Abstract
Alkoxy (RO; R = CH3 C2H5, i-C3H7) radicals are important oxidation intermediates in air pollution, combustion phenomena, and astrophysical processes. The alkylthio (RS) radicals are chemical intermediates involved in natural sulfur emission in our atmosphere and contribute to acid precipitation, we have used the technique of laser-induced fluorescence (LIF) in conjunction with a supersonic jet expansion to record rotationally resolved excitation spectra of cold polyatomic RO and RS radicals.
© 1993 Optical Society of America
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