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Ring Opening and Rigidity: A Comparison of Time Resolved Photoelectron Spectroscopy Measurements and Calculations for 1,3 -Cyclohexadiene and cis, cis-1,3 - Cyclooctadiene

Samuel McClung, Yusong Liu, Pratip Chakraborty, Spiridoula Matsika, and Thomas Weinacht

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Abstract

We compare time resolved photoelectron spectroscopy measurements and trajectory surface hopping calculations for 1,3 - Cyclohexadiene (CHD) and cis,cis-1,3 - Cyclooctadiene (COD). We find qualitative agreement between experiment and theory for both but quantitative agreement only for CHD.

© 2022 The Author(s)

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