Abstract

We demonstrate 2.6 µm mid-infrared lasing at room temperature in a planar waveguide structure. Planar waveguides were fabricated using pulsed laser deposition (PLD) by depositing chromium doped zinc selenide thin films on sapphire substrate (Cr2+:ZnSe/sapphire). Highly doped Cr2+:ZnSe/Sapphire thin film sample was also used to demonstrate passive Q-switching of Er:YAG laser operating at 1.645 µm.

©2010 Optical Society of America

1. Introduction

Transition metal doped II-VI semiconductor laser crystals have stimulated extensive interest in the scientific community as active materials for tunable middle infrared (mid-IR) lasers operating over the 2–5 µm range [15]. Of particular interest are Cr2+ ions incorporated in ZnSe crystals (Cr2+:ZnSe) featuring intra-center 2–3 µm transitions between the crystal-field-split ground 5T2 and first excited 5E states [6]. The availability of affordable low loss polycrystalline ZnSe, and the ability to fabricate high quality uniformly doped Cr2+:ZnSe crystals via post-growth thermal diffusion make them the gain materials of choice for development of high power mid-IR lasers, broadly tunable over the 2–3 µm spectral range [3,4]. Cr2+:ZnSe lasers documented in the literature operate at room temperature in continuous wave (CW) regime with a slope efficiency and output power greater than 60% and 10 W, respectively [3,79]. Further advancements in power scaling require thorough thermal management of the active element. Among different thermal management and beam quality control approaches, waveguide laser geometry design holds a lot of promise. The majority of reported Cr2+:ZnSe lasers relied on bulk gain material fabrication methods [3] and did not offer waveguiding of the optical field.

Thin film deposition techniques are promising for fabrication of Cr2+:ZnSe waveguide laser and electroluminescent structures. Previously, mid-IR electroluminescence has been reported for bulk [1012] and thin film [13,14] Cr2+:ZnSe samples. Thin film fabrication technique offers a versatile fabrication method minimizing layer interface roughness and enabling the development of the entire structure in situ in vacuum. Several Cr2+:ZnSe thin film structures featuring room temperature photoluminescence (PL) from the optically active Cr2+ions have been fabricated by means of molecular beam epitaxy [15], radio frequency magnetron sputtering [16] and pulsed laser deposition (PLD) [17]. Building on the success of PLD growth of Cr2+:ZnSe film, we report here the first PLD grown Cr2+:ZnSe planar waveguide structure exhibiting mid-IR lasing. In addition, highly doped PLD grown Cr2+:ZnSe thin film was used for the first time as a saturable absorber for passive Q-switching of Er:YAG laser operating at 1645 nm.

2. Thin film deposition

Chromium doped ZnSe films were deposited on epi-ready double-side-polished c-plane (0001) oriented sapphire substrates (Cr2+:ZnSe/sapphire) by means of laser ablation of a solid chromium doped ZnSe target. Since the index of refraction of ZnSe is nZnSe ~2.44 and that of sapphire is nsapphire ~1.73 in the 2–3 µm region, the structure air/Cr2+:ZnSe/sapphire should provide waveguiding-confinement of the optical field within the Cr2+:ZnSe active region. Laser ablation targets were fabricated in-house by manually mixing powders of ZnSe (99.99% purity) and CrSe (99.9% purity) in the appropriate weight percentages to obtain the desired chromium doping concentrations within the targets. The mixed powders were compressed into a solid pellet approximately 1 inch in diameter which was then vacuum sealed at 10−4 Torr in a quartz ampoule and annealed at 1000 C for 10 days. The target was then ablated by a KrF excimer laser at 2 J/cm2. The details of the deposition procedure are described in Ref [17].

3. Experimental results

3.1 Characterization of the crystalline quality of deposited films

The surface roughness of the deposited films was analyzed with atomic force microscopy (AFM) in contact mode. The AFM images of a 10 μm thick Cr2+:ZnSe film deposited on sapphire is shown in Fig. 1 . An image of a 50 × 50 μm scan area is depicted in Fig. 1(a) and Fig. 1(b) shows a closer 5 × 5 μm scan area of the film’s surface. Both images showed a surface area root mean square (RMS) roughness of less than 7 nm. On average, the area RMS roughness of all the Cr2+:ZnSe film surfaces deposited by PLD was less than 10 nm which indicates a very good smooth surface morphology.

 figure: Fig. 1

Fig. 1 AFM images of (a) 50 × 50 μm scan area and (b) 5 × 5 μm scan area of a 10 μm thick Cr2+:ZnSe film deposited on sapphire. The surface areas RMS roughness was smaller than 10 nm.

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The crystalline quality of the films was determined using X-ray diffraction (XRD) with CuKα radiation of 1.5418 Å and room temperature Raman scattering. In Fig. 2(a) the θ-2θ XRD scans of Cr2+:ZnSe/sapphire films deposited at various deposition temperatures are shown. All XRD patterns obtained indicated that the films deposited were polycrystalline ZnSe in a cubic (zinc blende) structure. The XRD patterns showed the (111), (220), and (311) cubic ZnSe planes perpendicular to the substrates surface along with reflections from the substrate (0006) plane. At growth temperatures lower than 475 C, there appears to be some mixture of ZnSe hexagonal crystallites within the films as evident from the ZnSe wurtzite (100) XRD peak seen around 2θ~25.9. As growth temperature increases, the degree of hexagonality of the films diminished as the XRD peak corresponding to the ZnSe wurtzite structure gradually disappeared. This suggests that at growth temperatures of 600 C, the films deposited were purely cubic as oppose to a mixed-polytype structure of cubic and hexagonal ZnSe structures seen in films deposited at lower temperatures. The full width at half maximum (FWHM) of the (111) and (311) peaks decreased from 0.852 to 0.472 and 1.226 to 0.683, respectively, with increasing deposition temperature from 350 C to 600 C. The narrowing of the FWHM with increasing growth temperatures indicated the formation of higher quality crystalline ZnSe lattices within the films.

 figure: Fig. 2

Fig. 2 (a) θ-2θ XRD patterns and (b) Raman spectra of Cr2+:ZnSe films deposited on sapphire substrate at various growth temperatures.

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The Raman spectra for Cr2+:ZnSe films deposited on sapphire at various temperatures are shown in Fig. 2(b) with comparison to a bulk ZnSe polycrystal Raman spectrum. The Raman measurements are consistent with XRD analysis that the crystal quality of the films was better at deposition temperatures above 425 C. This assertion is supported by the well resolved intense peaks at 205 cm−1 and 250 cm−1 attributed to the transversal optical (TO) and longitudinal optical (LO) phonon modes of ZnSe, respectively [18], indicating the growth of high crystalline quality ZnSe lattice in samples deposited at the higher temperatures. Also visible at higher growth temperatures is a broader weak transversal acoustic (2TA) ZnSe phonon mode around 140 cm−1. At growth temperatures below 475 C, only a much broader LO phonon mode of ZnSe is distinguishable from the Raman spectra indicating that the films deposited at these temperatures were partially amorphous.

3.2 Optical characterization of deposited films

The optical transmission spectrum over 1000–270`0 nm spectral range of a typical Cr2+:ZnSe/sapphire film deposited at a substrate temperature of 400 οC is shown in Fig. 3 . The interference pattern revealed a good homogeneous film. By using the transmission oscillation period with the index of refraction of nZnSe ~2.44, the thickness of each deposited film was determined. The absorption dip seen near 1700 nm resulted from the 5T25E transition of Cr2+ ions. Using the obtained film thickness and assuming a peak absorption cross section of σ~1 × 10−18 cm2 for the Cr2+ ions similar to that measured through spectroscopic experiments in bulk samples [19,20], the Cr2+ ion concentration in each film was estimated. The Cr2+ concentrations were determined in this manner for several Cr2+:ZnSe/sapphire films deposited at various substrate temperatures from 375 C to 575 C using the same laser ablation target. The overall variation in calculated dopant ion concentration was less than 15% over the analyzed films. This result indicates that the ablation targets produced in-house were fairly uniformly doped and that there was adequate transfer of stoichiometry from target to film during PLD growth independently of substrate temperature.

 figure: Fig. 3

Fig. 3 The transmission spectrum of a 7.5 µm thick Cr2+:ZnSe/sapphire sample with Cr2+ concentration of ~6 × 1019 cm−3 deposited at 400 C.

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Figure 4(a) shows the normalized room temperature mid-IR PL spectra obtained under the same experimental conditions from Cr2+:ZnSe/sapphire sample of approximately 10 µm thick films with Cr2+ dopant concentrations of (i) 6 × 1019 cm−3, (ii) 3 × 1019 cm−3, (iii) < 2 × 1018 cm−3 (estimated from CrSe powder wt. % in target since Cr2+ absorption was below spectrometer detection limit), and (iv) 6 × 1018 cm−3. The PL measurements were obtained from direct optical excitation of the Cr2+ ions using a 1532 nm CW Er doped fiber laser. The PL emission signal was collected with a CaF2 lens and detected by an Acton Research Spectra-Pro 300i (ARC-300i) spectrometer equipped with a liquid nitrogen cooled InSb detector/lock-in-amplifier combination. The signal intensities were collected over the 2–3 µm spectral range, while the scattered pump radiation was filtered using a 2 µm germanium filter. All PL spectra obtained were typical for Cr2+:ZnSe crystals and resulted from the 5T25E Cr2+ intra-center transition. The PL signal intensities obtained from samples with concentrations greater that 1 × 1019 cm−3 were significantly weaker than the PL signal obtained from samples with dopant concentration below 1 × 1019 cm−3. This was attributed to concentration quenching within the highly doped samples (NCr > 1 × 1019 cm−3) resulting in the lifetime of emission being much shorter than in lower doped films. This result is in accordance with previous studies [19,21] showing that concentration quenching in bulk Cr2+:ZnSe begins above the critical dopant ion concentration of NCr~1019 cm−3 where the excited state Cr2+ lifetime drastically decreases. However, depending on the application, low-doped or highly-doped ZnSe films may be desirable. In the case of CW laser operation of Cr2+:ZnSe thin films, a low dopant concentration with a longer lifetime of emissions is desirable as opposed to the case of saturable Cr2+:ZnSe thin films for potential passive Q-switching and passive mode-locking where highly-doped films are more favorable.

 figure: Fig. 4

Fig. 4 (a) Normalized room temperature PL spectra measured from Cr2+:ZnSe/sapphire films with various dopant concentrations deposited at a substrate temperature of 475 οC. (b) Emission spectra measured (i) below and (ii) above laser threshold from Cr2+:ZnSe film of Cr2+ concentration of 6 × 1019 cm−3 deposited on sapphire substrate.(iii) Gain (in arbitrary units) and (iv) absorption (in cm−1) spectra of Cr2+:ZnSe with Cr2+ concentration of 6 × 1019 cm−3 from Ref [22]. (c) The output-input signal characteristics of the Cr2+:ZnSe/sapphire film deposited which depicts a lasing threshold energy density of approximately 0.11 J/cm2.

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Mid-IR planar waveguide lasing in gain-switched mode was demonstrated using a Cr2+:ZnSe film of thickness 7.5 μm deposited on sapphire at a substrate temperature of 400 C. From the sample’s transmission spectrum shown in Fig. 3, the Cr2+ concentration was estimated to be 6 × 1019 cm−3. The Cr2+:ZnSe/sapphire sample was optically pumped at room temperature by 1560 nm D2-Raman shifted Nd:YAG laser radiation with a pulse duration of 5 ns. The pump beam of diameter ~3.1 mm was directed perpendicularly to the front facet of the film. The resulting mid-IR emission spectrum along the waveguided direction of the Cr2+:ZnSe/sapphire sample edge facet was collected with a CaF2 lens and detected with an ARC-300i spectrometer and a liquid nitrogen cooled InSb detector. The PL kinetics were measured using a digital oscilloscope and the PL intensity was processed through a boxcar averager. At low pumped energies (Fig. 4(b)(i)), the typical PL measurement similar to the spectral characteristics seen in Fig. 4(a) was obtained from the sample. The kinetics of the luminescence from the film was measured to be shorter than the InSb detector response time (~500 ns) and significantly shorter that Cr2+ PL lifetime in low concentration doped ZnSe bulk samples (~5.4 µs). This is understandable since the film dopant concentration of 6 × 1019 cm−3 is much greater than the critical dopant concentration Ncr~1 × 1019 cm−3 that marks the beginning of concentration quenching. However, for Cr2+ concentration of 6 × 1019 cm−3, the estimated lifetime of luminescence should be longer than the pump pulse duration of 5 ns used for gain-switched excitation and a high concentration of the active ions should provide high amplification in the planar waveguide. Figure 4(b)(ii) shows that pumping above threshold resulted in the appearance of an intense, much narrower stimulated emission with a central peak around 2600 nm, much different than the typical PL seen at lower pumped energies. This stimulated emission is attributed to the planar waveguiding of the optical field set up by the lower index of refraction of the sapphire substrate with respect to the Cr2+:ZnSe film. The lasing peak at 2600 nm is shifted to the longer wavelengths with respect to the PL peak around 2100 nm. This shift resulted from the trade-off between maximum emission cross-section at ~2400 nm [22] (see Fig. 4(b)(iii)) and optical losses in the waveguide due to non-saturated chromium absorption (see Fig. 4(b)(iv)). Figure 4(c) depicts the dependence of the intensity of Cr2+:ZnSe planar waveguide emission at 2600 nm versus pump energy. The output-input characteristics clearly show the threshold-like behavior of the output signal with a threshold pumped energy density for planar lasing around 0.11 J/cm2.

Highly-doped Cr2+:ZnSe thin-film could be potentially used for passive Q-switching of the cavities of Er, Tm, and Ho lasers operating over 1.5–2.1 µm spectral range. Experiments were conducted to study CW and passively Q-switched Er:YAG laser pumped by an Er-fiber laser. A 5 mm diameter antireflection coated Er:YAG rod with Er concentration of 0.5 atomic % was used for the experiments. A 20 W Er fiber laser (ELR-20 IPG Photonics Corporation) with polarized oscillation at 1532 nm wavelength was used as the pump source. The optical scheme for the laser experiments is shown in Fig. 5(a) . The features of the input-output characteristics of the passively Q-switched Er:YAG laser using a 6 × 1019 cm−3 doped Cr2+:ZnSe thin film sample, and (i) 80% and (ii) 95% reflectivity of the output couplers is shown in Fig. 5(b). The output power obtained reached the level of 100 mW at 3W pumped power. For comparison, the CW oscillation of the Er:YAG laser with 80% output coupler was measured in the same cavity without the Cr2+:ZnSe sample (Fig. 5(b)(iii)). As one can see from Fig. 5(b) (i) and (iii), the slope efficiencies obtained were similar. However, the use of Cr2+:ZnSe thin-film Q-switcher results in laser threshold increasing from 0.6 W to 1.5 W for 80% reflectivity of the output coupler. Figure 5(c) represents a characteristic train of Q-switched Er:YAG pulses at 1.645μm obtained for input power of 1.5 W and 95% reflectivity of the output coupler. The emission spectrum shows that the passively Q-switched Er:YAG laser operates at repetition rate of 21 kHz and features an output pulse energy on the order of magnitude of several microjoules. This successful Q-switch demonstration exemplify the potential for Cr2+:ZnSe thin films to be used as possible passive mode-lockers of Er:YAG laser by increasing the Cr2+ concentration to the level higher than that used in the current Q-switch laser experiments. By increasing the dopant concentration, the excited state lifetime of the Cr2+ ions continues to drastically diminish as concentration quenching becomes dominant. This short-lived excited state of the Cr2+ ions is desirable for passive mode-lock applications involving Er, Tm, and Ho lasers operating in the 1.5–2.1 µm.

 figure: Fig. 5

Fig. 5 (a) The optical scheme used for the laser experiments. (b) Comparative Er:YAG input-output laser characteristics in Cr2+:ZnSe thin film Q-switched regime with (i) output coupler reflectivity R = 80%, (ii) R = 95%, and (iii) free running (R = 80%) regimes of operation. (c) The output pulses from passively Q-switched Er:YAG laser at pump power of 1.5 W with 95% output coupler.

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4. Conclusions

In summary, we report that highly doped Cr2+:ZnSe thin films can be used as saturable absorbers for passive Q-switching of Er:YAG laser cavity with potential to be used as a passive mode-locker of Er, Tm, and Ho lasers operating over 1.5–2.1 µm spectral region. The first demonstration of 2.6 μm mid-IR lasing in Cr2+:ZnSe waveguide structures grown by PLD is also reported. The transition metal doped II-VI planar waveguide laser structures could be attractive for chip-integrated optical laser design with diode laser excitation and electronic control of tunability required for highly sensitive portable opto-chemical sensors.

Acknowledgements

The authors would like to acknowledge funding support from the University of Dayton Research Institiute (Subcontract RSC 09011) and Materials and Manufacturing Directorate of AFRL, Prime Contract No. FA8650-06-D-5401/0013), and the National Science Foundation under grants DMR-0116098, EPS-0814103, and ECCS-0901376.

The work reported here partially involves intellectual property developed at the University of Alabama at Birmingham. This intellectual property has been licensed to the IPG Photonics Corporation. The UAB co-authors declare competing financial interests.

Currently a part of IPG Photonics Corporation.

References and links

1. L. D. DeLoach, R. H. Page, G. D. Wilke, S. A. Payne, and W. F. Krupke, “Transition metal-doped zinc chalcogenides: spectroscopy and laser demonstration of a new class of gain media,” IEEE J. Sel. Top. Quantum Electron. 32(6), 885–895 (1996). [CrossRef]  

2. R. H. Page, K. I. Schaffers, L. D. Deloach, G. D. Wilke, F. D. Patel, J. B. Tassano, S. A. Payne, W. F. Krupke, K. T. Chen, and A. Burger, “Cr2+-doped Zinc Chalcogenides as efficient, widely tunable mid-infrared lasers,” IEEE J. Sel. Top. Quantum Electron. 33(4), 609–619 (1997). [CrossRef]  

3. S. Mirov, V. Fedorov, I. Moskalev, D. Martyshkin, and C. Kim, “Progess in Cr2+ and Fe2+ doped mid-IR laser materials,” Laser Photonics Rev. 4(1), 21–41 (2010). [CrossRef]  

4. S. B. Mirov, V. V. Fedorov, I. S. Moskalev, and D. V. Martyshkin, “Recent progress in transition metal doped II-VI mid-IR lasers,” IEEE J. Sel. Top. Quantum Electron. 13(3), 810–822 (2007). [CrossRef]  

5. V. V. Fedorov, S. B. Mirov, A. Gallian, D. V. Badikov, M. P. Frolov, Y. V. Korostelin, V. I. Kozlovsky, A. I. Landman, Y. P. Podmar’kov, and V. A. Voronov, “3.77–5.05 µm Tunable solid state lasers based on Fe2+-doped ZnSe crystals operating at low and room temperatures,” IEEE J. Sel. Top. Quantum Electron. 42(9), 907–917 (2006). [CrossRef]  

6. A. Fazzio, M. J. Caldas, and A. Zunger, “Many-electron multiplet effects in the spectra of 3d impurities in heteropolar semiconductors,” Phys. Rev. B 30(6), 3430–3455 (1984). [CrossRef]  

7. G. J. Wagner, T. J. Carrig, R. H. Page, K. I. Schaffers, J. O. Ndap, X. Ma, and A. Burger, “Continuous-wave broadly tunable Cr2+:ZnSe laser,” Opt. Lett. 24(1), 19–21 (1999). [CrossRef]  

8. I. S. Moskalev, V. V. Fedorov, and S. B. Mirov, “10-watt, pure continuous-wave, polycrystalline Cr2+:ZnS laser,” Opt. Express 17(4), 2048–2056 (2009). [CrossRef]   [PubMed]  

9. I. S. Moskalev, V. V. Fedorov, S. B. Mirov, P. A. Berry, and K. L. Schepler, “12-Watt CW polycrystalline Cr2+:ZnSe laser pumped by Tm-fiber laser,” in Advance Solid-State Photonics, on CD-ROM (The Optical Society of America, Washington, DC, 2009).

10. V. V. Fedorov, A. Gallian, I. Moskalev, and S. B. Mirov, “En route to electrically pumped broadly tunable middle infrared lasers based on transition metal doped II-VI semiconductors,” J. Lumin. 125(1-2), 184–195 (2007). [CrossRef]  

11. J. Jaeck, R. Haidar, E. Rosencher, M. Caes, M. Tauvy, S. Collin, N. Bardou, J. Luc Pelouard, F. Pardo, and P. Lemasson, “Room-temperature electroluminescence in the mid-infrared (2-3 mµ) from bulk chromium-doped ZnSe,” Opt. Lett. 31(23), 3501–3503 (2006). [CrossRef]   [PubMed]  

12. N. A. Vlasenko, P. F. Oleksenko, Z. L. Denisova, M. O. Mukhlyo, and L. I. Veligura, “Cr-related energy levels and mechanism of Cr2+ ion photorecharge in ZnSe:Cr,” Phys. Status Solidi 245(11), 2550–2557 (2008) (b). [CrossRef]  

13. A. V. Vasilyev, N. A. Vlasenko, Z. L. Denisova, Ya. F. Kononets, A. I. Riskin, and A. Ya. Chomyak, “Electroluminescent emitters on range of 1.8-2.7 mkm,” Optoelecktronika I poluprovodnikovaya technika, Naukova Dumka 25, 68 (1993).

14. N. A. Vlasenko, Z. L. Denisova, Ya. F. Kononets, L. I. Veligura, and Yu. A. Tsyrkunov, “Near-infrared-emitting ZnSe:Er and ZnS(Se):Cr TFEL devices,” SID J. 12, 179–182 (2004).

15. A. Gallian, V. V. Fedorov, J. Kernal, J. Allman, S. B. Mirov, E. M. Dianov, A. O. Zabezhaylov, and I. P. Kazakov, “Spectroscopic studies of molecular-beam epitaxially grown Cr2+-doped ZnSe thin films,” Appl. Phys. Lett. 86(9), 091105 (2005). [CrossRef]  

16. N. Vivet, M. Morales, M. Levalois, J. L. Doualan, and R. Moncorge, “Photoluminescence properties of Cr2+:ZnSe films deposited by radio frequency magnetron cosputtering,” Appl. Phys. Lett. 90(18), 181915 (2007). [CrossRef]  

17. J. E. Williams, R. P. Camata, V. V. Fedorov, and S. B. Mirov, “Pulsed laser deposition of chromium-doped zinc selenide thin films for mid-infrared applications,” Appl. Phys., A Mater. Sci. Process. 91(2), 333–335 (2008). [CrossRef]  

18. O. Madelung, U. Rossler, and W. V. Osten, “Intristic properties of group IV elements and III-V, II-VI and II-VI compounds,” in Landolt-Bornstein: Numerical data and functional relationships in science and technology, H. Landolt, and R. Bornstein (Springer, 1987).

19. J. T. Vallin, G. A. Slack, S. Roberts, and A. E. Hughes, “Infrared absorption in some II-VI compounds doped with Cr,” Phys. Rev. B 2(11), 4313–4333 (1970). [CrossRef]  

20. A. Burger, K. Chattopadhyay, J. O. Ndap, X. Ma, S. H. Morgan, C. I. Rablau, C. H. Su, S. Feth, R. H. Page, K. I. Schaffers, and S. A. Payne, “Preparation conditions of chromium doped ZnSe and their infrared luminescence properties,” J. Cryst. Growth 225(2-4), 249–256 (2001). [CrossRef]  

21. A. Sennaroglu, U. Demirbas, A. Kurt, and M. Somer, “Direct experimental determination of the optimum chromium concentration in continuous-wave Cr2+:ZnSe lasers,” IEEE J. Sel. Top. Quantum Electron. 13(3), 823–830 (2007). [CrossRef]  

22. I. T. Sorokina, “Cr2+-doped II-VI materials for laser and nonlinear optics,” Opt. Mater. 26(4), 395–412 (2004). [CrossRef]  

References

  • View by:

  1. L. D. DeLoach, R. H. Page, G. D. Wilke, S. A. Payne, and W. F. Krupke, “Transition metal-doped zinc chalcogenides: spectroscopy and laser demonstration of a new class of gain media,” IEEE J. Sel. Top. Quantum Electron. 32(6), 885–895 (1996).
    [Crossref]
  2. R. H. Page, K. I. Schaffers, L. D. Deloach, G. D. Wilke, F. D. Patel, J. B. Tassano, S. A. Payne, W. F. Krupke, K. T. Chen, and A. Burger, “Cr2+-doped Zinc Chalcogenides as efficient, widely tunable mid-infrared lasers,” IEEE J. Sel. Top. Quantum Electron. 33(4), 609–619 (1997).
    [Crossref]
  3. S. Mirov, V. Fedorov, I. Moskalev, D. Martyshkin, and C. Kim, “Progess in Cr2+ and Fe2+ doped mid-IR laser materials,” Laser Photonics Rev. 4(1), 21–41 (2010).
    [Crossref]
  4. S. B. Mirov, V. V. Fedorov, I. S. Moskalev, and D. V. Martyshkin, “Recent progress in transition metal doped II-VI mid-IR lasers,” IEEE J. Sel. Top. Quantum Electron. 13(3), 810–822 (2007).
    [Crossref]
  5. V. V. Fedorov, S. B. Mirov, A. Gallian, D. V. Badikov, M. P. Frolov, Y. V. Korostelin, V. I. Kozlovsky, A. I. Landman, Y. P. Podmar’kov, and V. A. Voronov, “3.77–5.05 µm Tunable solid state lasers based on Fe2+-doped ZnSe crystals operating at low and room temperatures,” IEEE J. Sel. Top. Quantum Electron. 42(9), 907–917 (2006).
    [Crossref]
  6. A. Fazzio, M. J. Caldas, and A. Zunger, “Many-electron multiplet effects in the spectra of 3d impurities in heteropolar semiconductors,” Phys. Rev. B 30(6), 3430–3455 (1984).
    [Crossref]
  7. G. J. Wagner, T. J. Carrig, R. H. Page, K. I. Schaffers, J. O. Ndap, X. Ma, and A. Burger, “Continuous-wave broadly tunable Cr2+:ZnSe laser,” Opt. Lett. 24(1), 19–21 (1999).
    [Crossref]
  8. I. S. Moskalev, V. V. Fedorov, and S. B. Mirov, “10-watt, pure continuous-wave, polycrystalline Cr2+:ZnS laser,” Opt. Express 17(4), 2048–2056 (2009).
    [Crossref] [PubMed]
  9. I. S. Moskalev, V. V. Fedorov, S. B. Mirov, P. A. Berry, and K. L. Schepler, “12-Watt CW polycrystalline Cr2+:ZnSe laser pumped by Tm-fiber laser,” in Advance Solid-State Photonics, on CD-ROM (The Optical Society of America, Washington, DC, 2009).
  10. V. V. Fedorov, A. Gallian, I. Moskalev, and S. B. Mirov, “En route to electrically pumped broadly tunable middle infrared lasers based on transition metal doped II-VI semiconductors,” J. Lumin. 125(1-2), 184–195 (2007).
    [Crossref]
  11. J. Jaeck, R. Haidar, E. Rosencher, M. Caes, M. Tauvy, S. Collin, N. Bardou, J. Luc Pelouard, F. Pardo, and P. Lemasson, “Room-temperature electroluminescence in the mid-infrared (2-3 mµ) from bulk chromium-doped ZnSe,” Opt. Lett. 31(23), 3501–3503 (2006).
    [Crossref] [PubMed]
  12. N. A. Vlasenko, P. F. Oleksenko, Z. L. Denisova, M. O. Mukhlyo, and L. I. Veligura, “Cr-related energy levels and mechanism of Cr2+ ion photorecharge in ZnSe:Cr,” Phys. Status Solidi 245(11), 2550–2557 (2008) (b).
    [Crossref]
  13. A. V. Vasilyev, N. A. Vlasenko, Z. L. Denisova, Ya. F. Kononets, A. I. Riskin, and A. Ya. Chomyak, “Electroluminescent emitters on range of 1.8-2.7 mkm,” Optoelecktronika I poluprovodnikovaya technika, Naukova Dumka 25, 68 (1993).
  14. N. A. Vlasenko, Z. L. Denisova, Ya. F. Kononets, L. I. Veligura, and Yu. A. Tsyrkunov, “Near-infrared-emitting ZnSe:Er and ZnS(Se):Cr TFEL devices,” SID J. 12, 179–182 (2004).
  15. A. Gallian, V. V. Fedorov, J. Kernal, J. Allman, S. B. Mirov, E. M. Dianov, A. O. Zabezhaylov, and I. P. Kazakov, “Spectroscopic studies of molecular-beam epitaxially grown Cr2+-doped ZnSe thin films,” Appl. Phys. Lett. 86(9), 091105 (2005).
    [Crossref]
  16. N. Vivet, M. Morales, M. Levalois, J. L. Doualan, and R. Moncorge, “Photoluminescence properties of Cr2+:ZnSe films deposited by radio frequency magnetron cosputtering,” Appl. Phys. Lett. 90(18), 181915 (2007).
    [Crossref]
  17. J. E. Williams, R. P. Camata, V. V. Fedorov, and S. B. Mirov, “Pulsed laser deposition of chromium-doped zinc selenide thin films for mid-infrared applications,” Appl. Phys., A Mater. Sci. Process. 91(2), 333–335 (2008).
    [Crossref]
  18. O. Madelung, U. Rossler, and W. V. Osten, “Intristic properties of group IV elements and III-V, II-VI and II-VI compounds,” in Landolt-Bornstein: Numerical data and functional relationships in science and technology, H. Landolt, and R. Bornstein (Springer, 1987).
  19. J. T. Vallin, G. A. Slack, S. Roberts, and A. E. Hughes, “Infrared absorption in some II-VI compounds doped with Cr,” Phys. Rev. B 2(11), 4313–4333 (1970).
    [Crossref]
  20. A. Burger, K. Chattopadhyay, J. O. Ndap, X. Ma, S. H. Morgan, C. I. Rablau, C. H. Su, S. Feth, R. H. Page, K. I. Schaffers, and S. A. Payne, “Preparation conditions of chromium doped ZnSe and their infrared luminescence properties,” J. Cryst. Growth 225(2-4), 249–256 (2001).
    [Crossref]
  21. A. Sennaroglu, U. Demirbas, A. Kurt, and M. Somer, “Direct experimental determination of the optimum chromium concentration in continuous-wave Cr2+:ZnSe lasers,” IEEE J. Sel. Top. Quantum Electron. 13(3), 823–830 (2007).
    [Crossref]
  22. I. T. Sorokina, “Cr2+-doped II-VI materials for laser and nonlinear optics,” Opt. Mater. 26(4), 395–412 (2004).
    [Crossref]

2010 (1)

S. Mirov, V. Fedorov, I. Moskalev, D. Martyshkin, and C. Kim, “Progess in Cr2+ and Fe2+ doped mid-IR laser materials,” Laser Photonics Rev. 4(1), 21–41 (2010).
[Crossref]

2009 (1)

2008 (2)

N. A. Vlasenko, P. F. Oleksenko, Z. L. Denisova, M. O. Mukhlyo, and L. I. Veligura, “Cr-related energy levels and mechanism of Cr2+ ion photorecharge in ZnSe:Cr,” Phys. Status Solidi 245(11), 2550–2557 (2008) (b).
[Crossref]

J. E. Williams, R. P. Camata, V. V. Fedorov, and S. B. Mirov, “Pulsed laser deposition of chromium-doped zinc selenide thin films for mid-infrared applications,” Appl. Phys., A Mater. Sci. Process. 91(2), 333–335 (2008).
[Crossref]

2007 (4)

N. Vivet, M. Morales, M. Levalois, J. L. Doualan, and R. Moncorge, “Photoluminescence properties of Cr2+:ZnSe films deposited by radio frequency magnetron cosputtering,” Appl. Phys. Lett. 90(18), 181915 (2007).
[Crossref]

V. V. Fedorov, A. Gallian, I. Moskalev, and S. B. Mirov, “En route to electrically pumped broadly tunable middle infrared lasers based on transition metal doped II-VI semiconductors,” J. Lumin. 125(1-2), 184–195 (2007).
[Crossref]

S. B. Mirov, V. V. Fedorov, I. S. Moskalev, and D. V. Martyshkin, “Recent progress in transition metal doped II-VI mid-IR lasers,” IEEE J. Sel. Top. Quantum Electron. 13(3), 810–822 (2007).
[Crossref]

A. Sennaroglu, U. Demirbas, A. Kurt, and M. Somer, “Direct experimental determination of the optimum chromium concentration in continuous-wave Cr2+:ZnSe lasers,” IEEE J. Sel. Top. Quantum Electron. 13(3), 823–830 (2007).
[Crossref]

2006 (2)

V. V. Fedorov, S. B. Mirov, A. Gallian, D. V. Badikov, M. P. Frolov, Y. V. Korostelin, V. I. Kozlovsky, A. I. Landman, Y. P. Podmar’kov, and V. A. Voronov, “3.77–5.05 µm Tunable solid state lasers based on Fe2+-doped ZnSe crystals operating at low and room temperatures,” IEEE J. Sel. Top. Quantum Electron. 42(9), 907–917 (2006).
[Crossref]

J. Jaeck, R. Haidar, E. Rosencher, M. Caes, M. Tauvy, S. Collin, N. Bardou, J. Luc Pelouard, F. Pardo, and P. Lemasson, “Room-temperature electroluminescence in the mid-infrared (2-3 mµ) from bulk chromium-doped ZnSe,” Opt. Lett. 31(23), 3501–3503 (2006).
[Crossref] [PubMed]

2005 (1)

A. Gallian, V. V. Fedorov, J. Kernal, J. Allman, S. B. Mirov, E. M. Dianov, A. O. Zabezhaylov, and I. P. Kazakov, “Spectroscopic studies of molecular-beam epitaxially grown Cr2+-doped ZnSe thin films,” Appl. Phys. Lett. 86(9), 091105 (2005).
[Crossref]

2004 (2)

N. A. Vlasenko, Z. L. Denisova, Ya. F. Kononets, L. I. Veligura, and Yu. A. Tsyrkunov, “Near-infrared-emitting ZnSe:Er and ZnS(Se):Cr TFEL devices,” SID J. 12, 179–182 (2004).

I. T. Sorokina, “Cr2+-doped II-VI materials for laser and nonlinear optics,” Opt. Mater. 26(4), 395–412 (2004).
[Crossref]

2001 (1)

A. Burger, K. Chattopadhyay, J. O. Ndap, X. Ma, S. H. Morgan, C. I. Rablau, C. H. Su, S. Feth, R. H. Page, K. I. Schaffers, and S. A. Payne, “Preparation conditions of chromium doped ZnSe and their infrared luminescence properties,” J. Cryst. Growth 225(2-4), 249–256 (2001).
[Crossref]

1999 (1)

1997 (1)

R. H. Page, K. I. Schaffers, L. D. Deloach, G. D. Wilke, F. D. Patel, J. B. Tassano, S. A. Payne, W. F. Krupke, K. T. Chen, and A. Burger, “Cr2+-doped Zinc Chalcogenides as efficient, widely tunable mid-infrared lasers,” IEEE J. Sel. Top. Quantum Electron. 33(4), 609–619 (1997).
[Crossref]

1996 (1)

L. D. DeLoach, R. H. Page, G. D. Wilke, S. A. Payne, and W. F. Krupke, “Transition metal-doped zinc chalcogenides: spectroscopy and laser demonstration of a new class of gain media,” IEEE J. Sel. Top. Quantum Electron. 32(6), 885–895 (1996).
[Crossref]

1993 (1)

A. V. Vasilyev, N. A. Vlasenko, Z. L. Denisova, Ya. F. Kononets, A. I. Riskin, and A. Ya. Chomyak, “Electroluminescent emitters on range of 1.8-2.7 mkm,” Optoelecktronika I poluprovodnikovaya technika, Naukova Dumka 25, 68 (1993).

1984 (1)

A. Fazzio, M. J. Caldas, and A. Zunger, “Many-electron multiplet effects in the spectra of 3d impurities in heteropolar semiconductors,” Phys. Rev. B 30(6), 3430–3455 (1984).
[Crossref]

1970 (1)

J. T. Vallin, G. A. Slack, S. Roberts, and A. E. Hughes, “Infrared absorption in some II-VI compounds doped with Cr,” Phys. Rev. B 2(11), 4313–4333 (1970).
[Crossref]

Allman, J.

A. Gallian, V. V. Fedorov, J. Kernal, J. Allman, S. B. Mirov, E. M. Dianov, A. O. Zabezhaylov, and I. P. Kazakov, “Spectroscopic studies of molecular-beam epitaxially grown Cr2+-doped ZnSe thin films,” Appl. Phys. Lett. 86(9), 091105 (2005).
[Crossref]

Badikov, D. V.

V. V. Fedorov, S. B. Mirov, A. Gallian, D. V. Badikov, M. P. Frolov, Y. V. Korostelin, V. I. Kozlovsky, A. I. Landman, Y. P. Podmar’kov, and V. A. Voronov, “3.77–5.05 µm Tunable solid state lasers based on Fe2+-doped ZnSe crystals operating at low and room temperatures,” IEEE J. Sel. Top. Quantum Electron. 42(9), 907–917 (2006).
[Crossref]

Bardou, N.

Burger, A.

A. Burger, K. Chattopadhyay, J. O. Ndap, X. Ma, S. H. Morgan, C. I. Rablau, C. H. Su, S. Feth, R. H. Page, K. I. Schaffers, and S. A. Payne, “Preparation conditions of chromium doped ZnSe and their infrared luminescence properties,” J. Cryst. Growth 225(2-4), 249–256 (2001).
[Crossref]

G. J. Wagner, T. J. Carrig, R. H. Page, K. I. Schaffers, J. O. Ndap, X. Ma, and A. Burger, “Continuous-wave broadly tunable Cr2+:ZnSe laser,” Opt. Lett. 24(1), 19–21 (1999).
[Crossref]

R. H. Page, K. I. Schaffers, L. D. Deloach, G. D. Wilke, F. D. Patel, J. B. Tassano, S. A. Payne, W. F. Krupke, K. T. Chen, and A. Burger, “Cr2+-doped Zinc Chalcogenides as efficient, widely tunable mid-infrared lasers,” IEEE J. Sel. Top. Quantum Electron. 33(4), 609–619 (1997).
[Crossref]

Caes, M.

Caldas, M. J.

A. Fazzio, M. J. Caldas, and A. Zunger, “Many-electron multiplet effects in the spectra of 3d impurities in heteropolar semiconductors,” Phys. Rev. B 30(6), 3430–3455 (1984).
[Crossref]

Camata, R. P.

J. E. Williams, R. P. Camata, V. V. Fedorov, and S. B. Mirov, “Pulsed laser deposition of chromium-doped zinc selenide thin films for mid-infrared applications,” Appl. Phys., A Mater. Sci. Process. 91(2), 333–335 (2008).
[Crossref]

Carrig, T. J.

Chattopadhyay, K.

A. Burger, K. Chattopadhyay, J. O. Ndap, X. Ma, S. H. Morgan, C. I. Rablau, C. H. Su, S. Feth, R. H. Page, K. I. Schaffers, and S. A. Payne, “Preparation conditions of chromium doped ZnSe and their infrared luminescence properties,” J. Cryst. Growth 225(2-4), 249–256 (2001).
[Crossref]

Chen, K. T.

R. H. Page, K. I. Schaffers, L. D. Deloach, G. D. Wilke, F. D. Patel, J. B. Tassano, S. A. Payne, W. F. Krupke, K. T. Chen, and A. Burger, “Cr2+-doped Zinc Chalcogenides as efficient, widely tunable mid-infrared lasers,” IEEE J. Sel. Top. Quantum Electron. 33(4), 609–619 (1997).
[Crossref]

Chomyak, A. Ya.

A. V. Vasilyev, N. A. Vlasenko, Z. L. Denisova, Ya. F. Kononets, A. I. Riskin, and A. Ya. Chomyak, “Electroluminescent emitters on range of 1.8-2.7 mkm,” Optoelecktronika I poluprovodnikovaya technika, Naukova Dumka 25, 68 (1993).

Collin, S.

Deloach, L. D.

R. H. Page, K. I. Schaffers, L. D. Deloach, G. D. Wilke, F. D. Patel, J. B. Tassano, S. A. Payne, W. F. Krupke, K. T. Chen, and A. Burger, “Cr2+-doped Zinc Chalcogenides as efficient, widely tunable mid-infrared lasers,” IEEE J. Sel. Top. Quantum Electron. 33(4), 609–619 (1997).
[Crossref]

L. D. DeLoach, R. H. Page, G. D. Wilke, S. A. Payne, and W. F. Krupke, “Transition metal-doped zinc chalcogenides: spectroscopy and laser demonstration of a new class of gain media,” IEEE J. Sel. Top. Quantum Electron. 32(6), 885–895 (1996).
[Crossref]

Demirbas, U.

A. Sennaroglu, U. Demirbas, A. Kurt, and M. Somer, “Direct experimental determination of the optimum chromium concentration in continuous-wave Cr2+:ZnSe lasers,” IEEE J. Sel. Top. Quantum Electron. 13(3), 823–830 (2007).
[Crossref]

Denisova, Z. L.

N. A. Vlasenko, P. F. Oleksenko, Z. L. Denisova, M. O. Mukhlyo, and L. I. Veligura, “Cr-related energy levels and mechanism of Cr2+ ion photorecharge in ZnSe:Cr,” Phys. Status Solidi 245(11), 2550–2557 (2008) (b).
[Crossref]

N. A. Vlasenko, Z. L. Denisova, Ya. F. Kononets, L. I. Veligura, and Yu. A. Tsyrkunov, “Near-infrared-emitting ZnSe:Er and ZnS(Se):Cr TFEL devices,” SID J. 12, 179–182 (2004).

A. V. Vasilyev, N. A. Vlasenko, Z. L. Denisova, Ya. F. Kononets, A. I. Riskin, and A. Ya. Chomyak, “Electroluminescent emitters on range of 1.8-2.7 mkm,” Optoelecktronika I poluprovodnikovaya technika, Naukova Dumka 25, 68 (1993).

Dianov, E. M.

A. Gallian, V. V. Fedorov, J. Kernal, J. Allman, S. B. Mirov, E. M. Dianov, A. O. Zabezhaylov, and I. P. Kazakov, “Spectroscopic studies of molecular-beam epitaxially grown Cr2+-doped ZnSe thin films,” Appl. Phys. Lett. 86(9), 091105 (2005).
[Crossref]

Doualan, J. L.

N. Vivet, M. Morales, M. Levalois, J. L. Doualan, and R. Moncorge, “Photoluminescence properties of Cr2+:ZnSe films deposited by radio frequency magnetron cosputtering,” Appl. Phys. Lett. 90(18), 181915 (2007).
[Crossref]

Fazzio, A.

A. Fazzio, M. J. Caldas, and A. Zunger, “Many-electron multiplet effects in the spectra of 3d impurities in heteropolar semiconductors,” Phys. Rev. B 30(6), 3430–3455 (1984).
[Crossref]

Fedorov, V.

S. Mirov, V. Fedorov, I. Moskalev, D. Martyshkin, and C. Kim, “Progess in Cr2+ and Fe2+ doped mid-IR laser materials,” Laser Photonics Rev. 4(1), 21–41 (2010).
[Crossref]

Fedorov, V. V.

I. S. Moskalev, V. V. Fedorov, and S. B. Mirov, “10-watt, pure continuous-wave, polycrystalline Cr2+:ZnS laser,” Opt. Express 17(4), 2048–2056 (2009).
[Crossref] [PubMed]

J. E. Williams, R. P. Camata, V. V. Fedorov, and S. B. Mirov, “Pulsed laser deposition of chromium-doped zinc selenide thin films for mid-infrared applications,” Appl. Phys., A Mater. Sci. Process. 91(2), 333–335 (2008).
[Crossref]

V. V. Fedorov, A. Gallian, I. Moskalev, and S. B. Mirov, “En route to electrically pumped broadly tunable middle infrared lasers based on transition metal doped II-VI semiconductors,” J. Lumin. 125(1-2), 184–195 (2007).
[Crossref]

S. B. Mirov, V. V. Fedorov, I. S. Moskalev, and D. V. Martyshkin, “Recent progress in transition metal doped II-VI mid-IR lasers,” IEEE J. Sel. Top. Quantum Electron. 13(3), 810–822 (2007).
[Crossref]

V. V. Fedorov, S. B. Mirov, A. Gallian, D. V. Badikov, M. P. Frolov, Y. V. Korostelin, V. I. Kozlovsky, A. I. Landman, Y. P. Podmar’kov, and V. A. Voronov, “3.77–5.05 µm Tunable solid state lasers based on Fe2+-doped ZnSe crystals operating at low and room temperatures,” IEEE J. Sel. Top. Quantum Electron. 42(9), 907–917 (2006).
[Crossref]

A. Gallian, V. V. Fedorov, J. Kernal, J. Allman, S. B. Mirov, E. M. Dianov, A. O. Zabezhaylov, and I. P. Kazakov, “Spectroscopic studies of molecular-beam epitaxially grown Cr2+-doped ZnSe thin films,” Appl. Phys. Lett. 86(9), 091105 (2005).
[Crossref]

Feth, S.

A. Burger, K. Chattopadhyay, J. O. Ndap, X. Ma, S. H. Morgan, C. I. Rablau, C. H. Su, S. Feth, R. H. Page, K. I. Schaffers, and S. A. Payne, “Preparation conditions of chromium doped ZnSe and their infrared luminescence properties,” J. Cryst. Growth 225(2-4), 249–256 (2001).
[Crossref]

Frolov, M. P.

V. V. Fedorov, S. B. Mirov, A. Gallian, D. V. Badikov, M. P. Frolov, Y. V. Korostelin, V. I. Kozlovsky, A. I. Landman, Y. P. Podmar’kov, and V. A. Voronov, “3.77–5.05 µm Tunable solid state lasers based on Fe2+-doped ZnSe crystals operating at low and room temperatures,” IEEE J. Sel. Top. Quantum Electron. 42(9), 907–917 (2006).
[Crossref]

Gallian, A.

V. V. Fedorov, A. Gallian, I. Moskalev, and S. B. Mirov, “En route to electrically pumped broadly tunable middle infrared lasers based on transition metal doped II-VI semiconductors,” J. Lumin. 125(1-2), 184–195 (2007).
[Crossref]

V. V. Fedorov, S. B. Mirov, A. Gallian, D. V. Badikov, M. P. Frolov, Y. V. Korostelin, V. I. Kozlovsky, A. I. Landman, Y. P. Podmar’kov, and V. A. Voronov, “3.77–5.05 µm Tunable solid state lasers based on Fe2+-doped ZnSe crystals operating at low and room temperatures,” IEEE J. Sel. Top. Quantum Electron. 42(9), 907–917 (2006).
[Crossref]

A. Gallian, V. V. Fedorov, J. Kernal, J. Allman, S. B. Mirov, E. M. Dianov, A. O. Zabezhaylov, and I. P. Kazakov, “Spectroscopic studies of molecular-beam epitaxially grown Cr2+-doped ZnSe thin films,” Appl. Phys. Lett. 86(9), 091105 (2005).
[Crossref]

Haidar, R.

Hughes, A. E.

J. T. Vallin, G. A. Slack, S. Roberts, and A. E. Hughes, “Infrared absorption in some II-VI compounds doped with Cr,” Phys. Rev. B 2(11), 4313–4333 (1970).
[Crossref]

Jaeck, J.

Kazakov, I. P.

A. Gallian, V. V. Fedorov, J. Kernal, J. Allman, S. B. Mirov, E. M. Dianov, A. O. Zabezhaylov, and I. P. Kazakov, “Spectroscopic studies of molecular-beam epitaxially grown Cr2+-doped ZnSe thin films,” Appl. Phys. Lett. 86(9), 091105 (2005).
[Crossref]

Kernal, J.

A. Gallian, V. V. Fedorov, J. Kernal, J. Allman, S. B. Mirov, E. M. Dianov, A. O. Zabezhaylov, and I. P. Kazakov, “Spectroscopic studies of molecular-beam epitaxially grown Cr2+-doped ZnSe thin films,” Appl. Phys. Lett. 86(9), 091105 (2005).
[Crossref]

Kim, C.

S. Mirov, V. Fedorov, I. Moskalev, D. Martyshkin, and C. Kim, “Progess in Cr2+ and Fe2+ doped mid-IR laser materials,” Laser Photonics Rev. 4(1), 21–41 (2010).
[Crossref]

Kononets, Ya. F.

N. A. Vlasenko, Z. L. Denisova, Ya. F. Kononets, L. I. Veligura, and Yu. A. Tsyrkunov, “Near-infrared-emitting ZnSe:Er and ZnS(Se):Cr TFEL devices,” SID J. 12, 179–182 (2004).

A. V. Vasilyev, N. A. Vlasenko, Z. L. Denisova, Ya. F. Kononets, A. I. Riskin, and A. Ya. Chomyak, “Electroluminescent emitters on range of 1.8-2.7 mkm,” Optoelecktronika I poluprovodnikovaya technika, Naukova Dumka 25, 68 (1993).

Korostelin, Y. V.

V. V. Fedorov, S. B. Mirov, A. Gallian, D. V. Badikov, M. P. Frolov, Y. V. Korostelin, V. I. Kozlovsky, A. I. Landman, Y. P. Podmar’kov, and V. A. Voronov, “3.77–5.05 µm Tunable solid state lasers based on Fe2+-doped ZnSe crystals operating at low and room temperatures,” IEEE J. Sel. Top. Quantum Electron. 42(9), 907–917 (2006).
[Crossref]

Kozlovsky, V. I.

V. V. Fedorov, S. B. Mirov, A. Gallian, D. V. Badikov, M. P. Frolov, Y. V. Korostelin, V. I. Kozlovsky, A. I. Landman, Y. P. Podmar’kov, and V. A. Voronov, “3.77–5.05 µm Tunable solid state lasers based on Fe2+-doped ZnSe crystals operating at low and room temperatures,” IEEE J. Sel. Top. Quantum Electron. 42(9), 907–917 (2006).
[Crossref]

Krupke, W. F.

R. H. Page, K. I. Schaffers, L. D. Deloach, G. D. Wilke, F. D. Patel, J. B. Tassano, S. A. Payne, W. F. Krupke, K. T. Chen, and A. Burger, “Cr2+-doped Zinc Chalcogenides as efficient, widely tunable mid-infrared lasers,” IEEE J. Sel. Top. Quantum Electron. 33(4), 609–619 (1997).
[Crossref]

L. D. DeLoach, R. H. Page, G. D. Wilke, S. A. Payne, and W. F. Krupke, “Transition metal-doped zinc chalcogenides: spectroscopy and laser demonstration of a new class of gain media,” IEEE J. Sel. Top. Quantum Electron. 32(6), 885–895 (1996).
[Crossref]

Kurt, A.

A. Sennaroglu, U. Demirbas, A. Kurt, and M. Somer, “Direct experimental determination of the optimum chromium concentration in continuous-wave Cr2+:ZnSe lasers,” IEEE J. Sel. Top. Quantum Electron. 13(3), 823–830 (2007).
[Crossref]

Landman, A. I.

V. V. Fedorov, S. B. Mirov, A. Gallian, D. V. Badikov, M. P. Frolov, Y. V. Korostelin, V. I. Kozlovsky, A. I. Landman, Y. P. Podmar’kov, and V. A. Voronov, “3.77–5.05 µm Tunable solid state lasers based on Fe2+-doped ZnSe crystals operating at low and room temperatures,” IEEE J. Sel. Top. Quantum Electron. 42(9), 907–917 (2006).
[Crossref]

Lemasson, P.

Levalois, M.

N. Vivet, M. Morales, M. Levalois, J. L. Doualan, and R. Moncorge, “Photoluminescence properties of Cr2+:ZnSe films deposited by radio frequency magnetron cosputtering,” Appl. Phys. Lett. 90(18), 181915 (2007).
[Crossref]

Luc Pelouard, J.

Ma, X.

A. Burger, K. Chattopadhyay, J. O. Ndap, X. Ma, S. H. Morgan, C. I. Rablau, C. H. Su, S. Feth, R. H. Page, K. I. Schaffers, and S. A. Payne, “Preparation conditions of chromium doped ZnSe and their infrared luminescence properties,” J. Cryst. Growth 225(2-4), 249–256 (2001).
[Crossref]

G. J. Wagner, T. J. Carrig, R. H. Page, K. I. Schaffers, J. O. Ndap, X. Ma, and A. Burger, “Continuous-wave broadly tunable Cr2+:ZnSe laser,” Opt. Lett. 24(1), 19–21 (1999).
[Crossref]

Martyshkin, D.

S. Mirov, V. Fedorov, I. Moskalev, D. Martyshkin, and C. Kim, “Progess in Cr2+ and Fe2+ doped mid-IR laser materials,” Laser Photonics Rev. 4(1), 21–41 (2010).
[Crossref]

Martyshkin, D. V.

S. B. Mirov, V. V. Fedorov, I. S. Moskalev, and D. V. Martyshkin, “Recent progress in transition metal doped II-VI mid-IR lasers,” IEEE J. Sel. Top. Quantum Electron. 13(3), 810–822 (2007).
[Crossref]

Mirov, S.

S. Mirov, V. Fedorov, I. Moskalev, D. Martyshkin, and C. Kim, “Progess in Cr2+ and Fe2+ doped mid-IR laser materials,” Laser Photonics Rev. 4(1), 21–41 (2010).
[Crossref]

Mirov, S. B.

I. S. Moskalev, V. V. Fedorov, and S. B. Mirov, “10-watt, pure continuous-wave, polycrystalline Cr2+:ZnS laser,” Opt. Express 17(4), 2048–2056 (2009).
[Crossref] [PubMed]

J. E. Williams, R. P. Camata, V. V. Fedorov, and S. B. Mirov, “Pulsed laser deposition of chromium-doped zinc selenide thin films for mid-infrared applications,” Appl. Phys., A Mater. Sci. Process. 91(2), 333–335 (2008).
[Crossref]

V. V. Fedorov, A. Gallian, I. Moskalev, and S. B. Mirov, “En route to electrically pumped broadly tunable middle infrared lasers based on transition metal doped II-VI semiconductors,” J. Lumin. 125(1-2), 184–195 (2007).
[Crossref]

S. B. Mirov, V. V. Fedorov, I. S. Moskalev, and D. V. Martyshkin, “Recent progress in transition metal doped II-VI mid-IR lasers,” IEEE J. Sel. Top. Quantum Electron. 13(3), 810–822 (2007).
[Crossref]

V. V. Fedorov, S. B. Mirov, A. Gallian, D. V. Badikov, M. P. Frolov, Y. V. Korostelin, V. I. Kozlovsky, A. I. Landman, Y. P. Podmar’kov, and V. A. Voronov, “3.77–5.05 µm Tunable solid state lasers based on Fe2+-doped ZnSe crystals operating at low and room temperatures,” IEEE J. Sel. Top. Quantum Electron. 42(9), 907–917 (2006).
[Crossref]

A. Gallian, V. V. Fedorov, J. Kernal, J. Allman, S. B. Mirov, E. M. Dianov, A. O. Zabezhaylov, and I. P. Kazakov, “Spectroscopic studies of molecular-beam epitaxially grown Cr2+-doped ZnSe thin films,” Appl. Phys. Lett. 86(9), 091105 (2005).
[Crossref]

Moncorge, R.

N. Vivet, M. Morales, M. Levalois, J. L. Doualan, and R. Moncorge, “Photoluminescence properties of Cr2+:ZnSe films deposited by radio frequency magnetron cosputtering,” Appl. Phys. Lett. 90(18), 181915 (2007).
[Crossref]

Morales, M.

N. Vivet, M. Morales, M. Levalois, J. L. Doualan, and R. Moncorge, “Photoluminescence properties of Cr2+:ZnSe films deposited by radio frequency magnetron cosputtering,” Appl. Phys. Lett. 90(18), 181915 (2007).
[Crossref]

Morgan, S. H.

A. Burger, K. Chattopadhyay, J. O. Ndap, X. Ma, S. H. Morgan, C. I. Rablau, C. H. Su, S. Feth, R. H. Page, K. I. Schaffers, and S. A. Payne, “Preparation conditions of chromium doped ZnSe and their infrared luminescence properties,” J. Cryst. Growth 225(2-4), 249–256 (2001).
[Crossref]

Moskalev, I.

S. Mirov, V. Fedorov, I. Moskalev, D. Martyshkin, and C. Kim, “Progess in Cr2+ and Fe2+ doped mid-IR laser materials,” Laser Photonics Rev. 4(1), 21–41 (2010).
[Crossref]

V. V. Fedorov, A. Gallian, I. Moskalev, and S. B. Mirov, “En route to electrically pumped broadly tunable middle infrared lasers based on transition metal doped II-VI semiconductors,” J. Lumin. 125(1-2), 184–195 (2007).
[Crossref]

Moskalev, I. S.

I. S. Moskalev, V. V. Fedorov, and S. B. Mirov, “10-watt, pure continuous-wave, polycrystalline Cr2+:ZnS laser,” Opt. Express 17(4), 2048–2056 (2009).
[Crossref] [PubMed]

S. B. Mirov, V. V. Fedorov, I. S. Moskalev, and D. V. Martyshkin, “Recent progress in transition metal doped II-VI mid-IR lasers,” IEEE J. Sel. Top. Quantum Electron. 13(3), 810–822 (2007).
[Crossref]

Mukhlyo, M. O.

N. A. Vlasenko, P. F. Oleksenko, Z. L. Denisova, M. O. Mukhlyo, and L. I. Veligura, “Cr-related energy levels and mechanism of Cr2+ ion photorecharge in ZnSe:Cr,” Phys. Status Solidi 245(11), 2550–2557 (2008) (b).
[Crossref]

Ndap, J. O.

A. Burger, K. Chattopadhyay, J. O. Ndap, X. Ma, S. H. Morgan, C. I. Rablau, C. H. Su, S. Feth, R. H. Page, K. I. Schaffers, and S. A. Payne, “Preparation conditions of chromium doped ZnSe and their infrared luminescence properties,” J. Cryst. Growth 225(2-4), 249–256 (2001).
[Crossref]

G. J. Wagner, T. J. Carrig, R. H. Page, K. I. Schaffers, J. O. Ndap, X. Ma, and A. Burger, “Continuous-wave broadly tunable Cr2+:ZnSe laser,” Opt. Lett. 24(1), 19–21 (1999).
[Crossref]

Oleksenko, P. F.

N. A. Vlasenko, P. F. Oleksenko, Z. L. Denisova, M. O. Mukhlyo, and L. I. Veligura, “Cr-related energy levels and mechanism of Cr2+ ion photorecharge in ZnSe:Cr,” Phys. Status Solidi 245(11), 2550–2557 (2008) (b).
[Crossref]

Page, R. H.

A. Burger, K. Chattopadhyay, J. O. Ndap, X. Ma, S. H. Morgan, C. I. Rablau, C. H. Su, S. Feth, R. H. Page, K. I. Schaffers, and S. A. Payne, “Preparation conditions of chromium doped ZnSe and their infrared luminescence properties,” J. Cryst. Growth 225(2-4), 249–256 (2001).
[Crossref]

G. J. Wagner, T. J. Carrig, R. H. Page, K. I. Schaffers, J. O. Ndap, X. Ma, and A. Burger, “Continuous-wave broadly tunable Cr2+:ZnSe laser,” Opt. Lett. 24(1), 19–21 (1999).
[Crossref]

R. H. Page, K. I. Schaffers, L. D. Deloach, G. D. Wilke, F. D. Patel, J. B. Tassano, S. A. Payne, W. F. Krupke, K. T. Chen, and A. Burger, “Cr2+-doped Zinc Chalcogenides as efficient, widely tunable mid-infrared lasers,” IEEE J. Sel. Top. Quantum Electron. 33(4), 609–619 (1997).
[Crossref]

L. D. DeLoach, R. H. Page, G. D. Wilke, S. A. Payne, and W. F. Krupke, “Transition metal-doped zinc chalcogenides: spectroscopy and laser demonstration of a new class of gain media,” IEEE J. Sel. Top. Quantum Electron. 32(6), 885–895 (1996).
[Crossref]

Pardo, F.

Patel, F. D.

R. H. Page, K. I. Schaffers, L. D. Deloach, G. D. Wilke, F. D. Patel, J. B. Tassano, S. A. Payne, W. F. Krupke, K. T. Chen, and A. Burger, “Cr2+-doped Zinc Chalcogenides as efficient, widely tunable mid-infrared lasers,” IEEE J. Sel. Top. Quantum Electron. 33(4), 609–619 (1997).
[Crossref]

Payne, S. A.

A. Burger, K. Chattopadhyay, J. O. Ndap, X. Ma, S. H. Morgan, C. I. Rablau, C. H. Su, S. Feth, R. H. Page, K. I. Schaffers, and S. A. Payne, “Preparation conditions of chromium doped ZnSe and their infrared luminescence properties,” J. Cryst. Growth 225(2-4), 249–256 (2001).
[Crossref]

R. H. Page, K. I. Schaffers, L. D. Deloach, G. D. Wilke, F. D. Patel, J. B. Tassano, S. A. Payne, W. F. Krupke, K. T. Chen, and A. Burger, “Cr2+-doped Zinc Chalcogenides as efficient, widely tunable mid-infrared lasers,” IEEE J. Sel. Top. Quantum Electron. 33(4), 609–619 (1997).
[Crossref]

L. D. DeLoach, R. H. Page, G. D. Wilke, S. A. Payne, and W. F. Krupke, “Transition metal-doped zinc chalcogenides: spectroscopy and laser demonstration of a new class of gain media,” IEEE J. Sel. Top. Quantum Electron. 32(6), 885–895 (1996).
[Crossref]

Podmar’kov, Y. P.

V. V. Fedorov, S. B. Mirov, A. Gallian, D. V. Badikov, M. P. Frolov, Y. V. Korostelin, V. I. Kozlovsky, A. I. Landman, Y. P. Podmar’kov, and V. A. Voronov, “3.77–5.05 µm Tunable solid state lasers based on Fe2+-doped ZnSe crystals operating at low and room temperatures,” IEEE J. Sel. Top. Quantum Electron. 42(9), 907–917 (2006).
[Crossref]

Rablau, C. I.

A. Burger, K. Chattopadhyay, J. O. Ndap, X. Ma, S. H. Morgan, C. I. Rablau, C. H. Su, S. Feth, R. H. Page, K. I. Schaffers, and S. A. Payne, “Preparation conditions of chromium doped ZnSe and their infrared luminescence properties,” J. Cryst. Growth 225(2-4), 249–256 (2001).
[Crossref]

Riskin, A. I.

A. V. Vasilyev, N. A. Vlasenko, Z. L. Denisova, Ya. F. Kononets, A. I. Riskin, and A. Ya. Chomyak, “Electroluminescent emitters on range of 1.8-2.7 mkm,” Optoelecktronika I poluprovodnikovaya technika, Naukova Dumka 25, 68 (1993).

Roberts, S.

J. T. Vallin, G. A. Slack, S. Roberts, and A. E. Hughes, “Infrared absorption in some II-VI compounds doped with Cr,” Phys. Rev. B 2(11), 4313–4333 (1970).
[Crossref]

Rosencher, E.

Schaffers, K. I.

A. Burger, K. Chattopadhyay, J. O. Ndap, X. Ma, S. H. Morgan, C. I. Rablau, C. H. Su, S. Feth, R. H. Page, K. I. Schaffers, and S. A. Payne, “Preparation conditions of chromium doped ZnSe and their infrared luminescence properties,” J. Cryst. Growth 225(2-4), 249–256 (2001).
[Crossref]

G. J. Wagner, T. J. Carrig, R. H. Page, K. I. Schaffers, J. O. Ndap, X. Ma, and A. Burger, “Continuous-wave broadly tunable Cr2+:ZnSe laser,” Opt. Lett. 24(1), 19–21 (1999).
[Crossref]

R. H. Page, K. I. Schaffers, L. D. Deloach, G. D. Wilke, F. D. Patel, J. B. Tassano, S. A. Payne, W. F. Krupke, K. T. Chen, and A. Burger, “Cr2+-doped Zinc Chalcogenides as efficient, widely tunable mid-infrared lasers,” IEEE J. Sel. Top. Quantum Electron. 33(4), 609–619 (1997).
[Crossref]

Sennaroglu, A.

A. Sennaroglu, U. Demirbas, A. Kurt, and M. Somer, “Direct experimental determination of the optimum chromium concentration in continuous-wave Cr2+:ZnSe lasers,” IEEE J. Sel. Top. Quantum Electron. 13(3), 823–830 (2007).
[Crossref]

Slack, G. A.

J. T. Vallin, G. A. Slack, S. Roberts, and A. E. Hughes, “Infrared absorption in some II-VI compounds doped with Cr,” Phys. Rev. B 2(11), 4313–4333 (1970).
[Crossref]

Somer, M.

A. Sennaroglu, U. Demirbas, A. Kurt, and M. Somer, “Direct experimental determination of the optimum chromium concentration in continuous-wave Cr2+:ZnSe lasers,” IEEE J. Sel. Top. Quantum Electron. 13(3), 823–830 (2007).
[Crossref]

Sorokina, I. T.

I. T. Sorokina, “Cr2+-doped II-VI materials for laser and nonlinear optics,” Opt. Mater. 26(4), 395–412 (2004).
[Crossref]

Su, C. H.

A. Burger, K. Chattopadhyay, J. O. Ndap, X. Ma, S. H. Morgan, C. I. Rablau, C. H. Su, S. Feth, R. H. Page, K. I. Schaffers, and S. A. Payne, “Preparation conditions of chromium doped ZnSe and their infrared luminescence properties,” J. Cryst. Growth 225(2-4), 249–256 (2001).
[Crossref]

Tassano, J. B.

R. H. Page, K. I. Schaffers, L. D. Deloach, G. D. Wilke, F. D. Patel, J. B. Tassano, S. A. Payne, W. F. Krupke, K. T. Chen, and A. Burger, “Cr2+-doped Zinc Chalcogenides as efficient, widely tunable mid-infrared lasers,” IEEE J. Sel. Top. Quantum Electron. 33(4), 609–619 (1997).
[Crossref]

Tauvy, M.

Tsyrkunov, Yu. A.

N. A. Vlasenko, Z. L. Denisova, Ya. F. Kononets, L. I. Veligura, and Yu. A. Tsyrkunov, “Near-infrared-emitting ZnSe:Er and ZnS(Se):Cr TFEL devices,” SID J. 12, 179–182 (2004).

Vallin, J. T.

J. T. Vallin, G. A. Slack, S. Roberts, and A. E. Hughes, “Infrared absorption in some II-VI compounds doped with Cr,” Phys. Rev. B 2(11), 4313–4333 (1970).
[Crossref]

Vasilyev, A. V.

A. V. Vasilyev, N. A. Vlasenko, Z. L. Denisova, Ya. F. Kononets, A. I. Riskin, and A. Ya. Chomyak, “Electroluminescent emitters on range of 1.8-2.7 mkm,” Optoelecktronika I poluprovodnikovaya technika, Naukova Dumka 25, 68 (1993).

Veligura, L. I.

N. A. Vlasenko, P. F. Oleksenko, Z. L. Denisova, M. O. Mukhlyo, and L. I. Veligura, “Cr-related energy levels and mechanism of Cr2+ ion photorecharge in ZnSe:Cr,” Phys. Status Solidi 245(11), 2550–2557 (2008) (b).
[Crossref]

N. A. Vlasenko, Z. L. Denisova, Ya. F. Kononets, L. I. Veligura, and Yu. A. Tsyrkunov, “Near-infrared-emitting ZnSe:Er and ZnS(Se):Cr TFEL devices,” SID J. 12, 179–182 (2004).

Vivet, N.

N. Vivet, M. Morales, M. Levalois, J. L. Doualan, and R. Moncorge, “Photoluminescence properties of Cr2+:ZnSe films deposited by radio frequency magnetron cosputtering,” Appl. Phys. Lett. 90(18), 181915 (2007).
[Crossref]

Vlasenko, N. A.

N. A. Vlasenko, P. F. Oleksenko, Z. L. Denisova, M. O. Mukhlyo, and L. I. Veligura, “Cr-related energy levels and mechanism of Cr2+ ion photorecharge in ZnSe:Cr,” Phys. Status Solidi 245(11), 2550–2557 (2008) (b).
[Crossref]

N. A. Vlasenko, Z. L. Denisova, Ya. F. Kononets, L. I. Veligura, and Yu. A. Tsyrkunov, “Near-infrared-emitting ZnSe:Er and ZnS(Se):Cr TFEL devices,” SID J. 12, 179–182 (2004).

A. V. Vasilyev, N. A. Vlasenko, Z. L. Denisova, Ya. F. Kononets, A. I. Riskin, and A. Ya. Chomyak, “Electroluminescent emitters on range of 1.8-2.7 mkm,” Optoelecktronika I poluprovodnikovaya technika, Naukova Dumka 25, 68 (1993).

Voronov, V. A.

V. V. Fedorov, S. B. Mirov, A. Gallian, D. V. Badikov, M. P. Frolov, Y. V. Korostelin, V. I. Kozlovsky, A. I. Landman, Y. P. Podmar’kov, and V. A. Voronov, “3.77–5.05 µm Tunable solid state lasers based on Fe2+-doped ZnSe crystals operating at low and room temperatures,” IEEE J. Sel. Top. Quantum Electron. 42(9), 907–917 (2006).
[Crossref]

Wagner, G. J.

Wilke, G. D.

R. H. Page, K. I. Schaffers, L. D. Deloach, G. D. Wilke, F. D. Patel, J. B. Tassano, S. A. Payne, W. F. Krupke, K. T. Chen, and A. Burger, “Cr2+-doped Zinc Chalcogenides as efficient, widely tunable mid-infrared lasers,” IEEE J. Sel. Top. Quantum Electron. 33(4), 609–619 (1997).
[Crossref]

L. D. DeLoach, R. H. Page, G. D. Wilke, S. A. Payne, and W. F. Krupke, “Transition metal-doped zinc chalcogenides: spectroscopy and laser demonstration of a new class of gain media,” IEEE J. Sel. Top. Quantum Electron. 32(6), 885–895 (1996).
[Crossref]

Williams, J. E.

J. E. Williams, R. P. Camata, V. V. Fedorov, and S. B. Mirov, “Pulsed laser deposition of chromium-doped zinc selenide thin films for mid-infrared applications,” Appl. Phys., A Mater. Sci. Process. 91(2), 333–335 (2008).
[Crossref]

Zabezhaylov, A. O.

A. Gallian, V. V. Fedorov, J. Kernal, J. Allman, S. B. Mirov, E. M. Dianov, A. O. Zabezhaylov, and I. P. Kazakov, “Spectroscopic studies of molecular-beam epitaxially grown Cr2+-doped ZnSe thin films,” Appl. Phys. Lett. 86(9), 091105 (2005).
[Crossref]

Zunger, A.

A. Fazzio, M. J. Caldas, and A. Zunger, “Many-electron multiplet effects in the spectra of 3d impurities in heteropolar semiconductors,” Phys. Rev. B 30(6), 3430–3455 (1984).
[Crossref]

Appl. Phys. Lett. (2)

A. Gallian, V. V. Fedorov, J. Kernal, J. Allman, S. B. Mirov, E. M. Dianov, A. O. Zabezhaylov, and I. P. Kazakov, “Spectroscopic studies of molecular-beam epitaxially grown Cr2+-doped ZnSe thin films,” Appl. Phys. Lett. 86(9), 091105 (2005).
[Crossref]

N. Vivet, M. Morales, M. Levalois, J. L. Doualan, and R. Moncorge, “Photoluminescence properties of Cr2+:ZnSe films deposited by radio frequency magnetron cosputtering,” Appl. Phys. Lett. 90(18), 181915 (2007).
[Crossref]

Appl. Phys., A Mater. Sci. Process. (1)

J. E. Williams, R. P. Camata, V. V. Fedorov, and S. B. Mirov, “Pulsed laser deposition of chromium-doped zinc selenide thin films for mid-infrared applications,” Appl. Phys., A Mater. Sci. Process. 91(2), 333–335 (2008).
[Crossref]

IEEE J. Sel. Top. Quantum Electron. (5)

L. D. DeLoach, R. H. Page, G. D. Wilke, S. A. Payne, and W. F. Krupke, “Transition metal-doped zinc chalcogenides: spectroscopy and laser demonstration of a new class of gain media,” IEEE J. Sel. Top. Quantum Electron. 32(6), 885–895 (1996).
[Crossref]

R. H. Page, K. I. Schaffers, L. D. Deloach, G. D. Wilke, F. D. Patel, J. B. Tassano, S. A. Payne, W. F. Krupke, K. T. Chen, and A. Burger, “Cr2+-doped Zinc Chalcogenides as efficient, widely tunable mid-infrared lasers,” IEEE J. Sel. Top. Quantum Electron. 33(4), 609–619 (1997).
[Crossref]

S. B. Mirov, V. V. Fedorov, I. S. Moskalev, and D. V. Martyshkin, “Recent progress in transition metal doped II-VI mid-IR lasers,” IEEE J. Sel. Top. Quantum Electron. 13(3), 810–822 (2007).
[Crossref]

V. V. Fedorov, S. B. Mirov, A. Gallian, D. V. Badikov, M. P. Frolov, Y. V. Korostelin, V. I. Kozlovsky, A. I. Landman, Y. P. Podmar’kov, and V. A. Voronov, “3.77–5.05 µm Tunable solid state lasers based on Fe2+-doped ZnSe crystals operating at low and room temperatures,” IEEE J. Sel. Top. Quantum Electron. 42(9), 907–917 (2006).
[Crossref]

A. Sennaroglu, U. Demirbas, A. Kurt, and M. Somer, “Direct experimental determination of the optimum chromium concentration in continuous-wave Cr2+:ZnSe lasers,” IEEE J. Sel. Top. Quantum Electron. 13(3), 823–830 (2007).
[Crossref]

J. Cryst. Growth (1)

A. Burger, K. Chattopadhyay, J. O. Ndap, X. Ma, S. H. Morgan, C. I. Rablau, C. H. Su, S. Feth, R. H. Page, K. I. Schaffers, and S. A. Payne, “Preparation conditions of chromium doped ZnSe and their infrared luminescence properties,” J. Cryst. Growth 225(2-4), 249–256 (2001).
[Crossref]

J. Lumin. (1)

V. V. Fedorov, A. Gallian, I. Moskalev, and S. B. Mirov, “En route to electrically pumped broadly tunable middle infrared lasers based on transition metal doped II-VI semiconductors,” J. Lumin. 125(1-2), 184–195 (2007).
[Crossref]

Laser Photonics Rev. (1)

S. Mirov, V. Fedorov, I. Moskalev, D. Martyshkin, and C. Kim, “Progess in Cr2+ and Fe2+ doped mid-IR laser materials,” Laser Photonics Rev. 4(1), 21–41 (2010).
[Crossref]

Opt. Express (1)

Opt. Lett. (2)

Opt. Mater. (1)

I. T. Sorokina, “Cr2+-doped II-VI materials for laser and nonlinear optics,” Opt. Mater. 26(4), 395–412 (2004).
[Crossref]

Optoelecktronika I poluprovodnikovaya technika, Naukova Dumka (1)

A. V. Vasilyev, N. A. Vlasenko, Z. L. Denisova, Ya. F. Kononets, A. I. Riskin, and A. Ya. Chomyak, “Electroluminescent emitters on range of 1.8-2.7 mkm,” Optoelecktronika I poluprovodnikovaya technika, Naukova Dumka 25, 68 (1993).

Phys. Rev. B (2)

J. T. Vallin, G. A. Slack, S. Roberts, and A. E. Hughes, “Infrared absorption in some II-VI compounds doped with Cr,” Phys. Rev. B 2(11), 4313–4333 (1970).
[Crossref]

A. Fazzio, M. J. Caldas, and A. Zunger, “Many-electron multiplet effects in the spectra of 3d impurities in heteropolar semiconductors,” Phys. Rev. B 30(6), 3430–3455 (1984).
[Crossref]

Phys. Status Solidi (1)

N. A. Vlasenko, P. F. Oleksenko, Z. L. Denisova, M. O. Mukhlyo, and L. I. Veligura, “Cr-related energy levels and mechanism of Cr2+ ion photorecharge in ZnSe:Cr,” Phys. Status Solidi 245(11), 2550–2557 (2008) (b).
[Crossref]

SID J. (1)

N. A. Vlasenko, Z. L. Denisova, Ya. F. Kononets, L. I. Veligura, and Yu. A. Tsyrkunov, “Near-infrared-emitting ZnSe:Er and ZnS(Se):Cr TFEL devices,” SID J. 12, 179–182 (2004).

Other (2)

O. Madelung, U. Rossler, and W. V. Osten, “Intristic properties of group IV elements and III-V, II-VI and II-VI compounds,” in Landolt-Bornstein: Numerical data and functional relationships in science and technology, H. Landolt, and R. Bornstein (Springer, 1987).

I. S. Moskalev, V. V. Fedorov, S. B. Mirov, P. A. Berry, and K. L. Schepler, “12-Watt CW polycrystalline Cr2+:ZnSe laser pumped by Tm-fiber laser,” in Advance Solid-State Photonics, on CD-ROM (The Optical Society of America, Washington, DC, 2009).

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Figures (5)

Fig. 1
Fig. 1 AFM images of (a) 50 × 50 μm scan area and (b) 5 × 5 μm scan area of a 10 μm thick Cr2+:ZnSe film deposited on sapphire. The surface areas RMS roughness was smaller than 10 nm.
Fig. 2
Fig. 2 (a) θ-2θ XRD patterns and (b) Raman spectra of Cr2+:ZnSe films deposited on sapphire substrate at various growth temperatures.
Fig. 3
Fig. 3 The transmission spectrum of a 7.5 µm thick Cr2+:ZnSe/sapphire sample with Cr2+ concentration of ~6 × 1019 cm−3 deposited at 400 C.
Fig. 4
Fig. 4 (a) Normalized room temperature PL spectra measured from Cr2+:ZnSe/sapphire films with various dopant concentrations deposited at a substrate temperature of 475 οC. (b) Emission spectra measured (i) below and (ii) above laser threshold from Cr2+:ZnSe film of Cr2+ concentration of 6 × 1019 cm−3 deposited on sapphire substrate.(iii) Gain (in arbitrary units) and (iv) absorption (in cm−1) spectra of Cr2+:ZnSe with Cr2+ concentration of 6 × 1019 cm−3 from Ref [22]. (c) The output-input signal characteristics of the Cr2+:ZnSe/sapphire film deposited which depicts a lasing threshold energy density of approximately 0.11 J/cm2.
Fig. 5
Fig. 5 (a) The optical scheme used for the laser experiments. (b) Comparative Er:YAG input-output laser characteristics in Cr2+:ZnSe thin film Q-switched regime with (i) output coupler reflectivity R = 80%, (ii) R = 95%, and (iii) free running (R = 80%) regimes of operation. (c) The output pulses from passively Q-switched Er:YAG laser at pump power of 1.5 W with 95% output coupler.

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