Abstract

3 at.%Yb: Sr1-xGdxF2+x (x = 0,0.01,0.03,0.06,0.09) single crystals are grown by the temperature gradient technique (TGT), where the Gd3+ ions were used as a lattice structural modifier to form a disordered lattice site. The Yb: Sr1-xGdxF2+x crystals maintain cubic structure Fm3m. Specifically, the absorption cross section of 3 at.%Yb: Sr0.97Gd0.03F2.03 crystal was increased by more than 10% compared with that of 3 at.%Yb:SrF2. The emission cross section σem in 3 at.%Yb: Sr0.97Gd0.03F2.03 was 1.21 × 10−20 cm2 at a central wavelength of 976 nm with an enhancement of 11% as compared with that of 3 at.%Yb:SrF2. A direct continuous-wave diode pumped 3 at.%Yb: Sr0.97Gd0.03F2.03 laser could generate an output power of 3.8 W at 1052 nm with an optic-optic efficiency of 46.5% by using output coupler with a transmission T = 3%.

© 2018 Optical Society of America under the terms of the OSA Open Access Publishing Agreement

1. Introduction

In recent years, with the development of laser diode (LD) technology, laser crystals doped with Yb3+ ions have drawn much attention. At present, a variety of Yb3+ -doped laser crystals have been reported, because trivalent ytterbium (Yb3+) doped materials have demonstrated significant potential for application in ultrafast laser, high-power laser and amplifier system. Yb3+ ions possess two electronic states of ground state 2F7/2 and excited state 2F5/2 that retaining the advantages of low quantum defect, long fluorescence lifetime and high conversion efficiency [1–3].

Compared with oxide host materials, fluorides (CaF2, SrF2) have superior properties such as wide transmission wavelength, higher thermal conductivity, lower refractive index, and lower phonon energy [4,5] In 2004, the first CW and tunable laser operation of an Yb3+:CaF2 single crystal was obtained [6]. In 2008, Mathias reported the first time chirped-pulse amplification to the terawatt level in a fully diode-pumped scheme employing Yb3+:CaF2 [7]. However, there are less research on strontium fluoride applied in laser. In 2007, first tunable laser operation of maximum average output power of 270 mW and a tuning range of 73 nm was observed in single crystalline Yb3+:SrF2 [8]. In 2009, Femtosecond mode-locked operation of shortest pulse duration is 143 fs for an average power of 450 mW and highest average power is 620 mW for a pulse duration of 173 fs were demonstrated for the first time with Yb3+:SrF2 crystal [9]. Due to the different valencies of the dopant Yb3+ and the substituted alkaline cations (Ca2+, Sr2+), interstitial fluoride are generated in fluoride, tending to form clusters even in low doping concentrations, which generally act as emission quenching centers. We can use R3+(Y3+,La3+,Gd3+,Lu3+,etc.) ions as structural modifier, which can break the clusters and change the environment of Yb3+ [10–12]. The validity of this method has been proved in CaF2 system in recent years. In 2014, a 330 fs pulse at a center wavelength of 1049 nm with average output power of 224 mW at a repetition rate of ~83 MHz is obtained in Yb3+ doped Ca1-xYxF2 crystal [13].

In this article, for the first time, we study the spectroscopic properties of 3 at.%Yb: Sr1-xGdxF2+x single crystals, grown by the temperature gradient technique (TGT) method, including absorption and emission cross-section. we also report on diode-pumped, true CW laser operation in 3 at.%Yb: Sr1-xGdxF2+x crystal.

2. Experimental

3 at.%Yb: Sr1-xGdxF2+x single crystals are grown by the temperature gradient technique (TGT) method. The starting materials were YbF3 (4N), GdF3 (4N) and SrF2 (4N) powders, and 1 at.% PbF2 as an oxygen scavenger mixed in SrF2 powder.

The segregation coefficients of Yb3+ ions and R3+ ions were detected by inductively coupled plasma atomic emission spectrometry (ICP-AES). The principle of quantitatively determining the element contents is to measure the emission intensity of each element and compare with those in standard solutions. The concentration of the element could be determined accordingly.

The cell parameters of the grown 3 at.%Yb: Sr1-xGdxF2+x crystals were characterized by X-ray Diffraction (Ultima IV diffractometer, Rigaku, Japan) measurement using Cu Kα radiation at a scan width of 0.02° within 2θ = 10 – 80°.The lattice parameters of the crystals were calculated by Jade 5 program.

The spectral measurement was done in polished samples with thickness of 0.5 mm. The absorption spectra were measured by using a UV/VIS/NIR spectrophotometer (VARIAN Cary 5000) with scanning step of 1 nm. The fluorescence spectra and fluorescence lifetime were obtained from InSb detector (Hamamatsu) by using a Time Resolved Fluorimeter (FLS980, Edinburgh Instruments, UK) with pump wavelengths of 915 nm. All measurements were conducted at room temperature.

The laser operation was carried out in a plano-concave cavity. The cavity consisted of a plane mirror (M1, high-reflection (HR) @ 1040 nm) and a concave-plane (r = 200 mm) output coupler (OC) with transmission of 3% @ 1064 nm. The pump source was a fiber-coupled diode laser operating at 976 nm. The laser beam was collimated into the gain medium with a spot waist radius of 105 μm through a 1:2 coupling optics system. An uncoated 3 at.%Yb: Sr1-xGdxF2+x crystal with aperture 3 × 3 mm2 and thickness 3 mm was used as gain medium. To remove accumulated heat, the crystal was wrapped with indium foil and mounted in a water-cooled copper block maintaining the temperature at 13°C. The average output power was measured by a 30A-SH-V1 power meter (Israel).

3. Results and discussions

3.1 X-ray diffraction patterns

Figure 1(a) shows the X-ray diffraction patterns of the as-grown 3 at.%Yb: Sr1-xGdxF2+x crystal. The XRD pattern of 3 at.%Yb: Sr1-xGdxF2+x crystal is consistent with standard pattern stemming from PDF standard card(PDF#06-0262). It reveals that the 3 at.%Yb: Sr1-xGdxF2+x crystal maintains a cubic structure Fm3m, which is the same as that in 3 at.%Yb:SrF2 crystal.

 

Fig. 1 X-ray Diffraction measurement of the as-grown 3 at.%Yb: Sr1-xGdxF2+x single crystal. (a). the whole comparison from 10° to 80° of X-ray Diffraction intensity in 3 at.%Yb: Sr1-xGdxF2+x single crystal; (b). the partial comparison from 25° to 29° of X-ray Diffraction intensity in 3 at.%Yb: Sr1-xGdxF2+x single crystal

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In Fig. 1(b), it is obvious that the diffraction peaks of Yb-doped single or mixed crystals shifted slightly towards the longer angle side and lattice constants decreased compared with standard card. This is mainly ascribed to the replacement of Sr2+ with the relatively smaller radius of Gd3+ and Yb3+. However, it presents a nonlinear relationship between the concentration of Gd3+ and the sites of peaks due to the effect of interstitial fluoride ions.

3.2 Segregation coefficients

Table 1 shows that segregation coefficients of Yb3+ and Gd3+ ions in 3 at.%Yb: Sr1-xGdxF2+x crystal. It is obvious that the segregation coefficients of Yb3+ and Gd3+ are decreasing with the concentration of Gd3+ increasing. It can be contributed to competition on Yb3+ and Gd3+ ions, when they enter into the lattice of Sr4+.With the concentration of Gd3+ increasing, the Yb3+ ions become difficult to enter the lattice, thereby reducing the real concentration of Yb3+ ions and reducing the segregation coefficient of Yb3+ ions in the crystal.

Tables Icon

Table 1. Segregation coefficient of Yb3+ and Gd3+ ions in 3 at.%Yb: Sr1-xGdxF2+x crystal.

3.3 Absorption and emission spectra

Figure 2 shows the absorption spectra of 3 at.%Yb: Sr1-xGdxF2+x crystals at room temperature. The absorption coefficient α was determined by the equation α=2.303OD/ and absorption cross-section was calculated from the equation σabs=α/N. Here, OD stands for optical density. L is sample thickness. N is the concentration of Yb3+ ions. According to the absorption spectra depicted in Fig. 2, the absorption peak position of 3 at.%Yb: Sr1-xGdxF2+x disordered crystal were same as compared with that of 3 at.%Yb:SrF2 crystal. The absorption coefficient and absorption cross section in 3 at.%Yb: Sr1-xGdxF2+x crystal were shown in Fig. 2(a) and Fig. 2(b), respectively. The absorption coefficient of disordered crystals is lower than 3 at.%Yb: SrF2 crystal, but the absorption cross-section of disordered crystals is higher. Furthermore, in Fig. (b), we can draw that the absorption cross-section of 3 at.%Yb: Sr1-xGdxF2+x crystal is increasing with the concentration of Gd3+ increasing, and tends to be saturated under high concentration of Gd3+ ions. The absorption cross section in 3 at.%Yb: Sr0.97Gd0.03F2.03, 3 at.%Yb: Sr0.94Gd0.06F2.06 and 3 at.%Yb: Sr0.91Gd0.09F2.09 crystal enhanced to 0.884 × 10−20 cm2, 0.902 × 10−20 cm2 and 0.906 × 10−20 cm2 at 975 nm comparing with that of the absorption cross section of 0.800 × 10−20 cm2 in 3at%Yb:SrF2 crystal, respectively. The structural modifier of Gd3+ ions affect the local environment of Yb3+ ions, resulting in breaking crystal local symmetry, which could enhance the absorption transition oscillation strengthen.

 

Fig. 2 Absorption spectra of 3 at.%Yb: Sr1-xGdxF2+x single crystal. a) absorption coefficient; b) absorption cross-section.

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The emission cross-section σem of Yb3+ ion was calculated from reciprocity method formula σem (υ)=(σabs(υ) Zl)/Zu  exp[(EZLhυ)/kT] [14]. Here, σabs(v) is the absorption cross section, Zu is the partition function of the upper energy level, Zl is the partition function of the lower energy level, h is the Planck's constant, k is Boltzmann's constant, EZL is the zero line energy which, is defined to be the energy separation between the lowest components of the upper and lower states, respectively.

Figure 3(a) gives the emission cross section spectra in 3 at.%Yb: Sr1-xGdxF2+x crystals. There are wide emission bands from 940 nm to 1120 nm, which is mainly ascribed to 2F5/22F7/2 transition process of Yb3+. Meanwhile, the emission peaks of 976 nm, 1012 nm, 1029 nm and 1041 nm can be observed, corresponding to transfer from upper level 2F5/2 to different stark levels. The strong emission at 976 nm reflects obvious self-absorption of Yb3+ ions in mixed crystals.

 

Fig. 3 a) The emission cross section spectra for in 3 at.%Yb: Sr1-xGdxF2+x crystals; b) the emission cross-section at 976 nm, 1012 nm, 1029 nm and 1041nm varying with the concentration of Gd3+ ions in 3 at.%Yb: Sr1-xGdxF2+x crystals.

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Figure 3(b) shows that the emission cross-section at 976 nm and 1041nm of mixed crystals are enhanced, compared with single doped crystal. However, the emission cross-section at 1029 nm of mixed crystals are higher in the lower concentration of Gd3+ ions, smaller in the higher concentration. Specially, the emission cross-section at 1012 nm of 3 at.%Yb: Sr0.97Gd0.03F2.03 is better than 3 at.%Yb: SrF2 crystal only. After doping regulating ions of Gd3+ in lower concentration, fluorescence quenching center of [Yb3+-Yb3+] clusters is destroyed and changed to be [Yb3+-Gd3+], resulting in the emission cross section increasing. However, there is an opposite effect that the real concentration of Yb3+ ions becomes lower, when Gd3+ ions doped in high concentration. In comparison, the highest emission cross section can be obtained in 3 at.%Yb: Sr0.97Gd0.03F2.03 crystal about 1.21 × 10−20 cm2 at 976 nm, 0.45 × 10−20 cm2 at 1012 nm, 0.32 × 10−20 cm2 at 1029 nm and 0.29 × 10−20 cm2 at 1041 nm. Moreover, the Gd3+ ions tend to form [Gd3+-Gd3+] clusters instead of [Yb3+-Gd3+] clusters at high concentration of Gd ion, which makes them not play a good role in dispersing Yb3+ ions. So, the emission cross-section are slightly decreasing when the concentration of Gd over 3 at.%.

As shown in Table 2, compared with other Yb-doped crystals, Yb:Sr1-xGdxF2+x crystals have relatively high emission cross-section, such as SrF2, LiYF4, BaF2 Y2SiO5 and Sc2SiO5.

Tables Icon

Table 2. The emission cross section σem of different Yb-doped crystals.

3.4 Fluorescence lifetime and laser parameters

As shown in Fig. 4(a), emission decays of 2F5/2 emitting energy level were recorded for the different 3 at.%Yb: Sr1-xGdxF2+x samples, whose the single-exponential character of decay curves can be observed. Therefore, the decay curves of 3 at.%Yb: Sr1-xGdxF2+x samples were fitting by single-exponential model, and the lifetime τ of 5.41 ms, 2.53 ms, 5.56 ms, 2.37 ms and 2.60 ms are obtained for the different concentrations of Gd3+ ions at 0 at%, 1 at%, 3 at%, 6 at% and 9 at%, respectively.

 

Fig. 4 a) The fluorescence lifetime of 3 at.%Yb: Sr1-xGdxF2+x crystals; b) The average output power as a function of input power for CW laser; c) FOM Gain at 1052 nm and optic-optic efficiency in 3 at.%Yb: Sr1-xGdxF2+x crystals; d) The average output power as a function of absorbed pump power for CW laser in 3 at.%Yb: Sr0.97Gd0.03F2.03 crystal.

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Figure 4(b) shows the output power from 3 at.%Yb: Sr1-xGdxF2+x crystals at different input power. The slopes of fitting curves stand for optic-optic efficiency. For 3 at.%Yb: Sr0.97Gd0.03F2.03 sample, we get the best optic-optic efficiency of 46.49%. Moreover, the optic-optic efficiency vary with the concentration of Gd3+ ion as shown in Fig. 4(c). Unexpectedly, there is a zigzag variation drawn from the figure, which reveal that doping Gd3+ ions have multiple and complex effects on laser performance.

For an amplifier device, the figure-of-merit (FOM) for gain is defined as the product of lifetime and emission cross-section: σem × τ [15]. Illustrated in Fig. 4(c), FOM gain at 1052 nm in 3 at.%Yb: Sr1-xGdxF2+x crystals can be calculated to be 1.03 × 10−20 ms·cm2, 0.51 × 10−20 ms·cm2, 1.22 × 10−20 ms·cm2, 0.51 × 10−20 ms·cm2 and 0.54 × 10−20 ms·cm2 for the different concentrations of Gd3+ ions at 0 at%, 1 at%, 3 at%, 6 at% and 9 at%, respectively. Interestingly, the change regular of FOM gain is consistent with that of optic-optic efficiency, which is a good explanation for the best laser performance in 3 at.%Yb: Sr0.97Gd0.03F2.03 crystal. The higher FOM gain of 3 at.%Yb: Sr0.97Gd0.03F2.03 crystal leads to better laser performance due to its higher emission cross section and longer fluorescence lifetime.

The output power of 3 at.%Yb: Sr0.97Gd0.03F2.03 sample at different absorbed power can be described as follows Fig. 4(d). When the absorbed pump power reached 8.02 W, the maximum output power of 3.8W could be obtained by using an output coupler with transmission TOC = 3% around 1052 nm, corresponding to an optical conversion efficiency of 46.49%, and a slope efficiency of 53.5%. It could be noted that the condition for maximum slope efficiency was not yet optimized. In the future experiments, we would optimize the transmission value of output coupler as well as the pump wavelength.

4. Conclusions

In summary, 3 at.%Yb: Sr1-xGdxF2+x single crystals were successfully obtained with higher emission cross section as compared with that of 3 at.%Yb:SrF2 crystal. The 3 at.%Yb: Sr1-xGdxF2+x crystal maintains a cubic structure Fm3m, which is the same as that in 3 at.%Yb:SrF2 crystal. Specifically, the absorption cross section of 3 at.%Yb: Sr0.97Gd0.03F2.03 crystal was increased by more than 10% when compared with that of 3 at.%Yb:SrF2. Both the emission cross section σem and fluorescence lifetime in 3 at.%Yb: Sr0.97Gd0.03F2.03 crystal were enhanced as compared with that in 3 at.%Yb:SrF2. A primary but not yet optimized laser experiment produced out power of 3.8 W with a optic-optic efficiency of 46.5% in 3 at.%Yb: Sr0.97Gd0.03F2.03 crystal. So, Yb: Sr1-xGdxF2+x crystals may be a promising laser material in high-power laser system application.

Funding

National Key Research and Development Program of China (No. 2016YFB0402101); Strategic Priority Program of the Chinese Academy of Sciences (No. XDB16030000); National Natural Science Foundation of China (Nos. U1530152 and 61635012).

References and links

1. Q. Hu, Z. Jia, A. Volpi, S. Veronesi, M. Tonelli, and X. Tao, “Crystal growth and spectral broadening of a promising Yb:CaLuxGd1−xAlO4 disordered crystal for ultrafast laser application,” CrystEngComm 19(12), 1643–1647 (2017). [CrossRef]  

2. T. Dietrich, S. Piehler, M. Rumpel, P. Villeval, D. Lupinski, M. Abdou-Ahmed, and T. Graf, “Highly-efficient continuous-wave intra-cavity frequency-doubled Yb:LuAG thin-disk laser with 1 kW of output power,” Opt. Express 25(5), 4917–4925 (2017). [CrossRef]   [PubMed]  

3. A. Pellegrina, A. Courjaud, D. N. Papadopoulos, E. Mottay, F. Druon, J. L. Doualan, R. Moncorgé, A. Courjaud, E. Mottay, and P. Georges, “On Yb:CaF2 and Yb:SrF2: review of spectroscopic and thermal properties and their impact on femtosecond and high power laser performance,” Opt. Mater. Express 1(3), 489–502 (2011). [CrossRef]  

4. L. B. Su, Q. G. Wang, H. J. Li, G. Brasse, P. Camy, J. L. Doualan, A. Braud, R. Moncorge, Y. Y. Zhan, L. H. Zheng, X. B. Qian, and J. Xu, “Spectroscopic properties and CW laser operation of Nd, Y-codoped CaF2 single crystals,” Laser Phys. Lett. 10(3), 035804 (2013). [CrossRef]  

5. J. Liu, J. F. Liu, L. B. Su, Q. Zhang, F. K. Ma, D. P. Jiang, and J. Xu, “Effects of Gd3+/Y3+ codoping on the spectral properties of Nd:CaF2 crystals,” Wuli Xuebao 65, 5 (2016).

6. V. Petit, J. L. Doualan, P. Camy, V. Ménard, and R. Moncorgé, “Cw and tunable laser operation of Yb doped CaF2,” Appl. Phys. B 78(6), 681–684 (2004). [CrossRef]  

7. M. Siebold, M. Hornung, R. Boedefeld, S. Podleska, S. Klingebiel, C. Wandt, F. Krausz, S. Karsch, R. Uecker, A. Jochmann, J. Hein, and M. C. Kaluza, “Terawatt diode-pumped Yb:CaF2 laser,” Opt. Lett. 33(23), 2770–2772 (2008). [CrossRef]   [PubMed]  

8. M. Siebold, J. Hein, M. C. Kaluza, and R. Uecker, “High-peak-power tunable laser operation of Yb:SrF2.,” Opt. Lett. 32(13), 1818–1820 (2007). [CrossRef]   [PubMed]  

9. F. Druon, D. N. Papadopoulos, J. Boudeile, M. Hanna, P. Georges, A. Benayad, P. Camy, J. L. Doualan, V. Ménard, and R. Moncorgé, “Mode-locked operation of a diode-pumped femtosecond Yb:SrF2 laser,” Opt. Lett. 34(15), 2354–2356 (2009). [CrossRef]   [PubMed]  

10. L. Su, J. Xu, H. Li, L. Wen, Y. Zhu, Z. Zhao, Y. Dong, G. Zhou, and J. Si, “Sites structure and spectroscopic properties of Yb-doped and Yb, Na-codoped CaF2 laser crystals,” Chem. Phys. Lett. 406(1–3), 254–258 (2005). [CrossRef]  

11. Y. Wu, L. Su, Q. Wang, H. Li, Y. Zhan, D. Jang, X. Qian, C. Wang, L. Zheng, H. Chen, J. Xu, R. Witold, S. Piotr, and L. Radoslaw, “Spectroscopic properties of Yb-doped CaF2-YF3 solid-solution laser crystal,” Laser Phys. 23(10), 105805 (2013). [CrossRef]  

12. Y. He, Y. Xue, W. Liu, L. Su, F. Tang, and J. Wang, “Structure and Property of Yb Doped Ca1-xRxF2+x (R=La, Gd) Laser Crystals,” J. Inorg. Mater. 32(8), 857–862 (2017).

13. W. B. Xu, L. Chai, J. K. Shi, M. L. Hu, C. Y. Wang, L. B. Su, D. P. Jiang, and J. Xu, “Operational characteristics of a ld-pumped novel Yb,Y:CaF2 mode-locked laser using a sesam,” Laser Phys. Lett. 11(11), 115816 (2014). [CrossRef]  

14. X. Zou and H. Toratani, “Evaluation of spectroscopic properties of Yb3+-doped glasses,” Phys. Rev. B Condens. Matter 52(22), 15889–15897 (1995). [CrossRef]   [PubMed]  

15. S. Shen and A. Jha, “The influence of f-ion doping on the fluorescence (4I13/24I15/2) line shape broadening in er-doped oxyfluoride silicate glasses,” Opt. Mater. 25(3), 321–333 (2004). [CrossRef]  

16. L. DeLoach, S. Payne, L. Chase, L. Smith, W. Kway, and W. Krupke, “Evaluation of absorption and emission properties of Yb3+, doped crystals for laser applications,” IEEE J. Quantum Electron. 29(4), 1179–1191 (1993). [CrossRef]  

17. L. Zheng, J. Xu, G. Zhao, L. Su, F. Wu, and X. Liang, “Bulk crystal growth and efficient diode-pumped laser performance of Yb3+:Sc2SiO5,” Appl. Phys. B 91(3-4), 443–445 (2008). [CrossRef]  

References

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  1. Q. Hu, Z. Jia, A. Volpi, S. Veronesi, M. Tonelli, and X. Tao, “Crystal growth and spectral broadening of a promising Yb:CaLuxGd1−xAlO4 disordered crystal for ultrafast laser application,” CrystEngComm 19(12), 1643–1647 (2017).
    [Crossref]
  2. T. Dietrich, S. Piehler, M. Rumpel, P. Villeval, D. Lupinski, M. Abdou-Ahmed, and T. Graf, “Highly-efficient continuous-wave intra-cavity frequency-doubled Yb:LuAG thin-disk laser with 1 kW of output power,” Opt. Express 25(5), 4917–4925 (2017).
    [Crossref] [PubMed]
  3. A. Pellegrina, A. Courjaud, D. N. Papadopoulos, E. Mottay, F. Druon, J. L. Doualan, R. Moncorgé, A. Courjaud, E. Mottay, and P. Georges, “On Yb:CaF2 and Yb:SrF2: review of spectroscopic and thermal properties and their impact on femtosecond and high power laser performance,” Opt. Mater. Express 1(3), 489–502 (2011).
    [Crossref]
  4. L. B. Su, Q. G. Wang, H. J. Li, G. Brasse, P. Camy, J. L. Doualan, A. Braud, R. Moncorge, Y. Y. Zhan, L. H. Zheng, X. B. Qian, and J. Xu, “Spectroscopic properties and CW laser operation of Nd, Y-codoped CaF2 single crystals,” Laser Phys. Lett. 10(3), 035804 (2013).
    [Crossref]
  5. J. Liu, J. F. Liu, L. B. Su, Q. Zhang, F. K. Ma, D. P. Jiang, and J. Xu, “Effects of Gd3+/Y3+ codoping on the spectral properties of Nd:CaF2 crystals,” Wuli Xuebao 65, 5 (2016).
  6. V. Petit, J. L. Doualan, P. Camy, V. Ménard, and R. Moncorgé, “Cw and tunable laser operation of Yb doped CaF2,” Appl. Phys. B 78(6), 681–684 (2004).
    [Crossref]
  7. M. Siebold, M. Hornung, R. Boedefeld, S. Podleska, S. Klingebiel, C. Wandt, F. Krausz, S. Karsch, R. Uecker, A. Jochmann, J. Hein, and M. C. Kaluza, “Terawatt diode-pumped Yb:CaF2 laser,” Opt. Lett. 33(23), 2770–2772 (2008).
    [Crossref] [PubMed]
  8. M. Siebold, J. Hein, M. C. Kaluza, and R. Uecker, “High-peak-power tunable laser operation of Yb:SrF2.,” Opt. Lett. 32(13), 1818–1820 (2007).
    [Crossref] [PubMed]
  9. F. Druon, D. N. Papadopoulos, J. Boudeile, M. Hanna, P. Georges, A. Benayad, P. Camy, J. L. Doualan, V. Ménard, and R. Moncorgé, “Mode-locked operation of a diode-pumped femtosecond Yb:SrF2 laser,” Opt. Lett. 34(15), 2354–2356 (2009).
    [Crossref] [PubMed]
  10. L. Su, J. Xu, H. Li, L. Wen, Y. Zhu, Z. Zhao, Y. Dong, G. Zhou, and J. Si, “Sites structure and spectroscopic properties of Yb-doped and Yb, Na-codoped CaF2 laser crystals,” Chem. Phys. Lett. 406(1–3), 254–258 (2005).
    [Crossref]
  11. Y. Wu, L. Su, Q. Wang, H. Li, Y. Zhan, D. Jang, X. Qian, C. Wang, L. Zheng, H. Chen, J. Xu, R. Witold, S. Piotr, and L. Radoslaw, “Spectroscopic properties of Yb-doped CaF2-YF3 solid-solution laser crystal,” Laser Phys. 23(10), 105805 (2013).
    [Crossref]
  12. Y. He, Y. Xue, W. Liu, L. Su, F. Tang, and J. Wang, “Structure and Property of Yb Doped Ca1-xRxF2+x (R=La, Gd) Laser Crystals,” J. Inorg. Mater. 32(8), 857–862 (2017).
  13. W. B. Xu, L. Chai, J. K. Shi, M. L. Hu, C. Y. Wang, L. B. Su, D. P. Jiang, and J. Xu, “Operational characteristics of a ld-pumped novel Yb,Y:CaF2 mode-locked laser using a sesam,” Laser Phys. Lett. 11(11), 115816 (2014).
    [Crossref]
  14. X. Zou and H. Toratani, “Evaluation of spectroscopic properties of Yb3+-doped glasses,” Phys. Rev. B Condens. Matter 52(22), 15889–15897 (1995).
    [Crossref] [PubMed]
  15. S. Shen and A. Jha, “The influence of f-ion doping on the fluorescence (4I13/2 → 4I15/2) line shape broadening in er-doped oxyfluoride silicate glasses,” Opt. Mater. 25(3), 321–333 (2004).
    [Crossref]
  16. L. DeLoach, S. Payne, L. Chase, L. Smith, W. Kway, and W. Krupke, “Evaluation of absorption and emission properties of Yb3+, doped crystals for laser applications,” IEEE J. Quantum Electron. 29(4), 1179–1191 (1993).
    [Crossref]
  17. L. Zheng, J. Xu, G. Zhao, L. Su, F. Wu, and X. Liang, “Bulk crystal growth and efficient diode-pumped laser performance of Yb3+:Sc2SiO5,” Appl. Phys. B 91(3-4), 443–445 (2008).
    [Crossref]

2017 (3)

Q. Hu, Z. Jia, A. Volpi, S. Veronesi, M. Tonelli, and X. Tao, “Crystal growth and spectral broadening of a promising Yb:CaLuxGd1−xAlO4 disordered crystal for ultrafast laser application,” CrystEngComm 19(12), 1643–1647 (2017).
[Crossref]

T. Dietrich, S. Piehler, M. Rumpel, P. Villeval, D. Lupinski, M. Abdou-Ahmed, and T. Graf, “Highly-efficient continuous-wave intra-cavity frequency-doubled Yb:LuAG thin-disk laser with 1 kW of output power,” Opt. Express 25(5), 4917–4925 (2017).
[Crossref] [PubMed]

Y. He, Y. Xue, W. Liu, L. Su, F. Tang, and J. Wang, “Structure and Property of Yb Doped Ca1-xRxF2+x (R=La, Gd) Laser Crystals,” J. Inorg. Mater. 32(8), 857–862 (2017).

2016 (1)

J. Liu, J. F. Liu, L. B. Su, Q. Zhang, F. K. Ma, D. P. Jiang, and J. Xu, “Effects of Gd3+/Y3+ codoping on the spectral properties of Nd:CaF2 crystals,” Wuli Xuebao 65, 5 (2016).

2014 (1)

W. B. Xu, L. Chai, J. K. Shi, M. L. Hu, C. Y. Wang, L. B. Su, D. P. Jiang, and J. Xu, “Operational characteristics of a ld-pumped novel Yb,Y:CaF2 mode-locked laser using a sesam,” Laser Phys. Lett. 11(11), 115816 (2014).
[Crossref]

2013 (2)

L. B. Su, Q. G. Wang, H. J. Li, G. Brasse, P. Camy, J. L. Doualan, A. Braud, R. Moncorge, Y. Y. Zhan, L. H. Zheng, X. B. Qian, and J. Xu, “Spectroscopic properties and CW laser operation of Nd, Y-codoped CaF2 single crystals,” Laser Phys. Lett. 10(3), 035804 (2013).
[Crossref]

Y. Wu, L. Su, Q. Wang, H. Li, Y. Zhan, D. Jang, X. Qian, C. Wang, L. Zheng, H. Chen, J. Xu, R. Witold, S. Piotr, and L. Radoslaw, “Spectroscopic properties of Yb-doped CaF2-YF3 solid-solution laser crystal,” Laser Phys. 23(10), 105805 (2013).
[Crossref]

2011 (1)

2009 (1)

2008 (2)

M. Siebold, M. Hornung, R. Boedefeld, S. Podleska, S. Klingebiel, C. Wandt, F. Krausz, S. Karsch, R. Uecker, A. Jochmann, J. Hein, and M. C. Kaluza, “Terawatt diode-pumped Yb:CaF2 laser,” Opt. Lett. 33(23), 2770–2772 (2008).
[Crossref] [PubMed]

L. Zheng, J. Xu, G. Zhao, L. Su, F. Wu, and X. Liang, “Bulk crystal growth and efficient diode-pumped laser performance of Yb3+:Sc2SiO5,” Appl. Phys. B 91(3-4), 443–445 (2008).
[Crossref]

2007 (1)

2005 (1)

L. Su, J. Xu, H. Li, L. Wen, Y. Zhu, Z. Zhao, Y. Dong, G. Zhou, and J. Si, “Sites structure and spectroscopic properties of Yb-doped and Yb, Na-codoped CaF2 laser crystals,” Chem. Phys. Lett. 406(1–3), 254–258 (2005).
[Crossref]

2004 (2)

V. Petit, J. L. Doualan, P. Camy, V. Ménard, and R. Moncorgé, “Cw and tunable laser operation of Yb doped CaF2,” Appl. Phys. B 78(6), 681–684 (2004).
[Crossref]

S. Shen and A. Jha, “The influence of f-ion doping on the fluorescence (4I13/2 → 4I15/2) line shape broadening in er-doped oxyfluoride silicate glasses,” Opt. Mater. 25(3), 321–333 (2004).
[Crossref]

1995 (1)

X. Zou and H. Toratani, “Evaluation of spectroscopic properties of Yb3+-doped glasses,” Phys. Rev. B Condens. Matter 52(22), 15889–15897 (1995).
[Crossref] [PubMed]

1993 (1)

L. DeLoach, S. Payne, L. Chase, L. Smith, W. Kway, and W. Krupke, “Evaluation of absorption and emission properties of Yb3+, doped crystals for laser applications,” IEEE J. Quantum Electron. 29(4), 1179–1191 (1993).
[Crossref]

Abdou-Ahmed, M.

Benayad, A.

Boedefeld, R.

Boudeile, J.

Brasse, G.

L. B. Su, Q. G. Wang, H. J. Li, G. Brasse, P. Camy, J. L. Doualan, A. Braud, R. Moncorge, Y. Y. Zhan, L. H. Zheng, X. B. Qian, and J. Xu, “Spectroscopic properties and CW laser operation of Nd, Y-codoped CaF2 single crystals,” Laser Phys. Lett. 10(3), 035804 (2013).
[Crossref]

Braud, A.

L. B. Su, Q. G. Wang, H. J. Li, G. Brasse, P. Camy, J. L. Doualan, A. Braud, R. Moncorge, Y. Y. Zhan, L. H. Zheng, X. B. Qian, and J. Xu, “Spectroscopic properties and CW laser operation of Nd, Y-codoped CaF2 single crystals,” Laser Phys. Lett. 10(3), 035804 (2013).
[Crossref]

Camy, P.

L. B. Su, Q. G. Wang, H. J. Li, G. Brasse, P. Camy, J. L. Doualan, A. Braud, R. Moncorge, Y. Y. Zhan, L. H. Zheng, X. B. Qian, and J. Xu, “Spectroscopic properties and CW laser operation of Nd, Y-codoped CaF2 single crystals,” Laser Phys. Lett. 10(3), 035804 (2013).
[Crossref]

F. Druon, D. N. Papadopoulos, J. Boudeile, M. Hanna, P. Georges, A. Benayad, P. Camy, J. L. Doualan, V. Ménard, and R. Moncorgé, “Mode-locked operation of a diode-pumped femtosecond Yb:SrF2 laser,” Opt. Lett. 34(15), 2354–2356 (2009).
[Crossref] [PubMed]

V. Petit, J. L. Doualan, P. Camy, V. Ménard, and R. Moncorgé, “Cw and tunable laser operation of Yb doped CaF2,” Appl. Phys. B 78(6), 681–684 (2004).
[Crossref]

Chai, L.

W. B. Xu, L. Chai, J. K. Shi, M. L. Hu, C. Y. Wang, L. B. Su, D. P. Jiang, and J. Xu, “Operational characteristics of a ld-pumped novel Yb,Y:CaF2 mode-locked laser using a sesam,” Laser Phys. Lett. 11(11), 115816 (2014).
[Crossref]

Chase, L.

L. DeLoach, S. Payne, L. Chase, L. Smith, W. Kway, and W. Krupke, “Evaluation of absorption and emission properties of Yb3+, doped crystals for laser applications,” IEEE J. Quantum Electron. 29(4), 1179–1191 (1993).
[Crossref]

Chen, H.

Y. Wu, L. Su, Q. Wang, H. Li, Y. Zhan, D. Jang, X. Qian, C. Wang, L. Zheng, H. Chen, J. Xu, R. Witold, S. Piotr, and L. Radoslaw, “Spectroscopic properties of Yb-doped CaF2-YF3 solid-solution laser crystal,” Laser Phys. 23(10), 105805 (2013).
[Crossref]

Courjaud, A.

DeLoach, L.

L. DeLoach, S. Payne, L. Chase, L. Smith, W. Kway, and W. Krupke, “Evaluation of absorption and emission properties of Yb3+, doped crystals for laser applications,” IEEE J. Quantum Electron. 29(4), 1179–1191 (1993).
[Crossref]

Dietrich, T.

Dong, Y.

L. Su, J. Xu, H. Li, L. Wen, Y. Zhu, Z. Zhao, Y. Dong, G. Zhou, and J. Si, “Sites structure and spectroscopic properties of Yb-doped and Yb, Na-codoped CaF2 laser crystals,” Chem. Phys. Lett. 406(1–3), 254–258 (2005).
[Crossref]

Doualan, J. L.

L. B. Su, Q. G. Wang, H. J. Li, G. Brasse, P. Camy, J. L. Doualan, A. Braud, R. Moncorge, Y. Y. Zhan, L. H. Zheng, X. B. Qian, and J. Xu, “Spectroscopic properties and CW laser operation of Nd, Y-codoped CaF2 single crystals,” Laser Phys. Lett. 10(3), 035804 (2013).
[Crossref]

A. Pellegrina, A. Courjaud, D. N. Papadopoulos, E. Mottay, F. Druon, J. L. Doualan, R. Moncorgé, A. Courjaud, E. Mottay, and P. Georges, “On Yb:CaF2 and Yb:SrF2: review of spectroscopic and thermal properties and their impact on femtosecond and high power laser performance,” Opt. Mater. Express 1(3), 489–502 (2011).
[Crossref]

F. Druon, D. N. Papadopoulos, J. Boudeile, M. Hanna, P. Georges, A. Benayad, P. Camy, J. L. Doualan, V. Ménard, and R. Moncorgé, “Mode-locked operation of a diode-pumped femtosecond Yb:SrF2 laser,” Opt. Lett. 34(15), 2354–2356 (2009).
[Crossref] [PubMed]

V. Petit, J. L. Doualan, P. Camy, V. Ménard, and R. Moncorgé, “Cw and tunable laser operation of Yb doped CaF2,” Appl. Phys. B 78(6), 681–684 (2004).
[Crossref]

Druon, F.

Georges, P.

Graf, T.

Hanna, M.

He, Y.

Y. He, Y. Xue, W. Liu, L. Su, F. Tang, and J. Wang, “Structure and Property of Yb Doped Ca1-xRxF2+x (R=La, Gd) Laser Crystals,” J. Inorg. Mater. 32(8), 857–862 (2017).

Hein, J.

Hornung, M.

Hu, M. L.

W. B. Xu, L. Chai, J. K. Shi, M. L. Hu, C. Y. Wang, L. B. Su, D. P. Jiang, and J. Xu, “Operational characteristics of a ld-pumped novel Yb,Y:CaF2 mode-locked laser using a sesam,” Laser Phys. Lett. 11(11), 115816 (2014).
[Crossref]

Hu, Q.

Q. Hu, Z. Jia, A. Volpi, S. Veronesi, M. Tonelli, and X. Tao, “Crystal growth and spectral broadening of a promising Yb:CaLuxGd1−xAlO4 disordered crystal for ultrafast laser application,” CrystEngComm 19(12), 1643–1647 (2017).
[Crossref]

Jang, D.

Y. Wu, L. Su, Q. Wang, H. Li, Y. Zhan, D. Jang, X. Qian, C. Wang, L. Zheng, H. Chen, J. Xu, R. Witold, S. Piotr, and L. Radoslaw, “Spectroscopic properties of Yb-doped CaF2-YF3 solid-solution laser crystal,” Laser Phys. 23(10), 105805 (2013).
[Crossref]

Jha, A.

S. Shen and A. Jha, “The influence of f-ion doping on the fluorescence (4I13/2 → 4I15/2) line shape broadening in er-doped oxyfluoride silicate glasses,” Opt. Mater. 25(3), 321–333 (2004).
[Crossref]

Jia, Z.

Q. Hu, Z. Jia, A. Volpi, S. Veronesi, M. Tonelli, and X. Tao, “Crystal growth and spectral broadening of a promising Yb:CaLuxGd1−xAlO4 disordered crystal for ultrafast laser application,” CrystEngComm 19(12), 1643–1647 (2017).
[Crossref]

Jiang, D. P.

J. Liu, J. F. Liu, L. B. Su, Q. Zhang, F. K. Ma, D. P. Jiang, and J. Xu, “Effects of Gd3+/Y3+ codoping on the spectral properties of Nd:CaF2 crystals,” Wuli Xuebao 65, 5 (2016).

W. B. Xu, L. Chai, J. K. Shi, M. L. Hu, C. Y. Wang, L. B. Su, D. P. Jiang, and J. Xu, “Operational characteristics of a ld-pumped novel Yb,Y:CaF2 mode-locked laser using a sesam,” Laser Phys. Lett. 11(11), 115816 (2014).
[Crossref]

Jochmann, A.

Kaluza, M. C.

Karsch, S.

Klingebiel, S.

Krausz, F.

Krupke, W.

L. DeLoach, S. Payne, L. Chase, L. Smith, W. Kway, and W. Krupke, “Evaluation of absorption and emission properties of Yb3+, doped crystals for laser applications,” IEEE J. Quantum Electron. 29(4), 1179–1191 (1993).
[Crossref]

Kway, W.

L. DeLoach, S. Payne, L. Chase, L. Smith, W. Kway, and W. Krupke, “Evaluation of absorption and emission properties of Yb3+, doped crystals for laser applications,” IEEE J. Quantum Electron. 29(4), 1179–1191 (1993).
[Crossref]

Li, H.

Y. Wu, L. Su, Q. Wang, H. Li, Y. Zhan, D. Jang, X. Qian, C. Wang, L. Zheng, H. Chen, J. Xu, R. Witold, S. Piotr, and L. Radoslaw, “Spectroscopic properties of Yb-doped CaF2-YF3 solid-solution laser crystal,” Laser Phys. 23(10), 105805 (2013).
[Crossref]

L. Su, J. Xu, H. Li, L. Wen, Y. Zhu, Z. Zhao, Y. Dong, G. Zhou, and J. Si, “Sites structure and spectroscopic properties of Yb-doped and Yb, Na-codoped CaF2 laser crystals,” Chem. Phys. Lett. 406(1–3), 254–258 (2005).
[Crossref]

Li, H. J.

L. B. Su, Q. G. Wang, H. J. Li, G. Brasse, P. Camy, J. L. Doualan, A. Braud, R. Moncorge, Y. Y. Zhan, L. H. Zheng, X. B. Qian, and J. Xu, “Spectroscopic properties and CW laser operation of Nd, Y-codoped CaF2 single crystals,” Laser Phys. Lett. 10(3), 035804 (2013).
[Crossref]

Liang, X.

L. Zheng, J. Xu, G. Zhao, L. Su, F. Wu, and X. Liang, “Bulk crystal growth and efficient diode-pumped laser performance of Yb3+:Sc2SiO5,” Appl. Phys. B 91(3-4), 443–445 (2008).
[Crossref]

Liu, J.

J. Liu, J. F. Liu, L. B. Su, Q. Zhang, F. K. Ma, D. P. Jiang, and J. Xu, “Effects of Gd3+/Y3+ codoping on the spectral properties of Nd:CaF2 crystals,” Wuli Xuebao 65, 5 (2016).

Liu, J. F.

J. Liu, J. F. Liu, L. B. Su, Q. Zhang, F. K. Ma, D. P. Jiang, and J. Xu, “Effects of Gd3+/Y3+ codoping on the spectral properties of Nd:CaF2 crystals,” Wuli Xuebao 65, 5 (2016).

Liu, W.

Y. He, Y. Xue, W. Liu, L. Su, F. Tang, and J. Wang, “Structure and Property of Yb Doped Ca1-xRxF2+x (R=La, Gd) Laser Crystals,” J. Inorg. Mater. 32(8), 857–862 (2017).

Lupinski, D.

Ma, F. K.

J. Liu, J. F. Liu, L. B. Su, Q. Zhang, F. K. Ma, D. P. Jiang, and J. Xu, “Effects of Gd3+/Y3+ codoping on the spectral properties of Nd:CaF2 crystals,” Wuli Xuebao 65, 5 (2016).

Ménard, V.

Moncorge, R.

L. B. Su, Q. G. Wang, H. J. Li, G. Brasse, P. Camy, J. L. Doualan, A. Braud, R. Moncorge, Y. Y. Zhan, L. H. Zheng, X. B. Qian, and J. Xu, “Spectroscopic properties and CW laser operation of Nd, Y-codoped CaF2 single crystals,” Laser Phys. Lett. 10(3), 035804 (2013).
[Crossref]

Moncorgé, R.

Mottay, E.

Papadopoulos, D. N.

Payne, S.

L. DeLoach, S. Payne, L. Chase, L. Smith, W. Kway, and W. Krupke, “Evaluation of absorption and emission properties of Yb3+, doped crystals for laser applications,” IEEE J. Quantum Electron. 29(4), 1179–1191 (1993).
[Crossref]

Pellegrina, A.

Petit, V.

V. Petit, J. L. Doualan, P. Camy, V. Ménard, and R. Moncorgé, “Cw and tunable laser operation of Yb doped CaF2,” Appl. Phys. B 78(6), 681–684 (2004).
[Crossref]

Piehler, S.

Piotr, S.

Y. Wu, L. Su, Q. Wang, H. Li, Y. Zhan, D. Jang, X. Qian, C. Wang, L. Zheng, H. Chen, J. Xu, R. Witold, S. Piotr, and L. Radoslaw, “Spectroscopic properties of Yb-doped CaF2-YF3 solid-solution laser crystal,” Laser Phys. 23(10), 105805 (2013).
[Crossref]

Podleska, S.

Qian, X.

Y. Wu, L. Su, Q. Wang, H. Li, Y. Zhan, D. Jang, X. Qian, C. Wang, L. Zheng, H. Chen, J. Xu, R. Witold, S. Piotr, and L. Radoslaw, “Spectroscopic properties of Yb-doped CaF2-YF3 solid-solution laser crystal,” Laser Phys. 23(10), 105805 (2013).
[Crossref]

Qian, X. B.

L. B. Su, Q. G. Wang, H. J. Li, G. Brasse, P. Camy, J. L. Doualan, A. Braud, R. Moncorge, Y. Y. Zhan, L. H. Zheng, X. B. Qian, and J. Xu, “Spectroscopic properties and CW laser operation of Nd, Y-codoped CaF2 single crystals,” Laser Phys. Lett. 10(3), 035804 (2013).
[Crossref]

Radoslaw, L.

Y. Wu, L. Su, Q. Wang, H. Li, Y. Zhan, D. Jang, X. Qian, C. Wang, L. Zheng, H. Chen, J. Xu, R. Witold, S. Piotr, and L. Radoslaw, “Spectroscopic properties of Yb-doped CaF2-YF3 solid-solution laser crystal,” Laser Phys. 23(10), 105805 (2013).
[Crossref]

Rumpel, M.

Shen, S.

S. Shen and A. Jha, “The influence of f-ion doping on the fluorescence (4I13/2 → 4I15/2) line shape broadening in er-doped oxyfluoride silicate glasses,” Opt. Mater. 25(3), 321–333 (2004).
[Crossref]

Shi, J. K.

W. B. Xu, L. Chai, J. K. Shi, M. L. Hu, C. Y. Wang, L. B. Su, D. P. Jiang, and J. Xu, “Operational characteristics of a ld-pumped novel Yb,Y:CaF2 mode-locked laser using a sesam,” Laser Phys. Lett. 11(11), 115816 (2014).
[Crossref]

Si, J.

L. Su, J. Xu, H. Li, L. Wen, Y. Zhu, Z. Zhao, Y. Dong, G. Zhou, and J. Si, “Sites structure and spectroscopic properties of Yb-doped and Yb, Na-codoped CaF2 laser crystals,” Chem. Phys. Lett. 406(1–3), 254–258 (2005).
[Crossref]

Siebold, M.

Smith, L.

L. DeLoach, S. Payne, L. Chase, L. Smith, W. Kway, and W. Krupke, “Evaluation of absorption and emission properties of Yb3+, doped crystals for laser applications,” IEEE J. Quantum Electron. 29(4), 1179–1191 (1993).
[Crossref]

Su, L.

Y. He, Y. Xue, W. Liu, L. Su, F. Tang, and J. Wang, “Structure and Property of Yb Doped Ca1-xRxF2+x (R=La, Gd) Laser Crystals,” J. Inorg. Mater. 32(8), 857–862 (2017).

Y. Wu, L. Su, Q. Wang, H. Li, Y. Zhan, D. Jang, X. Qian, C. Wang, L. Zheng, H. Chen, J. Xu, R. Witold, S. Piotr, and L. Radoslaw, “Spectroscopic properties of Yb-doped CaF2-YF3 solid-solution laser crystal,” Laser Phys. 23(10), 105805 (2013).
[Crossref]

L. Zheng, J. Xu, G. Zhao, L. Su, F. Wu, and X. Liang, “Bulk crystal growth and efficient diode-pumped laser performance of Yb3+:Sc2SiO5,” Appl. Phys. B 91(3-4), 443–445 (2008).
[Crossref]

L. Su, J. Xu, H. Li, L. Wen, Y. Zhu, Z. Zhao, Y. Dong, G. Zhou, and J. Si, “Sites structure and spectroscopic properties of Yb-doped and Yb, Na-codoped CaF2 laser crystals,” Chem. Phys. Lett. 406(1–3), 254–258 (2005).
[Crossref]

Su, L. B.

J. Liu, J. F. Liu, L. B. Su, Q. Zhang, F. K. Ma, D. P. Jiang, and J. Xu, “Effects of Gd3+/Y3+ codoping on the spectral properties of Nd:CaF2 crystals,” Wuli Xuebao 65, 5 (2016).

W. B. Xu, L. Chai, J. K. Shi, M. L. Hu, C. Y. Wang, L. B. Su, D. P. Jiang, and J. Xu, “Operational characteristics of a ld-pumped novel Yb,Y:CaF2 mode-locked laser using a sesam,” Laser Phys. Lett. 11(11), 115816 (2014).
[Crossref]

L. B. Su, Q. G. Wang, H. J. Li, G. Brasse, P. Camy, J. L. Doualan, A. Braud, R. Moncorge, Y. Y. Zhan, L. H. Zheng, X. B. Qian, and J. Xu, “Spectroscopic properties and CW laser operation of Nd, Y-codoped CaF2 single crystals,” Laser Phys. Lett. 10(3), 035804 (2013).
[Crossref]

Tang, F.

Y. He, Y. Xue, W. Liu, L. Su, F. Tang, and J. Wang, “Structure and Property of Yb Doped Ca1-xRxF2+x (R=La, Gd) Laser Crystals,” J. Inorg. Mater. 32(8), 857–862 (2017).

Tao, X.

Q. Hu, Z. Jia, A. Volpi, S. Veronesi, M. Tonelli, and X. Tao, “Crystal growth and spectral broadening of a promising Yb:CaLuxGd1−xAlO4 disordered crystal for ultrafast laser application,” CrystEngComm 19(12), 1643–1647 (2017).
[Crossref]

Tonelli, M.

Q. Hu, Z. Jia, A. Volpi, S. Veronesi, M. Tonelli, and X. Tao, “Crystal growth and spectral broadening of a promising Yb:CaLuxGd1−xAlO4 disordered crystal for ultrafast laser application,” CrystEngComm 19(12), 1643–1647 (2017).
[Crossref]

Toratani, H.

X. Zou and H. Toratani, “Evaluation of spectroscopic properties of Yb3+-doped glasses,” Phys. Rev. B Condens. Matter 52(22), 15889–15897 (1995).
[Crossref] [PubMed]

Uecker, R.

Veronesi, S.

Q. Hu, Z. Jia, A. Volpi, S. Veronesi, M. Tonelli, and X. Tao, “Crystal growth and spectral broadening of a promising Yb:CaLuxGd1−xAlO4 disordered crystal for ultrafast laser application,” CrystEngComm 19(12), 1643–1647 (2017).
[Crossref]

Villeval, P.

Volpi, A.

Q. Hu, Z. Jia, A. Volpi, S. Veronesi, M. Tonelli, and X. Tao, “Crystal growth and spectral broadening of a promising Yb:CaLuxGd1−xAlO4 disordered crystal for ultrafast laser application,” CrystEngComm 19(12), 1643–1647 (2017).
[Crossref]

Wandt, C.

Wang, C.

Y. Wu, L. Su, Q. Wang, H. Li, Y. Zhan, D. Jang, X. Qian, C. Wang, L. Zheng, H. Chen, J. Xu, R. Witold, S. Piotr, and L. Radoslaw, “Spectroscopic properties of Yb-doped CaF2-YF3 solid-solution laser crystal,” Laser Phys. 23(10), 105805 (2013).
[Crossref]

Wang, C. Y.

W. B. Xu, L. Chai, J. K. Shi, M. L. Hu, C. Y. Wang, L. B. Su, D. P. Jiang, and J. Xu, “Operational characteristics of a ld-pumped novel Yb,Y:CaF2 mode-locked laser using a sesam,” Laser Phys. Lett. 11(11), 115816 (2014).
[Crossref]

Wang, J.

Y. He, Y. Xue, W. Liu, L. Su, F. Tang, and J. Wang, “Structure and Property of Yb Doped Ca1-xRxF2+x (R=La, Gd) Laser Crystals,” J. Inorg. Mater. 32(8), 857–862 (2017).

Wang, Q.

Y. Wu, L. Su, Q. Wang, H. Li, Y. Zhan, D. Jang, X. Qian, C. Wang, L. Zheng, H. Chen, J. Xu, R. Witold, S. Piotr, and L. Radoslaw, “Spectroscopic properties of Yb-doped CaF2-YF3 solid-solution laser crystal,” Laser Phys. 23(10), 105805 (2013).
[Crossref]

Wang, Q. G.

L. B. Su, Q. G. Wang, H. J. Li, G. Brasse, P. Camy, J. L. Doualan, A. Braud, R. Moncorge, Y. Y. Zhan, L. H. Zheng, X. B. Qian, and J. Xu, “Spectroscopic properties and CW laser operation of Nd, Y-codoped CaF2 single crystals,” Laser Phys. Lett. 10(3), 035804 (2013).
[Crossref]

Wen, L.

L. Su, J. Xu, H. Li, L. Wen, Y. Zhu, Z. Zhao, Y. Dong, G. Zhou, and J. Si, “Sites structure and spectroscopic properties of Yb-doped and Yb, Na-codoped CaF2 laser crystals,” Chem. Phys. Lett. 406(1–3), 254–258 (2005).
[Crossref]

Witold, R.

Y. Wu, L. Su, Q. Wang, H. Li, Y. Zhan, D. Jang, X. Qian, C. Wang, L. Zheng, H. Chen, J. Xu, R. Witold, S. Piotr, and L. Radoslaw, “Spectroscopic properties of Yb-doped CaF2-YF3 solid-solution laser crystal,” Laser Phys. 23(10), 105805 (2013).
[Crossref]

Wu, F.

L. Zheng, J. Xu, G. Zhao, L. Su, F. Wu, and X. Liang, “Bulk crystal growth and efficient diode-pumped laser performance of Yb3+:Sc2SiO5,” Appl. Phys. B 91(3-4), 443–445 (2008).
[Crossref]

Wu, Y.

Y. Wu, L. Su, Q. Wang, H. Li, Y. Zhan, D. Jang, X. Qian, C. Wang, L. Zheng, H. Chen, J. Xu, R. Witold, S. Piotr, and L. Radoslaw, “Spectroscopic properties of Yb-doped CaF2-YF3 solid-solution laser crystal,” Laser Phys. 23(10), 105805 (2013).
[Crossref]

Xu, J.

J. Liu, J. F. Liu, L. B. Su, Q. Zhang, F. K. Ma, D. P. Jiang, and J. Xu, “Effects of Gd3+/Y3+ codoping on the spectral properties of Nd:CaF2 crystals,” Wuli Xuebao 65, 5 (2016).

W. B. Xu, L. Chai, J. K. Shi, M. L. Hu, C. Y. Wang, L. B. Su, D. P. Jiang, and J. Xu, “Operational characteristics of a ld-pumped novel Yb,Y:CaF2 mode-locked laser using a sesam,” Laser Phys. Lett. 11(11), 115816 (2014).
[Crossref]

Y. Wu, L. Su, Q. Wang, H. Li, Y. Zhan, D. Jang, X. Qian, C. Wang, L. Zheng, H. Chen, J. Xu, R. Witold, S. Piotr, and L. Radoslaw, “Spectroscopic properties of Yb-doped CaF2-YF3 solid-solution laser crystal,” Laser Phys. 23(10), 105805 (2013).
[Crossref]

L. B. Su, Q. G. Wang, H. J. Li, G. Brasse, P. Camy, J. L. Doualan, A. Braud, R. Moncorge, Y. Y. Zhan, L. H. Zheng, X. B. Qian, and J. Xu, “Spectroscopic properties and CW laser operation of Nd, Y-codoped CaF2 single crystals,” Laser Phys. Lett. 10(3), 035804 (2013).
[Crossref]

L. Zheng, J. Xu, G. Zhao, L. Su, F. Wu, and X. Liang, “Bulk crystal growth and efficient diode-pumped laser performance of Yb3+:Sc2SiO5,” Appl. Phys. B 91(3-4), 443–445 (2008).
[Crossref]

L. Su, J. Xu, H. Li, L. Wen, Y. Zhu, Z. Zhao, Y. Dong, G. Zhou, and J. Si, “Sites structure and spectroscopic properties of Yb-doped and Yb, Na-codoped CaF2 laser crystals,” Chem. Phys. Lett. 406(1–3), 254–258 (2005).
[Crossref]

Xu, W. B.

W. B. Xu, L. Chai, J. K. Shi, M. L. Hu, C. Y. Wang, L. B. Su, D. P. Jiang, and J. Xu, “Operational characteristics of a ld-pumped novel Yb,Y:CaF2 mode-locked laser using a sesam,” Laser Phys. Lett. 11(11), 115816 (2014).
[Crossref]

Xue, Y.

Y. He, Y. Xue, W. Liu, L. Su, F. Tang, and J. Wang, “Structure and Property of Yb Doped Ca1-xRxF2+x (R=La, Gd) Laser Crystals,” J. Inorg. Mater. 32(8), 857–862 (2017).

Zhan, Y.

Y. Wu, L. Su, Q. Wang, H. Li, Y. Zhan, D. Jang, X. Qian, C. Wang, L. Zheng, H. Chen, J. Xu, R. Witold, S. Piotr, and L. Radoslaw, “Spectroscopic properties of Yb-doped CaF2-YF3 solid-solution laser crystal,” Laser Phys. 23(10), 105805 (2013).
[Crossref]

Zhan, Y. Y.

L. B. Su, Q. G. Wang, H. J. Li, G. Brasse, P. Camy, J. L. Doualan, A. Braud, R. Moncorge, Y. Y. Zhan, L. H. Zheng, X. B. Qian, and J. Xu, “Spectroscopic properties and CW laser operation of Nd, Y-codoped CaF2 single crystals,” Laser Phys. Lett. 10(3), 035804 (2013).
[Crossref]

Zhang, Q.

J. Liu, J. F. Liu, L. B. Su, Q. Zhang, F. K. Ma, D. P. Jiang, and J. Xu, “Effects of Gd3+/Y3+ codoping on the spectral properties of Nd:CaF2 crystals,” Wuli Xuebao 65, 5 (2016).

Zhao, G.

L. Zheng, J. Xu, G. Zhao, L. Su, F. Wu, and X. Liang, “Bulk crystal growth and efficient diode-pumped laser performance of Yb3+:Sc2SiO5,” Appl. Phys. B 91(3-4), 443–445 (2008).
[Crossref]

Zhao, Z.

L. Su, J. Xu, H. Li, L. Wen, Y. Zhu, Z. Zhao, Y. Dong, G. Zhou, and J. Si, “Sites structure and spectroscopic properties of Yb-doped and Yb, Na-codoped CaF2 laser crystals,” Chem. Phys. Lett. 406(1–3), 254–258 (2005).
[Crossref]

Zheng, L.

Y. Wu, L. Su, Q. Wang, H. Li, Y. Zhan, D. Jang, X. Qian, C. Wang, L. Zheng, H. Chen, J. Xu, R. Witold, S. Piotr, and L. Radoslaw, “Spectroscopic properties of Yb-doped CaF2-YF3 solid-solution laser crystal,” Laser Phys. 23(10), 105805 (2013).
[Crossref]

L. Zheng, J. Xu, G. Zhao, L. Su, F. Wu, and X. Liang, “Bulk crystal growth and efficient diode-pumped laser performance of Yb3+:Sc2SiO5,” Appl. Phys. B 91(3-4), 443–445 (2008).
[Crossref]

Zheng, L. H.

L. B. Su, Q. G. Wang, H. J. Li, G. Brasse, P. Camy, J. L. Doualan, A. Braud, R. Moncorge, Y. Y. Zhan, L. H. Zheng, X. B. Qian, and J. Xu, “Spectroscopic properties and CW laser operation of Nd, Y-codoped CaF2 single crystals,” Laser Phys. Lett. 10(3), 035804 (2013).
[Crossref]

Zhou, G.

L. Su, J. Xu, H. Li, L. Wen, Y. Zhu, Z. Zhao, Y. Dong, G. Zhou, and J. Si, “Sites structure and spectroscopic properties of Yb-doped and Yb, Na-codoped CaF2 laser crystals,” Chem. Phys. Lett. 406(1–3), 254–258 (2005).
[Crossref]

Zhu, Y.

L. Su, J. Xu, H. Li, L. Wen, Y. Zhu, Z. Zhao, Y. Dong, G. Zhou, and J. Si, “Sites structure and spectroscopic properties of Yb-doped and Yb, Na-codoped CaF2 laser crystals,” Chem. Phys. Lett. 406(1–3), 254–258 (2005).
[Crossref]

Zou, X.

X. Zou and H. Toratani, “Evaluation of spectroscopic properties of Yb3+-doped glasses,” Phys. Rev. B Condens. Matter 52(22), 15889–15897 (1995).
[Crossref] [PubMed]

Appl. Phys. B (2)

V. Petit, J. L. Doualan, P. Camy, V. Ménard, and R. Moncorgé, “Cw and tunable laser operation of Yb doped CaF2,” Appl. Phys. B 78(6), 681–684 (2004).
[Crossref]

L. Zheng, J. Xu, G. Zhao, L. Su, F. Wu, and X. Liang, “Bulk crystal growth and efficient diode-pumped laser performance of Yb3+:Sc2SiO5,” Appl. Phys. B 91(3-4), 443–445 (2008).
[Crossref]

Chem. Phys. Lett. (1)

L. Su, J. Xu, H. Li, L. Wen, Y. Zhu, Z. Zhao, Y. Dong, G. Zhou, and J. Si, “Sites structure and spectroscopic properties of Yb-doped and Yb, Na-codoped CaF2 laser crystals,” Chem. Phys. Lett. 406(1–3), 254–258 (2005).
[Crossref]

CrystEngComm (1)

Q. Hu, Z. Jia, A. Volpi, S. Veronesi, M. Tonelli, and X. Tao, “Crystal growth and spectral broadening of a promising Yb:CaLuxGd1−xAlO4 disordered crystal for ultrafast laser application,” CrystEngComm 19(12), 1643–1647 (2017).
[Crossref]

IEEE J. Quantum Electron. (1)

L. DeLoach, S. Payne, L. Chase, L. Smith, W. Kway, and W. Krupke, “Evaluation of absorption and emission properties of Yb3+, doped crystals for laser applications,” IEEE J. Quantum Electron. 29(4), 1179–1191 (1993).
[Crossref]

J. Inorg. Mater. (1)

Y. He, Y. Xue, W. Liu, L. Su, F. Tang, and J. Wang, “Structure and Property of Yb Doped Ca1-xRxF2+x (R=La, Gd) Laser Crystals,” J. Inorg. Mater. 32(8), 857–862 (2017).

Laser Phys. (1)

Y. Wu, L. Su, Q. Wang, H. Li, Y. Zhan, D. Jang, X. Qian, C. Wang, L. Zheng, H. Chen, J. Xu, R. Witold, S. Piotr, and L. Radoslaw, “Spectroscopic properties of Yb-doped CaF2-YF3 solid-solution laser crystal,” Laser Phys. 23(10), 105805 (2013).
[Crossref]

Laser Phys. Lett. (2)

W. B. Xu, L. Chai, J. K. Shi, M. L. Hu, C. Y. Wang, L. B. Su, D. P. Jiang, and J. Xu, “Operational characteristics of a ld-pumped novel Yb,Y:CaF2 mode-locked laser using a sesam,” Laser Phys. Lett. 11(11), 115816 (2014).
[Crossref]

L. B. Su, Q. G. Wang, H. J. Li, G. Brasse, P. Camy, J. L. Doualan, A. Braud, R. Moncorge, Y. Y. Zhan, L. H. Zheng, X. B. Qian, and J. Xu, “Spectroscopic properties and CW laser operation of Nd, Y-codoped CaF2 single crystals,” Laser Phys. Lett. 10(3), 035804 (2013).
[Crossref]

Opt. Express (1)

Opt. Lett. (3)

Opt. Mater. (1)

S. Shen and A. Jha, “The influence of f-ion doping on the fluorescence (4I13/2 → 4I15/2) line shape broadening in er-doped oxyfluoride silicate glasses,” Opt. Mater. 25(3), 321–333 (2004).
[Crossref]

Opt. Mater. Express (1)

Phys. Rev. B Condens. Matter (1)

X. Zou and H. Toratani, “Evaluation of spectroscopic properties of Yb3+-doped glasses,” Phys. Rev. B Condens. Matter 52(22), 15889–15897 (1995).
[Crossref] [PubMed]

Wuli Xuebao (1)

J. Liu, J. F. Liu, L. B. Su, Q. Zhang, F. K. Ma, D. P. Jiang, and J. Xu, “Effects of Gd3+/Y3+ codoping on the spectral properties of Nd:CaF2 crystals,” Wuli Xuebao 65, 5 (2016).

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Figures (4)

Fig. 1
Fig. 1 X-ray Diffraction measurement of the as-grown 3 at.%Yb: Sr1-xGdxF2+x single crystal. (a). the whole comparison from 10° to 80° of X-ray Diffraction intensity in 3 at.%Yb: Sr1-xGdxF2+x single crystal; (b). the partial comparison from 25° to 29° of X-ray Diffraction intensity in 3 at.%Yb: Sr1-xGdxF2+x single crystal
Fig. 2
Fig. 2 Absorption spectra of 3 at.%Yb: Sr1-xGdxF2+x single crystal. a) absorption coefficient; b) absorption cross-section.
Fig. 3
Fig. 3 a) The emission cross section spectra for in 3 at.%Yb: Sr1-xGdxF2+x crystals; b) the emission cross-section at 976 nm, 1012 nm, 1029 nm and 1041nm varying with the concentration of Gd3+ ions in 3 at.%Yb: Sr1-xGdxF2+x crystals.
Fig. 4
Fig. 4 a) The fluorescence lifetime of 3 at.%Yb: Sr1-xGdxF2+x crystals; b) The average output power as a function of input power for CW laser; c) FOM Gain at 1052 nm and optic-optic efficiency in 3 at.%Yb: Sr1-xGdxF2+x crystals; d) The average output power as a function of absorbed pump power for CW laser in 3 at.%Yb: Sr0.97Gd0.03F2.03 crystal.

Tables (2)

Tables Icon

Table 1 Segregation coefficient of Yb3+ and Gd3+ ions in 3 at.%Yb: Sr1-xGdxF2+x crystal.

Tables Icon

Table 2 The emission cross section σem of different Yb-doped crystals.

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