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Soft x-ray emission from Li–Mg and Li–Al alloys and comparisons with KKR-CPA calculations

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Abstract

The K emission band of Li and L23 emission bands of Mg and Al have been measured for Li–Mg and Li–Al prepared in a range of concentrations either by coevaporation or by evaporating thin films of Li on Mg(Al) substrates or Mg(Al) on Li substrates. The Li K spectrum is nearly unchanged at all alloy concentrations in the Li–Mg system but broadens and develops a low energy shoulder for large Al concentrations in the Li–Al system. Both Mg and Al L23 spectra are narrower and more peaked at low energy in the equilibrium alloys than in the pure metals. The many-body threshold peaks on the Al and Mg L23 spectra are generally suppressed by alloying with Li, except for low temperature coevaporated Li–Al samples where the peak persists to very Li-rich alloys. Data for a Li80Mg20 alloy are compared with KKR-CPA calculations, and good agreement is found for both the Li K spectrum and the Mg L spectrum.

© 1980 Optical Society of America

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