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Vacuum Ultraviolet Photoionization of Cold Molecular Beams: Single and Multiphoton Ionization and Photoelectron Spectroscopy

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Abstract

A versatile apparatus for the study of vacuum ultraviolet (VUV) spectroscopy and photoionization of molecules has been developed. A pulsed, supersonic molecular beam is crossed with the focused beam of a pulsed dye laser or its doubled or tripled output. Ions are created by multiphoton ionization (MPI) with the fundamental beam (three to five photons), two-photon ionization using the doubled or tripled beam, or one-photon ionization with VUV. Use of a second laser for two-color experiments is also possible.

© 1984 Optical Society of America

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