Assignment of methyl alcohol submillimeter laser transitions

T. L. Worchesky

doi:10.1364/OL.3.000232

Optics Letters
Vol. 3,
Issue 6,
pp. 232-234
(1978)
•https://doi.org/10.1364/OL.3.000232

Assignment of methyl alcohol submillimeter laser transitions

T. L. Worchesky

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T. L. Worchesky, "Assignment of methyl alcohol submillimeter laser transitions," Opt. Lett. 3, 232-234 (1978)

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Abstract

Several submillimeter laser transitions of methyl alcohol have been assigned by using combination relations.

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Line	Frequency (cm⁻¹)	Typea	Assigned Transition	Ref.
A	1050.4445	Ab	^QR(10,0,1,0)	1
B	1049.036	Ab	^QR(9,0,1,0)	1
C	1048.890	Ab	^QR(8,0,1,0)	1
D	1047.602	Ab	^QR(9,0,3,1⁺)	1
a	17.52638	Em	1,11,0,1,0 → 1,10,0,1,0b	3
b	8.1722	Em	1,11,0,1,0 → 1,10,0,3,1⁺	3
c	16.1158	Em	1,10,0,1,0, → 1,9,0,1,0	3
d	6.6180	Ab	0,9,0,1,0 → 0,10,0,1,0	2
e	15.9400	Ab	0,9,0,3,1⁺ → 0,10,0,1,0	2
f	14.5076	Ab	0,8,0,1,0 → 0,9,0,1,0	2
—	27.09192	Em	Unassigned	3
—	44.74	Em	Unassigned	3

Line	Frequency (cm⁻¹)	Typea	Assigned Transition	Ref.
A	1045.152	Ab	^QR(6,0,1,1)	1
B	1046.613	Ab	^QR(7,0,1,1)	1
C	1046.369	Ab	^QR(7,0,3,2)	1
D	1044.905	Ab	^QR(6,0,3,2)	1
a	17.79	Em	1,8,0,3,2 → 1,7,0,3,2b	4
b	26.60	Em	1,8,0,3,2 → 1,7,0,1,1	4
c	13.81	Em	1,8,0,3,2 → 1,8,0,1,1	4
d	11.2984	Ab	0,6,0,3,2 → 0,7,0,3,2	2
e	14.1525	Ab	0,7,0,1,1 → 0,7,0,3,2	2
f	11.2939	Ab	0,6,0,1,1 → 0,7,0,1,1	2

Pump Laser	Frequency	Infrared Absorptions	Submillimeter Emission (μm)	Transitiona
⁹P₁₉ CO₂	1044.5913 cm⁻¹	^QR(6,0,3,1⁺)	478.8	1,7,0,3,1⁺ → 1,6,0,1,0
			903.9	1,7,0,3,1⁺ → 1,6,0,3,1⁺
			1052.7	1,7,0,3,1⁺ → 1,7,0,1,0
⁹R₂₀ ¹³C–¹⁸O₂	1040.2432 cm⁻¹	^QR(3,0,3,1⁻)	1540.0	1,4,0,3,1⁻ → 1,3,0,3,1⁻
			2086.0	1,3,0,3,1⁻ → 1,2,0,3,1⁻

Line	Frequency (cm⁻¹)	Typea	Assigned Transition	Ref.
A	1050.4445	Ab	^QR(10,0,1,0)	1
B	1049.036	Ab	^QR(9,0,1,0)	1
C	1048.890	Ab	^QR(8,0,1,0)	1
D	1047.602	Ab	^QR(9,0,3,1⁺)	1
a	17.52638	Em	1,11,0,1,0 → 1,10,0,1,0b	3
b	8.1722	Em	1,11,0,1,0 → 1,10,0,3,1⁺	3
c	16.1158	Em	1,10,0,1,0, → 1,9,0,1,0	3
d	6.6180	Ab	0,9,0,1,0 → 0,10,0,1,0	2
e	15.9400	Ab	0,9,0,3,1⁺ → 0,10,0,1,0	2
f	14.5076	Ab	0,8,0,1,0 → 0,9,0,1,0	2
—	27.09192	Em	Unassigned	3
—	44.74	Em	Unassigned	3

Line	Frequency (cm⁻¹)	Typea	Assigned Transition	Ref.
A	1045.152	Ab	^QR(6,0,1,1)	1
B	1046.613	Ab	^QR(7,0,1,1)	1
C	1046.369	Ab	^QR(7,0,3,2)	1
D	1044.905	Ab	^QR(6,0,3,2)	1
a	17.79	Em	1,8,0,3,2 → 1,7,0,3,2b	4
b	26.60	Em	1,8,0,3,2 → 1,7,0,1,1	4
c	13.81	Em	1,8,0,3,2 → 1,8,0,1,1	4
d	11.2984	Ab	0,6,0,3,2 → 0,7,0,3,2	2
e	14.1525	Ab	0,7,0,1,1 → 0,7,0,3,2	2
f	11.2939	Ab	0,6,0,1,1 → 0,7,0,1,1	2

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