Abstract

The present work investigates the photoinduced Second Harmonic Generation processes in thermally poled arsenic sulfide glasses. SHG Maker fringes patterns associated to SHG kinetic measurements about illumination and Raman spectroscopy have been conducted in order to bring new information which confirm the combined influence of charge carriers and mid-range glass structural modification on the poling and the photodarkening mechanisms.

©2011 Optical Society of America

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References

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    [Crossref]
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    [Crossref]
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    [Crossref]
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    [Crossref]
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    [Crossref]
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    [Crossref]
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    [Crossref]
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    [Crossref] [PubMed]
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    [Crossref]
  33. K. Shimakawa, “Photoinduced Fluidity enhanced by electric field in amorphous chalcogenides,” J. Optoelectron. Adv. Mater. 7(1), 145–151 (2005).

2011 (3)

B. J. Eggleton, B. Luther-Davies, and K. Richardson, “Chalcogenide photonics,” Nat. Photonics 5, 141–148 (2011).

S. N. Yannopoulos, F. Kyriazis, and I. P. Chochliouros, “Composition-dependent photosensitivity in As-S glasses induced by bandgap light: structural origin by Raman scattering,” Opt. Lett. 36(4), 534–536 (2011).
[Crossref] [PubMed]

P. Bonazzi, L. Bindi, M. Muniz-Miranda, L. Chelazzi, T. Rodl, and A. Pfitzner, “Light-induced molecular change in HgI2·As4S4: Evidence by single-crystal X-ray diffraction and Raman spectroscopy,” Am. Mineral. 96(4), 646–653 (2011).
[Crossref]

2010 (3)

2008 (1)

S. Gu, Z. Ma, H. Tao, C. Lin, H. Hu, X. Zhao, and Y. Gong, “Second-harmonic generation in the thermal/electrical poling (100-x)GeS2·x(0.5Ga2S3·0.5CdS) chalcogenide glasses,” J. Phys. Chem. Solids 69(1), 97–100 (2008).
[Crossref]

2007 (3)

H. Guo, X. Zheng, X. Zhao, G. Gao, Y. Gong, and S. Gu, “Composition dependence of thermally induced second-harmonic generation in chalcohalide glasses,” J. Mater. Sci. 42(16), 6549–6554 (2007).
[Crossref]

M. Guignard, V. Nazabal, F. Smektala, J.-L. Adam, O. Bohnke, C. Duverger, A. Moréac, H. Zeghlache, A. Kudlinski, G. Martinelli, and Y. Quiquempois, “Chalcogenide glasses based on germanium disulfide for Second Harmonic Generation,” Adv. Funct. Mater. 17(16), 3284–3294 (2007).
[Crossref]

H. Zeghlache, M. Guignard, A. Kudlinski, Y. Quiquempois, G. Martinelli, V. Nazabal, and F. Smektala, “Stabilization of the second-order susceptibility induced in a sulfide chalcogenide glass by thermal poling,” J. Appl. Phys. 101(8), 084905 (2007).
[Crossref]

2006 (2)

R. Jing, Y. Guang, Z. Huidan, C. Guorong, K. Tanaka, K. Fujita, S. Murai, and Y. Tsujiie, “Second-harmonic generation in thermally poled chalcohalide glass,” Opt. Lett. 31(23), 3492–3494 (2006).
[Crossref] [PubMed]

G. Chen, H. Jain, M. Vlcek, and A. Ganjoo, “Photoinduced volume change in arsenic chalcogenides by band-gap light,” Phys. Rev. B 74(17), 174203 (2006).
[Crossref]

2005 (3)

2004 (1)

K. Shimakawa, T. Kato, and T. Hamagishi, “Acceleration of photodarkening under dc electric field in amorphous As2Se3 films,” J. Non-Cryst. Solids 338–340, 548–551 (2004).
[Crossref]

2003 (1)

S. N. Yannopoulos, “Intramolecular structural model for photoinduced plasticity in chalcogenide glasses,” Phys. Rev. B 68(6), 064206 (2003).
[Crossref]

2001 (2)

O. M. Efimov, L. B. Glebov, K. A. Richardson, E. Van Stryland, T. Cardinal, S. H. Park, M. Couzi, and J. L. Bruneel, “Waveguide writing in chalcogenide glasses by a train of femtosecond laser pulses,” Opt. Mater. 17(3), 379–386 (2001).
[Crossref]

D. Kastrissios, G. Papatheodorou, and S. Yannopoulos, “Vibrational modes in the athermally photoinduced fluidity regime of glassy As2S3,” Phys. Rev. B 64(21), 214203 (2001).
[Crossref]

1998 (3)

K. Tanaka, “Photoexpansion in As2S3 glass,” Phys. Rev. B 57(9), 5163–5167 (1998).
[Crossref]

K. Tanaka and K. Ishida, “Photinduced anisotropic structures in chalcogenide glasses,” J. Non-Cryst. Solids 227–230, 673–676 (1998).
[Crossref]

A. Kolobov, H. Oyanagi, A. Roy, and K. Tanaka, “Role of lone-pair electrons in reversible photostructural changes in amorphous chalcogenides,” J. Non-Cryst. Solids 227–230, 710–714 (1998).
[Crossref]

1996 (2)

M. Muniz-Miranda, G. Sbrana, P. Bonazzi, S. Menchetti, and G. Pratesi, “Spectroscopic investigation and normal mode analysis of As4S4 polymorphs,” Spectrochim. Acta [A] 52(11), 1391–1401 (1996).
[Crossref]

X. Prieto and J. Liñares, “Increasing resistivity effects in field-assisted ion exchange for planar optical waveguide fabrication,” Opt. Lett. 21(17), 1363–1365 (1996).
[Crossref] [PubMed]

1992 (2)

D. L. Douglass, C. Shing, and G. Wang, “The light-induced alteration of realgar to pararealgar,” Am. Mineral. 77, 1266–1274 (1992).

K. Shimakawa, S. Inami, T. Kato, and S. R. Elliott, “Origin of photoindued metastable defects in amorphous chalcogenides,” Phys. Rev. B 46(16), 10062–10069 (1992).
[Crossref]

1991 (2)

M. A. Paesler and G. Pfeiffer, “Modeling the structure and photostructural changes in amorphous arsenic sulfide,” J. Non-Cryst. Solids 137–138, 967–972 (1991).
[Crossref]

G. Pfeiffer, M. A. Paesler, and S. C. Agarwal, “Reversible photodarkening of amorphous arsenic chalcogens,” J. Non-Cryst. Solids 130(2), 111–143 (1991).
[Crossref]

1990 (1)

K. Shimakawa, S. Inami, and S. R. Elliott, “Reversible photoinduced change of photoconductivity in amorphous chalcogenide films,” Phys. Rev. B Condens. Matter 42(18), 11857–11861 (1990).
[Crossref] [PubMed]

1987 (1)

C. Y. Yang, M. A. Paesler, and D. E. Sayers, “Measurement of local structural configurations associated with reversible photostructural changes in arsenic trisulfide films,” Phys. Rev. B Condens. Matter 36(17), 9160–9167 (1987).
[Crossref] [PubMed]

1972 (2)

G. Lucovsky, “Optic modes in amorphous As2S3 and As2Se3,” Phys. Rev. B 6(4), 1480–1489 (1972).
[Crossref]

G. Lucovsky and R. M. Martin, “A molecular model for the vibrational modes in chalcogenide glasses,” J. Non-Cryst. Solids 8–10, 185–190 (1972).
[Crossref]

1968 (1)

A. T. Ward, “Raman spectroscopy of sulfur, sulfur-selenium, and sulfur-arsenic mixtures,” J. Phys. Chem. 72(12), 4133–4139 (1968).
[Crossref]

Adam, J.-L.

M. Guignard, V. Nazabal, F. Smektala, J.-L. Adam, O. Bohnke, C. Duverger, A. Moréac, H. Zeghlache, A. Kudlinski, G. Martinelli, and Y. Quiquempois, “Chalcogenide glasses based on germanium disulfide for Second Harmonic Generation,” Adv. Funct. Mater. 17(16), 3284–3294 (2007).
[Crossref]

Adamietz, F.

Agarwal, S. C.

G. Pfeiffer, M. A. Paesler, and S. C. Agarwal, “Reversible photodarkening of amorphous arsenic chalcogens,” J. Non-Cryst. Solids 130(2), 111–143 (1991).
[Crossref]

Bindi, L.

P. Bonazzi, L. Bindi, M. Muniz-Miranda, L. Chelazzi, T. Rodl, and A. Pfitzner, “Light-induced molecular change in HgI2·As4S4: Evidence by single-crystal X-ray diffraction and Raman spectroscopy,” Am. Mineral. 96(4), 646–653 (2011).
[Crossref]

Bohnke, O.

M. Guignard, V. Nazabal, F. Smektala, J.-L. Adam, O. Bohnke, C. Duverger, A. Moréac, H. Zeghlache, A. Kudlinski, G. Martinelli, and Y. Quiquempois, “Chalcogenide glasses based on germanium disulfide for Second Harmonic Generation,” Adv. Funct. Mater. 17(16), 3284–3294 (2007).
[Crossref]

Bonazzi, P.

P. Bonazzi, L. Bindi, M. Muniz-Miranda, L. Chelazzi, T. Rodl, and A. Pfitzner, “Light-induced molecular change in HgI2·As4S4: Evidence by single-crystal X-ray diffraction and Raman spectroscopy,” Am. Mineral. 96(4), 646–653 (2011).
[Crossref]

M. Muniz-Miranda, G. Sbrana, P. Bonazzi, S. Menchetti, and G. Pratesi, “Spectroscopic investigation and normal mode analysis of As4S4 polymorphs,” Spectrochim. Acta [A] 52(11), 1391–1401 (1996).
[Crossref]

Brilland, L.

Bruneel, J. L.

O. M. Efimov, L. B. Glebov, K. A. Richardson, E. Van Stryland, T. Cardinal, S. H. Park, M. Couzi, and J. L. Bruneel, “Waveguide writing in chalcogenide glasses by a train of femtosecond laser pulses,” Opt. Mater. 17(3), 379–386 (2001).
[Crossref]

Bulla, D.

Cardinal, T.

O. M. Efimov, L. B. Glebov, K. A. Richardson, E. Van Stryland, T. Cardinal, S. H. Park, M. Couzi, and J. L. Bruneel, “Waveguide writing in chalcogenide glasses by a train of femtosecond laser pulses,” Opt. Mater. 17(3), 379–386 (2001).
[Crossref]

Chelazzi, L.

P. Bonazzi, L. Bindi, M. Muniz-Miranda, L. Chelazzi, T. Rodl, and A. Pfitzner, “Light-induced molecular change in HgI2·As4S4: Evidence by single-crystal X-ray diffraction and Raman spectroscopy,” Am. Mineral. 96(4), 646–653 (2011).
[Crossref]

Chen, G.

G. Chen, H. Jain, M. Vlcek, and A. Ganjoo, “Photoinduced volume change in arsenic chalcogenides by band-gap light,” Phys. Rev. B 74(17), 174203 (2006).
[Crossref]

Chochliouros, I. P.

Choi, D.-Y.

Couzi, M.

O. M. Efimov, L. B. Glebov, K. A. Richardson, E. Van Stryland, T. Cardinal, S. H. Park, M. Couzi, and J. L. Bruneel, “Waveguide writing in chalcogenide glasses by a train of femtosecond laser pulses,” Opt. Mater. 17(3), 379–386 (2001).
[Crossref]

Désévédavy, F.

Douglass, D. L.

D. L. Douglass, C. Shing, and G. Wang, “The light-induced alteration of realgar to pararealgar,” Am. Mineral. 77, 1266–1274 (1992).

Dussauze, M.

Duverger, C.

M. Guignard, V. Nazabal, F. Smektala, J.-L. Adam, O. Bohnke, C. Duverger, A. Moréac, H. Zeghlache, A. Kudlinski, G. Martinelli, and Y. Quiquempois, “Chalcogenide glasses based on germanium disulfide for Second Harmonic Generation,” Adv. Funct. Mater. 17(16), 3284–3294 (2007).
[Crossref]

Efimov, O. M.

O. M. Efimov, L. B. Glebov, K. A. Richardson, E. Van Stryland, T. Cardinal, S. H. Park, M. Couzi, and J. L. Bruneel, “Waveguide writing in chalcogenide glasses by a train of femtosecond laser pulses,” Opt. Mater. 17(3), 379–386 (2001).
[Crossref]

Eggleton, B. J.

B. J. Eggleton, B. Luther-Davies, and K. Richardson, “Chalcogenide photonics,” Nat. Photonics 5, 141–148 (2011).

El-Amraoui, M.

Elliott, S. R.

K. Shimakawa, S. Inami, T. Kato, and S. R. Elliott, “Origin of photoindued metastable defects in amorphous chalcogenides,” Phys. Rev. B 46(16), 10062–10069 (1992).
[Crossref]

K. Shimakawa, S. Inami, and S. R. Elliott, “Reversible photoinduced change of photoconductivity in amorphous chalcogenide films,” Phys. Rev. B Condens. Matter 42(18), 11857–11861 (1990).
[Crossref] [PubMed]

Fargin, E.

Fatome, J.

Fortier, C.

Fujita, K.

Gadret, G.

Gai, X.

Ganjoo, A.

G. Chen, H. Jain, M. Vlcek, and A. Ganjoo, “Photoinduced volume change in arsenic chalcogenides by band-gap light,” Phys. Rev. B 74(17), 174203 (2006).
[Crossref]

Gao, G.

H. Guo, X. Zheng, X. Zhao, G. Gao, Y. Gong, and S. Gu, “Composition dependence of thermally induced second-harmonic generation in chalcohalide glasses,” J. Mater. Sci. 42(16), 6549–6554 (2007).
[Crossref]

Gao, W.

Glebov, L. B.

O. M. Efimov, L. B. Glebov, K. A. Richardson, E. Van Stryland, T. Cardinal, S. H. Park, M. Couzi, and J. L. Bruneel, “Waveguide writing in chalcogenide glasses by a train of femtosecond laser pulses,” Opt. Mater. 17(3), 379–386 (2001).
[Crossref]

Gong, Y.

S. Gu, Z. Ma, H. Tao, C. Lin, H. Hu, X. Zhao, and Y. Gong, “Second-harmonic generation in the thermal/electrical poling (100-x)GeS2·x(0.5Ga2S3·0.5CdS) chalcogenide glasses,” J. Phys. Chem. Solids 69(1), 97–100 (2008).
[Crossref]

H. Guo, X. Zheng, X. Zhao, G. Gao, Y. Gong, and S. Gu, “Composition dependence of thermally induced second-harmonic generation in chalcohalide glasses,” J. Mater. Sci. 42(16), 6549–6554 (2007).
[Crossref]

Gu, S.

S. Gu, Z. Ma, H. Tao, C. Lin, H. Hu, X. Zhao, and Y. Gong, “Second-harmonic generation in the thermal/electrical poling (100-x)GeS2·x(0.5Ga2S3·0.5CdS) chalcogenide glasses,” J. Phys. Chem. Solids 69(1), 97–100 (2008).
[Crossref]

H. Guo, X. Zheng, X. Zhao, G. Gao, Y. Gong, and S. Gu, “Composition dependence of thermally induced second-harmonic generation in chalcohalide glasses,” J. Mater. Sci. 42(16), 6549–6554 (2007).
[Crossref]

Guang, Y.

Guignard, M.

M. Guignard, V. Nazabal, F. Smektala, J.-L. Adam, O. Bohnke, C. Duverger, A. Moréac, H. Zeghlache, A. Kudlinski, G. Martinelli, and Y. Quiquempois, “Chalcogenide glasses based on germanium disulfide for Second Harmonic Generation,” Adv. Funct. Mater. 17(16), 3284–3294 (2007).
[Crossref]

H. Zeghlache, M. Guignard, A. Kudlinski, Y. Quiquempois, G. Martinelli, V. Nazabal, and F. Smektala, “Stabilization of the second-order susceptibility induced in a sulfide chalcogenide glass by thermal poling,” J. Appl. Phys. 101(8), 084905 (2007).
[Crossref]

M. Guignard, V. Nazabal, J. Troles, F. Smektala, H. Zeghlache, Y. Quiquempois, A. Kudlinski, and G. Martinelli, “Second-harmonic generation of thermally poled chalcogenide glass,” Opt. Express 13(3), 789–795 (2005).
[Crossref] [PubMed]

Guo, H.

H. Guo, X. Zheng, X. Zhao, G. Gao, Y. Gong, and S. Gu, “Composition dependence of thermally induced second-harmonic generation in chalcohalide glasses,” J. Mater. Sci. 42(16), 6549–6554 (2007).
[Crossref]

Guorong, C.

Hamagishi, T.

K. Shimakawa, T. Kato, and T. Hamagishi, “Acceleration of photodarkening under dc electric field in amorphous As2Se3 films,” J. Non-Cryst. Solids 338–340, 548–551 (2004).
[Crossref]

Han, T.

Hirao, K.

K. Richardson, D. Krol, and K. Hirao, “Glasses for Photonic Applications,” Int. J. Appl. Glass Sci. 1(1), 74–86 (2010).
[Crossref]

Hu, H.

S. Gu, Z. Ma, H. Tao, C. Lin, H. Hu, X. Zhao, and Y. Gong, “Second-harmonic generation in the thermal/electrical poling (100-x)GeS2·x(0.5Ga2S3·0.5CdS) chalcogenide glasses,” J. Phys. Chem. Solids 69(1), 97–100 (2008).
[Crossref]

Huidan, Z.

Inami, S.

K. Shimakawa, S. Inami, T. Kato, and S. R. Elliott, “Origin of photoindued metastable defects in amorphous chalcogenides,” Phys. Rev. B 46(16), 10062–10069 (1992).
[Crossref]

K. Shimakawa, S. Inami, and S. R. Elliott, “Reversible photoinduced change of photoconductivity in amorphous chalcogenide films,” Phys. Rev. B Condens. Matter 42(18), 11857–11861 (1990).
[Crossref] [PubMed]

Ishida, K.

K. Tanaka and K. Ishida, “Photinduced anisotropic structures in chalcogenide glasses,” J. Non-Cryst. Solids 227–230, 673–676 (1998).
[Crossref]

Jain, H.

G. Chen, H. Jain, M. Vlcek, and A. Ganjoo, “Photoinduced volume change in arsenic chalcogenides by band-gap light,” Phys. Rev. B 74(17), 174203 (2006).
[Crossref]

Jing, R.

Jules, J. C.

Kastrissios, D.

D. Kastrissios, G. Papatheodorou, and S. Yannopoulos, “Vibrational modes in the athermally photoinduced fluidity regime of glassy As2S3,” Phys. Rev. B 64(21), 214203 (2001).
[Crossref]

Kato, T.

K. Shimakawa, T. Kato, and T. Hamagishi, “Acceleration of photodarkening under dc electric field in amorphous As2Se3 films,” J. Non-Cryst. Solids 338–340, 548–551 (2004).
[Crossref]

K. Shimakawa, S. Inami, T. Kato, and S. R. Elliott, “Origin of photoindued metastable defects in amorphous chalcogenides,” Phys. Rev. B 46(16), 10062–10069 (1992).
[Crossref]

Kolobov, A.

A. Kolobov, H. Oyanagi, A. Roy, and K. Tanaka, “Role of lone-pair electrons in reversible photostructural changes in amorphous chalcogenides,” J. Non-Cryst. Solids 227–230, 710–714 (1998).
[Crossref]

Krol, D.

K. Richardson, D. Krol, and K. Hirao, “Glasses for Photonic Applications,” Int. J. Appl. Glass Sci. 1(1), 74–86 (2010).
[Crossref]

Kudlinski, A.

M. Guignard, V. Nazabal, F. Smektala, J.-L. Adam, O. Bohnke, C. Duverger, A. Moréac, H. Zeghlache, A. Kudlinski, G. Martinelli, and Y. Quiquempois, “Chalcogenide glasses based on germanium disulfide for Second Harmonic Generation,” Adv. Funct. Mater. 17(16), 3284–3294 (2007).
[Crossref]

H. Zeghlache, M. Guignard, A. Kudlinski, Y. Quiquempois, G. Martinelli, V. Nazabal, and F. Smektala, “Stabilization of the second-order susceptibility induced in a sulfide chalcogenide glass by thermal poling,” J. Appl. Phys. 101(8), 084905 (2007).
[Crossref]

M. Guignard, V. Nazabal, J. Troles, F. Smektala, H. Zeghlache, Y. Quiquempois, A. Kudlinski, and G. Martinelli, “Second-harmonic generation of thermally poled chalcogenide glass,” Opt. Express 13(3), 789–795 (2005).
[Crossref] [PubMed]

Kyriazis, F.

Lahaye, M.

Lin, C.

S. Gu, Z. Ma, H. Tao, C. Lin, H. Hu, X. Zhao, and Y. Gong, “Second-harmonic generation in the thermal/electrical poling (100-x)GeS2·x(0.5Ga2S3·0.5CdS) chalcogenide glasses,” J. Phys. Chem. Solids 69(1), 97–100 (2008).
[Crossref]

Liñares, J.

Lucovsky, G.

G. Lucovsky, “Optic modes in amorphous As2S3 and As2Se3,” Phys. Rev. B 6(4), 1480–1489 (1972).
[Crossref]

G. Lucovsky and R. M. Martin, “A molecular model for the vibrational modes in chalcogenide glasses,” J. Non-Cryst. Solids 8–10, 185–190 (1972).
[Crossref]

Luther-Davies, B.

Ma, Z.

S. Gu, Z. Ma, H. Tao, C. Lin, H. Hu, X. Zhao, and Y. Gong, “Second-harmonic generation in the thermal/electrical poling (100-x)GeS2·x(0.5Ga2S3·0.5CdS) chalcogenide glasses,” J. Phys. Chem. Solids 69(1), 97–100 (2008).
[Crossref]

Madden, S.

Martin, R. M.

G. Lucovsky and R. M. Martin, “A molecular model for the vibrational modes in chalcogenide glasses,” J. Non-Cryst. Solids 8–10, 185–190 (1972).
[Crossref]

Martinelli, G.

H. Zeghlache, M. Guignard, A. Kudlinski, Y. Quiquempois, G. Martinelli, V. Nazabal, and F. Smektala, “Stabilization of the second-order susceptibility induced in a sulfide chalcogenide glass by thermal poling,” J. Appl. Phys. 101(8), 084905 (2007).
[Crossref]

M. Guignard, V. Nazabal, F. Smektala, J.-L. Adam, O. Bohnke, C. Duverger, A. Moréac, H. Zeghlache, A. Kudlinski, G. Martinelli, and Y. Quiquempois, “Chalcogenide glasses based on germanium disulfide for Second Harmonic Generation,” Adv. Funct. Mater. 17(16), 3284–3294 (2007).
[Crossref]

M. Guignard, V. Nazabal, J. Troles, F. Smektala, H. Zeghlache, Y. Quiquempois, A. Kudlinski, and G. Martinelli, “Second-harmonic generation of thermally poled chalcogenide glass,” Opt. Express 13(3), 789–795 (2005).
[Crossref] [PubMed]

Menchetti, S.

M. Muniz-Miranda, G. Sbrana, P. Bonazzi, S. Menchetti, and G. Pratesi, “Spectroscopic investigation and normal mode analysis of As4S4 polymorphs,” Spectrochim. Acta [A] 52(11), 1391–1401 (1996).
[Crossref]

Messaddeq, Y.

Moréac, A.

M. Guignard, V. Nazabal, F. Smektala, J.-L. Adam, O. Bohnke, C. Duverger, A. Moréac, H. Zeghlache, A. Kudlinski, G. Martinelli, and Y. Quiquempois, “Chalcogenide glasses based on germanium disulfide for Second Harmonic Generation,” Adv. Funct. Mater. 17(16), 3284–3294 (2007).
[Crossref]

Muniz-Miranda, M.

P. Bonazzi, L. Bindi, M. Muniz-Miranda, L. Chelazzi, T. Rodl, and A. Pfitzner, “Light-induced molecular change in HgI2·As4S4: Evidence by single-crystal X-ray diffraction and Raman spectroscopy,” Am. Mineral. 96(4), 646–653 (2011).
[Crossref]

M. Muniz-Miranda, G. Sbrana, P. Bonazzi, S. Menchetti, and G. Pratesi, “Spectroscopic investigation and normal mode analysis of As4S4 polymorphs,” Spectrochim. Acta [A] 52(11), 1391–1401 (1996).
[Crossref]

Murai, S.

Nazabal, V.

H. Zeghlache, M. Guignard, A. Kudlinski, Y. Quiquempois, G. Martinelli, V. Nazabal, and F. Smektala, “Stabilization of the second-order susceptibility induced in a sulfide chalcogenide glass by thermal poling,” J. Appl. Phys. 101(8), 084905 (2007).
[Crossref]

M. Guignard, V. Nazabal, F. Smektala, J.-L. Adam, O. Bohnke, C. Duverger, A. Moréac, H. Zeghlache, A. Kudlinski, G. Martinelli, and Y. Quiquempois, “Chalcogenide glasses based on germanium disulfide for Second Harmonic Generation,” Adv. Funct. Mater. 17(16), 3284–3294 (2007).
[Crossref]

M. Guignard, V. Nazabal, J. Troles, F. Smektala, H. Zeghlache, Y. Quiquempois, A. Kudlinski, and G. Martinelli, “Second-harmonic generation of thermally poled chalcogenide glass,” Opt. Express 13(3), 789–795 (2005).
[Crossref] [PubMed]

Ohishi, Y.

Oyanagi, H.

A. Kolobov, H. Oyanagi, A. Roy, and K. Tanaka, “Role of lone-pair electrons in reversible photostructural changes in amorphous chalcogenides,” J. Non-Cryst. Solids 227–230, 710–714 (1998).
[Crossref]

Paesler, M. A.

M. A. Paesler and G. Pfeiffer, “Modeling the structure and photostructural changes in amorphous arsenic sulfide,” J. Non-Cryst. Solids 137–138, 967–972 (1991).
[Crossref]

G. Pfeiffer, M. A. Paesler, and S. C. Agarwal, “Reversible photodarkening of amorphous arsenic chalcogens,” J. Non-Cryst. Solids 130(2), 111–143 (1991).
[Crossref]

C. Y. Yang, M. A. Paesler, and D. E. Sayers, “Measurement of local structural configurations associated with reversible photostructural changes in arsenic trisulfide films,” Phys. Rev. B Condens. Matter 36(17), 9160–9167 (1987).
[Crossref] [PubMed]

Papatheodorou, G.

D. Kastrissios, G. Papatheodorou, and S. Yannopoulos, “Vibrational modes in the athermally photoinduced fluidity regime of glassy As2S3,” Phys. Rev. B 64(21), 214203 (2001).
[Crossref]

Park, S. H.

O. M. Efimov, L. B. Glebov, K. A. Richardson, E. Van Stryland, T. Cardinal, S. H. Park, M. Couzi, and J. L. Bruneel, “Waveguide writing in chalcogenide glasses by a train of femtosecond laser pulses,” Opt. Mater. 17(3), 379–386 (2001).
[Crossref]

Pfeiffer, G.

M. A. Paesler and G. Pfeiffer, “Modeling the structure and photostructural changes in amorphous arsenic sulfide,” J. Non-Cryst. Solids 137–138, 967–972 (1991).
[Crossref]

G. Pfeiffer, M. A. Paesler, and S. C. Agarwal, “Reversible photodarkening of amorphous arsenic chalcogens,” J. Non-Cryst. Solids 130(2), 111–143 (1991).
[Crossref]

Pfitzner, A.

P. Bonazzi, L. Bindi, M. Muniz-Miranda, L. Chelazzi, T. Rodl, and A. Pfitzner, “Light-induced molecular change in HgI2·As4S4: Evidence by single-crystal X-ray diffraction and Raman spectroscopy,” Am. Mineral. 96(4), 646–653 (2011).
[Crossref]

Prasad, A.

Pratesi, G.

M. Muniz-Miranda, G. Sbrana, P. Bonazzi, S. Menchetti, and G. Pratesi, “Spectroscopic investigation and normal mode analysis of As4S4 polymorphs,” Spectrochim. Acta [A] 52(11), 1391–1401 (1996).
[Crossref]

Prieto, X.

Quiquempois, Y.

H. Zeghlache, M. Guignard, A. Kudlinski, Y. Quiquempois, G. Martinelli, V. Nazabal, and F. Smektala, “Stabilization of the second-order susceptibility induced in a sulfide chalcogenide glass by thermal poling,” J. Appl. Phys. 101(8), 084905 (2007).
[Crossref]

M. Guignard, V. Nazabal, F. Smektala, J.-L. Adam, O. Bohnke, C. Duverger, A. Moréac, H. Zeghlache, A. Kudlinski, G. Martinelli, and Y. Quiquempois, “Chalcogenide glasses based on germanium disulfide for Second Harmonic Generation,” Adv. Funct. Mater. 17(16), 3284–3294 (2007).
[Crossref]

M. Guignard, V. Nazabal, J. Troles, F. Smektala, H. Zeghlache, Y. Quiquempois, A. Kudlinski, and G. Martinelli, “Second-harmonic generation of thermally poled chalcogenide glass,” Opt. Express 13(3), 789–795 (2005).
[Crossref] [PubMed]

Richardson, K.

B. J. Eggleton, B. Luther-Davies, and K. Richardson, “Chalcogenide photonics,” Nat. Photonics 5, 141–148 (2011).

K. Richardson, D. Krol, and K. Hirao, “Glasses for Photonic Applications,” Int. J. Appl. Glass Sci. 1(1), 74–86 (2010).
[Crossref]

Richardson, K. A.

O. M. Efimov, L. B. Glebov, K. A. Richardson, E. Van Stryland, T. Cardinal, S. H. Park, M. Couzi, and J. L. Bruneel, “Waveguide writing in chalcogenide glasses by a train of femtosecond laser pulses,” Opt. Mater. 17(3), 379–386 (2001).
[Crossref]

Rodl, T.

P. Bonazzi, L. Bindi, M. Muniz-Miranda, L. Chelazzi, T. Rodl, and A. Pfitzner, “Light-induced molecular change in HgI2·As4S4: Evidence by single-crystal X-ray diffraction and Raman spectroscopy,” Am. Mineral. 96(4), 646–653 (2011).
[Crossref]

Rodriguez, V.

Roy, A.

A. Kolobov, H. Oyanagi, A. Roy, and K. Tanaka, “Role of lone-pair electrons in reversible photostructural changes in amorphous chalcogenides,” J. Non-Cryst. Solids 227–230, 710–714 (1998).
[Crossref]

Sayers, D. E.

C. Y. Yang, M. A. Paesler, and D. E. Sayers, “Measurement of local structural configurations associated with reversible photostructural changes in arsenic trisulfide films,” Phys. Rev. B Condens. Matter 36(17), 9160–9167 (1987).
[Crossref] [PubMed]

Sbrana, G.

M. Muniz-Miranda, G. Sbrana, P. Bonazzi, S. Menchetti, and G. Pratesi, “Spectroscopic investigation and normal mode analysis of As4S4 polymorphs,” Spectrochim. Acta [A] 52(11), 1391–1401 (1996).
[Crossref]

Shimakawa, K.

K. Shimakawa, “Photoinduced Fluidity enhanced by electric field in amorphous chalcogenides,” J. Optoelectron. Adv. Mater. 7(1), 145–151 (2005).

K. Shimakawa, T. Kato, and T. Hamagishi, “Acceleration of photodarkening under dc electric field in amorphous As2Se3 films,” J. Non-Cryst. Solids 338–340, 548–551 (2004).
[Crossref]

K. Shimakawa, S. Inami, T. Kato, and S. R. Elliott, “Origin of photoindued metastable defects in amorphous chalcogenides,” Phys. Rev. B 46(16), 10062–10069 (1992).
[Crossref]

K. Shimakawa, S. Inami, and S. R. Elliott, “Reversible photoinduced change of photoconductivity in amorphous chalcogenide films,” Phys. Rev. B Condens. Matter 42(18), 11857–11861 (1990).
[Crossref] [PubMed]

Shing, C.

D. L. Douglass, C. Shing, and G. Wang, “The light-induced alteration of realgar to pararealgar,” Am. Mineral. 77, 1266–1274 (1992).

Skripatchev, I.

Smektala, F.

M. El-Amraoui, G. Gadret, J. C. Jules, J. Fatome, C. Fortier, F. Désévédavy, I. Skripatchev, Y. Messaddeq, J. Troles, L. Brilland, W. Gao, T. Suzuki, Y. Ohishi, and F. Smektala, “Microstructured chalcogenide optical fibers from As2S3 glass: towards new IR broadband sources,” Opt. Express 18(25), 26655–26665 (2010).
[Crossref] [PubMed]

H. Zeghlache, M. Guignard, A. Kudlinski, Y. Quiquempois, G. Martinelli, V. Nazabal, and F. Smektala, “Stabilization of the second-order susceptibility induced in a sulfide chalcogenide glass by thermal poling,” J. Appl. Phys. 101(8), 084905 (2007).
[Crossref]

M. Guignard, V. Nazabal, F. Smektala, J.-L. Adam, O. Bohnke, C. Duverger, A. Moréac, H. Zeghlache, A. Kudlinski, G. Martinelli, and Y. Quiquempois, “Chalcogenide glasses based on germanium disulfide for Second Harmonic Generation,” Adv. Funct. Mater. 17(16), 3284–3294 (2007).
[Crossref]

M. Guignard, V. Nazabal, J. Troles, F. Smektala, H. Zeghlache, Y. Quiquempois, A. Kudlinski, and G. Martinelli, “Second-harmonic generation of thermally poled chalcogenide glass,” Opt. Express 13(3), 789–795 (2005).
[Crossref] [PubMed]

Suzuki, T.

Tanaka, K.

R. Jing, Y. Guang, Z. Huidan, C. Guorong, K. Tanaka, K. Fujita, S. Murai, and Y. Tsujiie, “Second-harmonic generation in thermally poled chalcohalide glass,” Opt. Lett. 31(23), 3492–3494 (2006).
[Crossref] [PubMed]

K. Tanaka, “Photoexpansion in As2S3 glass,” Phys. Rev. B 57(9), 5163–5167 (1998).
[Crossref]

K. Tanaka and K. Ishida, “Photinduced anisotropic structures in chalcogenide glasses,” J. Non-Cryst. Solids 227–230, 673–676 (1998).
[Crossref]

A. Kolobov, H. Oyanagi, A. Roy, and K. Tanaka, “Role of lone-pair electrons in reversible photostructural changes in amorphous chalcogenides,” J. Non-Cryst. Solids 227–230, 710–714 (1998).
[Crossref]

Tao, H.

S. Gu, Z. Ma, H. Tao, C. Lin, H. Hu, X. Zhao, and Y. Gong, “Second-harmonic generation in the thermal/electrical poling (100-x)GeS2·x(0.5Ga2S3·0.5CdS) chalcogenide glasses,” J. Phys. Chem. Solids 69(1), 97–100 (2008).
[Crossref]

Troles, J.

Tsujiie, Y.

Van Stryland, E.

O. M. Efimov, L. B. Glebov, K. A. Richardson, E. Van Stryland, T. Cardinal, S. H. Park, M. Couzi, and J. L. Bruneel, “Waveguide writing in chalcogenide glasses by a train of femtosecond laser pulses,” Opt. Mater. 17(3), 379–386 (2001).
[Crossref]

Vlcek, M.

G. Chen, H. Jain, M. Vlcek, and A. Ganjoo, “Photoinduced volume change in arsenic chalcogenides by band-gap light,” Phys. Rev. B 74(17), 174203 (2006).
[Crossref]

Wang, G.

D. L. Douglass, C. Shing, and G. Wang, “The light-induced alteration of realgar to pararealgar,” Am. Mineral. 77, 1266–1274 (1992).

Wang, R.

Ward, A. T.

A. T. Ward, “Raman spectroscopy of sulfur, sulfur-selenium, and sulfur-arsenic mixtures,” J. Phys. Chem. 72(12), 4133–4139 (1968).
[Crossref]

Yang, C. Y.

C. Y. Yang, M. A. Paesler, and D. E. Sayers, “Measurement of local structural configurations associated with reversible photostructural changes in arsenic trisulfide films,” Phys. Rev. B Condens. Matter 36(17), 9160–9167 (1987).
[Crossref] [PubMed]

Yannopoulos, S.

D. Kastrissios, G. Papatheodorou, and S. Yannopoulos, “Vibrational modes in the athermally photoinduced fluidity regime of glassy As2S3,” Phys. Rev. B 64(21), 214203 (2001).
[Crossref]

Yannopoulos, S. N.

Zeghlache, H.

H. Zeghlache, M. Guignard, A. Kudlinski, Y. Quiquempois, G. Martinelli, V. Nazabal, and F. Smektala, “Stabilization of the second-order susceptibility induced in a sulfide chalcogenide glass by thermal poling,” J. Appl. Phys. 101(8), 084905 (2007).
[Crossref]

M. Guignard, V. Nazabal, F. Smektala, J.-L. Adam, O. Bohnke, C. Duverger, A. Moréac, H. Zeghlache, A. Kudlinski, G. Martinelli, and Y. Quiquempois, “Chalcogenide glasses based on germanium disulfide for Second Harmonic Generation,” Adv. Funct. Mater. 17(16), 3284–3294 (2007).
[Crossref]

M. Guignard, V. Nazabal, J. Troles, F. Smektala, H. Zeghlache, Y. Quiquempois, A. Kudlinski, and G. Martinelli, “Second-harmonic generation of thermally poled chalcogenide glass,” Opt. Express 13(3), 789–795 (2005).
[Crossref] [PubMed]

Zhao, X.

S. Gu, Z. Ma, H. Tao, C. Lin, H. Hu, X. Zhao, and Y. Gong, “Second-harmonic generation in the thermal/electrical poling (100-x)GeS2·x(0.5Ga2S3·0.5CdS) chalcogenide glasses,” J. Phys. Chem. Solids 69(1), 97–100 (2008).
[Crossref]

H. Guo, X. Zheng, X. Zhao, G. Gao, Y. Gong, and S. Gu, “Composition dependence of thermally induced second-harmonic generation in chalcohalide glasses,” J. Mater. Sci. 42(16), 6549–6554 (2007).
[Crossref]

Zheng, X.

H. Guo, X. Zheng, X. Zhao, G. Gao, Y. Gong, and S. Gu, “Composition dependence of thermally induced second-harmonic generation in chalcohalide glasses,” J. Mater. Sci. 42(16), 6549–6554 (2007).
[Crossref]

Adv. Funct. Mater. (1)

M. Guignard, V. Nazabal, F. Smektala, J.-L. Adam, O. Bohnke, C. Duverger, A. Moréac, H. Zeghlache, A. Kudlinski, G. Martinelli, and Y. Quiquempois, “Chalcogenide glasses based on germanium disulfide for Second Harmonic Generation,” Adv. Funct. Mater. 17(16), 3284–3294 (2007).
[Crossref]

Am. Mineral. (2)

D. L. Douglass, C. Shing, and G. Wang, “The light-induced alteration of realgar to pararealgar,” Am. Mineral. 77, 1266–1274 (1992).

P. Bonazzi, L. Bindi, M. Muniz-Miranda, L. Chelazzi, T. Rodl, and A. Pfitzner, “Light-induced molecular change in HgI2·As4S4: Evidence by single-crystal X-ray diffraction and Raman spectroscopy,” Am. Mineral. 96(4), 646–653 (2011).
[Crossref]

Int. J. Appl. Glass Sci. (1)

K. Richardson, D. Krol, and K. Hirao, “Glasses for Photonic Applications,” Int. J. Appl. Glass Sci. 1(1), 74–86 (2010).
[Crossref]

J. Appl. Phys. (1)

H. Zeghlache, M. Guignard, A. Kudlinski, Y. Quiquempois, G. Martinelli, V. Nazabal, and F. Smektala, “Stabilization of the second-order susceptibility induced in a sulfide chalcogenide glass by thermal poling,” J. Appl. Phys. 101(8), 084905 (2007).
[Crossref]

J. Mater. Sci. (1)

H. Guo, X. Zheng, X. Zhao, G. Gao, Y. Gong, and S. Gu, “Composition dependence of thermally induced second-harmonic generation in chalcohalide glasses,” J. Mater. Sci. 42(16), 6549–6554 (2007).
[Crossref]

J. Non-Cryst. Solids (6)

M. A. Paesler and G. Pfeiffer, “Modeling the structure and photostructural changes in amorphous arsenic sulfide,” J. Non-Cryst. Solids 137–138, 967–972 (1991).
[Crossref]

K. Tanaka and K. Ishida, “Photinduced anisotropic structures in chalcogenide glasses,” J. Non-Cryst. Solids 227–230, 673–676 (1998).
[Crossref]

A. Kolobov, H. Oyanagi, A. Roy, and K. Tanaka, “Role of lone-pair electrons in reversible photostructural changes in amorphous chalcogenides,” J. Non-Cryst. Solids 227–230, 710–714 (1998).
[Crossref]

G. Lucovsky and R. M. Martin, “A molecular model for the vibrational modes in chalcogenide glasses,” J. Non-Cryst. Solids 8–10, 185–190 (1972).
[Crossref]

G. Pfeiffer, M. A. Paesler, and S. C. Agarwal, “Reversible photodarkening of amorphous arsenic chalcogens,” J. Non-Cryst. Solids 130(2), 111–143 (1991).
[Crossref]

K. Shimakawa, T. Kato, and T. Hamagishi, “Acceleration of photodarkening under dc electric field in amorphous As2Se3 films,” J. Non-Cryst. Solids 338–340, 548–551 (2004).
[Crossref]

J. Optoelectron. Adv. Mater. (1)

K. Shimakawa, “Photoinduced Fluidity enhanced by electric field in amorphous chalcogenides,” J. Optoelectron. Adv. Mater. 7(1), 145–151 (2005).

J. Phys. Chem. (1)

A. T. Ward, “Raman spectroscopy of sulfur, sulfur-selenium, and sulfur-arsenic mixtures,” J. Phys. Chem. 72(12), 4133–4139 (1968).
[Crossref]

J. Phys. Chem. Solids (1)

S. Gu, Z. Ma, H. Tao, C. Lin, H. Hu, X. Zhao, and Y. Gong, “Second-harmonic generation in the thermal/electrical poling (100-x)GeS2·x(0.5Ga2S3·0.5CdS) chalcogenide glasses,” J. Phys. Chem. Solids 69(1), 97–100 (2008).
[Crossref]

Nat. Photonics (1)

B. J. Eggleton, B. Luther-Davies, and K. Richardson, “Chalcogenide photonics,” Nat. Photonics 5, 141–148 (2011).

Opt. Express (4)

Opt. Lett. (3)

Opt. Mater. (1)

O. M. Efimov, L. B. Glebov, K. A. Richardson, E. Van Stryland, T. Cardinal, S. H. Park, M. Couzi, and J. L. Bruneel, “Waveguide writing in chalcogenide glasses by a train of femtosecond laser pulses,” Opt. Mater. 17(3), 379–386 (2001).
[Crossref]

Phys. Rev. B (6)

K. Shimakawa, S. Inami, T. Kato, and S. R. Elliott, “Origin of photoindued metastable defects in amorphous chalcogenides,” Phys. Rev. B 46(16), 10062–10069 (1992).
[Crossref]

K. Tanaka, “Photoexpansion in As2S3 glass,” Phys. Rev. B 57(9), 5163–5167 (1998).
[Crossref]

G. Lucovsky, “Optic modes in amorphous As2S3 and As2Se3,” Phys. Rev. B 6(4), 1480–1489 (1972).
[Crossref]

D. Kastrissios, G. Papatheodorou, and S. Yannopoulos, “Vibrational modes in the athermally photoinduced fluidity regime of glassy As2S3,” Phys. Rev. B 64(21), 214203 (2001).
[Crossref]

S. N. Yannopoulos, “Intramolecular structural model for photoinduced plasticity in chalcogenide glasses,” Phys. Rev. B 68(6), 064206 (2003).
[Crossref]

G. Chen, H. Jain, M. Vlcek, and A. Ganjoo, “Photoinduced volume change in arsenic chalcogenides by band-gap light,” Phys. Rev. B 74(17), 174203 (2006).
[Crossref]

Phys. Rev. B Condens. Matter (2)

K. Shimakawa, S. Inami, and S. R. Elliott, “Reversible photoinduced change of photoconductivity in amorphous chalcogenide films,” Phys. Rev. B Condens. Matter 42(18), 11857–11861 (1990).
[Crossref] [PubMed]

C. Y. Yang, M. A. Paesler, and D. E. Sayers, “Measurement of local structural configurations associated with reversible photostructural changes in arsenic trisulfide films,” Phys. Rev. B Condens. Matter 36(17), 9160–9167 (1987).
[Crossref] [PubMed]

Spectrochim. Acta [A] (1)

M. Muniz-Miranda, G. Sbrana, P. Bonazzi, S. Menchetti, and G. Pratesi, “Spectroscopic investigation and normal mode analysis of As4S4 polymorphs,” Spectrochim. Acta [A] 52(11), 1391–1401 (1996).
[Crossref]

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Figures (6)

Fig. 1
Fig. 1 Raman spectra of the arsenic sulfide initial glasses prepared without NaCl doping (AsNa0), with 10ppm (AsNa10) and with 100ppm (AsNa100) of NaCl doping.
Fig. 2
Fig. 2 θ scans measured on samples AsSNa0 (A) and AsSNa100 (B).
Fig. 3
Fig. 3 SHG kinetic measurements for the AsSNa10 poled sample under irradiations @ 1550 nm with 200 µJ and 150 µJ (A) and for poled samples AsSNa0, AsNa10 and AsSNa100 under irradiations @ 1550 nm with 150 µJ (B).
Fig. 4
Fig. 4 (A) Raman spectra of an AsSNa0 sample before and after an irradiation of 30 min @ 752 nm with 10mW. (B) Raman intensity ratio (I@223 cm−1/I@234cm−1) measured during the irradiation process for an initial AsSNa0 sample (up) and a poled AsSNa0 sample.
Fig. 5
Fig. 5 As4S4 molecule transition from realgar-type (A) to pararealgar-type (B) (fig. from [27]).
Fig. 6
Fig. 6 Tentative of molecular model for the photoinduced structural changes in Arsenic rich sulfide glasses.

Equations (1)

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2As-S  -As-As- + -S-S-

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