Nitrophenylhydrazone Based Phenoxy Thermoplastic Electro-Optic Polymers

R. J. Gulotty; D. J. Brennan; M. A. Chartier; J. K. Gillie; A. P. Haag; K. A. Hazard; M. N. Inbasekaran; P. R. Ashley; T. A. Tumolillo

doi:10.1364/OTFA.1993.WA.2

Organic Thin Films for Photonic Applications
Technical Digest Series (Optica Publishing Group, 1993),
paper WA.2
•https://doi.org/10.1364/OTFA.1993.WA.2

Nitrophenylhydrazone Based Phenoxy Thermoplastic Electro-Optic Polymers

R. J. Gulotty, D. J. Brennan, M. A. Chartier, J. K. Gillie, A. P. Haag, K. A. Hazard, M. N. Inbasekaran, P. R. Ashley, and T. A. Tumolillo

Organic Thin Films for Photonic Applications 1993

Ontario Canada
5–7 October 1993
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Electro-Optic Polymers 1 (WA)

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R. J. Gulotty, D. J. Brennan, M. A. Chartier, J. K. Gillie, A. P. Haag, K. A. Hazard, M. N. Inbasekaran, P. R. Ashley, and T. A. Tumolillo, "Nitrophenylhydrazone Based Phenoxy Thermoplastic Electro-Optic Polymers," in Organic Thin Films for Photonic Applications, Technical Digest Series (Optica Publishing Group, 1993), paper WA.2.

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Abstract

The first demonstration of a registered multilevel Mach-Zehnder intensity modulator array has recently been reported by Tumolillo et al. [1]. The nonlinear optical (NLO) polymer in these structures is a 4-nitrophenylhydrazone (NPH) based phenoxy thermoplastic developed at The Dow Chemical Co.[2] The properties of this and related NPH phenoxy NLO polymers and monomers are described below. In addition, a study of NLO activity versus chromophore loading is presented.

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