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Hyperfine structures in 91Zr by saturation optogalvanic spectroscopy

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Abstract

We report high-resolution Doppler-free hyperfine-structure determinations of eight excited levels in the first spectrum of zirconium. These structures have been obtained with optogalvanic intermodulated saturation and Polinex spectroscopic techniques on a zirconium vapor formed in a hollow-cathode-type generator. Quantitative values for the hyperfine splittings and for the A and B constants are given for the levels at 16297cm1(F32°), 16787cm1(F51°), 16844cm1(F33°), 17430cm1(D31°), 17556cm1(F34°), 17814cm1(D32°), 18244cm1(D33°) of the configuration 4d25s5pz and of the level at 15 120 cm−1 of the configuration 4d35sa3H6.

© 1988 Optical Society of America

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