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  • European Quantum Electronics Conference
  • Technical Digest Series (Optica Publishing Group, 1996),
  • paper QFA2

Collisional Deactivation of Vibrationally Highly Excited Azulene in Supercritical Fluids

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Abstract

In this work ground state azulene served as a model system to study the collisional deactivation dynamics of a vibrationally highly excited polyatomic molecule from gas phase up to liquid densities. Using supercritical fluids like helium, xenon, CO2, and ethane in the pressure range 6-4000 bar at temperatures ≥380 K measurements over the complete density range were performed without gaps due to gas-liquid phase transitions.

© 1996 IEEE

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