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Induced Fit and Ultrafast Vibrational Dynamics in Host-Guest-Chemistry Explored by 2DIR-Spectroscopy

Britta Valentin, Stephan Knop, Martin Olschewski, Jörg Lindner, and Peter Vöhringer

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Abstract

Femtosecond two-dimensional infrared spectroscopy in the NH- and CH-stretching spectral region was used to unravel structural details and the vibrational energy flow in the supramolecular host-guest complex of an ammonium cation and a cryptand.

© 2010 Optical Society of America

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