digit.

Table II

Measured Line Positions (cm⁻¹) for D₂

a Measurements at 600 Torr corrected to zero pressure (zero shift for υ = 0−0, 0.001-cm⁻¹ shift for υ = 1−0; see Refs. 16, 18, and 19).
b Errors in parentheses are one standard deviation in units of the least significant digit.

Table III

Dunham Coefficients for D₂

a These values were found from our measurements listed on Table II. The weighted standard error of the fit was 9.0 × 10⁻⁴ cm⁻¹.
b Errors in parentheses are one standard deviation in units of the least significant digit.