Near-infrared emission of Yb<sup>3+</sup> through energy transfer from ZnO to Yb<sup>3+</sup> in glass ceramic containing ZnO nanocrystals

Qun Luo; Xvsheng Qiao; Xianping Fan; Xianghua Zhang

doi:10.1364/OL.36.002767

Near-infrared emission of ${Yb}^{3 +}$ through energy transfer from ZnO to ${Yb}^{3 +}$ in glass ceramic containing ZnO nanocrystals

Qun Luo, Xvsheng Qiao, Xianping Fan, and Xianghua Zhang

Optics Letters
Vol. 36,
Issue 15,
pp. 2767-2769
(2011)
•https://doi.org/10.1364/OL.36.002767

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Qun Luo, Xvsheng Qiao, Xianping Fan, and Xianghua Zhang, "Near-infrared emission of Yb³⁺ through energy transfer from ZnO to Yb³⁺ in glass ceramic containing ZnO nanocrystals," Opt. Lett. 36, 2767-2769 (2011)

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Table of Contents Category
- Materials
Optics & Photonics Topics
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The topics in this list come from the OSA Optics and Photonics Topics applied to this article.
Previously assigned OCIS codes
- Glass and other amorphous materials (160.2750)
- Optical properties (160.4760)
- Rare-earth-doped materials (160.5690)
- Spectroscopy, fluorescence and luminescence (300.6280)

About this Article
History
- Original Manuscript: May 19, 2011
- Manuscript Accepted: June 20, 2011
- Published: July 19, 2011

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Abstract

${Yb}^{3 +}$ -doped glass and glass ceramic containing ZnO nanocrystals were prepared by the melting–quenching method and subsequent heat treatment. Intense near-IR emission around $1000 nm$ that originated from the transition of ${Yb}^{3 +} : {}^{2}{F_{5 / 2}} \to {}^{2}{F_{7 / 2}}$ was generated as a result of energy transfer from oxygen interstitials in ZnO nanocrystals to ${Yb}^{3 +}$ with energy transfer efficiency of about 10%. The quantum yield for the near-IR emission of ${Yb}^{3 +}$ under the excitation of $390 nm$ was about 16.7%. These materials have potential application in achieving high-efficiency Si solar cells via spectrum modification.

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