Abstract

The linear and nonlinear optical properties of a new quaternary tungstate tellurite crystal Na2TeW2O9 (NTW) are reported. It transmits well from 0.45 to 5 μm. The refractive indices have been measured and the crystal exhibits flexible phase-matching properties. The complete set of second-order nonlinear optical coefficients were obtained using Maker Fringe techniques, with the largest d13 = 9.3 pm/V. The crystal supports noncritical phase-matching (θ = 90°, φ = ± 48.6°), at the incident wavelength of 1064 nm, the effective nonlinear coefficient (deff) is 6.9 pm/V. The crystal structure and calculations of the dipole moment are discussed to explain the second-harmonic generation of NTW compared with Cs2TeMo3O12. Considering its good linear and nonlinear optical properties, NTW is a good candidate for nonlinear optical applications, especially for 3-5 μm region.

© 2015 Optical Society of America

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References

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2014 (1)

I. Chung and M. G. Kanatzidis, “Metal chalcogenides: a rich source of nonlinear optical materials,” Chem. Mater. 26(1), 849–869 (2014).
[Crossref]

2012 (3)

S. C. Kumar, M. Jelínek, M. Baudisch, K. T. Zawilski, P. G. Schunemann, V. Kubeček, J. Biegert, and M. Ebrahim-Zadeh, “Tunable, high-energy, mid-infrared, picosecond optical parametric generator based on CdSiP2,” Opt. Express 20(14), 15703–15709 (2012).
[Crossref] [PubMed]

W. Zhang, J. Sun, X. Wang, G. Shen, and D. Shen, “Crystal growth and optical properties of a noncentrosymmetric molybdenum tellurite, Na2Te3Mo3O16,” CrystEngComm 14(10), 3490–3494 (2012).
[Crossref]

Q. Yu, Z. Gao, S. Zhang, W. Zhang, S. Wang, and X. Tao, “Second order nonlinear properties of monoclinic single crystal BaTeMo2O9,” J. Appl. Phys. 111(1), 013506 (2012).
[Crossref]

2011 (2)

W. Zhang, P. S. Halasyamani, Z. Gao, S. Wang, J. Wang, and X. Tao, “Anisotropic Thermal Properties of the Nonlinear Optical and Polar,” Cryst. Growth Des. 11(8), 3636–3641 (2011).
[Crossref]

J. Zhang, X. Tao, Y. Sun, Z. Zhang, C. Zhang, Z. Gao, H. Xia, and S. Xia, “Top-Seeded Solution Growth, Morphology, and Properties of a Polar Crystal Cs2TeMo3O12,” Cryst. Growth Des. 11(5), 1863–1868 (2011).
[Crossref]

2010 (1)

W. Zhang, F. Li, S. H. Kim, and P. S. Halasyamani, “Top-seeded solution crystal growth and functional properties of a polar material-Na2TeW2O9,” Cryst. Growth Des. 10(9), 4091–4095 (2010).
[Crossref]

2008 (2)

E. Lippert, G. Rustad, G. Arisholm, and K. Stenersen, “High power and efficient long wave IR ZnGeP2 parametric oscillator,” Opt. Express 16(18), 13878–13884 (2008).
[Crossref] [PubMed]

W. Zhang, X. Tao, C. Zhang, Z. Gao, Y. Zhang, W. Yu, X. Cheng, X. Liu, and M. Jiang, “Bulk Growth and Characterization of a Novel Nonlinear Optical Crystal BaTeMo2O9,” Cryst. Growth Des. 8(1), 304–307 (2008).
[Crossref]

2007 (1)

2006 (2)

K. M. Ok, P. S. Halasyamani, D. Casanova, M. Llunell, P. Alemany, and S. Alvarez, “Distortions in octahedrally coordinated d0 transition metal oxides: A continuous symmetry measures approach,” Chem. Mater. 18(14), 3176–3183 (2006).
[Crossref]

T. J. Wang, Z. H. Kang, H. Z. Zhang, Q. Y. He, Y. Qu, Z. S. Feng, Y. Jiang, J. Y. Gao, Y. M. Andreev, and G. V. Lanskii, “Wide-tunable, high-energy AgGaS2 optical parametric oscillator,” Opt. Express 14(26), 13001–13006 (2006).
[Crossref] [PubMed]

2005 (1)

K. M. Ok and P. S. Halasyamani, “Mixed-metal tellurites: Synthesis, structure, and characterization of Na1.4Nb3Te4.9O18 and NaNb3Te4O16.,” Inorg. Chem. 44(11), 3919–3925 (2005).
[Crossref] [PubMed]

2004 (2)

M. Ghotbi and M. Ebrahim-Zadeh, “Optical second harmonic generation properties of BiB3O6.,” Opt. Express 12(24), 6002–6019 (2004).
[Crossref] [PubMed]

P. S. Halasyamani, “Asymmetric cation coordination in oxide materials: Influence of lone-Pair cations on the intra-octahedral distortion in d0 transition metals,” Chem. Mater. 16(19), 3586–3592 (2004).
[Crossref]

2002 (1)

J. Goodey, J. Broussard, and P. S. Halasyamani, “Synthesis, structure, and characterization of a new second-harmonic-generating tellurite: Na2TeW2O9,” Chem. Mater. 14(7), 3174–3180 (2002).
[Crossref]

2001 (1)

1989 (2)

S. X. Dou, M. H. Jiang, Z. S. Shao, and X. T. Tao, “Maker fringes in biaxial crystals and the nonlinear optical coefficients of thiosemicarbazide cadmium chloride monohydrate,” Appl. Phys. Lett. 54(12), 1101–1103 (1989).
[Crossref]

C. Chen, Y. Wu, and R. Li, “The anionic group theory of the non-linear optical effect and its applications in the development of new high-quality NLO crystals in the borate series,” Int. Rev. Phys. Chem. 8(1), 65–91 (1989).
[Crossref]

Alemany, P.

K. M. Ok, P. S. Halasyamani, D. Casanova, M. Llunell, P. Alemany, and S. Alvarez, “Distortions in octahedrally coordinated d0 transition metal oxides: A continuous symmetry measures approach,” Chem. Mater. 18(14), 3176–3183 (2006).
[Crossref]

Alvarez, S.

K. M. Ok, P. S. Halasyamani, D. Casanova, M. Llunell, P. Alemany, and S. Alvarez, “Distortions in octahedrally coordinated d0 transition metal oxides: A continuous symmetry measures approach,” Chem. Mater. 18(14), 3176–3183 (2006).
[Crossref]

Andreev, Y. M.

Arisholm, G.

Baudisch, M.

Biegert, J.

Broussard, J.

J. Goodey, J. Broussard, and P. S. Halasyamani, “Synthesis, structure, and characterization of a new second-harmonic-generating tellurite: Na2TeW2O9,” Chem. Mater. 14(7), 3174–3180 (2002).
[Crossref]

Casanova, D.

K. M. Ok, P. S. Halasyamani, D. Casanova, M. Llunell, P. Alemany, and S. Alvarez, “Distortions in octahedrally coordinated d0 transition metal oxides: A continuous symmetry measures approach,” Chem. Mater. 18(14), 3176–3183 (2006).
[Crossref]

Chen, C.

C. Chen, Y. Wu, and R. Li, “The anionic group theory of the non-linear optical effect and its applications in the development of new high-quality NLO crystals in the borate series,” Int. Rev. Phys. Chem. 8(1), 65–91 (1989).
[Crossref]

Chen, C. T.

Cheng, X.

W. Zhang, X. Tao, C. Zhang, Z. Gao, Y. Zhang, W. Yu, X. Cheng, X. Liu, and M. Jiang, “Bulk Growth and Characterization of a Novel Nonlinear Optical Crystal BaTeMo2O9,” Cryst. Growth Des. 8(1), 304–307 (2008).
[Crossref]

Chung, I.

I. Chung and M. G. Kanatzidis, “Metal chalcogenides: a rich source of nonlinear optical materials,” Chem. Mater. 26(1), 849–869 (2014).
[Crossref]

Dou, S. X.

S. X. Dou, M. H. Jiang, Z. S. Shao, and X. T. Tao, “Maker fringes in biaxial crystals and the nonlinear optical coefficients of thiosemicarbazide cadmium chloride monohydrate,” Appl. Phys. Lett. 54(12), 1101–1103 (1989).
[Crossref]

Ebrahim-Zadeh, M.

Feng, Z. S.

Gao, J. Y.

Gao, Z.

Q. Yu, Z. Gao, S. Zhang, W. Zhang, S. Wang, and X. Tao, “Second order nonlinear properties of monoclinic single crystal BaTeMo2O9,” J. Appl. Phys. 111(1), 013506 (2012).
[Crossref]

J. Zhang, X. Tao, Y. Sun, Z. Zhang, C. Zhang, Z. Gao, H. Xia, and S. Xia, “Top-Seeded Solution Growth, Morphology, and Properties of a Polar Crystal Cs2TeMo3O12,” Cryst. Growth Des. 11(5), 1863–1868 (2011).
[Crossref]

W. Zhang, P. S. Halasyamani, Z. Gao, S. Wang, J. Wang, and X. Tao, “Anisotropic Thermal Properties of the Nonlinear Optical and Polar,” Cryst. Growth Des. 11(8), 3636–3641 (2011).
[Crossref]

W. Zhang, X. Tao, C. Zhang, Z. Gao, Y. Zhang, W. Yu, X. Cheng, X. Liu, and M. Jiang, “Bulk Growth and Characterization of a Novel Nonlinear Optical Crystal BaTeMo2O9,” Cryst. Growth Des. 8(1), 304–307 (2008).
[Crossref]

Ghotbi, M.

Goodey, J.

J. Goodey, J. Broussard, and P. S. Halasyamani, “Synthesis, structure, and characterization of a new second-harmonic-generating tellurite: Na2TeW2O9,” Chem. Mater. 14(7), 3174–3180 (2002).
[Crossref]

Halasyamani, P. S.

W. Zhang, P. S. Halasyamani, Z. Gao, S. Wang, J. Wang, and X. Tao, “Anisotropic Thermal Properties of the Nonlinear Optical and Polar,” Cryst. Growth Des. 11(8), 3636–3641 (2011).
[Crossref]

W. Zhang, F. Li, S. H. Kim, and P. S. Halasyamani, “Top-seeded solution crystal growth and functional properties of a polar material-Na2TeW2O9,” Cryst. Growth Des. 10(9), 4091–4095 (2010).
[Crossref]

K. M. Ok, P. S. Halasyamani, D. Casanova, M. Llunell, P. Alemany, and S. Alvarez, “Distortions in octahedrally coordinated d0 transition metal oxides: A continuous symmetry measures approach,” Chem. Mater. 18(14), 3176–3183 (2006).
[Crossref]

K. M. Ok and P. S. Halasyamani, “Mixed-metal tellurites: Synthesis, structure, and characterization of Na1.4Nb3Te4.9O18 and NaNb3Te4O16.,” Inorg. Chem. 44(11), 3919–3925 (2005).
[Crossref] [PubMed]

P. S. Halasyamani, “Asymmetric cation coordination in oxide materials: Influence of lone-Pair cations on the intra-octahedral distortion in d0 transition metals,” Chem. Mater. 16(19), 3586–3592 (2004).
[Crossref]

J. Goodey, J. Broussard, and P. S. Halasyamani, “Synthesis, structure, and characterization of a new second-harmonic-generating tellurite: Na2TeW2O9,” Chem. Mater. 14(7), 3174–3180 (2002).
[Crossref]

He, Q. Y.

Isaenko, L.

Jelínek, M.

Jiang, M.

W. Zhang, X. Tao, C. Zhang, Z. Gao, Y. Zhang, W. Yu, X. Cheng, X. Liu, and M. Jiang, “Bulk Growth and Characterization of a Novel Nonlinear Optical Crystal BaTeMo2O9,” Cryst. Growth Des. 8(1), 304–307 (2008).
[Crossref]

Jiang, M. H.

S. X. Dou, M. H. Jiang, Z. S. Shao, and X. T. Tao, “Maker fringes in biaxial crystals and the nonlinear optical coefficients of thiosemicarbazide cadmium chloride monohydrate,” Appl. Phys. Lett. 54(12), 1101–1103 (1989).
[Crossref]

Jiang, Y.

Kanatzidis, M. G.

I. Chung and M. G. Kanatzidis, “Metal chalcogenides: a rich source of nonlinear optical materials,” Chem. Mater. 26(1), 849–869 (2014).
[Crossref]

Kang, Z. H.

Kim, S. H.

W. Zhang, F. Li, S. H. Kim, and P. S. Halasyamani, “Top-seeded solution crystal growth and functional properties of a polar material-Na2TeW2O9,” Cryst. Growth Des. 10(9), 4091–4095 (2010).
[Crossref]

Knippels, G. M. H.

Kubecek, V.

Kumar, S. C.

Lanskii, G. V.

Li, F.

W. Zhang, F. Li, S. H. Kim, and P. S. Halasyamani, “Top-seeded solution crystal growth and functional properties of a polar material-Na2TeW2O9,” Cryst. Growth Des. 10(9), 4091–4095 (2010).
[Crossref]

Li, R.

C. Chen, Y. Wu, and R. Li, “The anionic group theory of the non-linear optical effect and its applications in the development of new high-quality NLO crystals in the borate series,” Int. Rev. Phys. Chem. 8(1), 65–91 (1989).
[Crossref]

Lippert, E.

Liu, X.

W. Zhang, X. Tao, C. Zhang, Z. Gao, Y. Zhang, W. Yu, X. Cheng, X. Liu, and M. Jiang, “Bulk Growth and Characterization of a Novel Nonlinear Optical Crystal BaTeMo2O9,” Cryst. Growth Des. 8(1), 304–307 (2008).
[Crossref]

Llunell, M.

K. M. Ok, P. S. Halasyamani, D. Casanova, M. Llunell, P. Alemany, and S. Alvarez, “Distortions in octahedrally coordinated d0 transition metal oxides: A continuous symmetry measures approach,” Chem. Mater. 18(14), 3176–3183 (2006).
[Crossref]

Lobanov, S.

Macleod, A. M.

Ok, K. M.

K. M. Ok, P. S. Halasyamani, D. Casanova, M. Llunell, P. Alemany, and S. Alvarez, “Distortions in octahedrally coordinated d0 transition metal oxides: A continuous symmetry measures approach,” Chem. Mater. 18(14), 3176–3183 (2006).
[Crossref]

K. M. Ok and P. S. Halasyamani, “Mixed-metal tellurites: Synthesis, structure, and characterization of Na1.4Nb3Te4.9O18 and NaNb3Te4O16.,” Inorg. Chem. 44(11), 3919–3925 (2005).
[Crossref] [PubMed]

Qu, Y.

Rustad, G.

Schunemann, P. G.

Shao, Z. S.

S. X. Dou, M. H. Jiang, Z. S. Shao, and X. T. Tao, “Maker fringes in biaxial crystals and the nonlinear optical coefficients of thiosemicarbazide cadmium chloride monohydrate,” Appl. Phys. Lett. 54(12), 1101–1103 (1989).
[Crossref]

Shen, D.

W. Zhang, J. Sun, X. Wang, G. Shen, and D. Shen, “Crystal growth and optical properties of a noncentrosymmetric molybdenum tellurite, Na2Te3Mo3O16,” CrystEngComm 14(10), 3490–3494 (2012).
[Crossref]

Shen, G.

W. Zhang, J. Sun, X. Wang, G. Shen, and D. Shen, “Crystal growth and optical properties of a noncentrosymmetric molybdenum tellurite, Na2Te3Mo3O16,” CrystEngComm 14(10), 3490–3494 (2012).
[Crossref]

Stenersen, K.

Sun, J.

W. Zhang, J. Sun, X. Wang, G. Shen, and D. Shen, “Crystal growth and optical properties of a noncentrosymmetric molybdenum tellurite, Na2Te3Mo3O16,” CrystEngComm 14(10), 3490–3494 (2012).
[Crossref]

Sun, Y.

J. Zhang, X. Tao, Y. Sun, Z. Zhang, C. Zhang, Z. Gao, H. Xia, and S. Xia, “Top-Seeded Solution Growth, Morphology, and Properties of a Polar Crystal Cs2TeMo3O12,” Cryst. Growth Des. 11(5), 1863–1868 (2011).
[Crossref]

Tao, X.

Q. Yu, Z. Gao, S. Zhang, W. Zhang, S. Wang, and X. Tao, “Second order nonlinear properties of monoclinic single crystal BaTeMo2O9,” J. Appl. Phys. 111(1), 013506 (2012).
[Crossref]

J. Zhang, X. Tao, Y. Sun, Z. Zhang, C. Zhang, Z. Gao, H. Xia, and S. Xia, “Top-Seeded Solution Growth, Morphology, and Properties of a Polar Crystal Cs2TeMo3O12,” Cryst. Growth Des. 11(5), 1863–1868 (2011).
[Crossref]

W. Zhang, P. S. Halasyamani, Z. Gao, S. Wang, J. Wang, and X. Tao, “Anisotropic Thermal Properties of the Nonlinear Optical and Polar,” Cryst. Growth Des. 11(8), 3636–3641 (2011).
[Crossref]

W. Zhang, X. Tao, C. Zhang, Z. Gao, Y. Zhang, W. Yu, X. Cheng, X. Liu, and M. Jiang, “Bulk Growth and Characterization of a Novel Nonlinear Optical Crystal BaTeMo2O9,” Cryst. Growth Des. 8(1), 304–307 (2008).
[Crossref]

Tao, X. T.

S. X. Dou, M. H. Jiang, Z. S. Shao, and X. T. Tao, “Maker fringes in biaxial crystals and the nonlinear optical coefficients of thiosemicarbazide cadmium chloride monohydrate,” Appl. Phys. Lett. 54(12), 1101–1103 (1989).
[Crossref]

Thènot, I.

van der Meer, A. F. G.

Wang, G. L.

Wang, J.

W. Zhang, P. S. Halasyamani, Z. Gao, S. Wang, J. Wang, and X. Tao, “Anisotropic Thermal Properties of the Nonlinear Optical and Polar,” Cryst. Growth Des. 11(8), 3636–3641 (2011).
[Crossref]

Wang, S.

Q. Yu, Z. Gao, S. Zhang, W. Zhang, S. Wang, and X. Tao, “Second order nonlinear properties of monoclinic single crystal BaTeMo2O9,” J. Appl. Phys. 111(1), 013506 (2012).
[Crossref]

W. Zhang, P. S. Halasyamani, Z. Gao, S. Wang, J. Wang, and X. Tao, “Anisotropic Thermal Properties of the Nonlinear Optical and Polar,” Cryst. Growth Des. 11(8), 3636–3641 (2011).
[Crossref]

Wang, T. J.

Wang, X.

W. Zhang, J. Sun, X. Wang, G. Shen, and D. Shen, “Crystal growth and optical properties of a noncentrosymmetric molybdenum tellurite, Na2Te3Mo3O16,” CrystEngComm 14(10), 3490–3494 (2012).
[Crossref]

Wang, X. A.

Wu, Y.

C. Chen, Y. Wu, and R. Li, “The anionic group theory of the non-linear optical effect and its applications in the development of new high-quality NLO crystals in the borate series,” Int. Rev. Phys. Chem. 8(1), 65–91 (1989).
[Crossref]

Wu, Y. C.

Xia, H.

J. Zhang, X. Tao, Y. Sun, Z. Zhang, C. Zhang, Z. Gao, H. Xia, and S. Xia, “Top-Seeded Solution Growth, Morphology, and Properties of a Polar Crystal Cs2TeMo3O12,” Cryst. Growth Des. 11(5), 1863–1868 (2011).
[Crossref]

Xia, S.

J. Zhang, X. Tao, Y. Sun, Z. Zhang, C. Zhang, Z. Gao, H. Xia, and S. Xia, “Top-Seeded Solution Growth, Morphology, and Properties of a Polar Crystal Cs2TeMo3O12,” Cryst. Growth Des. 11(5), 1863–1868 (2011).
[Crossref]

Yelisseyev, A.

Yu, Q.

Q. Yu, Z. Gao, S. Zhang, W. Zhang, S. Wang, and X. Tao, “Second order nonlinear properties of monoclinic single crystal BaTeMo2O9,” J. Appl. Phys. 111(1), 013506 (2012).
[Crossref]

Yu, W.

W. Zhang, X. Tao, C. Zhang, Z. Gao, Y. Zhang, W. Yu, X. Cheng, X. Liu, and M. Jiang, “Bulk Growth and Characterization of a Novel Nonlinear Optical Crystal BaTeMo2O9,” Cryst. Growth Des. 8(1), 304–307 (2008).
[Crossref]

Zawilski, K. T.

Zhang, C.

J. Zhang, X. Tao, Y. Sun, Z. Zhang, C. Zhang, Z. Gao, H. Xia, and S. Xia, “Top-Seeded Solution Growth, Morphology, and Properties of a Polar Crystal Cs2TeMo3O12,” Cryst. Growth Des. 11(5), 1863–1868 (2011).
[Crossref]

W. Zhang, X. Tao, C. Zhang, Z. Gao, Y. Zhang, W. Yu, X. Cheng, X. Liu, and M. Jiang, “Bulk Growth and Characterization of a Novel Nonlinear Optical Crystal BaTeMo2O9,” Cryst. Growth Des. 8(1), 304–307 (2008).
[Crossref]

Zhang, H. Z.

Zhang, J.

J. Zhang, X. Tao, Y. Sun, Z. Zhang, C. Zhang, Z. Gao, H. Xia, and S. Xia, “Top-Seeded Solution Growth, Morphology, and Properties of a Polar Crystal Cs2TeMo3O12,” Cryst. Growth Des. 11(5), 1863–1868 (2011).
[Crossref]

Zhang, S.

Q. Yu, Z. Gao, S. Zhang, W. Zhang, S. Wang, and X. Tao, “Second order nonlinear properties of monoclinic single crystal BaTeMo2O9,” J. Appl. Phys. 111(1), 013506 (2012).
[Crossref]

Zhang, W.

Q. Yu, Z. Gao, S. Zhang, W. Zhang, S. Wang, and X. Tao, “Second order nonlinear properties of monoclinic single crystal BaTeMo2O9,” J. Appl. Phys. 111(1), 013506 (2012).
[Crossref]

W. Zhang, J. Sun, X. Wang, G. Shen, and D. Shen, “Crystal growth and optical properties of a noncentrosymmetric molybdenum tellurite, Na2Te3Mo3O16,” CrystEngComm 14(10), 3490–3494 (2012).
[Crossref]

W. Zhang, P. S. Halasyamani, Z. Gao, S. Wang, J. Wang, and X. Tao, “Anisotropic Thermal Properties of the Nonlinear Optical and Polar,” Cryst. Growth Des. 11(8), 3636–3641 (2011).
[Crossref]

W. Zhang, F. Li, S. H. Kim, and P. S. Halasyamani, “Top-seeded solution crystal growth and functional properties of a polar material-Na2TeW2O9,” Cryst. Growth Des. 10(9), 4091–4095 (2010).
[Crossref]

W. Zhang, X. Tao, C. Zhang, Z. Gao, Y. Zhang, W. Yu, X. Cheng, X. Liu, and M. Jiang, “Bulk Growth and Characterization of a Novel Nonlinear Optical Crystal BaTeMo2O9,” Cryst. Growth Des. 8(1), 304–307 (2008).
[Crossref]

Zhang, X.

Zhang, Y.

W. Zhang, X. Tao, C. Zhang, Z. Gao, Y. Zhang, W. Yu, X. Cheng, X. Liu, and M. Jiang, “Bulk Growth and Characterization of a Novel Nonlinear Optical Crystal BaTeMo2O9,” Cryst. Growth Des. 8(1), 304–307 (2008).
[Crossref]

Zhang, Z.

J. Zhang, X. Tao, Y. Sun, Z. Zhang, C. Zhang, Z. Gao, H. Xia, and S. Xia, “Top-Seeded Solution Growth, Morphology, and Properties of a Polar Crystal Cs2TeMo3O12,” Cryst. Growth Des. 11(5), 1863–1868 (2011).
[Crossref]

Zhu, Y.

Zondy, J. J.

Appl. Phys. Lett. (1)

S. X. Dou, M. H. Jiang, Z. S. Shao, and X. T. Tao, “Maker fringes in biaxial crystals and the nonlinear optical coefficients of thiosemicarbazide cadmium chloride monohydrate,” Appl. Phys. Lett. 54(12), 1101–1103 (1989).
[Crossref]

Chem. Mater. (4)

J. Goodey, J. Broussard, and P. S. Halasyamani, “Synthesis, structure, and characterization of a new second-harmonic-generating tellurite: Na2TeW2O9,” Chem. Mater. 14(7), 3174–3180 (2002).
[Crossref]

I. Chung and M. G. Kanatzidis, “Metal chalcogenides: a rich source of nonlinear optical materials,” Chem. Mater. 26(1), 849–869 (2014).
[Crossref]

K. M. Ok, P. S. Halasyamani, D. Casanova, M. Llunell, P. Alemany, and S. Alvarez, “Distortions in octahedrally coordinated d0 transition metal oxides: A continuous symmetry measures approach,” Chem. Mater. 18(14), 3176–3183 (2006).
[Crossref]

P. S. Halasyamani, “Asymmetric cation coordination in oxide materials: Influence of lone-Pair cations on the intra-octahedral distortion in d0 transition metals,” Chem. Mater. 16(19), 3586–3592 (2004).
[Crossref]

Cryst. Growth Des. (4)

W. Zhang, X. Tao, C. Zhang, Z. Gao, Y. Zhang, W. Yu, X. Cheng, X. Liu, and M. Jiang, “Bulk Growth and Characterization of a Novel Nonlinear Optical Crystal BaTeMo2O9,” Cryst. Growth Des. 8(1), 304–307 (2008).
[Crossref]

W. Zhang, F. Li, S. H. Kim, and P. S. Halasyamani, “Top-seeded solution crystal growth and functional properties of a polar material-Na2TeW2O9,” Cryst. Growth Des. 10(9), 4091–4095 (2010).
[Crossref]

J. Zhang, X. Tao, Y. Sun, Z. Zhang, C. Zhang, Z. Gao, H. Xia, and S. Xia, “Top-Seeded Solution Growth, Morphology, and Properties of a Polar Crystal Cs2TeMo3O12,” Cryst. Growth Des. 11(5), 1863–1868 (2011).
[Crossref]

W. Zhang, P. S. Halasyamani, Z. Gao, S. Wang, J. Wang, and X. Tao, “Anisotropic Thermal Properties of the Nonlinear Optical and Polar,” Cryst. Growth Des. 11(8), 3636–3641 (2011).
[Crossref]

CrystEngComm (1)

W. Zhang, J. Sun, X. Wang, G. Shen, and D. Shen, “Crystal growth and optical properties of a noncentrosymmetric molybdenum tellurite, Na2Te3Mo3O16,” CrystEngComm 14(10), 3490–3494 (2012).
[Crossref]

Inorg. Chem. (1)

K. M. Ok and P. S. Halasyamani, “Mixed-metal tellurites: Synthesis, structure, and characterization of Na1.4Nb3Te4.9O18 and NaNb3Te4O16.,” Inorg. Chem. 44(11), 3919–3925 (2005).
[Crossref] [PubMed]

Int. Rev. Phys. Chem. (1)

C. Chen, Y. Wu, and R. Li, “The anionic group theory of the non-linear optical effect and its applications in the development of new high-quality NLO crystals in the borate series,” Int. Rev. Phys. Chem. 8(1), 65–91 (1989).
[Crossref]

J. Appl. Phys. (1)

Q. Yu, Z. Gao, S. Zhang, W. Zhang, S. Wang, and X. Tao, “Second order nonlinear properties of monoclinic single crystal BaTeMo2O9,” J. Appl. Phys. 111(1), 013506 (2012).
[Crossref]

J. Opt. Soc. Am. B (1)

Opt. Express (4)

Opt. Lett. (1)

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Figures (6)

Fig. 1
Fig. 1 Dispersion of the refractive indices and calculated curves from the Sellmeir coefficients for the NTW crystal.
Fig. 2
Fig. 2 The UV-vis-NIR and mid-IR transmission spectra of NTW crystal.
Fig. 3
Fig. 3 Samples for measurements on NTW using the MF technique.
Fig. 4
Fig. 4 Maker fringes measurement for the coefficient d13: a) experimental fringes b) theoretical fringes.
Fig. 5
Fig. 5 Phase matching curves of NTW at 1064 nm. a) Type-I phase matching curve b) Type-II phase-matching curve.
Fig. 6
Fig. 6 Directions of dipole moments of each W-O6 and Te-O3 polyhedral and net dipole moment in NTW. The blue arrows indicate the directions of dipole moments for each W-O6 and Te-O3 polyhedron. The red arrow indicates the net dipole moment for each unit cell.

Tables (2)

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Table 1 Second-order NLO coefficients and the largest effective nonlinear coefficient of NTW at room temperature

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Table 2 Polyhedron distortion and net dipole moment in NTW and CTM

Equations (6)

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n x 2 =3.6246+ 0.0627 λ 2 0.0435 0.0084 λ 2
n y 2 =3.8688+ 0.0773 λ 2 0.0518 0.0111 λ 2
n z 2 =4.1915+ 0.1003 λ 2 0.0604 0.0186 λ 2
I 2 f(θ)× d ij 2 ×T
d ij(NTW) d 36(KDP) = I 2 (NTW) f (θ) (NTW ) × f (θ) (KDP) I 2 (KDP) × T ( KDP ) T (NTW ) | θ=0°
d eff II = a i e2 d ijk a j e1 a k e2

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