Abstract

A novel single phased white emitting phosphor Sr3La(PO4)3:Eu2+, Sm3+ was synthesized by the solid-state method, and the crystal structure and luminescence properties of phosphors were investigated in detail by the X-ray diffraction, photoluminescence spectra and decay curves. Through the energy transfer, the warm white light can be realized with superior chromaticity coordinates of (0.3824, 0.3381), low correlated color temperature (CCT = 3598 K), and Ra of 78.4 by varying the molar ratios of Eu2+ and Sm3+ in the Sr3La(PO4)3:Eu2+, Sm3+ phosphor. The results indicate that the developed phosphor can be used as a potential warm white emitting phosphor for white light emitting diodes.

© 2015 Optical Society of America

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    [Crossref]
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    [Crossref] [PubMed]
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    [Crossref]
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    [Crossref]
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    [Crossref]
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    [Crossref] [PubMed]
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    [Crossref]
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    [Crossref]
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    [Crossref]
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    [Crossref]
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    [Crossref]
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    [Crossref]
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    [Crossref]
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    [Crossref]
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    [Crossref]
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    [Crossref]
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    [Crossref]
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    [Crossref]

2015 (1)

X. G. Zhang, P. He, L. Y. Zhou, Q. Pang, J. X. Shi, and M. L. Gong, “Sr3La(PO4)3: Eu2+, Mn2+: a single-phased color-tunable phosphor and its energy transfer behavior,” J. Lumin. 157, 352–356 (2015).
[Crossref]

2014 (5)

Z. J. Wang, S. Q. Lou, and P. L. Li, “Luminescent properties and energy transfer of Sr3La(PO4)3:Sm3+, Eu3+ for white LEDs,” J. Alloys Compd. 586, 536–541 (2014).
[Crossref]

Z. J. Wang, S. Q. Lou, and P. L. Li, “Enhanced orange–red emission of Sr3La(PO4)3:Ce3+, Mn2+ via energy transfer,” J. Lumin. 156, 87–90 (2014).
[Crossref]

L. Wu, M. Y. Ji, H. R. Wang, Y. F. Kong, and Y. Zhang, “Site occupancy and photoluminescence of Sm3+ in KSr4(BO3)3:Sm3+ phosphors,” Opt. Mater. Express 4(8), 1535–1544 (2014).
[Crossref]

Y. Liu, G. Liu, J. Wang, X. Dong, and W. Yu, “Single-Component and Warm-White-Emitting Phosphor NaGd(WO4)2:Tm3+, Dy3+, Eu3+: Synthesis, Luminescence, Energy Transfer, and Tunable Color,” Inorg. Chem. 53(21), 11457–11466 (2014).
[Crossref] [PubMed]

L. Wang, H. M. Noh, B. K. Moon, S. H. Park, J. H. Jeong, and J. Shi, “Simultaneous realization of two approaches to white light in single-component phosphors,” Opt. Express 22(21), 25500–25505 (2014).
[Crossref] [PubMed]

2013 (4)

G. Y. Lee, W. B. Im, A. Kirakosyan, S. H. Cheong, J. Y. Han, and D. Y. Jeon, “Tunable emission from blue to white light in single-phase Na(0.34)Ca(0.66-x-y)Al(1.66)Si(2.34)O8:xEu2+,yMn2+ (x = 0.07) phosphor for white-light UV LEDs,” Opt. Express 21(3), 3287–3297 (2013).
[Crossref] [PubMed]

G. Zhu, Z. P. Ci, Q. Wang, Y. R. Shi, and Y. H. Wang, “Full-color emission generation from single phased phosphor Sr10[(PO4)5.5(BO4)0.5](BO2): Ce3+, Mn2+, Tb3+ for white light emitting diodes,” Opt. Mater. Express 3(11), 1810–1819 (2013).
[Crossref]

Y. Jia, W. Lü, N. Guo, W. Lü, Q. Zhao, and H. You, “Realization of color hue tuning via efficient Tb3+-Mn2+ energy transfer in Sr3Tb(PO4)3:Mn2+, a potential near-UV excited phosphor for white LEDs,” Phys. Chem. Chem. Phys. 15(16), 6057–6062 (2013).
[Crossref] [PubMed]

V. R. Bandi, B. K. Grandhe, K. Jang, D. S. Shin, S. S. Yi, and J. H. Jeong, “An investigation on photoluminescence and energy transfer of Eu3+/Sm3+ single-doped and co-doped Ca4YO(BO3)3 phosphors,” Mater. Chem. Phys. 140(2-3), 453–457 (2013).
[Crossref]

2012 (7)

P. L. Li, Z. J. Wang, Z. P. Yang, and Q. L. Guo, “Energy Transfer between Activators at Different crystallographic Sites in Sr3La(PO4)3,” J. Electrochem. Soc. 159(3), H307–H311 (2012).
[Crossref]

H. Y. Li, H. K. Yang, B. K. Moon, B. C. Choi, J. H. Jeong, K. Jang, H. S. Lee, and S. S. Yi, “Tunable photoluminescence properties of Eu(II)-and Sm(III)-coactivated Ca9Y(PO4)7 and energy transfer between Eu(II) and Sm(III),” Opt. Express 2(4), 443–451 (2012).
[Crossref]

D. L. Geng, G. G. Li, M. M. Shang, D. M. Yang, Y. Zhang, Z. Y. Cheng, and J. Lin, “Color tuning via energy transfer in Sr3In(PO4)3:Ce3+/Tb3+/Mn2+ phosphors,” J. Mater. Chem. 22(28), 14262–14271 (2012).
[Crossref]

Z. Xia and R. Liu, “Tunable Blue-Green Color Emission and Energy Transfer of Ca2Al3O6F:Ce3+,Tb3+ Phosphors for Near-UV White LEDs,” J. Phys. Chem. C 116(29), 15604–15609 (2012).
[Crossref]

N. Guo, Y. H. Zheng, Y. C. Jia, H. Qiao, and H. P. You, “A tunable warm-white-light Sr3Gd(PO4)3:Eu2+,Mn2+ phosphor system for LED-based solid-state lighting,” New J. Chem. 36(1), 168–172 (2012).
[Crossref]

N. Guo, Y. H. Zheng, Y. C. Jia, H. Qiao, and H. P. You, “Warm-White-Emitting from Eu2+/Mn2+-Codoped Sr3Lu(PO4)3 Phosphor with Tunable Color Tone and Correlated Color Temperature,” J. Phys. Chem. C 116(1), 1329–1334 (2012).
[Crossref]

Y. C. Jia, Y. J. Huang, Y. H. Zheng, N. Guo, H. Qiao, Q. Zhao, W. Z. Lv, and H. P. You, “Color point tuning of Y3Al5O12:Ce3+ phosphor via Mn2+-Si4+ incorporation for white light generation,” J. Mater. Chem. 22(30), 15146–15152 (2012).
[Crossref]

2011 (1)

2010 (2)

C. H. Huang and T. M. Chen, “Ca9La(PO4)7:Eu2+,Mn2+: an emission-tunable phosphor through efficient energy transfer for white light-emitting diodes,” Opt. Express 18(5), 5089–5099 (2010).
[Crossref] [PubMed]

T. W. Kuo and T. M. Chen, “A Green-Emitting Phosphor Sr3La(PO4)3:Ce3+,Tb3+ with Efficient Energy Transfer for Fluorescent Lamp,” J. Electrochem. Soc. 157(6), J216–J220 (2010).
[Crossref]

2009 (3)

X. Zhang, F. Zhou, J. Shi, and M. Gong, “Sr3.5Mg0.5Si3O8Cl4: Eu2+ bluish–green-emitting phosphor for NUV-based LED,” Mater. Lett. 63(11), 852–854 (2009).
[Crossref]

F. Xiao, Y. N. Xue, and Q. Y. Zhang, “Warm white light from Y4MgSi3O13:Bi3+, Eu3+ nanophosphor for white light-emitting diodes,” Spectrochim. Acta A Mol. Biomol. Spectrosc. 74(2), 498–501 (2009).
[Crossref] [PubMed]

H. A. Höppe, “Recent developments in the field of inorganic phosphors,” Angew. Chem. Int. Ed. Engl. 48(20), 3572–3582 (2009).
[Crossref] [PubMed]

2007 (1)

R. J. Xie and N. Hirosaki, “Silicon-based oxynitride and nitride phosphors for white LEDs-A review,” Sci. Technol. Adv. Mater. 8(7–8), 588–600 (2007).
[Crossref]

2006 (2)

X. Piao, T. Horikawa, H. Hanzawa, and K. Machida, “Characterization and luminescence properties of Sr2Si5N8: Eu phosphor for white light-emitting-diode illumination,” Appl. Phys. Lett. 88(16), 161908 (2006).
[Crossref]

Y. H. Won, H. S. Jang, W. B. Im, D. Y. Jeon, and J. S. Lee, “Tunable full-color-emitting La0.827Al11.9O19.09:Eu2+,Mn2+ phosphor for application to warm white-light-emitting diodes,” Appl. Phys. Lett. 89(23), 231909 (2006).
[Crossref]

2005 (1)

W. J. Yang, L. Luo, T. M. Chen, and N. S. Wang, “Luminescence and Energy Transfer of Eu- and Mn-Coactivated CaAl2Si2O8 as a Potential Phosphor for White-Light UVLED,” Chem. Mater. 17(15), 3883–3888 (2005).
[Crossref]

2004 (2)

J. S. Kim, P. E. Jeon, J. C. Choi, H. L. Park, S. I. Mho, and G. C. Kim, “Warm-white-light emitting diode utilizing a single-phase full-color Ba3MgSi2O8:Eu2+, Mn2+ phosphor,” Appl. Phys. Lett. 84(15), 2931–2934 (2004).
[Crossref]

J. S. Kim, P. E. Jeon, Y. H. Park, J. C. Choi, H. L. Park, G. C. Kim, and T. W. Kim, “White-light generation through ultraviolet-emitting diode and white-emitting phosphor,” Appl. Phys. Lett. 85(17), 3696–3698 (2004).
[Crossref]

1975 (1)

G. Blasse, “Influence of local charge compensation on site occupation and luminescence of apatites,” J. Solid State Chem. 14(2), 181–184 (1975).
[Crossref]

1969 (1)

G. Blasse, “Energy transfer in oxidic phosphors,” Philips Res. Rep. 24, 131–144 (1969).

Bandi, V. R.

V. R. Bandi, B. K. Grandhe, K. Jang, D. S. Shin, S. S. Yi, and J. H. Jeong, “An investigation on photoluminescence and energy transfer of Eu3+/Sm3+ single-doped and co-doped Ca4YO(BO3)3 phosphors,” Mater. Chem. Phys. 140(2-3), 453–457 (2013).
[Crossref]

Blasse, G.

G. Blasse, “Influence of local charge compensation on site occupation and luminescence of apatites,” J. Solid State Chem. 14(2), 181–184 (1975).
[Crossref]

G. Blasse, “Energy transfer in oxidic phosphors,” Philips Res. Rep. 24, 131–144 (1969).

Chen, T. M.

C. H. Huang and T. M. Chen, “Ca9La(PO4)7:Eu2+,Mn2+: an emission-tunable phosphor through efficient energy transfer for white light-emitting diodes,” Opt. Express 18(5), 5089–5099 (2010).
[Crossref] [PubMed]

T. W. Kuo and T. M. Chen, “A Green-Emitting Phosphor Sr3La(PO4)3:Ce3+,Tb3+ with Efficient Energy Transfer for Fluorescent Lamp,” J. Electrochem. Soc. 157(6), J216–J220 (2010).
[Crossref]

W. J. Yang, L. Luo, T. M. Chen, and N. S. Wang, “Luminescence and Energy Transfer of Eu- and Mn-Coactivated CaAl2Si2O8 as a Potential Phosphor for White-Light UVLED,” Chem. Mater. 17(15), 3883–3888 (2005).
[Crossref]

Cheng, Z. Y.

D. L. Geng, G. G. Li, M. M. Shang, D. M. Yang, Y. Zhang, Z. Y. Cheng, and J. Lin, “Color tuning via energy transfer in Sr3In(PO4)3:Ce3+/Tb3+/Mn2+ phosphors,” J. Mater. Chem. 22(28), 14262–14271 (2012).
[Crossref]

Cheong, S. H.

Choi, B. C.

H. Y. Li, H. K. Yang, B. K. Moon, B. C. Choi, J. H. Jeong, K. Jang, H. S. Lee, and S. S. Yi, “Tunable photoluminescence properties of Eu(II)-and Sm(III)-coactivated Ca9Y(PO4)7 and energy transfer between Eu(II) and Sm(III),” Opt. Express 2(4), 443–451 (2012).
[Crossref]

Choi, J. C.

J. S. Kim, P. E. Jeon, J. C. Choi, H. L. Park, S. I. Mho, and G. C. Kim, “Warm-white-light emitting diode utilizing a single-phase full-color Ba3MgSi2O8:Eu2+, Mn2+ phosphor,” Appl. Phys. Lett. 84(15), 2931–2934 (2004).
[Crossref]

J. S. Kim, P. E. Jeon, Y. H. Park, J. C. Choi, H. L. Park, G. C. Kim, and T. W. Kim, “White-light generation through ultraviolet-emitting diode and white-emitting phosphor,” Appl. Phys. Lett. 85(17), 3696–3698 (2004).
[Crossref]

Ci, Z. P.

Ding, X.

Dong, X.

Y. Liu, G. Liu, J. Wang, X. Dong, and W. Yu, “Single-Component and Warm-White-Emitting Phosphor NaGd(WO4)2:Tm3+, Dy3+, Eu3+: Synthesis, Luminescence, Energy Transfer, and Tunable Color,” Inorg. Chem. 53(21), 11457–11466 (2014).
[Crossref] [PubMed]

Gao, Z.

Geng, D. L.

D. L. Geng, G. G. Li, M. M. Shang, D. M. Yang, Y. Zhang, Z. Y. Cheng, and J. Lin, “Color tuning via energy transfer in Sr3In(PO4)3:Ce3+/Tb3+/Mn2+ phosphors,” J. Mater. Chem. 22(28), 14262–14271 (2012).
[Crossref]

Gong, M.

X. Zhang, F. Zhou, J. Shi, and M. Gong, “Sr3.5Mg0.5Si3O8Cl4: Eu2+ bluish–green-emitting phosphor for NUV-based LED,” Mater. Lett. 63(11), 852–854 (2009).
[Crossref]

Gong, M. L.

X. G. Zhang, P. He, L. Y. Zhou, Q. Pang, J. X. Shi, and M. L. Gong, “Sr3La(PO4)3: Eu2+, Mn2+: a single-phased color-tunable phosphor and its energy transfer behavior,” J. Lumin. 157, 352–356 (2015).
[Crossref]

Grandhe, B. K.

V. R. Bandi, B. K. Grandhe, K. Jang, D. S. Shin, S. S. Yi, and J. H. Jeong, “An investigation on photoluminescence and energy transfer of Eu3+/Sm3+ single-doped and co-doped Ca4YO(BO3)3 phosphors,” Mater. Chem. Phys. 140(2-3), 453–457 (2013).
[Crossref]

Guo, N.

Y. Jia, W. Lü, N. Guo, W. Lü, Q. Zhao, and H. You, “Realization of color hue tuning via efficient Tb3+-Mn2+ energy transfer in Sr3Tb(PO4)3:Mn2+, a potential near-UV excited phosphor for white LEDs,” Phys. Chem. Chem. Phys. 15(16), 6057–6062 (2013).
[Crossref] [PubMed]

N. Guo, Y. H. Zheng, Y. C. Jia, H. Qiao, and H. P. You, “A tunable warm-white-light Sr3Gd(PO4)3:Eu2+,Mn2+ phosphor system for LED-based solid-state lighting,” New J. Chem. 36(1), 168–172 (2012).
[Crossref]

N. Guo, Y. H. Zheng, Y. C. Jia, H. Qiao, and H. P. You, “Warm-White-Emitting from Eu2+/Mn2+-Codoped Sr3Lu(PO4)3 Phosphor with Tunable Color Tone and Correlated Color Temperature,” J. Phys. Chem. C 116(1), 1329–1334 (2012).
[Crossref]

Y. C. Jia, Y. J. Huang, Y. H. Zheng, N. Guo, H. Qiao, Q. Zhao, W. Z. Lv, and H. P. You, “Color point tuning of Y3Al5O12:Ce3+ phosphor via Mn2+-Si4+ incorporation for white light generation,” J. Mater. Chem. 22(30), 15146–15152 (2012).
[Crossref]

Guo, Q. L.

P. L. Li, Z. J. Wang, Z. P. Yang, and Q. L. Guo, “Energy Transfer between Activators at Different crystallographic Sites in Sr3La(PO4)3,” J. Electrochem. Soc. 159(3), H307–H311 (2012).
[Crossref]

Han, J. Y.

Hanzawa, H.

X. Piao, T. Horikawa, H. Hanzawa, and K. Machida, “Characterization and luminescence properties of Sr2Si5N8: Eu phosphor for white light-emitting-diode illumination,” Appl. Phys. Lett. 88(16), 161908 (2006).
[Crossref]

He, P.

X. G. Zhang, P. He, L. Y. Zhou, Q. Pang, J. X. Shi, and M. L. Gong, “Sr3La(PO4)3: Eu2+, Mn2+: a single-phased color-tunable phosphor and its energy transfer behavior,” J. Lumin. 157, 352–356 (2015).
[Crossref]

Hirosaki, N.

R. J. Xie and N. Hirosaki, “Silicon-based oxynitride and nitride phosphors for white LEDs-A review,” Sci. Technol. Adv. Mater. 8(7–8), 588–600 (2007).
[Crossref]

Höppe, H. A.

H. A. Höppe, “Recent developments in the field of inorganic phosphors,” Angew. Chem. Int. Ed. Engl. 48(20), 3572–3582 (2009).
[Crossref] [PubMed]

Horikawa, T.

X. Piao, T. Horikawa, H. Hanzawa, and K. Machida, “Characterization and luminescence properties of Sr2Si5N8: Eu phosphor for white light-emitting-diode illumination,” Appl. Phys. Lett. 88(16), 161908 (2006).
[Crossref]

Hou, D.

Huang, C. H.

Huang, Y.

Huang, Y. J.

Y. C. Jia, Y. J. Huang, Y. H. Zheng, N. Guo, H. Qiao, Q. Zhao, W. Z. Lv, and H. P. You, “Color point tuning of Y3Al5O12:Ce3+ phosphor via Mn2+-Si4+ incorporation for white light generation,” J. Mater. Chem. 22(30), 15146–15152 (2012).
[Crossref]

Im, W. B.

G. Y. Lee, W. B. Im, A. Kirakosyan, S. H. Cheong, J. Y. Han, and D. Y. Jeon, “Tunable emission from blue to white light in single-phase Na(0.34)Ca(0.66-x-y)Al(1.66)Si(2.34)O8:xEu2+,yMn2+ (x = 0.07) phosphor for white-light UV LEDs,” Opt. Express 21(3), 3287–3297 (2013).
[Crossref] [PubMed]

Y. H. Won, H. S. Jang, W. B. Im, D. Y. Jeon, and J. S. Lee, “Tunable full-color-emitting La0.827Al11.9O19.09:Eu2+,Mn2+ phosphor for application to warm white-light-emitting diodes,” Appl. Phys. Lett. 89(23), 231909 (2006).
[Crossref]

Jang, H. S.

Y. H. Won, H. S. Jang, W. B. Im, D. Y. Jeon, and J. S. Lee, “Tunable full-color-emitting La0.827Al11.9O19.09:Eu2+,Mn2+ phosphor for application to warm white-light-emitting diodes,” Appl. Phys. Lett. 89(23), 231909 (2006).
[Crossref]

Jang, K.

V. R. Bandi, B. K. Grandhe, K. Jang, D. S. Shin, S. S. Yi, and J. H. Jeong, “An investigation on photoluminescence and energy transfer of Eu3+/Sm3+ single-doped and co-doped Ca4YO(BO3)3 phosphors,” Mater. Chem. Phys. 140(2-3), 453–457 (2013).
[Crossref]

H. Y. Li, H. K. Yang, B. K. Moon, B. C. Choi, J. H. Jeong, K. Jang, H. S. Lee, and S. S. Yi, “Tunable photoluminescence properties of Eu(II)-and Sm(III)-coactivated Ca9Y(PO4)7 and energy transfer between Eu(II) and Sm(III),” Opt. Express 2(4), 443–451 (2012).
[Crossref]

Jeon, D. Y.

G. Y. Lee, W. B. Im, A. Kirakosyan, S. H. Cheong, J. Y. Han, and D. Y. Jeon, “Tunable emission from blue to white light in single-phase Na(0.34)Ca(0.66-x-y)Al(1.66)Si(2.34)O8:xEu2+,yMn2+ (x = 0.07) phosphor for white-light UV LEDs,” Opt. Express 21(3), 3287–3297 (2013).
[Crossref] [PubMed]

Y. H. Won, H. S. Jang, W. B. Im, D. Y. Jeon, and J. S. Lee, “Tunable full-color-emitting La0.827Al11.9O19.09:Eu2+,Mn2+ phosphor for application to warm white-light-emitting diodes,” Appl. Phys. Lett. 89(23), 231909 (2006).
[Crossref]

Jeon, P. E.

J. S. Kim, P. E. Jeon, J. C. Choi, H. L. Park, S. I. Mho, and G. C. Kim, “Warm-white-light emitting diode utilizing a single-phase full-color Ba3MgSi2O8:Eu2+, Mn2+ phosphor,” Appl. Phys. Lett. 84(15), 2931–2934 (2004).
[Crossref]

J. S. Kim, P. E. Jeon, Y. H. Park, J. C. Choi, H. L. Park, G. C. Kim, and T. W. Kim, “White-light generation through ultraviolet-emitting diode and white-emitting phosphor,” Appl. Phys. Lett. 85(17), 3696–3698 (2004).
[Crossref]

Jeong, J. H.

L. Wang, H. M. Noh, B. K. Moon, S. H. Park, J. H. Jeong, and J. Shi, “Simultaneous realization of two approaches to white light in single-component phosphors,” Opt. Express 22(21), 25500–25505 (2014).
[Crossref] [PubMed]

V. R. Bandi, B. K. Grandhe, K. Jang, D. S. Shin, S. S. Yi, and J. H. Jeong, “An investigation on photoluminescence and energy transfer of Eu3+/Sm3+ single-doped and co-doped Ca4YO(BO3)3 phosphors,” Mater. Chem. Phys. 140(2-3), 453–457 (2013).
[Crossref]

H. Y. Li, H. K. Yang, B. K. Moon, B. C. Choi, J. H. Jeong, K. Jang, H. S. Lee, and S. S. Yi, “Tunable photoluminescence properties of Eu(II)-and Sm(III)-coactivated Ca9Y(PO4)7 and energy transfer between Eu(II) and Sm(III),” Opt. Express 2(4), 443–451 (2012).
[Crossref]

Ji, M. Y.

Jia, Y.

Y. Jia, W. Lü, N. Guo, W. Lü, Q. Zhao, and H. You, “Realization of color hue tuning via efficient Tb3+-Mn2+ energy transfer in Sr3Tb(PO4)3:Mn2+, a potential near-UV excited phosphor for white LEDs,” Phys. Chem. Chem. Phys. 15(16), 6057–6062 (2013).
[Crossref] [PubMed]

Jia, Y. C.

N. Guo, Y. H. Zheng, Y. C. Jia, H. Qiao, and H. P. You, “Warm-White-Emitting from Eu2+/Mn2+-Codoped Sr3Lu(PO4)3 Phosphor with Tunable Color Tone and Correlated Color Temperature,” J. Phys. Chem. C 116(1), 1329–1334 (2012).
[Crossref]

N. Guo, Y. H. Zheng, Y. C. Jia, H. Qiao, and H. P. You, “A tunable warm-white-light Sr3Gd(PO4)3:Eu2+,Mn2+ phosphor system for LED-based solid-state lighting,” New J. Chem. 36(1), 168–172 (2012).
[Crossref]

Y. C. Jia, Y. J. Huang, Y. H. Zheng, N. Guo, H. Qiao, Q. Zhao, W. Z. Lv, and H. P. You, “Color point tuning of Y3Al5O12:Ce3+ phosphor via Mn2+-Si4+ incorporation for white light generation,” J. Mater. Chem. 22(30), 15146–15152 (2012).
[Crossref]

Kim, G. C.

J. S. Kim, P. E. Jeon, J. C. Choi, H. L. Park, S. I. Mho, and G. C. Kim, “Warm-white-light emitting diode utilizing a single-phase full-color Ba3MgSi2O8:Eu2+, Mn2+ phosphor,” Appl. Phys. Lett. 84(15), 2931–2934 (2004).
[Crossref]

J. S. Kim, P. E. Jeon, Y. H. Park, J. C. Choi, H. L. Park, G. C. Kim, and T. W. Kim, “White-light generation through ultraviolet-emitting diode and white-emitting phosphor,” Appl. Phys. Lett. 85(17), 3696–3698 (2004).
[Crossref]

Kim, J. S.

J. S. Kim, P. E. Jeon, Y. H. Park, J. C. Choi, H. L. Park, G. C. Kim, and T. W. Kim, “White-light generation through ultraviolet-emitting diode and white-emitting phosphor,” Appl. Phys. Lett. 85(17), 3696–3698 (2004).
[Crossref]

J. S. Kim, P. E. Jeon, J. C. Choi, H. L. Park, S. I. Mho, and G. C. Kim, “Warm-white-light emitting diode utilizing a single-phase full-color Ba3MgSi2O8:Eu2+, Mn2+ phosphor,” Appl. Phys. Lett. 84(15), 2931–2934 (2004).
[Crossref]

Kim, T. W.

J. S. Kim, P. E. Jeon, Y. H. Park, J. C. Choi, H. L. Park, G. C. Kim, and T. W. Kim, “White-light generation through ultraviolet-emitting diode and white-emitting phosphor,” Appl. Phys. Lett. 85(17), 3696–3698 (2004).
[Crossref]

Kirakosyan, A.

Kong, Y. F.

Kuo, T. W.

T. W. Kuo and T. M. Chen, “A Green-Emitting Phosphor Sr3La(PO4)3:Ce3+,Tb3+ with Efficient Energy Transfer for Fluorescent Lamp,” J. Electrochem. Soc. 157(6), J216–J220 (2010).
[Crossref]

Lee, G. Y.

Lee, H. S.

H. Y. Li, H. K. Yang, B. K. Moon, B. C. Choi, J. H. Jeong, K. Jang, H. S. Lee, and S. S. Yi, “Tunable photoluminescence properties of Eu(II)-and Sm(III)-coactivated Ca9Y(PO4)7 and energy transfer between Eu(II) and Sm(III),” Opt. Express 2(4), 443–451 (2012).
[Crossref]

Lee, J. S.

Y. H. Won, H. S. Jang, W. B. Im, D. Y. Jeon, and J. S. Lee, “Tunable full-color-emitting La0.827Al11.9O19.09:Eu2+,Mn2+ phosphor for application to warm white-light-emitting diodes,” Appl. Phys. Lett. 89(23), 231909 (2006).
[Crossref]

Li, G. G.

D. L. Geng, G. G. Li, M. M. Shang, D. M. Yang, Y. Zhang, Z. Y. Cheng, and J. Lin, “Color tuning via energy transfer in Sr3In(PO4)3:Ce3+/Tb3+/Mn2+ phosphors,” J. Mater. Chem. 22(28), 14262–14271 (2012).
[Crossref]

Li, H. Y.

H. Y. Li, H. K. Yang, B. K. Moon, B. C. Choi, J. H. Jeong, K. Jang, H. S. Lee, and S. S. Yi, “Tunable photoluminescence properties of Eu(II)-and Sm(III)-coactivated Ca9Y(PO4)7 and energy transfer between Eu(II) and Sm(III),” Opt. Express 2(4), 443–451 (2012).
[Crossref]

Li, P. L.

Z. J. Wang, S. Q. Lou, and P. L. Li, “Enhanced orange–red emission of Sr3La(PO4)3:Ce3+, Mn2+ via energy transfer,” J. Lumin. 156, 87–90 (2014).
[Crossref]

Z. J. Wang, S. Q. Lou, and P. L. Li, “Luminescent properties and energy transfer of Sr3La(PO4)3:Sm3+, Eu3+ for white LEDs,” J. Alloys Compd. 586, 536–541 (2014).
[Crossref]

P. L. Li, Z. J. Wang, Z. P. Yang, and Q. L. Guo, “Energy Transfer between Activators at Different crystallographic Sites in Sr3La(PO4)3,” J. Electrochem. Soc. 159(3), H307–H311 (2012).
[Crossref]

Liang, H.

Lin, J.

D. L. Geng, G. G. Li, M. M. Shang, D. M. Yang, Y. Zhang, Z. Y. Cheng, and J. Lin, “Color tuning via energy transfer in Sr3In(PO4)3:Ce3+/Tb3+/Mn2+ phosphors,” J. Mater. Chem. 22(28), 14262–14271 (2012).
[Crossref]

Liu, G.

Y. Liu, G. Liu, J. Wang, X. Dong, and W. Yu, “Single-Component and Warm-White-Emitting Phosphor NaGd(WO4)2:Tm3+, Dy3+, Eu3+: Synthesis, Luminescence, Energy Transfer, and Tunable Color,” Inorg. Chem. 53(21), 11457–11466 (2014).
[Crossref] [PubMed]

Liu, R.

Z. Xia and R. Liu, “Tunable Blue-Green Color Emission and Energy Transfer of Ca2Al3O6F:Ce3+,Tb3+ Phosphors for Near-UV White LEDs,” J. Phys. Chem. C 116(29), 15604–15609 (2012).
[Crossref]

Liu, Y.

Y. Liu, G. Liu, J. Wang, X. Dong, and W. Yu, “Single-Component and Warm-White-Emitting Phosphor NaGd(WO4)2:Tm3+, Dy3+, Eu3+: Synthesis, Luminescence, Energy Transfer, and Tunable Color,” Inorg. Chem. 53(21), 11457–11466 (2014).
[Crossref] [PubMed]

Lou, S. Q.

Z. J. Wang, S. Q. Lou, and P. L. Li, “Luminescent properties and energy transfer of Sr3La(PO4)3:Sm3+, Eu3+ for white LEDs,” J. Alloys Compd. 586, 536–541 (2014).
[Crossref]

Z. J. Wang, S. Q. Lou, and P. L. Li, “Enhanced orange–red emission of Sr3La(PO4)3:Ce3+, Mn2+ via energy transfer,” J. Lumin. 156, 87–90 (2014).
[Crossref]

Lü, W.

Y. Jia, W. Lü, N. Guo, W. Lü, Q. Zhao, and H. You, “Realization of color hue tuning via efficient Tb3+-Mn2+ energy transfer in Sr3Tb(PO4)3:Mn2+, a potential near-UV excited phosphor for white LEDs,” Phys. Chem. Chem. Phys. 15(16), 6057–6062 (2013).
[Crossref] [PubMed]

Y. Jia, W. Lü, N. Guo, W. Lü, Q. Zhao, and H. You, “Realization of color hue tuning via efficient Tb3+-Mn2+ energy transfer in Sr3Tb(PO4)3:Mn2+, a potential near-UV excited phosphor for white LEDs,” Phys. Chem. Chem. Phys. 15(16), 6057–6062 (2013).
[Crossref] [PubMed]

Luo, L.

W. J. Yang, L. Luo, T. M. Chen, and N. S. Wang, “Luminescence and Energy Transfer of Eu- and Mn-Coactivated CaAl2Si2O8 as a Potential Phosphor for White-Light UVLED,” Chem. Mater. 17(15), 3883–3888 (2005).
[Crossref]

Lv, W. Z.

Y. C. Jia, Y. J. Huang, Y. H. Zheng, N. Guo, H. Qiao, Q. Zhao, W. Z. Lv, and H. P. You, “Color point tuning of Y3Al5O12:Ce3+ phosphor via Mn2+-Si4+ incorporation for white light generation,” J. Mater. Chem. 22(30), 15146–15152 (2012).
[Crossref]

Machida, K.

X. Piao, T. Horikawa, H. Hanzawa, and K. Machida, “Characterization and luminescence properties of Sr2Si5N8: Eu phosphor for white light-emitting-diode illumination,” Appl. Phys. Lett. 88(16), 161908 (2006).
[Crossref]

Mho, S. I.

J. S. Kim, P. E. Jeon, J. C. Choi, H. L. Park, S. I. Mho, and G. C. Kim, “Warm-white-light emitting diode utilizing a single-phase full-color Ba3MgSi2O8:Eu2+, Mn2+ phosphor,” Appl. Phys. Lett. 84(15), 2931–2934 (2004).
[Crossref]

Moon, B. K.

L. Wang, H. M. Noh, B. K. Moon, S. H. Park, J. H. Jeong, and J. Shi, “Simultaneous realization of two approaches to white light in single-component phosphors,” Opt. Express 22(21), 25500–25505 (2014).
[Crossref] [PubMed]

H. Y. Li, H. K. Yang, B. K. Moon, B. C. Choi, J. H. Jeong, K. Jang, H. S. Lee, and S. S. Yi, “Tunable photoluminescence properties of Eu(II)-and Sm(III)-coactivated Ca9Y(PO4)7 and energy transfer between Eu(II) and Sm(III),” Opt. Express 2(4), 443–451 (2012).
[Crossref]

Noh, H. M.

Pang, Q.

X. G. Zhang, P. He, L. Y. Zhou, Q. Pang, J. X. Shi, and M. L. Gong, “Sr3La(PO4)3: Eu2+, Mn2+: a single-phased color-tunable phosphor and its energy transfer behavior,” J. Lumin. 157, 352–356 (2015).
[Crossref]

Park, H. L.

J. S. Kim, P. E. Jeon, Y. H. Park, J. C. Choi, H. L. Park, G. C. Kim, and T. W. Kim, “White-light generation through ultraviolet-emitting diode and white-emitting phosphor,” Appl. Phys. Lett. 85(17), 3696–3698 (2004).
[Crossref]

J. S. Kim, P. E. Jeon, J. C. Choi, H. L. Park, S. I. Mho, and G. C. Kim, “Warm-white-light emitting diode utilizing a single-phase full-color Ba3MgSi2O8:Eu2+, Mn2+ phosphor,” Appl. Phys. Lett. 84(15), 2931–2934 (2004).
[Crossref]

Park, S. H.

Park, Y. H.

J. S. Kim, P. E. Jeon, Y. H. Park, J. C. Choi, H. L. Park, G. C. Kim, and T. W. Kim, “White-light generation through ultraviolet-emitting diode and white-emitting phosphor,” Appl. Phys. Lett. 85(17), 3696–3698 (2004).
[Crossref]

Piao, X.

X. Piao, T. Horikawa, H. Hanzawa, and K. Machida, “Characterization and luminescence properties of Sr2Si5N8: Eu phosphor for white light-emitting-diode illumination,” Appl. Phys. Lett. 88(16), 161908 (2006).
[Crossref]

Qiao, H.

Y. C. Jia, Y. J. Huang, Y. H. Zheng, N. Guo, H. Qiao, Q. Zhao, W. Z. Lv, and H. P. You, “Color point tuning of Y3Al5O12:Ce3+ phosphor via Mn2+-Si4+ incorporation for white light generation,” J. Mater. Chem. 22(30), 15146–15152 (2012).
[Crossref]

N. Guo, Y. H. Zheng, Y. C. Jia, H. Qiao, and H. P. You, “Warm-White-Emitting from Eu2+/Mn2+-Codoped Sr3Lu(PO4)3 Phosphor with Tunable Color Tone and Correlated Color Temperature,” J. Phys. Chem. C 116(1), 1329–1334 (2012).
[Crossref]

N. Guo, Y. H. Zheng, Y. C. Jia, H. Qiao, and H. P. You, “A tunable warm-white-light Sr3Gd(PO4)3:Eu2+,Mn2+ phosphor system for LED-based solid-state lighting,” New J. Chem. 36(1), 168–172 (2012).
[Crossref]

Shang, M. M.

D. L. Geng, G. G. Li, M. M. Shang, D. M. Yang, Y. Zhang, Z. Y. Cheng, and J. Lin, “Color tuning via energy transfer in Sr3In(PO4)3:Ce3+/Tb3+/Mn2+ phosphors,” J. Mater. Chem. 22(28), 14262–14271 (2012).
[Crossref]

Shi, J.

L. Wang, H. M. Noh, B. K. Moon, S. H. Park, J. H. Jeong, and J. Shi, “Simultaneous realization of two approaches to white light in single-component phosphors,” Opt. Express 22(21), 25500–25505 (2014).
[Crossref] [PubMed]

X. Zhang, F. Zhou, J. Shi, and M. Gong, “Sr3.5Mg0.5Si3O8Cl4: Eu2+ bluish–green-emitting phosphor for NUV-based LED,” Mater. Lett. 63(11), 852–854 (2009).
[Crossref]

Shi, J. X.

X. G. Zhang, P. He, L. Y. Zhou, Q. Pang, J. X. Shi, and M. L. Gong, “Sr3La(PO4)3: Eu2+, Mn2+: a single-phased color-tunable phosphor and its energy transfer behavior,” J. Lumin. 157, 352–356 (2015).
[Crossref]

Shi, Y. R.

Shin, D. S.

V. R. Bandi, B. K. Grandhe, K. Jang, D. S. Shin, S. S. Yi, and J. H. Jeong, “An investigation on photoluminescence and energy transfer of Eu3+/Sm3+ single-doped and co-doped Ca4YO(BO3)3 phosphors,” Mater. Chem. Phys. 140(2-3), 453–457 (2013).
[Crossref]

Su, Q.

Tao, Y.

Wang, H. R.

Wang, J.

Y. Liu, G. Liu, J. Wang, X. Dong, and W. Yu, “Single-Component and Warm-White-Emitting Phosphor NaGd(WO4)2:Tm3+, Dy3+, Eu3+: Synthesis, Luminescence, Energy Transfer, and Tunable Color,” Inorg. Chem. 53(21), 11457–11466 (2014).
[Crossref] [PubMed]

Wang, L.

Wang, N. S.

W. J. Yang, L. Luo, T. M. Chen, and N. S. Wang, “Luminescence and Energy Transfer of Eu- and Mn-Coactivated CaAl2Si2O8 as a Potential Phosphor for White-Light UVLED,” Chem. Mater. 17(15), 3883–3888 (2005).
[Crossref]

Wang, Q.

Wang, Y. H.

Wang, Z. J.

Z. J. Wang, S. Q. Lou, and P. L. Li, “Enhanced orange–red emission of Sr3La(PO4)3:Ce3+, Mn2+ via energy transfer,” J. Lumin. 156, 87–90 (2014).
[Crossref]

Z. J. Wang, S. Q. Lou, and P. L. Li, “Luminescent properties and energy transfer of Sr3La(PO4)3:Sm3+, Eu3+ for white LEDs,” J. Alloys Compd. 586, 536–541 (2014).
[Crossref]

P. L. Li, Z. J. Wang, Z. P. Yang, and Q. L. Guo, “Energy Transfer between Activators at Different crystallographic Sites in Sr3La(PO4)3,” J. Electrochem. Soc. 159(3), H307–H311 (2012).
[Crossref]

Won, Y. H.

Y. H. Won, H. S. Jang, W. B. Im, D. Y. Jeon, and J. S. Lee, “Tunable full-color-emitting La0.827Al11.9O19.09:Eu2+,Mn2+ phosphor for application to warm white-light-emitting diodes,” Appl. Phys. Lett. 89(23), 231909 (2006).
[Crossref]

Wu, L.

Xia, Z.

Z. Xia and R. Liu, “Tunable Blue-Green Color Emission and Energy Transfer of Ca2Al3O6F:Ce3+,Tb3+ Phosphors for Near-UV White LEDs,” J. Phys. Chem. C 116(29), 15604–15609 (2012).
[Crossref]

Xiao, F.

F. Xiao, Y. N. Xue, and Q. Y. Zhang, “Warm white light from Y4MgSi3O13:Bi3+, Eu3+ nanophosphor for white light-emitting diodes,” Spectrochim. Acta A Mol. Biomol. Spectrosc. 74(2), 498–501 (2009).
[Crossref] [PubMed]

Xie, M.

Xie, R. J.

R. J. Xie and N. Hirosaki, “Silicon-based oxynitride and nitride phosphors for white LEDs-A review,” Sci. Technol. Adv. Mater. 8(7–8), 588–600 (2007).
[Crossref]

Xue, Y. N.

F. Xiao, Y. N. Xue, and Q. Y. Zhang, “Warm white light from Y4MgSi3O13:Bi3+, Eu3+ nanophosphor for white light-emitting diodes,” Spectrochim. Acta A Mol. Biomol. Spectrosc. 74(2), 498–501 (2009).
[Crossref] [PubMed]

Yang, D. M.

D. L. Geng, G. G. Li, M. M. Shang, D. M. Yang, Y. Zhang, Z. Y. Cheng, and J. Lin, “Color tuning via energy transfer in Sr3In(PO4)3:Ce3+/Tb3+/Mn2+ phosphors,” J. Mater. Chem. 22(28), 14262–14271 (2012).
[Crossref]

Yang, H. K.

H. Y. Li, H. K. Yang, B. K. Moon, B. C. Choi, J. H. Jeong, K. Jang, H. S. Lee, and S. S. Yi, “Tunable photoluminescence properties of Eu(II)-and Sm(III)-coactivated Ca9Y(PO4)7 and energy transfer between Eu(II) and Sm(III),” Opt. Express 2(4), 443–451 (2012).
[Crossref]

Yang, W. J.

W. J. Yang, L. Luo, T. M. Chen, and N. S. Wang, “Luminescence and Energy Transfer of Eu- and Mn-Coactivated CaAl2Si2O8 as a Potential Phosphor for White-Light UVLED,” Chem. Mater. 17(15), 3883–3888 (2005).
[Crossref]

Yang, Z. P.

P. L. Li, Z. J. Wang, Z. P. Yang, and Q. L. Guo, “Energy Transfer between Activators at Different crystallographic Sites in Sr3La(PO4)3,” J. Electrochem. Soc. 159(3), H307–H311 (2012).
[Crossref]

Yi, S. S.

V. R. Bandi, B. K. Grandhe, K. Jang, D. S. Shin, S. S. Yi, and J. H. Jeong, “An investigation on photoluminescence and energy transfer of Eu3+/Sm3+ single-doped and co-doped Ca4YO(BO3)3 phosphors,” Mater. Chem. Phys. 140(2-3), 453–457 (2013).
[Crossref]

H. Y. Li, H. K. Yang, B. K. Moon, B. C. Choi, J. H. Jeong, K. Jang, H. S. Lee, and S. S. Yi, “Tunable photoluminescence properties of Eu(II)-and Sm(III)-coactivated Ca9Y(PO4)7 and energy transfer between Eu(II) and Sm(III),” Opt. Express 2(4), 443–451 (2012).
[Crossref]

You, H.

Y. Jia, W. Lü, N. Guo, W. Lü, Q. Zhao, and H. You, “Realization of color hue tuning via efficient Tb3+-Mn2+ energy transfer in Sr3Tb(PO4)3:Mn2+, a potential near-UV excited phosphor for white LEDs,” Phys. Chem. Chem. Phys. 15(16), 6057–6062 (2013).
[Crossref] [PubMed]

You, H. P.

N. Guo, Y. H. Zheng, Y. C. Jia, H. Qiao, and H. P. You, “A tunable warm-white-light Sr3Gd(PO4)3:Eu2+,Mn2+ phosphor system for LED-based solid-state lighting,” New J. Chem. 36(1), 168–172 (2012).
[Crossref]

N. Guo, Y. H. Zheng, Y. C. Jia, H. Qiao, and H. P. You, “Warm-White-Emitting from Eu2+/Mn2+-Codoped Sr3Lu(PO4)3 Phosphor with Tunable Color Tone and Correlated Color Temperature,” J. Phys. Chem. C 116(1), 1329–1334 (2012).
[Crossref]

Y. C. Jia, Y. J. Huang, Y. H. Zheng, N. Guo, H. Qiao, Q. Zhao, W. Z. Lv, and H. P. You, “Color point tuning of Y3Al5O12:Ce3+ phosphor via Mn2+-Si4+ incorporation for white light generation,” J. Mater. Chem. 22(30), 15146–15152 (2012).
[Crossref]

Yu, W.

Y. Liu, G. Liu, J. Wang, X. Dong, and W. Yu, “Single-Component and Warm-White-Emitting Phosphor NaGd(WO4)2:Tm3+, Dy3+, Eu3+: Synthesis, Luminescence, Energy Transfer, and Tunable Color,” Inorg. Chem. 53(21), 11457–11466 (2014).
[Crossref] [PubMed]

Zhang, Q. Y.

F. Xiao, Y. N. Xue, and Q. Y. Zhang, “Warm white light from Y4MgSi3O13:Bi3+, Eu3+ nanophosphor for white light-emitting diodes,” Spectrochim. Acta A Mol. Biomol. Spectrosc. 74(2), 498–501 (2009).
[Crossref] [PubMed]

Zhang, X.

X. Zhang, F. Zhou, J. Shi, and M. Gong, “Sr3.5Mg0.5Si3O8Cl4: Eu2+ bluish–green-emitting phosphor for NUV-based LED,” Mater. Lett. 63(11), 852–854 (2009).
[Crossref]

Zhang, X. G.

X. G. Zhang, P. He, L. Y. Zhou, Q. Pang, J. X. Shi, and M. L. Gong, “Sr3La(PO4)3: Eu2+, Mn2+: a single-phased color-tunable phosphor and its energy transfer behavior,” J. Lumin. 157, 352–356 (2015).
[Crossref]

Zhang, Y.

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Y. Jia, W. Lü, N. Guo, W. Lü, Q. Zhao, and H. You, “Realization of color hue tuning via efficient Tb3+-Mn2+ energy transfer in Sr3Tb(PO4)3:Mn2+, a potential near-UV excited phosphor for white LEDs,” Phys. Chem. Chem. Phys. 15(16), 6057–6062 (2013).
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P. L. Li, Z. J. Wang, Z. P. Yang, and Q. L. Guo, “Energy Transfer between Activators at Different crystallographic Sites in Sr3La(PO4)3,” J. Electrochem. Soc. 159(3), H307–H311 (2012).
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Z. J. Wang, S. Q. Lou, and P. L. Li, “Enhanced orange–red emission of Sr3La(PO4)3:Ce3+, Mn2+ via energy transfer,” J. Lumin. 156, 87–90 (2014).
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[Crossref]

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D. L. Geng, G. G. Li, M. M. Shang, D. M. Yang, Y. Zhang, Z. Y. Cheng, and J. Lin, “Color tuning via energy transfer in Sr3In(PO4)3:Ce3+/Tb3+/Mn2+ phosphors,” J. Mater. Chem. 22(28), 14262–14271 (2012).
[Crossref]

Y. C. Jia, Y. J. Huang, Y. H. Zheng, N. Guo, H. Qiao, Q. Zhao, W. Z. Lv, and H. P. You, “Color point tuning of Y3Al5O12:Ce3+ phosphor via Mn2+-Si4+ incorporation for white light generation,” J. Mater. Chem. 22(30), 15146–15152 (2012).
[Crossref]

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N. Guo, Y. H. Zheng, Y. C. Jia, H. Qiao, and H. P. You, “Warm-White-Emitting from Eu2+/Mn2+-Codoped Sr3Lu(PO4)3 Phosphor with Tunable Color Tone and Correlated Color Temperature,” J. Phys. Chem. C 116(1), 1329–1334 (2012).
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X. Zhang, F. Zhou, J. Shi, and M. Gong, “Sr3.5Mg0.5Si3O8Cl4: Eu2+ bluish–green-emitting phosphor for NUV-based LED,” Mater. Lett. 63(11), 852–854 (2009).
[Crossref]

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N. Guo, Y. H. Zheng, Y. C. Jia, H. Qiao, and H. P. You, “A tunable warm-white-light Sr3Gd(PO4)3:Eu2+,Mn2+ phosphor system for LED-based solid-state lighting,” New J. Chem. 36(1), 168–172 (2012).
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Y. Jia, W. Lü, N. Guo, W. Lü, Q. Zhao, and H. You, “Realization of color hue tuning via efficient Tb3+-Mn2+ energy transfer in Sr3Tb(PO4)3:Mn2+, a potential near-UV excited phosphor for white LEDs,” Phys. Chem. Chem. Phys. 15(16), 6057–6062 (2013).
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Figures (9)

Fig. 1
Fig. 1 XRD patterns of SLP:3%Eu2+, ySm3+ (y = 0-15%) with the standard data of Sr3La(PO4)3 (JCPDS) No. 29-1306.
Fig. 2
Fig. 2 Three-dimensional view of Sr3La(PO4)3 eulytite structure.
Fig. 3
Fig. 3 Emission and excitation spectra of SLP:3%Eu2+ (a), and SLP:3%Sm3+ (b), and SLP:3%Eu2+, 3%Sm3+ (c).
Fig. 4
Fig. 4 Emission spectra of SLP:3%Eu2+, ySm3+ (y = 0-15%) (λex = 375 nm).
Fig. 5
Fig. 5 Decay curves of Eu2+ emission monitored at 421 nm for SLP:3%Eu2+, ySm3+ (y = 0-15%) phosphors under excitation at 320 nm.
Fig. 6
Fig. 6 Decay curves of Sm3+ emission monitored at 600 nm for SLP:3%Eu2+, ySm3+ (y = 1-15%) phosphors under excitation at 401 nm.
Fig. 7
Fig. 7 Dependence of emission intensity of SLP:ySm3+ and SLP:3%Eu2+, ySm3+ (y = 0-15%) under the 375nm excitation on Sm3+ concentration (y).
Fig. 8
Fig. 8 Energy level diagrams of Eu2+ and Sm3+ showing the energy transfer process from Eu2+ to Sm3+.
Fig. 9
Fig. 9 The CIE chromaticity coordinates of SLP:3%Eu2+,ySm3+ (y = 0-15%) (λex = 365 nm). The corresponding luminescence photos of SLP:3%Eu2+, ySm3+ (y = 0-15%) and SLP: 5%Sm3+ex = 365 nm).

Tables (1)

Tables Icon

Table 1 A comparison of CIE Chromaticity Coordinates (x, y), CCT (k) and EQE for SLP:3%Eu2+, ySm3+ phosphors (λex = 365 nm).

Equations (7)

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I= I 0 + A 1 exp( t/ τ 1 )+ A 2 exp( t/ τ 2 )
τ * =( A 1 τ 1 2 + A 2 τ 2 2 )/( A 1 τ 1 + A 2 τ 2 )
K tot = K F + K q = τ Eu 1
K tot = K F + K q + K ET = τ Eu,Sm 1
I= I 0 exp( t/τ )
K tot = K F + K q = τ Sm 1
R EuSm =2 [ 3V/( 4πCN ) ] 1 3

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