Abstract

Thin films of (x)GeO2:(1-x)SiO2, 0≤x≤0.4, were fabricated via the sol-gel technique. Many applications of optics and photonics can benefit from the knowledge of the optical dispersion relationship of this ubiquitous binary ceramic material. The optical properties of the homogeneous and amorphous silica-based films were derived by spectroscopic ellipsometry (SE) with a multi-sample and multi-angle technique. The physical model used in SE has been rigorously verified. A simple, yet reliable, method is described to produce a dispersion-composition surface for visualizing, and hence, predicting refractive indices of the films. The Sellmeier model was effectively used to describe the optical dispersion properties of the GeO2:SiO2 films for a range of wavelengths from 210 to 1700 nm. Dispersion parameters were determined to evaluate the change in the compositional-dependent dispersion characteristics. In addition, the material dispersion coefficient and zero-dispersion wavelength were found to vary with x.

©2005 Optical Society of America

1. Introduction

The binary material system of GeO2:SiO2 has been well studied in the past, primarily due to the advent of optical fiber communications in the early 1970s. As germanium is in the same group as silicon in the periodic table, they are chemically compatible substitutes for each other. The refractive index (RI) of pure SiO2 is ~1.46 and that of GeO2 is ~1.61 have allowed the respective binary system to be well-suited for numerous applications in optical communications. According to the Lorentz-Lorenz equation, the RI depends upon the polarizability of the atomic species. Germanium having a higher electron count and hence a larger atomic size understandably possess a higher polarizability, thus a higher RI, than Si. When mixed, the binary oxide has been observed to exhibit linear relationships with compositions for many physical properties like RI, density which enable the material to be used with facile. Besides being chemically stable comparing to other oxides, recent studies have found the GeO2:SiO2 system interesting due to such properties as photosensitivity, an efficient host for optically active dopants, nonlinearity upon UV radiation [15].

The versatility of spectroscopic ellipsometer (SE) in characterization of material properties of semiconductor and dielectric films has been evident through the abundance of work in the literature [6, 7]. By using SE, the optical function of the thin film can be determined to a fair degree of accuracy (~10-4). For an accurate determination of the optical function, the noise associated with SE measurements can be further reduced by performing a multi-sample analysis. Alternatively, by employing multiple incident-angles measurements, enabled by commercial variable-angle SEs, the number of samples used in optical function determination can, thus, be reduced. Such information provides details of the material dispersion that can be useful in applications such as dispersion management devices, linear and nonlinear optical applications. An accurate determination of the optical function of dense GeO2:SiO2 material also enables accurate ellipsometric porosimetry in applications as employed in Ref. [8]. GeO2:SiO2 is also finding applications in the microelectronics in the form of insulation for SiGe transistors [9] and interlayer dielectric in ULSI [10]. The knowledge of how the optical function of (x)GeO2:(1-x)SiO2 changes with the molar fraction of GeO2, x, will facilitate the characterization of such dielectric oxide films. Also, the anticipated expansion of the telecommunication window to wavelengths of 1.2–1.7 µm warrants a reliable and fast method to determine the spectral RI of ceramic films at different compositions for different photonics devices.

GeO2:SiO2 films have been studied using many deposition techniques such as flame hydrolysis deposition, plasma assisted CVD, RF sputtering and sol-gel process. The latter presents itself as a commercially attractive fabrication technique which is capable of yielding stoichiometric multi-component dielectric films at low costs. The study presented here deals with thin films of GeO2:SiO2 prepared by the sol-gel/spin-coating process and material characterization of (x)GeO2:(1-x)SiO2 thin films. However, reports [4, 1113], to-date, have not provided spectral RI for germanosilicate at different compositions. With the use of spectroscopic ellipsometer, the authors are able to determine spectral optical properties of (x)GeO2:(1-x)SiO2 glass over a substantial wavelength range. A simple and robust scheme based on the Sellmeier dispersion is demonstrated to predict any refractive index, for x≤0.4, between the wavelength of 210 and 1700 nm inclusively. The difference in the dispersion characteristics with varying concentration x will be discussed.

2. Experiments

The sol-gel solutions were prepared according to procedures similar to Ref. [14]. Briefly, the silicon precursor, TEOS (Aldrich, 99.999%) was pre-hydrolyzed by diluted HCl in de-ionized water before mixing with pre-dissolved germanium precursor (Germanium Isopropoxide, 99.99% Chemat Technology Inc.) in anhydrous isopropanol. The sols were kept at pH 3 to reduce the likelihood of GeO2 crystallization [15]. The mixed sols containing both Si and Ge precursors were aged for at least 3 hours before spin coating. The spinnable sol was then spin-coated at 1000 rpm under ~25°C in flowing N2. The substrates were resistive (12–16 Ω-cm) p-doped (Boron) Si <100> wafers. Conventional electric furnaces were used to heat treat the samples in air for 15 minutes. Two samples were made for each composition, one being ~100 nm and the other at ~300 nm thick. The thicker samples are made by multiple coating with 1 to 3 minutes of intermediate heating at the densifying temperature of 1000°C and 1100°C. The sol recipes were designed to yield films with atomically smooth surface, thickness uniformity and striation-free films.

A Spectroscopic Ellipsometer (VASE, J.A. Woollam Co.) was used to measure the ellipsometric values at incident angles of 60° and 75° for a spectral range of 210 to 1700 nm. The errors on the ellipsometric angles, Ψ and Δ, were less than 0.30° and 1.50°, respectively. The data acquisition and analysis software application used was WVASE32 by J.A. Woollam Co. It uses a Levenberg-Marquardt algorithm to search for optimized model parameters. Due to the complexity and the large volume of data involved to derive the dispersion spectra, the details of the data analysis are beyond the scope of this report. FTIR (Perkin-Elmer Spectrum 2000 spectrometer) transmission spectra were measured with a resolution of 4 cm-1. UV-VIS transmission spectra were taken by HP 8453 spectrophotometer. Raman scattering was measured by a micro-Raman Spectroscopy system (Renishaw Ramascope) using a 514.5 nm Argon Ion laser with an average output of 25 mW. Raman shifts in the range of 100 cm-1 to 1200 cm-1 were monitored. Glancing-angle XRD (Siemens D5005 using a CuKα source) was used to scan 2θ angles from 0 to 65°. Surface roughness of the films was measured by a Scanning Probe Microscope (SPM, Digital Instruments Dimension 3000 with a Nanoscope IIIa control module). Scan range was 1 µm×1 µm and 256 lines/µm. From the measured data of mircro-Raman, XRD and SPM, our films were found to be free of crystalline phases and surface roughness (RMS roughness < 1 nm). Cross-sectional TEM was performed with Philps/FEI CM200 FEG. Rutherford Backscattering (RBS) was carried out with 2 MeV He2+ (Errors on thickness values are ≤5% and on composition are ≤2%).

3. Results and discussions

FTIR measurements revealed all tested samples, up to x=0.400, to be dense with the prominent peaks representing Si-O-Si (1080–1200 cm-1), Si-O-Ge (960–1020 cm-1) and Ge-O-Ge (900–980 cm-1) bonds and indiscernible OH related absorption between 2700 to 3800 cm-1. UV-VIS transmission spectra were taken for similar films deposited on quartz substrates. The oxygen-deficient defects in GeO2:SiO2 films with an absorption peak at ca. 240 nm [4] are absent from all of the spectra. Hence, we conclude that our films are dense and stoichiometric in composition. Furthermore, XRD and micro-Raman measurements reveal that all the signature peaks of crystalline GeO2 are absent in all samples. These results demonstrate that our samples are indeed free of crystalline phases of GeO2 at a high temperature of 1000°C. With such a priori information, a physical model representing the film structure was constructed for analyzing the spectroscopic ellipsometer (SE) data.

As revealed by the UV-VIS spectra, the optical bandgap of the homogeneous GeO2:SiO2 films (x≤0.4) is less than 200 nm. The Sellmeier model (the material absorption is assumed to be negligible) is, thus, appropriate for the determination of the optical constants from 210 to 1700 nm. Using the Sellmeier model, the dispersion in RI is expressed as [7]

n2=ε=εoffset+aλ2λ2b2+cλ2,

where εoffset, a, b, c are the adjustable characteristic Sellmeier parameters. With the spectral dependence on optical constants now implicitly represented in n, λ refers to the wavelength in microns. The term, 2, accounts for the IR absorption tail of oxide materials. Another advantage of using the Sellmeier expression is that its simplicity warrants facile fitting of the SE data and it is easily differentiable to yield material dispersion coefficients.

The modeled physical structure of the sample used is shown in Fig. 1(a). A surface layer was omitted for the following reasons: i) adding such a surface layer does not improve fitting and ii) AFM measurements reveal sub-nanometer roughness for all our films. The TEM micrograph in Fig. 1(b) shows that a thermal SiO2 layer (in the lighter hue) is much thicker than ~2 nm (i.e. the thickness of an ambient-grown native SiO2). We suspect that during annealing in air, thermal oxidation occurs on the Si substrate. The multi-sample, multi-angle SE scans effectively lifted the correlation between the fitting parameters (due to their relatively similar RIs): the thickness of GeO2:SiO2, εoffset, a and the thickness of the interlayer thermal SiO2. The thickness of thermal SiO2 was determined by the reduction of the SE data to within 2.5 nm of the thickness values derived from RBS. The RBS measurements also served to verify that the actual composition (x) is within 0.008 of the nominal composition. The interface SiO2 layer (~1 nm) has been well characterized (see Ref. [7] and references therein) to be a transition layer between the Si substrate and the thermal oxide with an RI higher than the thermal oxide. The optical functions for the thermal SiO2 and interface SiO2 layers and the Si substrate layer were adopted from Herzinger et al. [7].

 figure: Fig. 1.

Fig. 1. (a) Film structure model for ellipsometer analysis. (b) TEM micrograph showing a 40 mol% Ge film after annealing of 1000°C for 15 mins.

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Tables Icon

Table 1. Sellmeier dispersion parameters for films of varying Ge content. (* taken from thermal oxide in Ref. [7])

The Sellmeier model satisfactorily represents the GeO2:SiO2 films yielding a mean-squared error (see Ref. [7]) of less than 3. Table 1 summarizes the final best fit parameters corresponding to the Sellmeier dispersion in Eqn. (1) for all test samples. The variation in Sellmeier parameters, as shown in Table 1, suggests a change in the curvature of the dispersion. By correlating the respective material dispersion, modeled by the Sellmeier expression, with composition, x, the RI-composition contour map is shown in Fig. 2(a). As seen in Table 1, the Sellmeier parameter values do not seem to vary in a simple relationship with composition; hence, extending the Sellmeier model to any arbitrary composition, 0≤x≤0.4, by parametrizing the Sellmeier model to the Ge content become difficult. However, by performing a linear interpolation, we have tested our RI-composition contour map in Fig. 2(a) by measuring the RI of a 16 mol% Ge (x=0.160) film annealed under 1000°C for 1 hour by using the prism-coupling technique. The estimated and measured RIs are respectively 1.4645 and 1.4650±0.0003 (1550 nm).

 figure: Fig. 2.

Fig. 2. (a) The RI-composition contour map showing the Sellmeier dispersion interpolated for a Ge content 0≤x≤0.4. (b) Linearity of RIs with variation in composition. The dash line represents the linear regression of the n(He-Ne) data from this work.

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In general, the RI of mixed oxides may not vary linearly with composition [16]. However, like other mixed oxides formed by network forming constituents, our results, as shown in Fig. 2(b), confirm previous findings that for germanosilicate systems, the RI-composition relationship is linear. In comparison with the RIs of Huang et al. at 598.3 nm [13], Chen et al. at 632.8 nm [12] and Bellman et al. at 1550 nm [11], our results very much agree with their reported values. Such agreement also verifies that the density of our films is comparable with glasses made by CVD and heat treated at over 1230°C and from a similar sol-gel method using dip-coating. It is worthwhile to note that the slopes of the linear relationships are not constant for different wavelengths (see the inset of Fig. 2(b)). This indicates that the dispersion curves change shape with composition. Hence, empirically determined linear parameterizations based on RI at a certain wavelength as formulated by Ref. [17, 18] are not necessarily applicable for all wavelengths. In the study of optical properties of glasses [16], the dispersion parameter, DFC=nF-nC (where nF and nC refer to the RIs measured at the blue F-line [486.13 nm], and the red C-line [656.28 nm], of excited hydrogen atom respectively), is often used to quantify and to compare the material dispersion. However, modern optical equipments are usually equipped with laser sources at 632.8 nm and 1550 nm. Therefore, we introduce here an additional dispersion parameter, DNIR=nHe-Ne-nNIR, with nHe-Ne and nNIR denoting RI measured respectively at 632.8 nm and 1550 nm. In Fig. 3(a), DFC exhibits a linear compositional dependence till x ~0.3 and thereafter the increment seems to deviate from linearity. This behaviour is quite common in other multi-component silicate glasses [16], whereby DFC increases linearly only in part of the x regime. On the other hand, DNIR decreases, then increases again at higher values of x. This trend is likely due to the shift of the Si-O-Si to Ge-O-Ge dominant IR absorption region ca. 1000 cm-1 (10 µm).

In optical communications, the material dispersion coefficient, DMAT, is expressed as

DMAT=λc2nλ2

where c refers to the speed of light in vacuum. We have substituted the Sellmeier dispersion expression of Eqn. (1) into (2) to calculate DMAT for each composition (x) using the respective parameter values in Table 1. The wavelength dependence of DMAT is plotted in Fig. 3(b). The variations in DFC, DNIR and DMAT with x reiterate the above observation of changing dispersion shape as seen from the Sellmeier parameters. Furthermore, in the inset of Fig. 3(b), the zero-dispersion wavelengths of the various compositions are plotted. The zero-dispersion wavelength increases with x. We then conclude that the material dispersion is sensitive to Ge content within the optical communication window and the zero-dispersion wavelength can be tailored by selecting a specific x. Leveraging on the flexibility of the sol-gel process, devices with different material compositions can be realized with ease and cost-effectiveness.

 figure: Fig. 3.

Fig. 3. (a) Change in dispersion parameters versus Ge content. The solid line represents an extrapolated linear fit of the DFC values without the data point at x=0.4. (b) Spectral material dispersion coefficient, DMAT, and the zero-dispersion wavelengths (inset) are shown for the different compositions.

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4. Conclusions

From the non-destructive, multi-sample and multi-angle SE analysis, an accurate 3-dimensional relationship of RI, wavelength (210–1700 nm) for (x)GeO2:(1-x)SiO2 films, 0≤x≤0.4 is presented. By linear interpolation on the Sellmeier-based dispersion relations, the RI at any given wavelength and Ge content can be predicted. In addition, refractive indices were found to be linear with composition in the whole wavelength range with diminishing change at longer wavelengths due to the compositional-dependent change in dispersion characteristics. Dispersion parameters, DFC, DNIR and DMAT are reported to facilitate a quantitative comparison of the change in the dispersion. The zero-dispersion wavelength was found to increase with GeO2 content. With continual developments in telecommunications and optical metrology in the field of microelectronics and photonics, the method demonstrated herein and results found in this work can be versatile in characterization and diagnosis of materials and processes.

Acknowledgments

The authors acknowledge the financial support of the A*STAR ONFIG project. We are indebted to Dr. Thomas Osipowicz at the Physics Department of the National University of Singapore for carrying out the RBS measurements and the useful discussion with Dr. Tom Tiwald at J.A. Woollam Co.

References and Links

1. A. C. Busacca and D. Faccio, “Electro-optic dynamics in thermally poled Ge core doped silica fibre,” Electron. Lett. 39, 28–9 (2003). [CrossRef]  

2. S. Matsumoto, T. Fujiwara, and A. J. Ikushima, “Large second-order optical nonlinearity in Ge-doped silica glass,” Opt. Mater. 18, 19–22 (2001). [CrossRef]  

3. C. Strohhofer, S. Capecchi, J. Fick, A. Martucci, G. Brusatin, and M. Guglielmi, “Active optical properties of erbium-doped GeO2-based sol-gel planar waveguides,” Thin Solid Films 326, 99–105 (1998). [CrossRef]  

4. Q. Y. Zhang, K. Pita, C. K. F. Ho, N. Q. Ngo, L. P. Zuo, and S. Takahashi, “Low optical loss germanosilicate planar waveguides by low-pressure inductively coupled plasma-enhanced chemical vapor deposition,” Chem. Phys. Lett. 368, 183–188 (2003). [CrossRef]  

5. Q. Y. Zhang, K. Pita, S. C. Tjin, C. H. Kam, L. P. Zuo, and S. Takahashi, “Laser-induced ultraviolet absorption and refractive index changes in Ge-B-SiO2 planar waveguides by inductively coupled plasma-enhanced chemical vapor deposition,” Chem. Phys. Lett. 379, 534–538 (2003). [CrossRef]  

6. A. B. Djurisic, Y. Chan, and E. H. Li, “Progress in the room-temperature optical functions of semiconductors,” Mat. Sci. Eng. R 38, 237–293 (2002). [CrossRef]  

7. C. M. Herzinger, B. Johs, W. A. McGahan, J. A. Woollam, and W. Paulson, “Ellipsometric determination of optical constants for silicon and thermally grown silicon dioxide via a multi-sample, multi-wavelength, multi-angle investigation,” J. Appl. Phys. 83, 3323–3336 (1998). [CrossRef]  

8. C. K. F. Ho, H. S. Djie, K. Pita, N. Q. Ngo, and C. H. Kam, “Sintering and porosity control of (x)GeO2:(1-x)SiO2 sol-gel derived films for optoelectronic applications,” Electrochem. Solid-State Lett. 7, 96–8 (2004). [CrossRef]  

9. T. Busani, H. Plantier, R. A. B. Devine, C. Hernandez, and Y. Campidelli, “Growth kinetics and physical characterisation of Si1-xGexO2 films obtained by plasma assisted oxidation,” J. Non-Cryst. Solids. 254, 80–88 (1999). [CrossRef]  

10. D. L. Simpson, R. T. Croswell, A. Reisman, D. Temple, and C. K. Williams, “Planarization processes and applications - I. Undoped GeO2-SiO2 glasses,” J. Electrochem. Soc. 146, 3860–3871 (1999). [CrossRef]  

11. R. A. Bellman, G. Bourdon, G. Alibert, A. Beguin, E. Guiot, L. B. Simpson, P. Lehuede, L. Guiziou, and E. LeGuen, “Ultralow loss high delta silica germania planar waveguides,” J. Electrochem. Soc. 151, G541–G547 (2004). [CrossRef]  

12. D.-G. Chen, B. G. Potter, and J. H. Simmons, “GeO2-SiO2 thin films for planar waveguide applications,” J. Non-Cryst. Solids. 178, 135–47 (1994). [CrossRef]  

13. Y. Y. Huang, A. Sarkar, and P. C. Schultz, “Relationship between composition, density and refractive index for germania silica glasses,” J. Non-Cryst. Solids. 27, 29–37 (1978). [CrossRef]  

14. C. K. F. Ho, D. C. L. Gwee, Rajni, K. Pita, N. Q. Ngo, and C. H. Kam, “Planar optical waveguides fabricated by sol-gel derived inorganic silicate glass,” presented at the 11th European Conference on Intergrated Optics 2003, Prague, Czech Republic, April 2–4, 2003. [PubMed]  

15. S. P. Mukherjee and S. K. Sharma, “Structural studies of gels and gel-glasses in the SiO2-GeO2 system using vibrational spectroscopy,” J. Am. Ceram. Soc. 69, 806–10 (1986). [CrossRef]  

16. H. Scholze, Glass : nature, structure, and properties (Springer-Verlag, New York, 1991).

17. R. R. A. Syms and A. S. Holmes, “Deposition of thick silica-titania sol-gel films on Si substrates,” J. Non-Cryst. Solids. 170, 223–33 (1994). [CrossRef]  

18. W. Que, Y. Zhou, Y. L. Lam, Y. C. Chan, Y. W. Chen, S. L. Ng, C. Y. Liaw, and C. H. Kam, “Fabrication of composite sol-gel optical channel waveguides by laser writing lithography,” presented at the Optical Engineering for Sensing and Nanotechnology (ICOSN ’99), Yokohama, Japan, 16–18 June, 1999.

References

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  1. A. C. Busacca and D. Faccio, “Electro-optic dynamics in thermally poled Ge core doped silica fibre,” Electron. Lett. 39, 28–9 (2003).
    [Crossref]
  2. S. Matsumoto, T. Fujiwara, and A. J. Ikushima, “Large second-order optical nonlinearity in Ge-doped silica glass,” Opt. Mater. 18, 19–22 (2001).
    [Crossref]
  3. C. Strohhofer, S. Capecchi, J. Fick, A. Martucci, G. Brusatin, and M. Guglielmi, “Active optical properties of erbium-doped GeO2-based sol-gel planar waveguides,” Thin Solid Films 326, 99–105 (1998).
    [Crossref]
  4. Q. Y. Zhang, K. Pita, C. K. F. Ho, N. Q. Ngo, L. P. Zuo, and S. Takahashi, “Low optical loss germanosilicate planar waveguides by low-pressure inductively coupled plasma-enhanced chemical vapor deposition,” Chem. Phys. Lett. 368, 183–188 (2003).
    [Crossref]
  5. Q. Y. Zhang, K. Pita, S. C. Tjin, C. H. Kam, L. P. Zuo, and S. Takahashi, “Laser-induced ultraviolet absorption and refractive index changes in Ge-B-SiO2 planar waveguides by inductively coupled plasma-enhanced chemical vapor deposition,” Chem. Phys. Lett. 379, 534–538 (2003).
    [Crossref]
  6. A. B. Djurisic, Y. Chan, and E. H. Li, “Progress in the room-temperature optical functions of semiconductors,” Mat. Sci. Eng. R 38, 237–293 (2002).
    [Crossref]
  7. C. M. Herzinger, B. Johs, W. A. McGahan, J. A. Woollam, and W. Paulson, “Ellipsometric determination of optical constants for silicon and thermally grown silicon dioxide via a multi-sample, multi-wavelength, multi-angle investigation,” J. Appl. Phys. 83, 3323–3336 (1998).
    [Crossref]
  8. C. K. F. Ho, H. S. Djie, K. Pita, N. Q. Ngo, and C. H. Kam, “Sintering and porosity control of (x)GeO2:(1-x)SiO2 sol-gel derived films for optoelectronic applications,” Electrochem. Solid-State Lett. 7, 96–8 (2004).
    [Crossref]
  9. T. Busani, H. Plantier, R. A. B. Devine, C. Hernandez, and Y. Campidelli, “Growth kinetics and physical characterisation of Si1-xGexO2 films obtained by plasma assisted oxidation,” J. Non-Cryst. Solids. 254, 80–88 (1999).
    [Crossref]
  10. D. L. Simpson, R. T. Croswell, A. Reisman, D. Temple, and C. K. Williams, “Planarization processes and applications - I. Undoped GeO2-SiO2 glasses,” J. Electrochem. Soc. 146, 3860–3871 (1999).
    [Crossref]
  11. R. A. Bellman, G. Bourdon, G. Alibert, A. Beguin, E. Guiot, L. B. Simpson, P. Lehuede, L. Guiziou, and E. LeGuen, “Ultralow loss high delta silica germania planar waveguides,” J. Electrochem. Soc. 151, G541–G547 (2004).
    [Crossref]
  12. D.-G. Chen, B. G. Potter, and J. H. Simmons, “GeO2-SiO2 thin films for planar waveguide applications,” J. Non-Cryst. Solids. 178, 135–47 (1994).
    [Crossref]
  13. Y. Y. Huang, A. Sarkar, and P. C. Schultz, “Relationship between composition, density and refractive index for germania silica glasses,” J. Non-Cryst. Solids. 27, 29–37 (1978).
    [Crossref]
  14. C. K. F. Ho, D. C. L. Gwee, Rajni, K. Pita, N. Q. Ngo, and C. H. Kam, “Planar optical waveguides fabricated by sol-gel derived inorganic silicate glass,” presented at the 11th European Conference on Intergrated Optics 2003, Prague, Czech Republic, April 2–4, 2003.
    [PubMed]
  15. S. P. Mukherjee and S. K. Sharma, “Structural studies of gels and gel-glasses in the SiO2-GeO2 system using vibrational spectroscopy,” J. Am. Ceram. Soc. 69, 806–10 (1986).
    [Crossref]
  16. H. Scholze, Glass : nature, structure, and properties (Springer-Verlag, New York, 1991).
  17. R. R. A. Syms and A. S. Holmes, “Deposition of thick silica-titania sol-gel films on Si substrates,” J. Non-Cryst. Solids. 170, 223–33 (1994).
    [Crossref]
  18. W. Que, Y. Zhou, Y. L. Lam, Y. C. Chan, Y. W. Chen, S. L. Ng, C. Y. Liaw, and C. H. Kam, “Fabrication of composite sol-gel optical channel waveguides by laser writing lithography,” presented at the Optical Engineering for Sensing and Nanotechnology (ICOSN ’99), Yokohama, Japan, 16–18 June, 1999.

2004 (2)

C. K. F. Ho, H. S. Djie, K. Pita, N. Q. Ngo, and C. H. Kam, “Sintering and porosity control of (x)GeO2:(1-x)SiO2 sol-gel derived films for optoelectronic applications,” Electrochem. Solid-State Lett. 7, 96–8 (2004).
[Crossref]

R. A. Bellman, G. Bourdon, G. Alibert, A. Beguin, E. Guiot, L. B. Simpson, P. Lehuede, L. Guiziou, and E. LeGuen, “Ultralow loss high delta silica germania planar waveguides,” J. Electrochem. Soc. 151, G541–G547 (2004).
[Crossref]

2003 (3)

A. C. Busacca and D. Faccio, “Electro-optic dynamics in thermally poled Ge core doped silica fibre,” Electron. Lett. 39, 28–9 (2003).
[Crossref]

Q. Y. Zhang, K. Pita, C. K. F. Ho, N. Q. Ngo, L. P. Zuo, and S. Takahashi, “Low optical loss germanosilicate planar waveguides by low-pressure inductively coupled plasma-enhanced chemical vapor deposition,” Chem. Phys. Lett. 368, 183–188 (2003).
[Crossref]

Q. Y. Zhang, K. Pita, S. C. Tjin, C. H. Kam, L. P. Zuo, and S. Takahashi, “Laser-induced ultraviolet absorption and refractive index changes in Ge-B-SiO2 planar waveguides by inductively coupled plasma-enhanced chemical vapor deposition,” Chem. Phys. Lett. 379, 534–538 (2003).
[Crossref]

2002 (1)

A. B. Djurisic, Y. Chan, and E. H. Li, “Progress in the room-temperature optical functions of semiconductors,” Mat. Sci. Eng. R 38, 237–293 (2002).
[Crossref]

2001 (1)

S. Matsumoto, T. Fujiwara, and A. J. Ikushima, “Large second-order optical nonlinearity in Ge-doped silica glass,” Opt. Mater. 18, 19–22 (2001).
[Crossref]

1999 (2)

T. Busani, H. Plantier, R. A. B. Devine, C. Hernandez, and Y. Campidelli, “Growth kinetics and physical characterisation of Si1-xGexO2 films obtained by plasma assisted oxidation,” J. Non-Cryst. Solids. 254, 80–88 (1999).
[Crossref]

D. L. Simpson, R. T. Croswell, A. Reisman, D. Temple, and C. K. Williams, “Planarization processes and applications - I. Undoped GeO2-SiO2 glasses,” J. Electrochem. Soc. 146, 3860–3871 (1999).
[Crossref]

1998 (2)

C. Strohhofer, S. Capecchi, J. Fick, A. Martucci, G. Brusatin, and M. Guglielmi, “Active optical properties of erbium-doped GeO2-based sol-gel planar waveguides,” Thin Solid Films 326, 99–105 (1998).
[Crossref]

C. M. Herzinger, B. Johs, W. A. McGahan, J. A. Woollam, and W. Paulson, “Ellipsometric determination of optical constants for silicon and thermally grown silicon dioxide via a multi-sample, multi-wavelength, multi-angle investigation,” J. Appl. Phys. 83, 3323–3336 (1998).
[Crossref]

1994 (2)

D.-G. Chen, B. G. Potter, and J. H. Simmons, “GeO2-SiO2 thin films for planar waveguide applications,” J. Non-Cryst. Solids. 178, 135–47 (1994).
[Crossref]

R. R. A. Syms and A. S. Holmes, “Deposition of thick silica-titania sol-gel films on Si substrates,” J. Non-Cryst. Solids. 170, 223–33 (1994).
[Crossref]

1986 (1)

S. P. Mukherjee and S. K. Sharma, “Structural studies of gels and gel-glasses in the SiO2-GeO2 system using vibrational spectroscopy,” J. Am. Ceram. Soc. 69, 806–10 (1986).
[Crossref]

1978 (1)

Y. Y. Huang, A. Sarkar, and P. C. Schultz, “Relationship between composition, density and refractive index for germania silica glasses,” J. Non-Cryst. Solids. 27, 29–37 (1978).
[Crossref]

Alibert, G.

R. A. Bellman, G. Bourdon, G. Alibert, A. Beguin, E. Guiot, L. B. Simpson, P. Lehuede, L. Guiziou, and E. LeGuen, “Ultralow loss high delta silica germania planar waveguides,” J. Electrochem. Soc. 151, G541–G547 (2004).
[Crossref]

Beguin, A.

R. A. Bellman, G. Bourdon, G. Alibert, A. Beguin, E. Guiot, L. B. Simpson, P. Lehuede, L. Guiziou, and E. LeGuen, “Ultralow loss high delta silica germania planar waveguides,” J. Electrochem. Soc. 151, G541–G547 (2004).
[Crossref]

Bellman, R. A.

R. A. Bellman, G. Bourdon, G. Alibert, A. Beguin, E. Guiot, L. B. Simpson, P. Lehuede, L. Guiziou, and E. LeGuen, “Ultralow loss high delta silica germania planar waveguides,” J. Electrochem. Soc. 151, G541–G547 (2004).
[Crossref]

Bourdon, G.

R. A. Bellman, G. Bourdon, G. Alibert, A. Beguin, E. Guiot, L. B. Simpson, P. Lehuede, L. Guiziou, and E. LeGuen, “Ultralow loss high delta silica germania planar waveguides,” J. Electrochem. Soc. 151, G541–G547 (2004).
[Crossref]

Brusatin, G.

C. Strohhofer, S. Capecchi, J. Fick, A. Martucci, G. Brusatin, and M. Guglielmi, “Active optical properties of erbium-doped GeO2-based sol-gel planar waveguides,” Thin Solid Films 326, 99–105 (1998).
[Crossref]

Busacca, A. C.

A. C. Busacca and D. Faccio, “Electro-optic dynamics in thermally poled Ge core doped silica fibre,” Electron. Lett. 39, 28–9 (2003).
[Crossref]

Busani, T.

T. Busani, H. Plantier, R. A. B. Devine, C. Hernandez, and Y. Campidelli, “Growth kinetics and physical characterisation of Si1-xGexO2 films obtained by plasma assisted oxidation,” J. Non-Cryst. Solids. 254, 80–88 (1999).
[Crossref]

Campidelli, Y.

T. Busani, H. Plantier, R. A. B. Devine, C. Hernandez, and Y. Campidelli, “Growth kinetics and physical characterisation of Si1-xGexO2 films obtained by plasma assisted oxidation,” J. Non-Cryst. Solids. 254, 80–88 (1999).
[Crossref]

Capecchi, S.

C. Strohhofer, S. Capecchi, J. Fick, A. Martucci, G. Brusatin, and M. Guglielmi, “Active optical properties of erbium-doped GeO2-based sol-gel planar waveguides,” Thin Solid Films 326, 99–105 (1998).
[Crossref]

Chan, Y.

A. B. Djurisic, Y. Chan, and E. H. Li, “Progress in the room-temperature optical functions of semiconductors,” Mat. Sci. Eng. R 38, 237–293 (2002).
[Crossref]

Chan, Y. C.

W. Que, Y. Zhou, Y. L. Lam, Y. C. Chan, Y. W. Chen, S. L. Ng, C. Y. Liaw, and C. H. Kam, “Fabrication of composite sol-gel optical channel waveguides by laser writing lithography,” presented at the Optical Engineering for Sensing and Nanotechnology (ICOSN ’99), Yokohama, Japan, 16–18 June, 1999.

Chen, D.-G.

D.-G. Chen, B. G. Potter, and J. H. Simmons, “GeO2-SiO2 thin films for planar waveguide applications,” J. Non-Cryst. Solids. 178, 135–47 (1994).
[Crossref]

Chen, Y. W.

W. Que, Y. Zhou, Y. L. Lam, Y. C. Chan, Y. W. Chen, S. L. Ng, C. Y. Liaw, and C. H. Kam, “Fabrication of composite sol-gel optical channel waveguides by laser writing lithography,” presented at the Optical Engineering for Sensing and Nanotechnology (ICOSN ’99), Yokohama, Japan, 16–18 June, 1999.

Croswell, R. T.

D. L. Simpson, R. T. Croswell, A. Reisman, D. Temple, and C. K. Williams, “Planarization processes and applications - I. Undoped GeO2-SiO2 glasses,” J. Electrochem. Soc. 146, 3860–3871 (1999).
[Crossref]

Devine, R. A. B.

T. Busani, H. Plantier, R. A. B. Devine, C. Hernandez, and Y. Campidelli, “Growth kinetics and physical characterisation of Si1-xGexO2 films obtained by plasma assisted oxidation,” J. Non-Cryst. Solids. 254, 80–88 (1999).
[Crossref]

Djie, H. S.

C. K. F. Ho, H. S. Djie, K. Pita, N. Q. Ngo, and C. H. Kam, “Sintering and porosity control of (x)GeO2:(1-x)SiO2 sol-gel derived films for optoelectronic applications,” Electrochem. Solid-State Lett. 7, 96–8 (2004).
[Crossref]

Djurisic, A. B.

A. B. Djurisic, Y. Chan, and E. H. Li, “Progress in the room-temperature optical functions of semiconductors,” Mat. Sci. Eng. R 38, 237–293 (2002).
[Crossref]

Faccio, D.

A. C. Busacca and D. Faccio, “Electro-optic dynamics in thermally poled Ge core doped silica fibre,” Electron. Lett. 39, 28–9 (2003).
[Crossref]

Fick, J.

C. Strohhofer, S. Capecchi, J. Fick, A. Martucci, G. Brusatin, and M. Guglielmi, “Active optical properties of erbium-doped GeO2-based sol-gel planar waveguides,” Thin Solid Films 326, 99–105 (1998).
[Crossref]

Fujiwara, T.

S. Matsumoto, T. Fujiwara, and A. J. Ikushima, “Large second-order optical nonlinearity in Ge-doped silica glass,” Opt. Mater. 18, 19–22 (2001).
[Crossref]

Guglielmi, M.

C. Strohhofer, S. Capecchi, J. Fick, A. Martucci, G. Brusatin, and M. Guglielmi, “Active optical properties of erbium-doped GeO2-based sol-gel planar waveguides,” Thin Solid Films 326, 99–105 (1998).
[Crossref]

Guiot, E.

R. A. Bellman, G. Bourdon, G. Alibert, A. Beguin, E. Guiot, L. B. Simpson, P. Lehuede, L. Guiziou, and E. LeGuen, “Ultralow loss high delta silica germania planar waveguides,” J. Electrochem. Soc. 151, G541–G547 (2004).
[Crossref]

Guiziou, L.

R. A. Bellman, G. Bourdon, G. Alibert, A. Beguin, E. Guiot, L. B. Simpson, P. Lehuede, L. Guiziou, and E. LeGuen, “Ultralow loss high delta silica germania planar waveguides,” J. Electrochem. Soc. 151, G541–G547 (2004).
[Crossref]

Gwee, D. C. L.

C. K. F. Ho, D. C. L. Gwee, Rajni, K. Pita, N. Q. Ngo, and C. H. Kam, “Planar optical waveguides fabricated by sol-gel derived inorganic silicate glass,” presented at the 11th European Conference on Intergrated Optics 2003, Prague, Czech Republic, April 2–4, 2003.
[PubMed]

Hernandez, C.

T. Busani, H. Plantier, R. A. B. Devine, C. Hernandez, and Y. Campidelli, “Growth kinetics and physical characterisation of Si1-xGexO2 films obtained by plasma assisted oxidation,” J. Non-Cryst. Solids. 254, 80–88 (1999).
[Crossref]

Herzinger, C. M.

C. M. Herzinger, B. Johs, W. A. McGahan, J. A. Woollam, and W. Paulson, “Ellipsometric determination of optical constants for silicon and thermally grown silicon dioxide via a multi-sample, multi-wavelength, multi-angle investigation,” J. Appl. Phys. 83, 3323–3336 (1998).
[Crossref]

Ho, C. K. F.

C. K. F. Ho, H. S. Djie, K. Pita, N. Q. Ngo, and C. H. Kam, “Sintering and porosity control of (x)GeO2:(1-x)SiO2 sol-gel derived films for optoelectronic applications,” Electrochem. Solid-State Lett. 7, 96–8 (2004).
[Crossref]

Q. Y. Zhang, K. Pita, C. K. F. Ho, N. Q. Ngo, L. P. Zuo, and S. Takahashi, “Low optical loss germanosilicate planar waveguides by low-pressure inductively coupled plasma-enhanced chemical vapor deposition,” Chem. Phys. Lett. 368, 183–188 (2003).
[Crossref]

C. K. F. Ho, D. C. L. Gwee, Rajni, K. Pita, N. Q. Ngo, and C. H. Kam, “Planar optical waveguides fabricated by sol-gel derived inorganic silicate glass,” presented at the 11th European Conference on Intergrated Optics 2003, Prague, Czech Republic, April 2–4, 2003.
[PubMed]

Holmes, A. S.

R. R. A. Syms and A. S. Holmes, “Deposition of thick silica-titania sol-gel films on Si substrates,” J. Non-Cryst. Solids. 170, 223–33 (1994).
[Crossref]

Huang, Y. Y.

Y. Y. Huang, A. Sarkar, and P. C. Schultz, “Relationship between composition, density and refractive index for germania silica glasses,” J. Non-Cryst. Solids. 27, 29–37 (1978).
[Crossref]

Ikushima, A. J.

S. Matsumoto, T. Fujiwara, and A. J. Ikushima, “Large second-order optical nonlinearity in Ge-doped silica glass,” Opt. Mater. 18, 19–22 (2001).
[Crossref]

Johs, B.

C. M. Herzinger, B. Johs, W. A. McGahan, J. A. Woollam, and W. Paulson, “Ellipsometric determination of optical constants for silicon and thermally grown silicon dioxide via a multi-sample, multi-wavelength, multi-angle investigation,” J. Appl. Phys. 83, 3323–3336 (1998).
[Crossref]

Kam, C. H.

C. K. F. Ho, H. S. Djie, K. Pita, N. Q. Ngo, and C. H. Kam, “Sintering and porosity control of (x)GeO2:(1-x)SiO2 sol-gel derived films for optoelectronic applications,” Electrochem. Solid-State Lett. 7, 96–8 (2004).
[Crossref]

Q. Y. Zhang, K. Pita, S. C. Tjin, C. H. Kam, L. P. Zuo, and S. Takahashi, “Laser-induced ultraviolet absorption and refractive index changes in Ge-B-SiO2 planar waveguides by inductively coupled plasma-enhanced chemical vapor deposition,” Chem. Phys. Lett. 379, 534–538 (2003).
[Crossref]

C. K. F. Ho, D. C. L. Gwee, Rajni, K. Pita, N. Q. Ngo, and C. H. Kam, “Planar optical waveguides fabricated by sol-gel derived inorganic silicate glass,” presented at the 11th European Conference on Intergrated Optics 2003, Prague, Czech Republic, April 2–4, 2003.
[PubMed]

W. Que, Y. Zhou, Y. L. Lam, Y. C. Chan, Y. W. Chen, S. L. Ng, C. Y. Liaw, and C. H. Kam, “Fabrication of composite sol-gel optical channel waveguides by laser writing lithography,” presented at the Optical Engineering for Sensing and Nanotechnology (ICOSN ’99), Yokohama, Japan, 16–18 June, 1999.

Lam, Y. L.

W. Que, Y. Zhou, Y. L. Lam, Y. C. Chan, Y. W. Chen, S. L. Ng, C. Y. Liaw, and C. H. Kam, “Fabrication of composite sol-gel optical channel waveguides by laser writing lithography,” presented at the Optical Engineering for Sensing and Nanotechnology (ICOSN ’99), Yokohama, Japan, 16–18 June, 1999.

LeGuen, E.

R. A. Bellman, G. Bourdon, G. Alibert, A. Beguin, E. Guiot, L. B. Simpson, P. Lehuede, L. Guiziou, and E. LeGuen, “Ultralow loss high delta silica germania planar waveguides,” J. Electrochem. Soc. 151, G541–G547 (2004).
[Crossref]

Lehuede, P.

R. A. Bellman, G. Bourdon, G. Alibert, A. Beguin, E. Guiot, L. B. Simpson, P. Lehuede, L. Guiziou, and E. LeGuen, “Ultralow loss high delta silica germania planar waveguides,” J. Electrochem. Soc. 151, G541–G547 (2004).
[Crossref]

Li, E. H.

A. B. Djurisic, Y. Chan, and E. H. Li, “Progress in the room-temperature optical functions of semiconductors,” Mat. Sci. Eng. R 38, 237–293 (2002).
[Crossref]

Liaw, C. Y.

W. Que, Y. Zhou, Y. L. Lam, Y. C. Chan, Y. W. Chen, S. L. Ng, C. Y. Liaw, and C. H. Kam, “Fabrication of composite sol-gel optical channel waveguides by laser writing lithography,” presented at the Optical Engineering for Sensing and Nanotechnology (ICOSN ’99), Yokohama, Japan, 16–18 June, 1999.

Martucci, A.

C. Strohhofer, S. Capecchi, J. Fick, A. Martucci, G. Brusatin, and M. Guglielmi, “Active optical properties of erbium-doped GeO2-based sol-gel planar waveguides,” Thin Solid Films 326, 99–105 (1998).
[Crossref]

Matsumoto, S.

S. Matsumoto, T. Fujiwara, and A. J. Ikushima, “Large second-order optical nonlinearity in Ge-doped silica glass,” Opt. Mater. 18, 19–22 (2001).
[Crossref]

McGahan, W. A.

C. M. Herzinger, B. Johs, W. A. McGahan, J. A. Woollam, and W. Paulson, “Ellipsometric determination of optical constants for silicon and thermally grown silicon dioxide via a multi-sample, multi-wavelength, multi-angle investigation,” J. Appl. Phys. 83, 3323–3336 (1998).
[Crossref]

Mukherjee, S. P.

S. P. Mukherjee and S. K. Sharma, “Structural studies of gels and gel-glasses in the SiO2-GeO2 system using vibrational spectroscopy,” J. Am. Ceram. Soc. 69, 806–10 (1986).
[Crossref]

Ng, S. L.

W. Que, Y. Zhou, Y. L. Lam, Y. C. Chan, Y. W. Chen, S. L. Ng, C. Y. Liaw, and C. H. Kam, “Fabrication of composite sol-gel optical channel waveguides by laser writing lithography,” presented at the Optical Engineering for Sensing and Nanotechnology (ICOSN ’99), Yokohama, Japan, 16–18 June, 1999.

Ngo, N. Q.

C. K. F. Ho, H. S. Djie, K. Pita, N. Q. Ngo, and C. H. Kam, “Sintering and porosity control of (x)GeO2:(1-x)SiO2 sol-gel derived films for optoelectronic applications,” Electrochem. Solid-State Lett. 7, 96–8 (2004).
[Crossref]

Q. Y. Zhang, K. Pita, C. K. F. Ho, N. Q. Ngo, L. P. Zuo, and S. Takahashi, “Low optical loss germanosilicate planar waveguides by low-pressure inductively coupled plasma-enhanced chemical vapor deposition,” Chem. Phys. Lett. 368, 183–188 (2003).
[Crossref]

C. K. F. Ho, D. C. L. Gwee, Rajni, K. Pita, N. Q. Ngo, and C. H. Kam, “Planar optical waveguides fabricated by sol-gel derived inorganic silicate glass,” presented at the 11th European Conference on Intergrated Optics 2003, Prague, Czech Republic, April 2–4, 2003.
[PubMed]

Paulson, W.

C. M. Herzinger, B. Johs, W. A. McGahan, J. A. Woollam, and W. Paulson, “Ellipsometric determination of optical constants for silicon and thermally grown silicon dioxide via a multi-sample, multi-wavelength, multi-angle investigation,” J. Appl. Phys. 83, 3323–3336 (1998).
[Crossref]

Pita, K.

C. K. F. Ho, H. S. Djie, K. Pita, N. Q. Ngo, and C. H. Kam, “Sintering and porosity control of (x)GeO2:(1-x)SiO2 sol-gel derived films for optoelectronic applications,” Electrochem. Solid-State Lett. 7, 96–8 (2004).
[Crossref]

Q. Y. Zhang, K. Pita, C. K. F. Ho, N. Q. Ngo, L. P. Zuo, and S. Takahashi, “Low optical loss germanosilicate planar waveguides by low-pressure inductively coupled plasma-enhanced chemical vapor deposition,” Chem. Phys. Lett. 368, 183–188 (2003).
[Crossref]

Q. Y. Zhang, K. Pita, S. C. Tjin, C. H. Kam, L. P. Zuo, and S. Takahashi, “Laser-induced ultraviolet absorption and refractive index changes in Ge-B-SiO2 planar waveguides by inductively coupled plasma-enhanced chemical vapor deposition,” Chem. Phys. Lett. 379, 534–538 (2003).
[Crossref]

C. K. F. Ho, D. C. L. Gwee, Rajni, K. Pita, N. Q. Ngo, and C. H. Kam, “Planar optical waveguides fabricated by sol-gel derived inorganic silicate glass,” presented at the 11th European Conference on Intergrated Optics 2003, Prague, Czech Republic, April 2–4, 2003.
[PubMed]

Plantier, H.

T. Busani, H. Plantier, R. A. B. Devine, C. Hernandez, and Y. Campidelli, “Growth kinetics and physical characterisation of Si1-xGexO2 films obtained by plasma assisted oxidation,” J. Non-Cryst. Solids. 254, 80–88 (1999).
[Crossref]

Potter, B. G.

D.-G. Chen, B. G. Potter, and J. H. Simmons, “GeO2-SiO2 thin films for planar waveguide applications,” J. Non-Cryst. Solids. 178, 135–47 (1994).
[Crossref]

Que, W.

W. Que, Y. Zhou, Y. L. Lam, Y. C. Chan, Y. W. Chen, S. L. Ng, C. Y. Liaw, and C. H. Kam, “Fabrication of composite sol-gel optical channel waveguides by laser writing lithography,” presented at the Optical Engineering for Sensing and Nanotechnology (ICOSN ’99), Yokohama, Japan, 16–18 June, 1999.

Rajni,

C. K. F. Ho, D. C. L. Gwee, Rajni, K. Pita, N. Q. Ngo, and C. H. Kam, “Planar optical waveguides fabricated by sol-gel derived inorganic silicate glass,” presented at the 11th European Conference on Intergrated Optics 2003, Prague, Czech Republic, April 2–4, 2003.
[PubMed]

Reisman, A.

D. L. Simpson, R. T. Croswell, A. Reisman, D. Temple, and C. K. Williams, “Planarization processes and applications - I. Undoped GeO2-SiO2 glasses,” J. Electrochem. Soc. 146, 3860–3871 (1999).
[Crossref]

Sarkar, A.

Y. Y. Huang, A. Sarkar, and P. C. Schultz, “Relationship between composition, density and refractive index for germania silica glasses,” J. Non-Cryst. Solids. 27, 29–37 (1978).
[Crossref]

Scholze, H.

H. Scholze, Glass : nature, structure, and properties (Springer-Verlag, New York, 1991).

Schultz, P. C.

Y. Y. Huang, A. Sarkar, and P. C. Schultz, “Relationship between composition, density and refractive index for germania silica glasses,” J. Non-Cryst. Solids. 27, 29–37 (1978).
[Crossref]

Sharma, S. K.

S. P. Mukherjee and S. K. Sharma, “Structural studies of gels and gel-glasses in the SiO2-GeO2 system using vibrational spectroscopy,” J. Am. Ceram. Soc. 69, 806–10 (1986).
[Crossref]

Simmons, J. H.

D.-G. Chen, B. G. Potter, and J. H. Simmons, “GeO2-SiO2 thin films for planar waveguide applications,” J. Non-Cryst. Solids. 178, 135–47 (1994).
[Crossref]

Simpson, D. L.

D. L. Simpson, R. T. Croswell, A. Reisman, D. Temple, and C. K. Williams, “Planarization processes and applications - I. Undoped GeO2-SiO2 glasses,” J. Electrochem. Soc. 146, 3860–3871 (1999).
[Crossref]

Simpson, L. B.

R. A. Bellman, G. Bourdon, G. Alibert, A. Beguin, E. Guiot, L. B. Simpson, P. Lehuede, L. Guiziou, and E. LeGuen, “Ultralow loss high delta silica germania planar waveguides,” J. Electrochem. Soc. 151, G541–G547 (2004).
[Crossref]

Strohhofer, C.

C. Strohhofer, S. Capecchi, J. Fick, A. Martucci, G. Brusatin, and M. Guglielmi, “Active optical properties of erbium-doped GeO2-based sol-gel planar waveguides,” Thin Solid Films 326, 99–105 (1998).
[Crossref]

Syms, R. R. A.

R. R. A. Syms and A. S. Holmes, “Deposition of thick silica-titania sol-gel films on Si substrates,” J. Non-Cryst. Solids. 170, 223–33 (1994).
[Crossref]

Takahashi, S.

Q. Y. Zhang, K. Pita, C. K. F. Ho, N. Q. Ngo, L. P. Zuo, and S. Takahashi, “Low optical loss germanosilicate planar waveguides by low-pressure inductively coupled plasma-enhanced chemical vapor deposition,” Chem. Phys. Lett. 368, 183–188 (2003).
[Crossref]

Q. Y. Zhang, K. Pita, S. C. Tjin, C. H. Kam, L. P. Zuo, and S. Takahashi, “Laser-induced ultraviolet absorption and refractive index changes in Ge-B-SiO2 planar waveguides by inductively coupled plasma-enhanced chemical vapor deposition,” Chem. Phys. Lett. 379, 534–538 (2003).
[Crossref]

Temple, D.

D. L. Simpson, R. T. Croswell, A. Reisman, D. Temple, and C. K. Williams, “Planarization processes and applications - I. Undoped GeO2-SiO2 glasses,” J. Electrochem. Soc. 146, 3860–3871 (1999).
[Crossref]

Tjin, S. C.

Q. Y. Zhang, K. Pita, S. C. Tjin, C. H. Kam, L. P. Zuo, and S. Takahashi, “Laser-induced ultraviolet absorption and refractive index changes in Ge-B-SiO2 planar waveguides by inductively coupled plasma-enhanced chemical vapor deposition,” Chem. Phys. Lett. 379, 534–538 (2003).
[Crossref]

Williams, C. K.

D. L. Simpson, R. T. Croswell, A. Reisman, D. Temple, and C. K. Williams, “Planarization processes and applications - I. Undoped GeO2-SiO2 glasses,” J. Electrochem. Soc. 146, 3860–3871 (1999).
[Crossref]

Woollam, J. A.

C. M. Herzinger, B. Johs, W. A. McGahan, J. A. Woollam, and W. Paulson, “Ellipsometric determination of optical constants for silicon and thermally grown silicon dioxide via a multi-sample, multi-wavelength, multi-angle investigation,” J. Appl. Phys. 83, 3323–3336 (1998).
[Crossref]

Zhang, Q. Y.

Q. Y. Zhang, K. Pita, S. C. Tjin, C. H. Kam, L. P. Zuo, and S. Takahashi, “Laser-induced ultraviolet absorption and refractive index changes in Ge-B-SiO2 planar waveguides by inductively coupled plasma-enhanced chemical vapor deposition,” Chem. Phys. Lett. 379, 534–538 (2003).
[Crossref]

Q. Y. Zhang, K. Pita, C. K. F. Ho, N. Q. Ngo, L. P. Zuo, and S. Takahashi, “Low optical loss germanosilicate planar waveguides by low-pressure inductively coupled plasma-enhanced chemical vapor deposition,” Chem. Phys. Lett. 368, 183–188 (2003).
[Crossref]

Zhou, Y.

W. Que, Y. Zhou, Y. L. Lam, Y. C. Chan, Y. W. Chen, S. L. Ng, C. Y. Liaw, and C. H. Kam, “Fabrication of composite sol-gel optical channel waveguides by laser writing lithography,” presented at the Optical Engineering for Sensing and Nanotechnology (ICOSN ’99), Yokohama, Japan, 16–18 June, 1999.

Zuo, L. P.

Q. Y. Zhang, K. Pita, C. K. F. Ho, N. Q. Ngo, L. P. Zuo, and S. Takahashi, “Low optical loss germanosilicate planar waveguides by low-pressure inductively coupled plasma-enhanced chemical vapor deposition,” Chem. Phys. Lett. 368, 183–188 (2003).
[Crossref]

Q. Y. Zhang, K. Pita, S. C. Tjin, C. H. Kam, L. P. Zuo, and S. Takahashi, “Laser-induced ultraviolet absorption and refractive index changes in Ge-B-SiO2 planar waveguides by inductively coupled plasma-enhanced chemical vapor deposition,” Chem. Phys. Lett. 379, 534–538 (2003).
[Crossref]

Chem. Phys. Lett. (2)

Q. Y. Zhang, K. Pita, C. K. F. Ho, N. Q. Ngo, L. P. Zuo, and S. Takahashi, “Low optical loss germanosilicate planar waveguides by low-pressure inductively coupled plasma-enhanced chemical vapor deposition,” Chem. Phys. Lett. 368, 183–188 (2003).
[Crossref]

Q. Y. Zhang, K. Pita, S. C. Tjin, C. H. Kam, L. P. Zuo, and S. Takahashi, “Laser-induced ultraviolet absorption and refractive index changes in Ge-B-SiO2 planar waveguides by inductively coupled plasma-enhanced chemical vapor deposition,” Chem. Phys. Lett. 379, 534–538 (2003).
[Crossref]

Electrochem. Solid-State Lett. (1)

C. K. F. Ho, H. S. Djie, K. Pita, N. Q. Ngo, and C. H. Kam, “Sintering and porosity control of (x)GeO2:(1-x)SiO2 sol-gel derived films for optoelectronic applications,” Electrochem. Solid-State Lett. 7, 96–8 (2004).
[Crossref]

Electron. Lett. (1)

A. C. Busacca and D. Faccio, “Electro-optic dynamics in thermally poled Ge core doped silica fibre,” Electron. Lett. 39, 28–9 (2003).
[Crossref]

J. Am. Ceram. Soc. (1)

S. P. Mukherjee and S. K. Sharma, “Structural studies of gels and gel-glasses in the SiO2-GeO2 system using vibrational spectroscopy,” J. Am. Ceram. Soc. 69, 806–10 (1986).
[Crossref]

J. Appl. Phys. (1)

C. M. Herzinger, B. Johs, W. A. McGahan, J. A. Woollam, and W. Paulson, “Ellipsometric determination of optical constants for silicon and thermally grown silicon dioxide via a multi-sample, multi-wavelength, multi-angle investigation,” J. Appl. Phys. 83, 3323–3336 (1998).
[Crossref]

J. Electrochem. Soc. (2)

D. L. Simpson, R. T. Croswell, A. Reisman, D. Temple, and C. K. Williams, “Planarization processes and applications - I. Undoped GeO2-SiO2 glasses,” J. Electrochem. Soc. 146, 3860–3871 (1999).
[Crossref]

R. A. Bellman, G. Bourdon, G. Alibert, A. Beguin, E. Guiot, L. B. Simpson, P. Lehuede, L. Guiziou, and E. LeGuen, “Ultralow loss high delta silica germania planar waveguides,” J. Electrochem. Soc. 151, G541–G547 (2004).
[Crossref]

J. Non-Cryst. Solids. (4)

D.-G. Chen, B. G. Potter, and J. H. Simmons, “GeO2-SiO2 thin films for planar waveguide applications,” J. Non-Cryst. Solids. 178, 135–47 (1994).
[Crossref]

Y. Y. Huang, A. Sarkar, and P. C. Schultz, “Relationship between composition, density and refractive index for germania silica glasses,” J. Non-Cryst. Solids. 27, 29–37 (1978).
[Crossref]

R. R. A. Syms and A. S. Holmes, “Deposition of thick silica-titania sol-gel films on Si substrates,” J. Non-Cryst. Solids. 170, 223–33 (1994).
[Crossref]

T. Busani, H. Plantier, R. A. B. Devine, C. Hernandez, and Y. Campidelli, “Growth kinetics and physical characterisation of Si1-xGexO2 films obtained by plasma assisted oxidation,” J. Non-Cryst. Solids. 254, 80–88 (1999).
[Crossref]

Mat. Sci. Eng. R (1)

A. B. Djurisic, Y. Chan, and E. H. Li, “Progress in the room-temperature optical functions of semiconductors,” Mat. Sci. Eng. R 38, 237–293 (2002).
[Crossref]

Opt. Mater. (1)

S. Matsumoto, T. Fujiwara, and A. J. Ikushima, “Large second-order optical nonlinearity in Ge-doped silica glass,” Opt. Mater. 18, 19–22 (2001).
[Crossref]

Thin Solid Films (1)

C. Strohhofer, S. Capecchi, J. Fick, A. Martucci, G. Brusatin, and M. Guglielmi, “Active optical properties of erbium-doped GeO2-based sol-gel planar waveguides,” Thin Solid Films 326, 99–105 (1998).
[Crossref]

Other (3)

C. K. F. Ho, D. C. L. Gwee, Rajni, K. Pita, N. Q. Ngo, and C. H. Kam, “Planar optical waveguides fabricated by sol-gel derived inorganic silicate glass,” presented at the 11th European Conference on Intergrated Optics 2003, Prague, Czech Republic, April 2–4, 2003.
[PubMed]

H. Scholze, Glass : nature, structure, and properties (Springer-Verlag, New York, 1991).

W. Que, Y. Zhou, Y. L. Lam, Y. C. Chan, Y. W. Chen, S. L. Ng, C. Y. Liaw, and C. H. Kam, “Fabrication of composite sol-gel optical channel waveguides by laser writing lithography,” presented at the Optical Engineering for Sensing and Nanotechnology (ICOSN ’99), Yokohama, Japan, 16–18 June, 1999.

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Figures (3)

Fig. 1.
Fig. 1. (a) Film structure model for ellipsometer analysis. (b) TEM micrograph showing a 40 mol% Ge film after annealing of 1000°C for 15 mins.
Fig. 2.
Fig. 2. (a) The RI-composition contour map showing the Sellmeier dispersion interpolated for a Ge content 0≤x≤0.4. (b) Linearity of RIs with variation in composition. The dash line represents the linear regression of the n(He-Ne) data from this work.
Fig. 3.
Fig. 3. (a) Change in dispersion parameters versus Ge content. The solid line represents an extrapolated linear fit of the DFC values without the data point at x=0.4. (b) Spectral material dispersion coefficient, DMAT , and the zero-dispersion wavelengths (inset) are shown for the different compositions.

Tables (1)

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Table 1. Sellmeier dispersion parameters for films of varying Ge content. (* taken from thermal oxide in Ref. [7])

Equations (2)

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n 2 = ε = ε offset + a λ 2 λ 2 b 2 + c λ 2 ,
D MAT = λ c 2 n λ 2

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