Abstract

Spectroscopic characterization of Fe:ZnSe(Cr:ZnSe) crystals under visible excitation into the charge transfer bands of Transition Metal ions were studied. The excitation efficiencies of mid-IR photoluminescence between 5T2(5E) and 5E(5T2) states via direct relaxation to the upper laser levels and via metastable upper 3T1 were investigated. It was demonstrated that the latter route is the dominant process for Cr2+ ions and could provide sufficient pump rate for mid-IR lasing. The pump efficiencies via direct relaxation to the upper laser levels were estimated to be <2% for both ions under 532 nm excitation wavelength.

© 2015 Optical Society of America

1. Introduction

Tunable middle infrared (mid-IR) lasers are promising for a broad range of applications such as medical diagnosis, remote sensing, and optical communication. Within this class of lasers, the transition metal (TM) doped (e.g. chromium and iron) II-VI (e.g. ZnSe and ZnS) crystals are arguably gain media of choice for the development of broadly tunable laser systems operating at room temperature (RT) over the 2-6 µm spectral range [14].

Cr2+:II-VI lasing has been demonstrated at room temperature in all regimes of operation with tunability over 1.9-3.3 µm range. Continuous wave (CW) output powers exceeding 30W and pulse energies of 1.1 J for free running and 50 mJ for gain-switched operation have been achieved [1]. This was made possible due to favorable spectroscopic characteristics. The tetrahedral crystal field of the II-VI hosts splits the ground level (5D) of Cr2+ into the triplet 5T2 and doublet 5E level. Transitions between these levels are symmetry allowed while transitions to higher lying levels are spin forbidden, resulting in strong gain without excited state absorption. Additionally, while there is some quenching of the lifetime at room temperature, the lifetime remains at the level of several µs and is sufficient to obtain lasing in the CW operational regime. Fe2+:II-VI also exhibits no excited state absorption and lasing has been demonstrated in all regimes of operation over the 3.5-6 µm spectral range with CW power of 1.6 W and pulse energies 2.1 J in free running, and 30 mJ in the gain-switched regime [1]. However, the strong quenching of Fe2+ lifetime at room temperature requires cryogenic systems to operate in all regimes except gain-switching, which has been demonstrated at room temperature.

The current prevailing excitation method for these lasers is intra-band optical excitation in the broad absorption bands of Cr2+ and Fe2+ ions centered at 1.8 µm and 3 µm, respectively. This enables a set of available pump sources in the case of Cr2+ (Er, Tm, Ho lasers) and only a few for Fe2+. Our recent work has been directed at extending the range of available avenues of excitation for these ions and we have demonstrated lasing with low pulse energy in Co:Fe:ZnSe and Co:Fe:ZnS through Co2+→Fe2+ energy transfer [5,6].

The focus of the current research is to extend the available pump source through the study of the relaxation of TM2+ ions subsequent to excitation into the charge transfer band. The introduction of chromium or iron into the lattice of ZnSe or ZnS wide bandgap semiconductors is accompanied by the formation of a charge transfer band in the bandgap. This results in strong visible absorption at wavelengths just above those corresponding to photon energies of 2.7 and 3.5 eV for ZnS and ZnSe, respectively. Previously, charge transfer processes of iron and chromium doped ZnSe/ZnS were studied using EPR and spectroscopic methods [714]. An understanding of the relaxation process under visible excitation in Cr2+ and Fe2+ ZnSe/ZnS crystals cannot only provide an alternative pumping method in the form of optical excitation, but also a better understanding of processes that could lead to the development of a new type of solid-state lasers with electrical pumping.

2. Experimental details

The polycrystalline samples utilized in these experiments were produced by thermal diffusion of transition metal ions into bulk II-VI hosts. A thin film of chromium or iron was deposited on the surface of ZnSe optical windows, which were then sealed in quartz ampoules under vacuum (~10−5 Torr) and annealed in a furnace at high temperature for several days to promote thermal diffusion from the facets to the crystal volume. The annealing temperature and exposure time have been carefully adjusted for each dopant to provide minimal distribution gradient while maintaining high crystal quality. Three samples were examined in this study. One low concentration Cr:ZnSe (NCr = 2.7 × 1018 cm−3) was used only for absorption measurements. All other experiments were carried out with Fe:ZnSe and Cr:ZnSe samples with concentrations typical for use as gain elements (NFe = 1.4 × 1019 cm−3 and NCr = 8.2 × 1018 cm−3 respectively). The concentration dependence of the photoluminescence (PL) in Cr:ZnSe and Fe:ZnSe were previously reported [15,16]. These studies demonstrated concentration quenching of the RT PL in Cr doped samples with concentration higher than 1019 cm−3 [16]. In iron doped samples the nonradiative relaxation processes at RT are more pronounced in comparison with chromium doped samples and the influence of iron concentration becomes apparent for concentrations larger than 5 × 1019 cm−3 [15] (see [15,16] for more detail). In our experiments we focused our study on samples with TM concentrations usually used for mid-IR laser oscillation.

The absorption spectra were measured at room temperature using Shimadzu UV-VIS-NIR-3101PC and FTIR spectrophotometers.

The excitation sources used for photoluminescence spectra and kinetics measurements were a Spectra-Physics Quanta-Ray Nd:YAG laser and MOPO system as well as an electro-optically Q-switched Cr:Er:YSGG laser.

Emission spectra were obtained by collecting PL radiation with a CaF2 lens and directing into a monochromator, with the signal detected by either Thorlabs PDA20H PbSe detector (λ = 1.5-4.8 µm) or photomultiplier tube (λ<1.2 µm) and signal processing performed with the aid of a Stanford Research Systems boxcar integrator and Acton Research Corporation spectral measurement system. PL kinetics were measured using three detectors; liquid nitrogen cooled InSb detector, VIGO Systems PVI-3TE-6 (HgCdTe) detector sensitive over the 2-12 μm range with response time < 200 ns, and Hamamatsu R406 Ag-O-Cs photomultiplier tube with sensitivity over the 0.4-1.1 μm range and 2 ns rise time for near infrared. Spectra were adjusted for detector sensitivity using Newport 6575 (mid-IR) and Oriel 63358 (near-IR) calibration lamps.

3. Experimental results and discussions

3.1 Fe:ZnSe samples

Energy level structure of the Fe2+(3d6) is shown in Fig. 1(a). The 5D ground states of the Fe2+ in the tetrahedral crystal field (Td) of ZnSe crystal are split into the doublet 5E (ground state) and triplet 5T2, (first excited state), respectively. The absorption and emission bands at the laser active 5E↔5T2 transition in Fe:ZnSe crystals are shown in Fig. 1(b). As one can see, the RT absorption and emission spectra of Fe2+ reveal broad bands between 2.5 and 4.0 μm and 3.5-5.0 μm, respectively. The RT luminescence lifetime was measured to be 380 ns, while radiative lifetime at this transition was estimated at τrad = 57 μs [15]. The short upper level life-time applies restrictions on the excitation rate for laser application. That is why these crystals could efficiently oscillate in gain-switched regime at RT, but require cooling for effective CW lasing. The remaining transitions from 5D sub-levels are spin forbidden. Near IR emission and absorption bands around ~1μm were attributed to the 5E(5D)↔3T1 (3H) transition of the Fe2+ ions in the II-VI semiconductors [13,17,18].

 figure: Fig. 1

Fig. 1 A. Energy levels of Fe2+ and energy transfer mechanisms. B. Cross-sections of near-IR and mid-IR transitions in Fe:ZnSe.

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As mentioned in the introduction, one of the research goals was to study the dynamics of excitation of the upper laser level (5T2(5D)) under excitation into the charge transfer band in Fe:ZnSe crystals. Figure 2 shows absorption of the undoped ZnSe crystal and Fe:ZnSe crystal with iron concentration NFe = 1.4 × 1019 cm−3 in the visible spectral range. As one can see from the Fig. 2, the absorption coefficient in the charge transfer band near 532nm is ~4 cm−1. This absorption coefficient is ~3 times smaller than for the direct excitation at 5E↔5T2 transition for the same crystal; however this value is sufficient for efficient absorption for longitudinal laser pumping.

 figure: Fig. 2

Fig. 2 A. Absorption spectra of undoped (i), iron doped (ii), and chromium doped (iii) ZnSe (NFe = 1.4 × 1019 cm−3, NCr = 2.7 × 1018 cm−3) crystals near band-gap, B. Zoom-in to show absorption of Fe:ZnSe near 532 nm.

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There are several relaxation processes which could populate the upper laser level after excitation into charge transfer band (see Fig. 1(a)). The fastest process is direct non-radiative relaxation from the excited complex (Fe3+ + e)* to the upper laser level 3T2 (5D) [13]. This relaxation process should be very fast (~10-100 ps) in comparison with upper level life time (380 ns). The second excitation route could involve cascade relaxation through higher levels of Fe2+ ions. The bottleneck for these relaxation processes could be long lifetime of meta-stable levels. The likely candidate for this bottleneck level is the 3T1(3H) state. In this case, the relaxation time could vary from μs to ms time scale resulting in a process that is too slow to provide effective inversion population at 3T2 (5D) level. Finally, the slowest process could result from ionization of Fe2+ ions. In this case the electron excited to the conduction band is localized at the shallow donor (or donor-accepter pair). These ionization processes were thoroughly studied using EPR [13,19]. The variation of the distances between iron ions and shallow donor (or donor-acceptor pair) results in a significant decrease of the relaxation rate. For example, Auger type recombination for the Cr1+→Cr2+ process in ZnSe crystals featuring characteristic non exponential decay with time constant of 12 sec at 78K was discussed in [14] and the decay of the EPR signal Fe3+ has been measured to be longer than tens of seconds at 100K in [20].

To study the possible excitation mechanisms of the upper laser level we measured near IR and mid-IR kinetics of the photo-luminescence under direct excitation and excitation into the charge transfer band. Figure 3(a) shows decay of the mid-IR PL at 5T25E transition in Fe:ZnSe crystal at RT under 2.78 μm (curve ii) and 0.532 μm (curve i) excitation. In our experiments with detector response time of ~40 ns we did not measure any slow rise-time of the mid-IR PL under green excitation. This is indicative of fast non-radiative relaxation from the excited complexes (Fe3+ + e)* to the upper laser level 5T2. Additional evidence for this process is also the fact that initial decay rates of the mid-IR signal under visible and direct excitation coincide. However, decay of the mid-IR PL signal reveals essentially non-exponential behavior. The curve (iii) in Fig. 3(b) shows the decay of the PL over long time-scale. For comparison, the near-IR PL at 950 nm with decay time 49 μs is also depicted in the Fig. 3(b) (curve iv). As one can see from the Fig. 3(b) the decay tail of PL signal under green excitation at ~100 μs time scale could result from cascade relaxation via 3T1 level. Additional evidence for this relaxation channel is documented in the literature luminescence signal ~1.4 μm at low temperature associated with the 3T1(3H)→5T2(5D) transition [18]. However, as one can see from Fig. 3(b), there is an excitation channel with characteristic time which is longer than the lifetime of 3T1(3H) level. This channel could be attributed to ionization transitions of iron ions. To estimate radiatave lifetime of the 3T1(3H)→5T2(5D) transition we measured kinetic at 970 nm at T = 20K. The exponential decay time was measured to be 390 μs. The maximum cross-section can be estimated using the formula of McCumber [21,22]:

σmax=ln2πA4πcn2λ04Δλ
Where λ0 is the peak emission wavelength, Δλ is the full width at half maximum, n is the refractive index, A = 1/τ is Einstein’s coefficient of spontaneous emission for radiative lifetime τ. We estimated the maximum RT emission cross-section of the 3T1(3H)→5T2(5D) transition to be 0.4 × 10−20 cm2 (see Fig. 1(b)).

 figure: Fig. 3

Fig. 3 A. Short PL kinetics of Fe:ZnSe under i) 532nm excitation and ii) 2780nm excitation. B. Long PL kinetics of Fe:ZnSe showing iii) mid-IR kinetics under 532nm excitation and iv) near-IR PL at 950nm.

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To estimate pump energy required for mid-IR lasing under green excitation we compared the PL signal under green and direct mid-IR excitation under the same experimental conditions and normalized PL signal to the absorbed energy. The total number of the excited ions is proportional to area under PL decay curve. However, for lasing excitation, only fast excitation rate (during time scale < τ = 380 ns) could provide effective population at upper laser level. Therefore, one must compare area under the kinetics during the 380 ns period after excitation. We mentioned previously that initial decay rate under green excitation and under direct mid-IR excitation is similar, and area under these curves will be proportional to the signal amplitudes. In our experiments, the PL signal with amplitude 147 mV was measured under 50μJ of absorbed energy at 2.78 μm; while the PL signal with amplitude 27 mV was measured under 1.7mJ of absorbed energy at 0.53 μm. From these data, the estimated pump energy for green excitation should be approximately 185 times larger under the same geometry and direct excitation.

Figure 4 depicts dependence of the mid-IR PL signal on pump energy density. Deviation from linear dependence was observed under high energy density excitation. The nonlinear behavior indicates existence of two-photon or two-step processes which can result in reduction of the excitation efficiency. To summarize the observations pertaining to Fe:ZnSe, we see that in spite of the fast relaxation rate for the excitation of the 5T2 level of Fe2+ ions under excitation into charge transfer band, the efficiency of this excitation is ~2% from absorbed photons. Considering that the RT laser threshold of Fe:ZnSe in the gain switched regime was demonstrated at ~1mJ, the estimated laser threshold under green excitation could be as much as 200 mJ. This could potentially be realized by using longer gain elements or multiple crystals in a cavity to reach laser threshold while avoiding optical damage.

 figure: Fig. 4

Fig. 4 Dependence of PL signal on energy of excitation for i) Fe:ZnSe and ii) Cr:ZnSe.

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3.2 Cr:ZnSe samples

Cr2+(3d4) ions have similar energy structure to Fe2+ ions, however the triplet 3T2 is the ground level and the doublet 5E is the first existed state level (see Fig. 5(a)). The laser transition between these levels is shifted to shorter wavelengths between 2 and 3.3 μm. Also the luminescence yield is 100% at RT with radiative lifetime 6.5 μs. The Cr2+ ions reveal stronger charge transfer band in comparison with Fe2+ ions (see Fig. 2(a)). The absorption coefficient at 590 nm has the same value as the maximum absorption coefficient under direct excitation at laser transitions between 3T2 and 5E levels. The high absorption cross section at 532 nm compared with mid-IR emission cross section necessitates transverse pump geometry.

 figure: Fig. 5

Fig. 5 A. Energy levels of Cr2+ and energy transfer mechanisms. B. Cross-sections of near-IR and mid-IR transitions in Cr:ZnSe

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In our experiments we studied kinetics of the PL signal in Cr:ZnSe under 532 nm excitation at 3T15T2 and 5E→5T2 transitions. The measured RT near-IR PL band at the 3T15T2 transition is similar to that in Fe:ZnSe between 880 and 1040 nm [2326]. However, the measured RT kinetics at 950 nm reveals single exponential decay with lifetime τ = 2.8 μs. We also observed rise time behavior with maximum signal ~500 ns after excitation pulse which could be explained by cascade relaxation from a higher-lying level to the 3T1 level. The radiative lifetime of the 3T15T2 transition was estimated using the decay time of the near-IR PL kinetics at low temperature (20K) of 1.7 ms. Using the formula of McCumber [21,22] we estimated the maximum RT emission cross-section of the 3T1(3H)→5T2(5D) transition to be 0.8 × 10−21 cm2 (see Fig. 5(b)). It is important to note that these results show that at room temperature the 3T1 level is quenched and the lifetime of the 3T1 (2.8 μs) level is shorter than that of the upper laser level 5E (6.5 μs). It is for this reason that the excitation route through 3T1 could be used for laser excitation.

Intra-shell excitation of Cr:ZnSe by 1560nm radiation results in short rise time of mid-IR PL kinetics with measurement limited by the sensitivity of the detection system followed by exponential decay with lifetime ~6μs. Excitation into the charge transfer band is followed by a delay in mid-IR PL kinetics rise time with the peak occurring at several μs after excitation. 532nm nanosecond scale pulsed excitation results in rise time in the PL kinetics of ~3.5 μs. This rise time is very close to the life-time of the 3T1 level. This suggests that the dominant excitation process to the 5E level involves cascade relaxation from higher excited levels. The fast components of the direct excitation of the 5E level could be seen only at low temperature when transition from 3T1 level is “frozen”. The efficiency of the fast excitation processes in comparison with relaxations via 3T1 level could be estimated by comparing the area under the fast and slow component of mid-IR kinetics. Calculations show that at low temperature excitation via 3T1 level is responsible for 98% of 5E level inversion under green excitation.

The dependence of the PL signal on pump energy density is shown in Fig. 4 (curve ii). The decrease of the excitation efficiency is clearly seen for energy density >0.2 mJ/cm2. The efficiency of excitation differs greatly with intensity of the 532nm pump, with ~100% efficiency measured under CW excitation and ~14% quantum efficiency measured under 10ns pulsed excitation with energy density of 7.7mJ/cm2. As previously stated, the higher peak power of pump pulses can enable additional channels for absorption of pump radiation such as two-step (Eq. (2)) or two-photon (Eq. (3)) processes:

Cr2++ωCr++h+followedbyCr++ω(Cr2+)*+e,or
Cr2++2ω(Cr+)*+(h+)*
where h+ denotes a positive charge carrier (hole), e- an electron, Cr2+ and Cr+ are ionization states of chromium. The asterisk (e.g. (Cr2+)* and (Cr+)*) denotes highly excited states.

The observed increase of the rise time of the mid-IR kinetics from 3.5 μs to ~10 μs delay measured under excitation by 35 ps pulses at 532 nm excitation (see Fig. 6 curve iii) in comparison with ns excitation could be explained by including slow relaxation processes under high power excitation.

 figure: Fig. 6

Fig. 6 A. Normalized PL kinetics of Cr:ZnSe illustrating rise time under i) intra-shell excitation at 1560nm, ii) 532nm nanosecond scale excitation, iii) 532nm picosecond scale excitation, and iv) Cr:ZnSe PL kinetics at 960nm under 532nm ns scale excitation. B. Lasing of Cr:ZnSe under 532nm 10ns pulsed excitation showing three pulses under 9.1mJ pump energy, with insert showing the averaged signal under 6.7mJ pump energy.

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The quenching of the 3T1 level to the value below lifetime of the 5E level at RT allows the use of this excitation route for laser applications. Cr:ZnSe lasing experiments were performed with transverse pumping geometry in an optical cavity composed of a gold back mirror with 5cm radius of curvature and a planar output coupler. The 532 nm radiation was focused into a line along the cavity axis with a cylindrical lens. The crystal used was 8.5mm long with chromium concentration of 8.2 × 1018 cm−3 and AR coated at laser wavelength. The results of these lasing experiments are shown in Fig. 6(b). Three laser pulses are visible in the kinetics beginning ~4μs after excitation, which are the result of slow accumulation of population in the upper laser level after excitation to higher lying levels. When this population reaches threshold, lasing depletes the population quickly allowing subsequent repopulation and lasing. This long timescale repopulation of the upper laser level produces pulse trains similar to free running. The graph insert in Fig. 6(b) shows lasing slightly above threshold to illustrate the timing of the lasing spike relative to the luminescence. The lasing was confirmed by shortening of the kinetics behavior and narrowing of the measured spectra. Unfortunately, the laser threshold was very close to the optical damage threshold of the Cr:ZnSe crystal, precluding measurement of the input-output characteristics.

4. Conclusions

Analysis of the mid IR luminescence of Fe2+ and Cr2+ ions in ZnSe under visible excitation allowed estimation of the excitation efficiency of the upper laser level. The near-IR emission cross sections from 3T1 levels were estimated to be 0.8 × 10−21 cm2 and 0.4 × 10−20 cm2 at RT for Cr2+ and Fe2+ ions, correspondingly. The efficiency of the fast non-radiative relaxation to the upper laser level for both ions was estimated to be not more than ~2% from absorbed energy of ns excitation pulses. However in Cr2+ ions the cascade relaxation over 3T1 level exhibits lifetime of 2.8 µs which is shorter than that of the upper laser level (6.5 μs) and could therefore provide pumping rate sufficient for laser operation. The similar excitation route for Fe2+ ions has relaxation time ~50 µs which is significantly longer than the lifetime of the upper level at RT (380 ns). This results in an estimated pump threshold under 532nm excitation of 185 times that of 2.78μm excitation, making this excitation method more susceptible to optical damage. One way to potentially increase efficiency of pumping under visible excitation would be the utilization of cross-relaxation processes in highly doped crystals, which is a subject for future investigation.

Acknowledgments

The authors would like to acknowledge funding support from the AF Office of Scientific Research (Award No. FA9550-13-1-0234), and the National Science Foundation under grant EPS-0814103. The work reported here partially involves intellectual property developed at the University of Alabama at Birmingham (UAB). This intellectual property has been licensed to the IPG Photonics Corporation. Drs. Fedorov and Mirov declare competing financial interests.

References and links

1. S. Mirov, V. Fedorov, D. Martyshkin, I. Moskalev, M. Mirov, and S. Vasilyev, “Progress in mid-IR lasers based on Cr and Fe doped II-VI chalcogenides,” IEEE J. Sel. Top. Quantum Electron. 21(1), 1601719 (2015). [CrossRef]  

2. S. B. Mirov, V. V. Fedorov, D. V. Martyshkin, I. S. Moskalev, M. S. Mirov, and V. P. Gapontsev, “Progress in mid-IR Cr2+ and Fe2+ doped II-VI materials and lasers [Invited],” Opt. Mater. Express 1(5), 898–910 (2011). [CrossRef]  

3. S. Mirov, V. Fedorov, I. S. Moskalev, D. Martyshkin, and C. Kim, “Progress in Cr2+ and Fe2+ doped mid-IR laser materials,” Laser Photonics Rev. 4(1), 21–41 (2010). [CrossRef]  

4. V. I. Kozlovsky, V. A. Akimov, M. P. Frolov, Yu. V. Korostelin, A. I. Landman, V. P. Martovitsky, V. V. Mislavskii, Y. P. Podmar’kov, Y. K. Skasyrsky, and A. A. Voronov, “Room-temperature tunable mid-infrared lasers on transition-metal doped II–VI compound crystals grown from vapor phase,” Phys. Status Solidi B 247(6), 1553–1556 (2010). [CrossRef]  

5. N. Myoung, D. V. Martyshkin, V. V. Fedorov, and S. B. Mirov, “Mid-IR lasing of iron–cobalt co-doped ZnS(Se) crystals via Co–Fe energy transfer,” J. Lumin. 133, 257–261 (2013). [CrossRef]  

6. J. Peppers, N. Myoung, V. V. Fedorov, and S. B. Mirov, “Mid-IR laser oscillation via energy transfer in the Co:Fe:ZnS/Se co-doped crystals,” Proc. SPIE 8235, 823503 (2012). [CrossRef]  

7. V. V. Fedorov, A. Gallian, I. Moskalev, and S. B. Mirov, “En route to electrically pumped broadly tunable middle infrared lasers based on transition metal doped II–VI semiconductors,” J. Lumin. 125(1–2), 184–195 (2007). [CrossRef]  

8. C. I. Rablau, “Photoluminescence and optical absorption spectroscopy of infrared materials Cr2+:Znse and ZnGeP2,” Ph.D. dissertation, West Virginia University, Morgantown, West Virginia (1999).

9. M. Surma, A. J. Zakrzewski, and M. Godlewski, “Nonradiative recombination processes in nickel- and iron-doped ZnS and ZnSe studied by photoinduced electron-spin resonance,” Phys. Rev. B Condens. Matter 52(16), 11879–11883 (1995). [CrossRef]   [PubMed]  

10. V. Yu. Ivanov, Y. G. Semenov, M. Surma, and M. Godlewski, “Anti-Stokes luminescence in chromium-doped ZnSe,” Phys. Rev. B Condens. Matter 54(7), 4696–4701 (1996). [CrossRef]   [PubMed]  

11. M. Godlewski, “On the application of the photo-EPR technique to the studies of photoionization, DAP recombination, and non-radiative recombination processes,” Phys. Status Solidi A 90(1), 11–52 (1985). [CrossRef]  

12. J. Kreissl and H.-J. Schulz, “Transition-metal impurities in II-VI semiconductors: characterization and switching of charge states,” J. Cryst. Growth 161(1–4), 239–249 (1996). [CrossRef]  

13. M. Godlewski and M. Skowronski, “Effective deactivation of the ZnS visible photoluminescence by iron impurities,” Phys. Rev. B Condens. Matter 32(6), 4007–4013 (1985). [CrossRef]   [PubMed]  

14. V. V. Fedorov, T. Konak, J. Dashdorj, M. E. Zvanut, and S. B. Mirov, “Optical and EPR spectroscopy of Zn:Cr:ZnSe and Zn:Fe:ZnSe crystals,” Opt. Mater. 37, 262–266 (2014). [CrossRef]  

15. N. Myoung, V. V. Fedorov, S. B. Mirov, and L. E. Wenger, “Temperature and concentration quenching of mid-IR photoluminescence in iron doped ZnSe and ZnS laser crystals,” J. Lumin. 132(3), 600–606 (2012). [CrossRef]  

16. A. Burger, K. Chattopadhyay, J. O. Ndap, X. Ma, S. H. Morgan, C. I. Rablau, C. H. Su, S. Feth, R. H. Page, K. I. Schaffers, and S. A. Payne, “Preparation conditions of chromium doped ZnSe and their infrared luminescence properties,” J. Cryst. Growth 225(2-4), 249–256 (2001). [CrossRef]  

17. M. Skowronski, Z. Liro, and W. Palosz, “Uniaxial stress effect on no-phonon lines of 3T1 to 5E transitions in ZnS:Fe,” J. Phys. Chem. 18(26), 5099–5110 (1985).

18. K. P. O’Donnell, K. M. Lee, and G. D. Watkins, “An ODMR study of a luminescence excitation process in ZnSe:Fe,” J. Phys. Chem. 16(20), L723 (1983).

19. A. Zakrzewski and M. Godlewski, “Direct evidence of three-center-Auger recombination processes in ZnS:Cu,Fe,” Phys. Rev. B Condens. Matter 34(12), 8993–8995 (1986). [CrossRef]   [PubMed]  

20. K. Swiatek, M. Godlewski, and T. P. Surkova, “Fe photoionization transitions in ZnSSe:Fe crystals – photo-ESR studies,” Phys. Status Solidi C 2(3), 1224–1227 (2005). [CrossRef]  

21. F. Träger, Springer Handbook of Lasers and Optics, (Springer Science + Business Media, 2007).

22. S. Kück, “Laser-related spectroscopy of ion-doped crystals for tunable solid-state lasers,” Appl. Phys. B 72(5), 515–562 (2001). [CrossRef]  

23. C. I. Rablau, J. O. Ndap, X. Ma, A. Burger, and N. C. Giles, “Absorption and photoluminescence spectroscopy of diffusion-doped ZnSe:Cr2+,” J. Electron. Mater. 28(6), 678–682 (1999). [CrossRef]  

24. M. U. Lehr, B. Litzenburger, J. Kreiss, U. W. Pohl, H. R. Selber, H.-J. Schulz, A. Klimakow, and L. Worschech, “Identification of near-infrared Cr2+ luminescence in ZnSe,” J. Phys. Condens. Matter 9(3), 753–763 (1997). [CrossRef]  

25. V. Yu. Ivanov, M. Godlewski, and T. Gregorkiewicz, “Two-colour spectroscopy of ZnSe:Cr,” Phys. Status Solidi B 244(5), 1618–1622 (2007). [CrossRef]  

26. G. Grebe, G. Roussos, and H.-J. Schulz, “Cr2+ excitation levels in ZnSe and ZnS,” J. Phys. Chem. 9(24), 4511–4516 (1976).

References

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  1. S. Mirov, V. Fedorov, D. Martyshkin, I. Moskalev, M. Mirov, and S. Vasilyev, “Progress in mid-IR lasers based on Cr and Fe doped II-VI chalcogenides,” IEEE J. Sel. Top. Quantum Electron. 21(1), 1601719 (2015).
    [Crossref]
  2. S. B. Mirov, V. V. Fedorov, D. V. Martyshkin, I. S. Moskalev, M. S. Mirov, and V. P. Gapontsev, “Progress in mid-IR Cr2+ and Fe2+ doped II-VI materials and lasers [Invited],” Opt. Mater. Express 1(5), 898–910 (2011).
    [Crossref]
  3. S. Mirov, V. Fedorov, I. S. Moskalev, D. Martyshkin, and C. Kim, “Progress in Cr2+ and Fe2+ doped mid-IR laser materials,” Laser Photonics Rev. 4(1), 21–41 (2010).
    [Crossref]
  4. V. I. Kozlovsky, V. A. Akimov, M. P. Frolov, Yu. V. Korostelin, A. I. Landman, V. P. Martovitsky, V. V. Mislavskii, Y. P. Podmar’kov, Y. K. Skasyrsky, and A. A. Voronov, “Room-temperature tunable mid-infrared lasers on transition-metal doped II–VI compound crystals grown from vapor phase,” Phys. Status Solidi B 247(6), 1553–1556 (2010).
    [Crossref]
  5. N. Myoung, D. V. Martyshkin, V. V. Fedorov, and S. B. Mirov, “Mid-IR lasing of iron–cobalt co-doped ZnS(Se) crystals via Co–Fe energy transfer,” J. Lumin. 133, 257–261 (2013).
    [Crossref]
  6. J. Peppers, N. Myoung, V. V. Fedorov, and S. B. Mirov, “Mid-IR laser oscillation via energy transfer in the Co:Fe:ZnS/Se co-doped crystals,” Proc. SPIE 8235, 823503 (2012).
    [Crossref]
  7. V. V. Fedorov, A. Gallian, I. Moskalev, and S. B. Mirov, “En route to electrically pumped broadly tunable middle infrared lasers based on transition metal doped II–VI semiconductors,” J. Lumin. 125(1–2), 184–195 (2007).
    [Crossref]
  8. C. I. Rablau, “Photoluminescence and optical absorption spectroscopy of infrared materials Cr2+:Znse and ZnGeP2,” Ph.D. dissertation, West Virginia University, Morgantown, West Virginia (1999).
  9. M. Surma, A. J. Zakrzewski, and M. Godlewski, “Nonradiative recombination processes in nickel- and iron-doped ZnS and ZnSe studied by photoinduced electron-spin resonance,” Phys. Rev. B Condens. Matter 52(16), 11879–11883 (1995).
    [Crossref] [PubMed]
  10. V. Yu. Ivanov, Y. G. Semenov, M. Surma, and M. Godlewski, “Anti-Stokes luminescence in chromium-doped ZnSe,” Phys. Rev. B Condens. Matter 54(7), 4696–4701 (1996).
    [Crossref] [PubMed]
  11. M. Godlewski, “On the application of the photo-EPR technique to the studies of photoionization, DAP recombination, and non-radiative recombination processes,” Phys. Status Solidi A 90(1), 11–52 (1985).
    [Crossref]
  12. J. Kreissl and H.-J. Schulz, “Transition-metal impurities in II-VI semiconductors: characterization and switching of charge states,” J. Cryst. Growth 161(1–4), 239–249 (1996).
    [Crossref]
  13. M. Godlewski and M. Skowronski, “Effective deactivation of the ZnS visible photoluminescence by iron impurities,” Phys. Rev. B Condens. Matter 32(6), 4007–4013 (1985).
    [Crossref] [PubMed]
  14. V. V. Fedorov, T. Konak, J. Dashdorj, M. E. Zvanut, and S. B. Mirov, “Optical and EPR spectroscopy of Zn:Cr:ZnSe and Zn:Fe:ZnSe crystals,” Opt. Mater. 37, 262–266 (2014).
    [Crossref]
  15. N. Myoung, V. V. Fedorov, S. B. Mirov, and L. E. Wenger, “Temperature and concentration quenching of mid-IR photoluminescence in iron doped ZnSe and ZnS laser crystals,” J. Lumin. 132(3), 600–606 (2012).
    [Crossref]
  16. A. Burger, K. Chattopadhyay, J. O. Ndap, X. Ma, S. H. Morgan, C. I. Rablau, C. H. Su, S. Feth, R. H. Page, K. I. Schaffers, and S. A. Payne, “Preparation conditions of chromium doped ZnSe and their infrared luminescence properties,” J. Cryst. Growth 225(2-4), 249–256 (2001).
    [Crossref]
  17. M. Skowronski, Z. Liro, and W. Palosz, “Uniaxial stress effect on no-phonon lines of 3T1 to 5E transitions in ZnS:Fe,” J. Phys. Chem. 18(26), 5099–5110 (1985).
  18. K. P. O’Donnell, K. M. Lee, and G. D. Watkins, “An ODMR study of a luminescence excitation process in ZnSe:Fe,” J. Phys. Chem. 16(20), L723 (1983).
  19. A. Zakrzewski and M. Godlewski, “Direct evidence of three-center-Auger recombination processes in ZnS:Cu,Fe,” Phys. Rev. B Condens. Matter 34(12), 8993–8995 (1986).
    [Crossref] [PubMed]
  20. K. Swiatek, M. Godlewski, and T. P. Surkova, “Fe photoionization transitions in ZnSSe:Fe crystals – photo-ESR studies,” Phys. Status Solidi C 2(3), 1224–1227 (2005).
    [Crossref]
  21. F. Träger, Springer Handbook of Lasers and Optics, (Springer Science + Business Media, 2007).
  22. S. Kück, “Laser-related spectroscopy of ion-doped crystals for tunable solid-state lasers,” Appl. Phys. B 72(5), 515–562 (2001).
    [Crossref]
  23. C. I. Rablau, J. O. Ndap, X. Ma, A. Burger, and N. C. Giles, “Absorption and photoluminescence spectroscopy of diffusion-doped ZnSe:Cr2+,” J. Electron. Mater. 28(6), 678–682 (1999).
    [Crossref]
  24. M. U. Lehr, B. Litzenburger, J. Kreiss, U. W. Pohl, H. R. Selber, H.-J. Schulz, A. Klimakow, and L. Worschech, “Identification of near-infrared Cr2+ luminescence in ZnSe,” J. Phys. Condens. Matter 9(3), 753–763 (1997).
    [Crossref]
  25. V. Yu. Ivanov, M. Godlewski, and T. Gregorkiewicz, “Two-colour spectroscopy of ZnSe:Cr,” Phys. Status Solidi B 244(5), 1618–1622 (2007).
    [Crossref]
  26. G. Grebe, G. Roussos, and H.-J. Schulz, “Cr2+ excitation levels in ZnSe and ZnS,” J. Phys. Chem. 9(24), 4511–4516 (1976).

2015 (1)

S. Mirov, V. Fedorov, D. Martyshkin, I. Moskalev, M. Mirov, and S. Vasilyev, “Progress in mid-IR lasers based on Cr and Fe doped II-VI chalcogenides,” IEEE J. Sel. Top. Quantum Electron. 21(1), 1601719 (2015).
[Crossref]

2014 (1)

V. V. Fedorov, T. Konak, J. Dashdorj, M. E. Zvanut, and S. B. Mirov, “Optical and EPR spectroscopy of Zn:Cr:ZnSe and Zn:Fe:ZnSe crystals,” Opt. Mater. 37, 262–266 (2014).
[Crossref]

2013 (1)

N. Myoung, D. V. Martyshkin, V. V. Fedorov, and S. B. Mirov, “Mid-IR lasing of iron–cobalt co-doped ZnS(Se) crystals via Co–Fe energy transfer,” J. Lumin. 133, 257–261 (2013).
[Crossref]

2012 (2)

J. Peppers, N. Myoung, V. V. Fedorov, and S. B. Mirov, “Mid-IR laser oscillation via energy transfer in the Co:Fe:ZnS/Se co-doped crystals,” Proc. SPIE 8235, 823503 (2012).
[Crossref]

N. Myoung, V. V. Fedorov, S. B. Mirov, and L. E. Wenger, “Temperature and concentration quenching of mid-IR photoluminescence in iron doped ZnSe and ZnS laser crystals,” J. Lumin. 132(3), 600–606 (2012).
[Crossref]

2011 (1)

2010 (2)

S. Mirov, V. Fedorov, I. S. Moskalev, D. Martyshkin, and C. Kim, “Progress in Cr2+ and Fe2+ doped mid-IR laser materials,” Laser Photonics Rev. 4(1), 21–41 (2010).
[Crossref]

V. I. Kozlovsky, V. A. Akimov, M. P. Frolov, Yu. V. Korostelin, A. I. Landman, V. P. Martovitsky, V. V. Mislavskii, Y. P. Podmar’kov, Y. K. Skasyrsky, and A. A. Voronov, “Room-temperature tunable mid-infrared lasers on transition-metal doped II–VI compound crystals grown from vapor phase,” Phys. Status Solidi B 247(6), 1553–1556 (2010).
[Crossref]

2007 (2)

V. V. Fedorov, A. Gallian, I. Moskalev, and S. B. Mirov, “En route to electrically pumped broadly tunable middle infrared lasers based on transition metal doped II–VI semiconductors,” J. Lumin. 125(1–2), 184–195 (2007).
[Crossref]

V. Yu. Ivanov, M. Godlewski, and T. Gregorkiewicz, “Two-colour spectroscopy of ZnSe:Cr,” Phys. Status Solidi B 244(5), 1618–1622 (2007).
[Crossref]

2005 (1)

K. Swiatek, M. Godlewski, and T. P. Surkova, “Fe photoionization transitions in ZnSSe:Fe crystals – photo-ESR studies,” Phys. Status Solidi C 2(3), 1224–1227 (2005).
[Crossref]

2001 (2)

S. Kück, “Laser-related spectroscopy of ion-doped crystals for tunable solid-state lasers,” Appl. Phys. B 72(5), 515–562 (2001).
[Crossref]

A. Burger, K. Chattopadhyay, J. O. Ndap, X. Ma, S. H. Morgan, C. I. Rablau, C. H. Su, S. Feth, R. H. Page, K. I. Schaffers, and S. A. Payne, “Preparation conditions of chromium doped ZnSe and their infrared luminescence properties,” J. Cryst. Growth 225(2-4), 249–256 (2001).
[Crossref]

1999 (1)

C. I. Rablau, J. O. Ndap, X. Ma, A. Burger, and N. C. Giles, “Absorption and photoluminescence spectroscopy of diffusion-doped ZnSe:Cr2+,” J. Electron. Mater. 28(6), 678–682 (1999).
[Crossref]

1997 (1)

M. U. Lehr, B. Litzenburger, J. Kreiss, U. W. Pohl, H. R. Selber, H.-J. Schulz, A. Klimakow, and L. Worschech, “Identification of near-infrared Cr2+ luminescence in ZnSe,” J. Phys. Condens. Matter 9(3), 753–763 (1997).
[Crossref]

1996 (2)

V. Yu. Ivanov, Y. G. Semenov, M. Surma, and M. Godlewski, “Anti-Stokes luminescence in chromium-doped ZnSe,” Phys. Rev. B Condens. Matter 54(7), 4696–4701 (1996).
[Crossref] [PubMed]

J. Kreissl and H.-J. Schulz, “Transition-metal impurities in II-VI semiconductors: characterization and switching of charge states,” J. Cryst. Growth 161(1–4), 239–249 (1996).
[Crossref]

1995 (1)

M. Surma, A. J. Zakrzewski, and M. Godlewski, “Nonradiative recombination processes in nickel- and iron-doped ZnS and ZnSe studied by photoinduced electron-spin resonance,” Phys. Rev. B Condens. Matter 52(16), 11879–11883 (1995).
[Crossref] [PubMed]

1986 (1)

A. Zakrzewski and M. Godlewski, “Direct evidence of three-center-Auger recombination processes in ZnS:Cu,Fe,” Phys. Rev. B Condens. Matter 34(12), 8993–8995 (1986).
[Crossref] [PubMed]

1985 (3)

M. Godlewski and M. Skowronski, “Effective deactivation of the ZnS visible photoluminescence by iron impurities,” Phys. Rev. B Condens. Matter 32(6), 4007–4013 (1985).
[Crossref] [PubMed]

M. Godlewski, “On the application of the photo-EPR technique to the studies of photoionization, DAP recombination, and non-radiative recombination processes,” Phys. Status Solidi A 90(1), 11–52 (1985).
[Crossref]

M. Skowronski, Z. Liro, and W. Palosz, “Uniaxial stress effect on no-phonon lines of 3T1 to 5E transitions in ZnS:Fe,” J. Phys. Chem. 18(26), 5099–5110 (1985).

1983 (1)

K. P. O’Donnell, K. M. Lee, and G. D. Watkins, “An ODMR study of a luminescence excitation process in ZnSe:Fe,” J. Phys. Chem. 16(20), L723 (1983).

1976 (1)

G. Grebe, G. Roussos, and H.-J. Schulz, “Cr2+ excitation levels in ZnSe and ZnS,” J. Phys. Chem. 9(24), 4511–4516 (1976).

Akimov, V. A.

V. I. Kozlovsky, V. A. Akimov, M. P. Frolov, Yu. V. Korostelin, A. I. Landman, V. P. Martovitsky, V. V. Mislavskii, Y. P. Podmar’kov, Y. K. Skasyrsky, and A. A. Voronov, “Room-temperature tunable mid-infrared lasers on transition-metal doped II–VI compound crystals grown from vapor phase,” Phys. Status Solidi B 247(6), 1553–1556 (2010).
[Crossref]

Burger, A.

A. Burger, K. Chattopadhyay, J. O. Ndap, X. Ma, S. H. Morgan, C. I. Rablau, C. H. Su, S. Feth, R. H. Page, K. I. Schaffers, and S. A. Payne, “Preparation conditions of chromium doped ZnSe and their infrared luminescence properties,” J. Cryst. Growth 225(2-4), 249–256 (2001).
[Crossref]

C. I. Rablau, J. O. Ndap, X. Ma, A. Burger, and N. C. Giles, “Absorption and photoluminescence spectroscopy of diffusion-doped ZnSe:Cr2+,” J. Electron. Mater. 28(6), 678–682 (1999).
[Crossref]

Chattopadhyay, K.

A. Burger, K. Chattopadhyay, J. O. Ndap, X. Ma, S. H. Morgan, C. I. Rablau, C. H. Su, S. Feth, R. H. Page, K. I. Schaffers, and S. A. Payne, “Preparation conditions of chromium doped ZnSe and their infrared luminescence properties,” J. Cryst. Growth 225(2-4), 249–256 (2001).
[Crossref]

Dashdorj, J.

V. V. Fedorov, T. Konak, J. Dashdorj, M. E. Zvanut, and S. B. Mirov, “Optical and EPR spectroscopy of Zn:Cr:ZnSe and Zn:Fe:ZnSe crystals,” Opt. Mater. 37, 262–266 (2014).
[Crossref]

Fedorov, V.

S. Mirov, V. Fedorov, D. Martyshkin, I. Moskalev, M. Mirov, and S. Vasilyev, “Progress in mid-IR lasers based on Cr and Fe doped II-VI chalcogenides,” IEEE J. Sel. Top. Quantum Electron. 21(1), 1601719 (2015).
[Crossref]

S. Mirov, V. Fedorov, I. S. Moskalev, D. Martyshkin, and C. Kim, “Progress in Cr2+ and Fe2+ doped mid-IR laser materials,” Laser Photonics Rev. 4(1), 21–41 (2010).
[Crossref]

Fedorov, V. V.

V. V. Fedorov, T. Konak, J. Dashdorj, M. E. Zvanut, and S. B. Mirov, “Optical and EPR spectroscopy of Zn:Cr:ZnSe and Zn:Fe:ZnSe crystals,” Opt. Mater. 37, 262–266 (2014).
[Crossref]

N. Myoung, D. V. Martyshkin, V. V. Fedorov, and S. B. Mirov, “Mid-IR lasing of iron–cobalt co-doped ZnS(Se) crystals via Co–Fe energy transfer,” J. Lumin. 133, 257–261 (2013).
[Crossref]

J. Peppers, N. Myoung, V. V. Fedorov, and S. B. Mirov, “Mid-IR laser oscillation via energy transfer in the Co:Fe:ZnS/Se co-doped crystals,” Proc. SPIE 8235, 823503 (2012).
[Crossref]

N. Myoung, V. V. Fedorov, S. B. Mirov, and L. E. Wenger, “Temperature and concentration quenching of mid-IR photoluminescence in iron doped ZnSe and ZnS laser crystals,” J. Lumin. 132(3), 600–606 (2012).
[Crossref]

S. B. Mirov, V. V. Fedorov, D. V. Martyshkin, I. S. Moskalev, M. S. Mirov, and V. P. Gapontsev, “Progress in mid-IR Cr2+ and Fe2+ doped II-VI materials and lasers [Invited],” Opt. Mater. Express 1(5), 898–910 (2011).
[Crossref]

V. V. Fedorov, A. Gallian, I. Moskalev, and S. B. Mirov, “En route to electrically pumped broadly tunable middle infrared lasers based on transition metal doped II–VI semiconductors,” J. Lumin. 125(1–2), 184–195 (2007).
[Crossref]

Feth, S.

A. Burger, K. Chattopadhyay, J. O. Ndap, X. Ma, S. H. Morgan, C. I. Rablau, C. H. Su, S. Feth, R. H. Page, K. I. Schaffers, and S. A. Payne, “Preparation conditions of chromium doped ZnSe and their infrared luminescence properties,” J. Cryst. Growth 225(2-4), 249–256 (2001).
[Crossref]

Frolov, M. P.

V. I. Kozlovsky, V. A. Akimov, M. P. Frolov, Yu. V. Korostelin, A. I. Landman, V. P. Martovitsky, V. V. Mislavskii, Y. P. Podmar’kov, Y. K. Skasyrsky, and A. A. Voronov, “Room-temperature tunable mid-infrared lasers on transition-metal doped II–VI compound crystals grown from vapor phase,” Phys. Status Solidi B 247(6), 1553–1556 (2010).
[Crossref]

Gallian, A.

V. V. Fedorov, A. Gallian, I. Moskalev, and S. B. Mirov, “En route to electrically pumped broadly tunable middle infrared lasers based on transition metal doped II–VI semiconductors,” J. Lumin. 125(1–2), 184–195 (2007).
[Crossref]

Gapontsev, V. P.

Giles, N. C.

C. I. Rablau, J. O. Ndap, X. Ma, A. Burger, and N. C. Giles, “Absorption and photoluminescence spectroscopy of diffusion-doped ZnSe:Cr2+,” J. Electron. Mater. 28(6), 678–682 (1999).
[Crossref]

Godlewski, M.

V. Yu. Ivanov, M. Godlewski, and T. Gregorkiewicz, “Two-colour spectroscopy of ZnSe:Cr,” Phys. Status Solidi B 244(5), 1618–1622 (2007).
[Crossref]

K. Swiatek, M. Godlewski, and T. P. Surkova, “Fe photoionization transitions in ZnSSe:Fe crystals – photo-ESR studies,” Phys. Status Solidi C 2(3), 1224–1227 (2005).
[Crossref]

V. Yu. Ivanov, Y. G. Semenov, M. Surma, and M. Godlewski, “Anti-Stokes luminescence in chromium-doped ZnSe,” Phys. Rev. B Condens. Matter 54(7), 4696–4701 (1996).
[Crossref] [PubMed]

M. Surma, A. J. Zakrzewski, and M. Godlewski, “Nonradiative recombination processes in nickel- and iron-doped ZnS and ZnSe studied by photoinduced electron-spin resonance,” Phys. Rev. B Condens. Matter 52(16), 11879–11883 (1995).
[Crossref] [PubMed]

A. Zakrzewski and M. Godlewski, “Direct evidence of three-center-Auger recombination processes in ZnS:Cu,Fe,” Phys. Rev. B Condens. Matter 34(12), 8993–8995 (1986).
[Crossref] [PubMed]

M. Godlewski, “On the application of the photo-EPR technique to the studies of photoionization, DAP recombination, and non-radiative recombination processes,” Phys. Status Solidi A 90(1), 11–52 (1985).
[Crossref]

M. Godlewski and M. Skowronski, “Effective deactivation of the ZnS visible photoluminescence by iron impurities,” Phys. Rev. B Condens. Matter 32(6), 4007–4013 (1985).
[Crossref] [PubMed]

Grebe, G.

G. Grebe, G. Roussos, and H.-J. Schulz, “Cr2+ excitation levels in ZnSe and ZnS,” J. Phys. Chem. 9(24), 4511–4516 (1976).

Gregorkiewicz, T.

V. Yu. Ivanov, M. Godlewski, and T. Gregorkiewicz, “Two-colour spectroscopy of ZnSe:Cr,” Phys. Status Solidi B 244(5), 1618–1622 (2007).
[Crossref]

Ivanov, V. Yu.

V. Yu. Ivanov, M. Godlewski, and T. Gregorkiewicz, “Two-colour spectroscopy of ZnSe:Cr,” Phys. Status Solidi B 244(5), 1618–1622 (2007).
[Crossref]

V. Yu. Ivanov, Y. G. Semenov, M. Surma, and M. Godlewski, “Anti-Stokes luminescence in chromium-doped ZnSe,” Phys. Rev. B Condens. Matter 54(7), 4696–4701 (1996).
[Crossref] [PubMed]

Kim, C.

S. Mirov, V. Fedorov, I. S. Moskalev, D. Martyshkin, and C. Kim, “Progress in Cr2+ and Fe2+ doped mid-IR laser materials,” Laser Photonics Rev. 4(1), 21–41 (2010).
[Crossref]

Klimakow, A.

M. U. Lehr, B. Litzenburger, J. Kreiss, U. W. Pohl, H. R. Selber, H.-J. Schulz, A. Klimakow, and L. Worschech, “Identification of near-infrared Cr2+ luminescence in ZnSe,” J. Phys. Condens. Matter 9(3), 753–763 (1997).
[Crossref]

Konak, T.

V. V. Fedorov, T. Konak, J. Dashdorj, M. E. Zvanut, and S. B. Mirov, “Optical and EPR spectroscopy of Zn:Cr:ZnSe and Zn:Fe:ZnSe crystals,” Opt. Mater. 37, 262–266 (2014).
[Crossref]

Korostelin, Yu. V.

V. I. Kozlovsky, V. A. Akimov, M. P. Frolov, Yu. V. Korostelin, A. I. Landman, V. P. Martovitsky, V. V. Mislavskii, Y. P. Podmar’kov, Y. K. Skasyrsky, and A. A. Voronov, “Room-temperature tunable mid-infrared lasers on transition-metal doped II–VI compound crystals grown from vapor phase,” Phys. Status Solidi B 247(6), 1553–1556 (2010).
[Crossref]

Kozlovsky, V. I.

V. I. Kozlovsky, V. A. Akimov, M. P. Frolov, Yu. V. Korostelin, A. I. Landman, V. P. Martovitsky, V. V. Mislavskii, Y. P. Podmar’kov, Y. K. Skasyrsky, and A. A. Voronov, “Room-temperature tunable mid-infrared lasers on transition-metal doped II–VI compound crystals grown from vapor phase,” Phys. Status Solidi B 247(6), 1553–1556 (2010).
[Crossref]

Kreiss, J.

M. U. Lehr, B. Litzenburger, J. Kreiss, U. W. Pohl, H. R. Selber, H.-J. Schulz, A. Klimakow, and L. Worschech, “Identification of near-infrared Cr2+ luminescence in ZnSe,” J. Phys. Condens. Matter 9(3), 753–763 (1997).
[Crossref]

Kreissl, J.

J. Kreissl and H.-J. Schulz, “Transition-metal impurities in II-VI semiconductors: characterization and switching of charge states,” J. Cryst. Growth 161(1–4), 239–249 (1996).
[Crossref]

Kück, S.

S. Kück, “Laser-related spectroscopy of ion-doped crystals for tunable solid-state lasers,” Appl. Phys. B 72(5), 515–562 (2001).
[Crossref]

Landman, A. I.

V. I. Kozlovsky, V. A. Akimov, M. P. Frolov, Yu. V. Korostelin, A. I. Landman, V. P. Martovitsky, V. V. Mislavskii, Y. P. Podmar’kov, Y. K. Skasyrsky, and A. A. Voronov, “Room-temperature tunable mid-infrared lasers on transition-metal doped II–VI compound crystals grown from vapor phase,” Phys. Status Solidi B 247(6), 1553–1556 (2010).
[Crossref]

Lee, K. M.

K. P. O’Donnell, K. M. Lee, and G. D. Watkins, “An ODMR study of a luminescence excitation process in ZnSe:Fe,” J. Phys. Chem. 16(20), L723 (1983).

Lehr, M. U.

M. U. Lehr, B. Litzenburger, J. Kreiss, U. W. Pohl, H. R. Selber, H.-J. Schulz, A. Klimakow, and L. Worschech, “Identification of near-infrared Cr2+ luminescence in ZnSe,” J. Phys. Condens. Matter 9(3), 753–763 (1997).
[Crossref]

Liro, Z.

M. Skowronski, Z. Liro, and W. Palosz, “Uniaxial stress effect on no-phonon lines of 3T1 to 5E transitions in ZnS:Fe,” J. Phys. Chem. 18(26), 5099–5110 (1985).

Litzenburger, B.

M. U. Lehr, B. Litzenburger, J. Kreiss, U. W. Pohl, H. R. Selber, H.-J. Schulz, A. Klimakow, and L. Worschech, “Identification of near-infrared Cr2+ luminescence in ZnSe,” J. Phys. Condens. Matter 9(3), 753–763 (1997).
[Crossref]

Ma, X.

A. Burger, K. Chattopadhyay, J. O. Ndap, X. Ma, S. H. Morgan, C. I. Rablau, C. H. Su, S. Feth, R. H. Page, K. I. Schaffers, and S. A. Payne, “Preparation conditions of chromium doped ZnSe and their infrared luminescence properties,” J. Cryst. Growth 225(2-4), 249–256 (2001).
[Crossref]

C. I. Rablau, J. O. Ndap, X. Ma, A. Burger, and N. C. Giles, “Absorption and photoluminescence spectroscopy of diffusion-doped ZnSe:Cr2+,” J. Electron. Mater. 28(6), 678–682 (1999).
[Crossref]

Martovitsky, V. P.

V. I. Kozlovsky, V. A. Akimov, M. P. Frolov, Yu. V. Korostelin, A. I. Landman, V. P. Martovitsky, V. V. Mislavskii, Y. P. Podmar’kov, Y. K. Skasyrsky, and A. A. Voronov, “Room-temperature tunable mid-infrared lasers on transition-metal doped II–VI compound crystals grown from vapor phase,” Phys. Status Solidi B 247(6), 1553–1556 (2010).
[Crossref]

Martyshkin, D.

S. Mirov, V. Fedorov, D. Martyshkin, I. Moskalev, M. Mirov, and S. Vasilyev, “Progress in mid-IR lasers based on Cr and Fe doped II-VI chalcogenides,” IEEE J. Sel. Top. Quantum Electron. 21(1), 1601719 (2015).
[Crossref]

S. Mirov, V. Fedorov, I. S. Moskalev, D. Martyshkin, and C. Kim, “Progress in Cr2+ and Fe2+ doped mid-IR laser materials,” Laser Photonics Rev. 4(1), 21–41 (2010).
[Crossref]

Martyshkin, D. V.

N. Myoung, D. V. Martyshkin, V. V. Fedorov, and S. B. Mirov, “Mid-IR lasing of iron–cobalt co-doped ZnS(Se) crystals via Co–Fe energy transfer,” J. Lumin. 133, 257–261 (2013).
[Crossref]

S. B. Mirov, V. V. Fedorov, D. V. Martyshkin, I. S. Moskalev, M. S. Mirov, and V. P. Gapontsev, “Progress in mid-IR Cr2+ and Fe2+ doped II-VI materials and lasers [Invited],” Opt. Mater. Express 1(5), 898–910 (2011).
[Crossref]

Mirov, M.

S. Mirov, V. Fedorov, D. Martyshkin, I. Moskalev, M. Mirov, and S. Vasilyev, “Progress in mid-IR lasers based on Cr and Fe doped II-VI chalcogenides,” IEEE J. Sel. Top. Quantum Electron. 21(1), 1601719 (2015).
[Crossref]

Mirov, M. S.

Mirov, S.

S. Mirov, V. Fedorov, D. Martyshkin, I. Moskalev, M. Mirov, and S. Vasilyev, “Progress in mid-IR lasers based on Cr and Fe doped II-VI chalcogenides,” IEEE J. Sel. Top. Quantum Electron. 21(1), 1601719 (2015).
[Crossref]

S. Mirov, V. Fedorov, I. S. Moskalev, D. Martyshkin, and C. Kim, “Progress in Cr2+ and Fe2+ doped mid-IR laser materials,” Laser Photonics Rev. 4(1), 21–41 (2010).
[Crossref]

Mirov, S. B.

V. V. Fedorov, T. Konak, J. Dashdorj, M. E. Zvanut, and S. B. Mirov, “Optical and EPR spectroscopy of Zn:Cr:ZnSe and Zn:Fe:ZnSe crystals,” Opt. Mater. 37, 262–266 (2014).
[Crossref]

N. Myoung, D. V. Martyshkin, V. V. Fedorov, and S. B. Mirov, “Mid-IR lasing of iron–cobalt co-doped ZnS(Se) crystals via Co–Fe energy transfer,” J. Lumin. 133, 257–261 (2013).
[Crossref]

J. Peppers, N. Myoung, V. V. Fedorov, and S. B. Mirov, “Mid-IR laser oscillation via energy transfer in the Co:Fe:ZnS/Se co-doped crystals,” Proc. SPIE 8235, 823503 (2012).
[Crossref]

N. Myoung, V. V. Fedorov, S. B. Mirov, and L. E. Wenger, “Temperature and concentration quenching of mid-IR photoluminescence in iron doped ZnSe and ZnS laser crystals,” J. Lumin. 132(3), 600–606 (2012).
[Crossref]

S. B. Mirov, V. V. Fedorov, D. V. Martyshkin, I. S. Moskalev, M. S. Mirov, and V. P. Gapontsev, “Progress in mid-IR Cr2+ and Fe2+ doped II-VI materials and lasers [Invited],” Opt. Mater. Express 1(5), 898–910 (2011).
[Crossref]

V. V. Fedorov, A. Gallian, I. Moskalev, and S. B. Mirov, “En route to electrically pumped broadly tunable middle infrared lasers based on transition metal doped II–VI semiconductors,” J. Lumin. 125(1–2), 184–195 (2007).
[Crossref]

Mislavskii, V. V.

V. I. Kozlovsky, V. A. Akimov, M. P. Frolov, Yu. V. Korostelin, A. I. Landman, V. P. Martovitsky, V. V. Mislavskii, Y. P. Podmar’kov, Y. K. Skasyrsky, and A. A. Voronov, “Room-temperature tunable mid-infrared lasers on transition-metal doped II–VI compound crystals grown from vapor phase,” Phys. Status Solidi B 247(6), 1553–1556 (2010).
[Crossref]

Morgan, S. H.

A. Burger, K. Chattopadhyay, J. O. Ndap, X. Ma, S. H. Morgan, C. I. Rablau, C. H. Su, S. Feth, R. H. Page, K. I. Schaffers, and S. A. Payne, “Preparation conditions of chromium doped ZnSe and their infrared luminescence properties,” J. Cryst. Growth 225(2-4), 249–256 (2001).
[Crossref]

Moskalev, I.

S. Mirov, V. Fedorov, D. Martyshkin, I. Moskalev, M. Mirov, and S. Vasilyev, “Progress in mid-IR lasers based on Cr and Fe doped II-VI chalcogenides,” IEEE J. Sel. Top. Quantum Electron. 21(1), 1601719 (2015).
[Crossref]

V. V. Fedorov, A. Gallian, I. Moskalev, and S. B. Mirov, “En route to electrically pumped broadly tunable middle infrared lasers based on transition metal doped II–VI semiconductors,” J. Lumin. 125(1–2), 184–195 (2007).
[Crossref]

Moskalev, I. S.

S. B. Mirov, V. V. Fedorov, D. V. Martyshkin, I. S. Moskalev, M. S. Mirov, and V. P. Gapontsev, “Progress in mid-IR Cr2+ and Fe2+ doped II-VI materials and lasers [Invited],” Opt. Mater. Express 1(5), 898–910 (2011).
[Crossref]

S. Mirov, V. Fedorov, I. S. Moskalev, D. Martyshkin, and C. Kim, “Progress in Cr2+ and Fe2+ doped mid-IR laser materials,” Laser Photonics Rev. 4(1), 21–41 (2010).
[Crossref]

Myoung, N.

N. Myoung, D. V. Martyshkin, V. V. Fedorov, and S. B. Mirov, “Mid-IR lasing of iron–cobalt co-doped ZnS(Se) crystals via Co–Fe energy transfer,” J. Lumin. 133, 257–261 (2013).
[Crossref]

N. Myoung, V. V. Fedorov, S. B. Mirov, and L. E. Wenger, “Temperature and concentration quenching of mid-IR photoluminescence in iron doped ZnSe and ZnS laser crystals,” J. Lumin. 132(3), 600–606 (2012).
[Crossref]

J. Peppers, N. Myoung, V. V. Fedorov, and S. B. Mirov, “Mid-IR laser oscillation via energy transfer in the Co:Fe:ZnS/Se co-doped crystals,” Proc. SPIE 8235, 823503 (2012).
[Crossref]

Ndap, J. O.

A. Burger, K. Chattopadhyay, J. O. Ndap, X. Ma, S. H. Morgan, C. I. Rablau, C. H. Su, S. Feth, R. H. Page, K. I. Schaffers, and S. A. Payne, “Preparation conditions of chromium doped ZnSe and their infrared luminescence properties,” J. Cryst. Growth 225(2-4), 249–256 (2001).
[Crossref]

C. I. Rablau, J. O. Ndap, X. Ma, A. Burger, and N. C. Giles, “Absorption and photoluminescence spectroscopy of diffusion-doped ZnSe:Cr2+,” J. Electron. Mater. 28(6), 678–682 (1999).
[Crossref]

O’Donnell, K. P.

K. P. O’Donnell, K. M. Lee, and G. D. Watkins, “An ODMR study of a luminescence excitation process in ZnSe:Fe,” J. Phys. Chem. 16(20), L723 (1983).

Page, R. H.

A. Burger, K. Chattopadhyay, J. O. Ndap, X. Ma, S. H. Morgan, C. I. Rablau, C. H. Su, S. Feth, R. H. Page, K. I. Schaffers, and S. A. Payne, “Preparation conditions of chromium doped ZnSe and their infrared luminescence properties,” J. Cryst. Growth 225(2-4), 249–256 (2001).
[Crossref]

Palosz, W.

M. Skowronski, Z. Liro, and W. Palosz, “Uniaxial stress effect on no-phonon lines of 3T1 to 5E transitions in ZnS:Fe,” J. Phys. Chem. 18(26), 5099–5110 (1985).

Payne, S. A.

A. Burger, K. Chattopadhyay, J. O. Ndap, X. Ma, S. H. Morgan, C. I. Rablau, C. H. Su, S. Feth, R. H. Page, K. I. Schaffers, and S. A. Payne, “Preparation conditions of chromium doped ZnSe and their infrared luminescence properties,” J. Cryst. Growth 225(2-4), 249–256 (2001).
[Crossref]

Peppers, J.

J. Peppers, N. Myoung, V. V. Fedorov, and S. B. Mirov, “Mid-IR laser oscillation via energy transfer in the Co:Fe:ZnS/Se co-doped crystals,” Proc. SPIE 8235, 823503 (2012).
[Crossref]

Podmar’kov, Y. P.

V. I. Kozlovsky, V. A. Akimov, M. P. Frolov, Yu. V. Korostelin, A. I. Landman, V. P. Martovitsky, V. V. Mislavskii, Y. P. Podmar’kov, Y. K. Skasyrsky, and A. A. Voronov, “Room-temperature tunable mid-infrared lasers on transition-metal doped II–VI compound crystals grown from vapor phase,” Phys. Status Solidi B 247(6), 1553–1556 (2010).
[Crossref]

Pohl, U. W.

M. U. Lehr, B. Litzenburger, J. Kreiss, U. W. Pohl, H. R. Selber, H.-J. Schulz, A. Klimakow, and L. Worschech, “Identification of near-infrared Cr2+ luminescence in ZnSe,” J. Phys. Condens. Matter 9(3), 753–763 (1997).
[Crossref]

Rablau, C. I.

A. Burger, K. Chattopadhyay, J. O. Ndap, X. Ma, S. H. Morgan, C. I. Rablau, C. H. Su, S. Feth, R. H. Page, K. I. Schaffers, and S. A. Payne, “Preparation conditions of chromium doped ZnSe and their infrared luminescence properties,” J. Cryst. Growth 225(2-4), 249–256 (2001).
[Crossref]

C. I. Rablau, J. O. Ndap, X. Ma, A. Burger, and N. C. Giles, “Absorption and photoluminescence spectroscopy of diffusion-doped ZnSe:Cr2+,” J. Electron. Mater. 28(6), 678–682 (1999).
[Crossref]

Roussos, G.

G. Grebe, G. Roussos, and H.-J. Schulz, “Cr2+ excitation levels in ZnSe and ZnS,” J. Phys. Chem. 9(24), 4511–4516 (1976).

Schaffers, K. I.

A. Burger, K. Chattopadhyay, J. O. Ndap, X. Ma, S. H. Morgan, C. I. Rablau, C. H. Su, S. Feth, R. H. Page, K. I. Schaffers, and S. A. Payne, “Preparation conditions of chromium doped ZnSe and their infrared luminescence properties,” J. Cryst. Growth 225(2-4), 249–256 (2001).
[Crossref]

Schulz, H.-J.

M. U. Lehr, B. Litzenburger, J. Kreiss, U. W. Pohl, H. R. Selber, H.-J. Schulz, A. Klimakow, and L. Worschech, “Identification of near-infrared Cr2+ luminescence in ZnSe,” J. Phys. Condens. Matter 9(3), 753–763 (1997).
[Crossref]

J. Kreissl and H.-J. Schulz, “Transition-metal impurities in II-VI semiconductors: characterization and switching of charge states,” J. Cryst. Growth 161(1–4), 239–249 (1996).
[Crossref]

G. Grebe, G. Roussos, and H.-J. Schulz, “Cr2+ excitation levels in ZnSe and ZnS,” J. Phys. Chem. 9(24), 4511–4516 (1976).

Selber, H. R.

M. U. Lehr, B. Litzenburger, J. Kreiss, U. W. Pohl, H. R. Selber, H.-J. Schulz, A. Klimakow, and L. Worschech, “Identification of near-infrared Cr2+ luminescence in ZnSe,” J. Phys. Condens. Matter 9(3), 753–763 (1997).
[Crossref]

Semenov, Y. G.

V. Yu. Ivanov, Y. G. Semenov, M. Surma, and M. Godlewski, “Anti-Stokes luminescence in chromium-doped ZnSe,” Phys. Rev. B Condens. Matter 54(7), 4696–4701 (1996).
[Crossref] [PubMed]

Skasyrsky, Y. K.

V. I. Kozlovsky, V. A. Akimov, M. P. Frolov, Yu. V. Korostelin, A. I. Landman, V. P. Martovitsky, V. V. Mislavskii, Y. P. Podmar’kov, Y. K. Skasyrsky, and A. A. Voronov, “Room-temperature tunable mid-infrared lasers on transition-metal doped II–VI compound crystals grown from vapor phase,” Phys. Status Solidi B 247(6), 1553–1556 (2010).
[Crossref]

Skowronski, M.

M. Godlewski and M. Skowronski, “Effective deactivation of the ZnS visible photoluminescence by iron impurities,” Phys. Rev. B Condens. Matter 32(6), 4007–4013 (1985).
[Crossref] [PubMed]

M. Skowronski, Z. Liro, and W. Palosz, “Uniaxial stress effect on no-phonon lines of 3T1 to 5E transitions in ZnS:Fe,” J. Phys. Chem. 18(26), 5099–5110 (1985).

Su, C. H.

A. Burger, K. Chattopadhyay, J. O. Ndap, X. Ma, S. H. Morgan, C. I. Rablau, C. H. Su, S. Feth, R. H. Page, K. I. Schaffers, and S. A. Payne, “Preparation conditions of chromium doped ZnSe and their infrared luminescence properties,” J. Cryst. Growth 225(2-4), 249–256 (2001).
[Crossref]

Surkova, T. P.

K. Swiatek, M. Godlewski, and T. P. Surkova, “Fe photoionization transitions in ZnSSe:Fe crystals – photo-ESR studies,” Phys. Status Solidi C 2(3), 1224–1227 (2005).
[Crossref]

Surma, M.

V. Yu. Ivanov, Y. G. Semenov, M. Surma, and M. Godlewski, “Anti-Stokes luminescence in chromium-doped ZnSe,” Phys. Rev. B Condens. Matter 54(7), 4696–4701 (1996).
[Crossref] [PubMed]

M. Surma, A. J. Zakrzewski, and M. Godlewski, “Nonradiative recombination processes in nickel- and iron-doped ZnS and ZnSe studied by photoinduced electron-spin resonance,” Phys. Rev. B Condens. Matter 52(16), 11879–11883 (1995).
[Crossref] [PubMed]

Swiatek, K.

K. Swiatek, M. Godlewski, and T. P. Surkova, “Fe photoionization transitions in ZnSSe:Fe crystals – photo-ESR studies,” Phys. Status Solidi C 2(3), 1224–1227 (2005).
[Crossref]

Vasilyev, S.

S. Mirov, V. Fedorov, D. Martyshkin, I. Moskalev, M. Mirov, and S. Vasilyev, “Progress in mid-IR lasers based on Cr and Fe doped II-VI chalcogenides,” IEEE J. Sel. Top. Quantum Electron. 21(1), 1601719 (2015).
[Crossref]

Voronov, A. A.

V. I. Kozlovsky, V. A. Akimov, M. P. Frolov, Yu. V. Korostelin, A. I. Landman, V. P. Martovitsky, V. V. Mislavskii, Y. P. Podmar’kov, Y. K. Skasyrsky, and A. A. Voronov, “Room-temperature tunable mid-infrared lasers on transition-metal doped II–VI compound crystals grown from vapor phase,” Phys. Status Solidi B 247(6), 1553–1556 (2010).
[Crossref]

Watkins, G. D.

K. P. O’Donnell, K. M. Lee, and G. D. Watkins, “An ODMR study of a luminescence excitation process in ZnSe:Fe,” J. Phys. Chem. 16(20), L723 (1983).

Wenger, L. E.

N. Myoung, V. V. Fedorov, S. B. Mirov, and L. E. Wenger, “Temperature and concentration quenching of mid-IR photoluminescence in iron doped ZnSe and ZnS laser crystals,” J. Lumin. 132(3), 600–606 (2012).
[Crossref]

Worschech, L.

M. U. Lehr, B. Litzenburger, J. Kreiss, U. W. Pohl, H. R. Selber, H.-J. Schulz, A. Klimakow, and L. Worschech, “Identification of near-infrared Cr2+ luminescence in ZnSe,” J. Phys. Condens. Matter 9(3), 753–763 (1997).
[Crossref]

Zakrzewski, A.

A. Zakrzewski and M. Godlewski, “Direct evidence of three-center-Auger recombination processes in ZnS:Cu,Fe,” Phys. Rev. B Condens. Matter 34(12), 8993–8995 (1986).
[Crossref] [PubMed]

Zakrzewski, A. J.

M. Surma, A. J. Zakrzewski, and M. Godlewski, “Nonradiative recombination processes in nickel- and iron-doped ZnS and ZnSe studied by photoinduced electron-spin resonance,” Phys. Rev. B Condens. Matter 52(16), 11879–11883 (1995).
[Crossref] [PubMed]

Zvanut, M. E.

V. V. Fedorov, T. Konak, J. Dashdorj, M. E. Zvanut, and S. B. Mirov, “Optical and EPR spectroscopy of Zn:Cr:ZnSe and Zn:Fe:ZnSe crystals,” Opt. Mater. 37, 262–266 (2014).
[Crossref]

Appl. Phys. B (1)

S. Kück, “Laser-related spectroscopy of ion-doped crystals for tunable solid-state lasers,” Appl. Phys. B 72(5), 515–562 (2001).
[Crossref]

IEEE J. Sel. Top. Quantum Electron. (1)

S. Mirov, V. Fedorov, D. Martyshkin, I. Moskalev, M. Mirov, and S. Vasilyev, “Progress in mid-IR lasers based on Cr and Fe doped II-VI chalcogenides,” IEEE J. Sel. Top. Quantum Electron. 21(1), 1601719 (2015).
[Crossref]

J. Cryst. Growth (2)

J. Kreissl and H.-J. Schulz, “Transition-metal impurities in II-VI semiconductors: characterization and switching of charge states,” J. Cryst. Growth 161(1–4), 239–249 (1996).
[Crossref]

A. Burger, K. Chattopadhyay, J. O. Ndap, X. Ma, S. H. Morgan, C. I. Rablau, C. H. Su, S. Feth, R. H. Page, K. I. Schaffers, and S. A. Payne, “Preparation conditions of chromium doped ZnSe and their infrared luminescence properties,” J. Cryst. Growth 225(2-4), 249–256 (2001).
[Crossref]

J. Electron. Mater. (1)

C. I. Rablau, J. O. Ndap, X. Ma, A. Burger, and N. C. Giles, “Absorption and photoluminescence spectroscopy of diffusion-doped ZnSe:Cr2+,” J. Electron. Mater. 28(6), 678–682 (1999).
[Crossref]

J. Lumin. (3)

N. Myoung, V. V. Fedorov, S. B. Mirov, and L. E. Wenger, “Temperature and concentration quenching of mid-IR photoluminescence in iron doped ZnSe and ZnS laser crystals,” J. Lumin. 132(3), 600–606 (2012).
[Crossref]

N. Myoung, D. V. Martyshkin, V. V. Fedorov, and S. B. Mirov, “Mid-IR lasing of iron–cobalt co-doped ZnS(Se) crystals via Co–Fe energy transfer,” J. Lumin. 133, 257–261 (2013).
[Crossref]

V. V. Fedorov, A. Gallian, I. Moskalev, and S. B. Mirov, “En route to electrically pumped broadly tunable middle infrared lasers based on transition metal doped II–VI semiconductors,” J. Lumin. 125(1–2), 184–195 (2007).
[Crossref]

J. Phys. Chem. (3)

M. Skowronski, Z. Liro, and W. Palosz, “Uniaxial stress effect on no-phonon lines of 3T1 to 5E transitions in ZnS:Fe,” J. Phys. Chem. 18(26), 5099–5110 (1985).

K. P. O’Donnell, K. M. Lee, and G. D. Watkins, “An ODMR study of a luminescence excitation process in ZnSe:Fe,” J. Phys. Chem. 16(20), L723 (1983).

G. Grebe, G. Roussos, and H.-J. Schulz, “Cr2+ excitation levels in ZnSe and ZnS,” J. Phys. Chem. 9(24), 4511–4516 (1976).

J. Phys. Condens. Matter (1)

M. U. Lehr, B. Litzenburger, J. Kreiss, U. W. Pohl, H. R. Selber, H.-J. Schulz, A. Klimakow, and L. Worschech, “Identification of near-infrared Cr2+ luminescence in ZnSe,” J. Phys. Condens. Matter 9(3), 753–763 (1997).
[Crossref]

Laser Photonics Rev. (1)

S. Mirov, V. Fedorov, I. S. Moskalev, D. Martyshkin, and C. Kim, “Progress in Cr2+ and Fe2+ doped mid-IR laser materials,” Laser Photonics Rev. 4(1), 21–41 (2010).
[Crossref]

Opt. Mater. (1)

V. V. Fedorov, T. Konak, J. Dashdorj, M. E. Zvanut, and S. B. Mirov, “Optical and EPR spectroscopy of Zn:Cr:ZnSe and Zn:Fe:ZnSe crystals,” Opt. Mater. 37, 262–266 (2014).
[Crossref]

Opt. Mater. Express (1)

Phys. Rev. B Condens. Matter (4)

A. Zakrzewski and M. Godlewski, “Direct evidence of three-center-Auger recombination processes in ZnS:Cu,Fe,” Phys. Rev. B Condens. Matter 34(12), 8993–8995 (1986).
[Crossref] [PubMed]

M. Godlewski and M. Skowronski, “Effective deactivation of the ZnS visible photoluminescence by iron impurities,” Phys. Rev. B Condens. Matter 32(6), 4007–4013 (1985).
[Crossref] [PubMed]

M. Surma, A. J. Zakrzewski, and M. Godlewski, “Nonradiative recombination processes in nickel- and iron-doped ZnS and ZnSe studied by photoinduced electron-spin resonance,” Phys. Rev. B Condens. Matter 52(16), 11879–11883 (1995).
[Crossref] [PubMed]

V. Yu. Ivanov, Y. G. Semenov, M. Surma, and M. Godlewski, “Anti-Stokes luminescence in chromium-doped ZnSe,” Phys. Rev. B Condens. Matter 54(7), 4696–4701 (1996).
[Crossref] [PubMed]

Phys. Status Solidi A (1)

M. Godlewski, “On the application of the photo-EPR technique to the studies of photoionization, DAP recombination, and non-radiative recombination processes,” Phys. Status Solidi A 90(1), 11–52 (1985).
[Crossref]

Phys. Status Solidi B (2)

V. I. Kozlovsky, V. A. Akimov, M. P. Frolov, Yu. V. Korostelin, A. I. Landman, V. P. Martovitsky, V. V. Mislavskii, Y. P. Podmar’kov, Y. K. Skasyrsky, and A. A. Voronov, “Room-temperature tunable mid-infrared lasers on transition-metal doped II–VI compound crystals grown from vapor phase,” Phys. Status Solidi B 247(6), 1553–1556 (2010).
[Crossref]

V. Yu. Ivanov, M. Godlewski, and T. Gregorkiewicz, “Two-colour spectroscopy of ZnSe:Cr,” Phys. Status Solidi B 244(5), 1618–1622 (2007).
[Crossref]

Phys. Status Solidi C (1)

K. Swiatek, M. Godlewski, and T. P. Surkova, “Fe photoionization transitions in ZnSSe:Fe crystals – photo-ESR studies,” Phys. Status Solidi C 2(3), 1224–1227 (2005).
[Crossref]

Proc. SPIE (1)

J. Peppers, N. Myoung, V. V. Fedorov, and S. B. Mirov, “Mid-IR laser oscillation via energy transfer in the Co:Fe:ZnS/Se co-doped crystals,” Proc. SPIE 8235, 823503 (2012).
[Crossref]

Other (2)

C. I. Rablau, “Photoluminescence and optical absorption spectroscopy of infrared materials Cr2+:Znse and ZnGeP2,” Ph.D. dissertation, West Virginia University, Morgantown, West Virginia (1999).

F. Träger, Springer Handbook of Lasers and Optics, (Springer Science + Business Media, 2007).

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Figures (6)

Fig. 1
Fig. 1 A. Energy levels of Fe2+ and energy transfer mechanisms. B. Cross-sections of near-IR and mid-IR transitions in Fe:ZnSe.
Fig. 2
Fig. 2 A. Absorption spectra of undoped (i), iron doped (ii), and chromium doped (iii) ZnSe (NFe = 1.4 × 1019 cm−3, NCr = 2.7 × 1018 cm−3) crystals near band-gap, B. Zoom-in to show absorption of Fe:ZnSe near 532 nm.
Fig. 3
Fig. 3 A. Short PL kinetics of Fe:ZnSe under i) 532nm excitation and ii) 2780nm excitation. B. Long PL kinetics of Fe:ZnSe showing iii) mid-IR kinetics under 532nm excitation and iv) near-IR PL at 950nm.
Fig. 4
Fig. 4 Dependence of PL signal on energy of excitation for i) Fe:ZnSe and ii) Cr:ZnSe.
Fig. 5
Fig. 5 A. Energy levels of Cr2+ and energy transfer mechanisms. B. Cross-sections of near-IR and mid-IR transitions in Cr:ZnSe
Fig. 6
Fig. 6 A. Normalized PL kinetics of Cr:ZnSe illustrating rise time under i) intra-shell excitation at 1560nm, ii) 532nm nanosecond scale excitation, iii) 532nm picosecond scale excitation, and iv) Cr:ZnSe PL kinetics at 960nm under 532nm ns scale excitation. B. Lasing of Cr:ZnSe under 532nm 10ns pulsed excitation showing three pulses under 9.1mJ pump energy, with insert showing the averaged signal under 6.7mJ pump energy.

Equations (3)

Equations on this page are rendered with MathJax. Learn more.

σ max = ln2 π A 4πc n 2 λ 0 4 Δλ
C r 2+ +ωC r + + h + followed by C r + +ω (C r 2+ ) * + e , or
C r 2+ +2ω (C r + ) * + ( h + ) *

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