Abstract

The microwave magnetic double-resonance spectrum of Cl atoms was observed by using the laser-magnetic-resonance (LMR) spectrum for the ²P_1/2–²P_3/2 transition. X-band microwave power supplied to the double-resonance cell discharged gaseous Cl₂ in the cell to generate Cl atoms and simultaneously brought about the double-resonance signals. The observed double-resonance frequencies provided accurate magnetic-field determination for the Lamb-dip positions for the ²P_1/2–²P_3/2 LMR Cl atom transition. The ²P_1/2–²P_3/2 splitting energies were determined to be 882.352 935(67) cm⁻¹ (³⁵Cl) and 882.353 786(67) cm⁻¹ (³⁷Cl).

© 1987 Optical Society of America

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