Analysis of 4-ionized vanadium (V v)†

Cornelius H. H. Van Deurzen

doi:10.1364/JOSA.67.000476

Journal of the Optical Society of America
Vol. 67,
Issue 4,
pp. 476-480
(1977)
•https://doi.org/10.1364/JOSA.67.000476

Analysis of 4-ionized vanadium (V v)

Cornelius H. H. Van Deurzen

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Cornelius H. H. Van Deurzen, "Analysis of 4-ionized vanadium (V v)†," J. Opt. Soc. Am. 67, 476-480 (1977)

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Abstract

The spectrum of V v has been observed by using 10 m grazing- and normal-incidence spectrographs and a vacuum sliding-spark light source to excite the spectrum. The analysis has been extended to include 38 newly classified lines in the region 199–7600 Å. Seven new levels have been identified, five in the 3p ⁶nl configuration and two in the 3p ⁵3d4s configuration. Calculated wavelengths given for 42 lines in the region 222–996 Å are suitable as reference lines and the ionization energy is revised to 526 532.0 ± 1.4 cm⁻¹ (65.2822 eV).

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Corrections

Cornelius H. H. Van Deurzen, "Erratum," J. Opt. Soc. Am. 67, 1135-1135 (1977)
https://opg.optica.org/josa/abstract.cfm?uri=josa-67-8-1135

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Int.^a	Wavelength (Å)		Wave number (cm⁻¹)	Level combination
Int.^a	Obs. ^b	Calc.	Wave number (cm⁻¹)	Even	Odd
1	8457.555	0.51	11 820.50	3p⁶6s ²S_1/2–3p⁶6p	²P_3/2
3	7595.511		13 162.05	8i ²I –7h	²H
4	6635.164	0.171	15 067.06	6d ²D_3/2–6f	²F_5/2
7	6628.796	0.788	15 081.53	²D_5/2–	²F_7/2
3	6541.429	0.437	15 282.96	6d ²D_3/2–7p	²P_1/2
6	6478.300	0.306	15 431.88	²D_5/2–	²P_3/2
1	6462.734	0.748	15 469.05	²D_3/2–	²P_3/2
5	6188.907	0.916	16 153.47	6d ²D_5/2–5f	²F_7/2
2	6135.907	0.907	16 293.00	8s ²S_1/2–7p	²P_3/2
1	6066.620	0.620	16 479.08	²S_1/2–	²P_1/2
3	6020.741	0.735	16 604.65	6d ²D_3/2–5f	²F_5/2
3	5442.704	0.703	18 368.12	5g ²G_9/2–3p⁵3d ²(²F)	²F_7/2
1	5366.750	0.747	18 628.07	6d ²D_3/2–6p	²P_3/2
8	5356.070	0.066	18 665.21	²D_5/2–	²P_3/2
4	5294.115	0.108	18 883.64	²D_3/2–	²P_1/2
1	5079.413		19 681.83	6g ²G_7/2–7f	²F_5/2
15w	4930.533		20 276.12	7i ²I–6h	²H
7w	4885.299		20 463. 86	6g ²G–7h	²H
3	4780.787	0.771	20 911.21	7g ²G_9/2–6f	²F_7/2
1	4769.064	0.081	20 962.61	²G_7/2–	²F_5/2
10	4293.735	0.732	23 283.20	5s ²S_1/2–5p	²P_1/2
20	4200.322	0.314	23 800.99	²S_1/2–	²P_3/2
1	3989.471	0.462	25 058. 89	4d ²D_5/2–3p⁵3d²(¹G)	²F_5/2
5	3966.598	0.607	25 203.39	²D_3/2–(¹G)	²F_5/2
12b	3476.36	0.449	26 685.0	²D_5/2–(¹G)	²F_7/2
4	3648.724	0.725	27 399.03	7s ²S_1/2–6p	²P_3/2
8	3642.887	0.874	27 442. 94	5d ²D_3/2–6p	²P_1/2
15	3617.966	0.961	27 631.96	²D_5/2–	²P_3/2
2h	3615.039	0.001	27 654.33	7s ²S_1/2–6p	²P_1/2
2	3609.269	0.259	27 698.54	5d ²D_3/2–6p	²P_3/2
1	3371.089	0.098	29 655.48	5d ²D_5/2–5f	²F_5/2
6	3363.517	0.541	29 722.24	²D_3/2–	²F_5/2
10	3316.470	0.480	30 143.86	²D_5/2–	²F_7/2
8b	3139.94	0.018	31 838.5	6g ²G_9/2–5f	²F_7/2
4	3092.641	0.641	32 325.44	²G_7/2–	²F_5/2
8w	2950.134		33 886. 87	5g ²G G–6h	²H
3	2780.959^c	0.966	35 958.82	5d ²D_3/2–5p	²P_3/2
15	2775.816^c	0.823	36 025.44	²D_5/2–	²P_3/2
10	2741.480^c	0.487	36 476.65	²D_3/2–	²P_1/2
10	2610.881^c	0.864	38 301.25	5d ²D_3/2–4f	²F_5/2
4h	2606.30^c	0.330	38 368.6	²D_5/2–	²F_5/2
20	2577.899^c	0.898	38 791.27	²D_5/2–	²F_7/2
1	2374. 183^c		42 119.75	6g ²G_7/2– 9f	²F_5/2
3	2370. 984^c		42 176.59	²G_9/2–	²F_7/2
6	2327. 463^c	0.457	42 965.23	4d ²D_5/2–3p⁵3d²(¹D)	²F_5/2
20b	2319.66^c	0.662	43 109.7	²D_3/2–(¹D)	²F_5/2
1	1962.154	0.151	50 964.41	5d ²D_3/2–3p⁵3d²(¹D)	²F_5/2
9	1929.138	0.132	51 836.63	6s ²S_1/2–5p	²P_3/2
1	1921.915	0.911	52 031.43	6g ²G_9/2–3p⁵3d²(³F)	²F_7/2
1	1917.686	0.682	52 146.17	7g ²G_9/2–5f	²F_7/2
4	1910.062	0.052	52 354.33	6s ²S_1/2–5p	²P_1/2
30	1811.425	0.425	55 205.15	4d ²D_5/2–4f	²F_7/2
6	1797.646	0.645	55 628.31	²D_5/2–	²F_5/2
25	1792.992	0.992	55 772.71	²D_3/2–	²F_5/2
10	1736.182	0.182	57 597.66	4d ²D_3/2–5p	²P_1/2
15	1724.994	0.998	57 971.23	²D_5/2–	²P_3/2
4	1720.712	0.712	58 115.48	²D_3/2–	²P_3/2
50	1716.725	0.727	58 250.43	4s ²S_1/2–4p	²P_1/2
100	1680.204	0.202	59 516.56	²S_1/2–	²P_3/2
10	1499.596	0.594	66 684.63	5g ²G_7/2–4f	²F_5/2
20	1490.107	0.105	67 109.29	²G_9/2–	²F_7/2
1	1260.278	0.276	79 347.57	5g ²G_7/2–3p⁵3d²(¹D)	²F_5/2
6	1159.516	0.516	86 242.87	4d ²D_3/2–4p	²P_3/2
25	1157.575	0.578	86 387.48	²D_5/2–	²P_3/2
1	1143.395	0.401	87 458. 84	5s ²S_1/2–6p	²P_3/2
15	1142.737	0.738	87 509.18	4d ²D_3/2–4p	²P_1/2
2	1098.222	0.221	91 056.27	7s ²S_1/2–5p	²P_3/2
1h	1092.00	0.011	91 575.0	²S_1/2–	²P_1/2
2	1045.711	0.7113	95 628.71	5g²G_7/2–3p⁵3d²(¹G)	²F_7/2
5	996.521	0.5224	100 349.1	6g ²G_7/2–4f	²F_5/2
10	992.330	0.3313	100 773.0	²G_9/2–	²F_7/2
1	979.547	0.5471	102 088. 1	4d ²D_5/2–3p⁵3d²(³F)	²F_5/2
10	978.166	0.1637	102 232.2	²D_3/2–(³F)	²F_5/2
15	962.031	0.0341	103 946.7	3p⁶ ²D_5/2–(³F)	²F_7/2
2	897. 124		111 467.3	7d ²D_5/2–4f	²F_7/2
30	829.483	0.4811	120 557.0	5s ²S_1/2–4p	²P_3/2
1	828.791	0.7903	120 657.7	7g ²G_7/2–4f	²F_5/2
2	825. 891	0.8910	121 081.3	²G_9/2–	²F_7/2
3	822.927	0.9285	121 517.4	4d ²D_3/2–6p	²P_1/2
1	822.668	0.6695	121 555.7	5s ²S_1/2–7p	²P_3/2
6	822.176	0.1761	121 628.5	4d ²D_5/2–6p	²P_3/2
1	821.202	0.2012	121 772.7	²D_3/2–	²P_3/2
20	820.859	0.8591	121 823.5	5s ²S_1/2–4p	²P_1/2
1	643.603	0.6032	155 375.3	4d ²D_5/2–6f	²F_7/2
2	509.697	0.6967	196 195.1	6s ²S_1/2–4p	²P_3/2
1	506.429	0.4281	197 461.0	²S_1/2–	²P_1/2
2	491.746	0.7457	203 357.2	4s ²S_1/2–5p	²P_1/2
4	490.496	0.4966	203 875.1	²S_1/2–	²P_3/2
25	484.510		206 393.74	3d ²D_3/2–4p	²P_1/2
35	483.009		207 035. 13	²D_5/2–	²P_3/2
8	481.556		207 660.00	²D_3/2–	²P_3/2
1	424. 782	0.7823	235 415.1	7s ²S_1/2–4p	²P_3/2
10	313.993	0. 9902	318 478	3d ²D_5/2–3p⁵4d²(¹G)	²F_5/2
14	313.376	0.3753	319 105	²D_3/2–(¹G) (¹G)	²F_5/2
17	312.394	0.3958	320 109	²D_5/2–(¹G) (¹G)	²F_7/2
10b	301.604		331 561	3d ²D_5/2–3p⁵3d²(¹D)	²F_7/2
2	297.276	0.2760	336 387.3	²D_5/2–(¹D)	²F_5/2
5	296.724	0.7248	337 013.6	²D_3/2–(¹D)	²F_5/2
20	286. 839	0.8391	348 627.0	3d ²D_5/2–4f	²F_7/2
5	286.490	0.4913	349 052.6	²D_5/2–	²F_5/2
18	285.979	0.9794	349 676. 0	²D_3/2–	²F_5/2
11	284.581	0.5813	351 393.4	3d ²D_5/2–5p	²P_3/2
8	284.494	0.4946	351 500.8	²D_3/2–	²P_1/2
2	284.075	0.0761	352 019.8	²D_3/2–	²P_3/2
8	252. 838	0.8379	395 509.7	3d ²D_5/2–3p⁵3d²(³F)	²F_5/2
18	252.440	0.4390	396 133.2	²D_3/2–(³F)	²F_5/2
20	251.655	0.6554	397 369.4	²D_5/2–(³F)	²F_7/2
7	240.933	0. 9343	415 052. 8	3d ²D_5/2–6p	²P_3/2
4	240.719	0.7202	415 422.5	²D_3/2–	²P_1/2
1	240.572	0.5722	415 676.2	²D_3/2–	²P_3/2
7	239.765	0.7655	417 075.7	3d ²D_5/2–5f	²F_5/2
19	239.485	0.4850	417 562.2	²D_5/2–5f	²F_7/2
16	239.407	0.4068	417 698.1	²D_3/2–	²F_5/2
14	228.301		438 018.3	3p ²D_3/2–3p⁵3d²(³P)	²F_1/2
17	227.885		438 817.2	²D_5/2–(³P)	²F_3/2
10	227.561		439 443.4	²D_3/2–(³P)	²F_3/2
20	225.465		443 527.6	3d ²D_5/2–3p⁵3d²(³F)	²F_5/2
13	225.225		444 000.5	²D_5/2–(³F)	²F_3/2
13	225.146		444 154. 8	²D_3/2–(³F)	²F_5/2
18	224.913		444 616.3	²D_3/2–(³F)	²F_3/2
3	222.842	0. 8432	448 748.0	3d ²D_5/2–6f	²F_5/2
13	222.818	0.8176	448 796.8	²D_5/2–	²F_7/2
10	222.533	0.5334	449 371.1	²D_3/2–	²F_5/2
9	213.178		469 092	3d ²D_5/2–7f	²F_7/2
7	212.901		469 702	²D_3/2–	²F_5/2
12	210.568		474 906	3d ²D_5/2–3p⁵3d(³F)4s	²F_7/2
1	209.230		477 942	²D_5/2–(³F)	²F_5/2
10	208.958		478 565	²D_3/2–(³F)	²F_5/2
6	207.291		482 414	3d ²D_5/2– 8f	²F_7/2
4	207.031		483 019	²D_3/2–	²F_5/2
5	203.428		491 574	3d ²D_5/2– 9f	²F_7/2
2	203. 194		492 141	²D_3/2–	²F_5/2
2	201.746		495 673	3d ²D_5/2–3p⁵3d(¹F)4s	²F_5/2
1	201.493		496 295	²D_3/2–(¹F)	²F_5/2
4	201.235		496 931	²D_5/2–(¹F)	²F_7/2
1	200.202		499 495	3d ²D_5/2–3p⁵3d(³D)4s	²D_5/2
5	200.050		499 876	²D_5/2–(³D)	²D_3/2
5	199.955		500 113	²D_3/2–(³D)	²D_5/2
1	199.799		500 503	²D_3/2–(³D)	²D_3/2

Designation	Energy (cm⁻¹)	Interval (cm⁻¹)	n*	10⁶ Δn*
3p⁶4s ²S_1/2	148 143.35		2.692624
5s ²S_1/2	328 217.30		3.719353
6s ²S_1/2	403.855.12		4. 728937
7s ²S_1/2	443 074.72		5.733406
8s ²S_1/2	466 065.79^a		6.735789
9s ²S_1/2	(480 704.7)^b
$4 p {² P}_{1 / 2}^{0}$	206 393.72		2.927359
${² P}_{3 / 2}^{0}$	207 660.00	1266.28	2.933166	5806
$5 p {² P}_{1 / 2}^{0}$	351 500.51		3.959011
${² P}_{3 / 2}^{0}$	352 018.34	517.83	3.964881	5869
$6 p {² P}_{1 / 2}^{0}$	415 420.10		4.968949
${² P}_{3 / 2}^{0}$	415 675.69	255.59	4.974674	5724
$7 p {² P}_{1 / 2}^{0}$	449 586.71^a		5.971093
${² P}_{3 / 2}^{0}$	449 772.79^a	186.08	5.978326	7233
3d ²D_3/2	0.00		2. 282614
²D_5/2	624.87	624.87	2.283969	1355
4d ²D_3/2	293 902.86		3.434099
²D_5/2	294 047.24	144.38	3.435165	1066
5d ²D_3/2	387 977.07		4.449732
²D_5/2	388 043.69	66.62	4.450802	1070
6d ²D_3/2	434 303.77		5. 453972
²D_5/2	434 340.92	37.15	5.455071	1098
7d ²D_3/2	(460 696.8)^b
²D_5/2	460 719.7^a	(22.9)	6.456413
$4 f {² F}_{5 / 2}^{0}$	349 675.57		3.938532
${² F}_{7 / 2}^{0}$	349 252.40	−423.17	3.933829	−4703
$5 f {² F}_{5 / 2}^{0}$	417 699.10		5.020705
${² F}_{7 / 2}^{0}$	418 187.47	488.37	5.032008	11302
$6 f {² F}_{5 / 2}^{0}$	449 370.81		5.962733
${² F}_{7 / 2}^{0}$	449 422.47	51.66	5.964730	1997
$7 f {² F}_{5 / 2}^{0}$	469 706.4		6.948208
${² F}_{7 / 2}^{0}$	469 721	15	6.949101	892
$8 f {² F}_{5 / 2}^{0}$	483 019		7. 940271
${² F}_{7 / 2}^{0}$	483 039	20	7.942096	1825
$9 f {² F}_{5 / 2}^{0}$	492 144.3		8.931886
${² F}_{7 / 2}^{0}$	492 201.8	57.5	8.939363	7476
5g ²G_7/2	416 360.29		4.990106
²G_9/2	416 361.78	1.49	4.990140	33
6g ²G_7/2	450 024.54		5.988154
²G_9/2	450 025.20	0.66	5.988179	25
7g ²G_7/2	470 333.35		6.986857
²G_9/2	470 333.75	0.40	6.986882	24
8g ²G	(483 515.7)^b
6h ²H⁰	450 247.99		5.996917
7h ²H⁰	470 488.77		6.996 539
8h ²H⁰	(483 626.4)^b
7i ²I	470 524.11		6.998746
8i ²I	483 650.82^a		7.998554
9i ²I	(492 651.5)^b
Limit 3p⁶ ¹S₀	526 532.0
$3 p^{5} 3 d^{2} (^{1} G) {² F}_{5 / 2}^{0}$	319 106.19
${² F}_{7 / 2}^{0}$	320 731.60	1625.41
$(^{1} D) {² F}_{5 / 2}^{0}$	337 012.59
${² F}_{7 / 2}^{0}$	332.198.1	−4814.5
$(^{3} F) {² F}_{5 / 2}^{0}$	396 135.24
$² F_{7 / 2}^{0}$	397 993.66	1858.42
$(^{3} P) {² P}_{1 / 2}^{0}$	438 018.3
${² P}_{3 / 2}^{0}$	439 442.7	1424.4
$(^{3} F) {² D}_{3 / 2}^{0}$	444 620.8
${² D}_{5 / 2}^{0}$	444 153.7	−467.1
$3 p^{5} 3 d (^{3} F) 4 s {² F}_{5 / 2}^{0}$	478 566
${² F}_{7 / 2}^{0}$	475 531	−3035
$(^{1} F) 4 s {² F}_{5 / 2}^{0}$	496 296
${² F}_{7 / 2}^{0}$	497 556	1260
$(^{3} D) 4 s {² D}_{3 / 2}^{0}$	500 502^a
${² D}_{5 / 2}^{0}$	500 117^a	−385

Terms used	E_∞(cm⁻¹)	$α_{d} (a_{0}^{3})$	$α_{q} (a_{0}^{5})$
5g, 6g, 7g	526 525.3	0.94	2.1
6h, 7h, 7i, 8i	526 532.0±1	1.01±.08	1.4±1.1
5g, 6g, 7g, 6h, 7h, 7i, 8i	526 530.3±2	0.93±.05	2.3±0.3

Int.^a	Wavelength (Å)		Wave number (cm⁻¹)	Level combination
Int.^a	Obs. ^b	Calc.	Wave number (cm⁻¹)	Even	Odd
1	8457.555	0.51	11 820.50	3p⁶6s ²S_1/2–3p⁶6p	²P_3/2
3	7595.511		13 162.05	8i ²I –7h	²H
4	6635.164	0.171	15 067.06	6d ²D_3/2–6f	²F_5/2
7	6628.796	0.788	15 081.53	²D_5/2–	²F_7/2
3	6541.429	0.437	15 282.96	6d ²D_3/2–7p	²P_1/2
6	6478.300	0.306	15 431.88	²D_5/2–	²P_3/2
1	6462.734	0.748	15 469.05	²D_3/2–	²P_3/2
5	6188.907	0.916	16 153.47	6d ²D_5/2–5f	²F_7/2
2	6135.907	0.907	16 293.00	8s ²S_1/2–7p	²P_3/2
1	6066.620	0.620	16 479.08	²S_1/2–	²P_1/2
3	6020.741	0.735	16 604.65	6d ²D_3/2–5f	²F_5/2
3	5442.704	0.703	18 368.12	5g ²G_9/2–3p⁵3d ²(²F)	²F_7/2
1	5366.750	0.747	18 628.07	6d ²D_3/2–6p	²P_3/2
8	5356.070	0.066	18 665.21	²D_5/2–	²P_3/2
4	5294.115	0.108	18 883.64	²D_3/2–	²P_1/2
1	5079.413		19 681.83	6g ²G_7/2–7f	²F_5/2
15w	4930.533		20 276.12	7i ²I–6h	²H
7w	4885.299		20 463. 86	6g ²G–7h	²H
3	4780.787	0.771	20 911.21	7g ²G_9/2–6f	²F_7/2
1	4769.064	0.081	20 962.61	²G_7/2–	²F_5/2
10	4293.735	0.732	23 283.20	5s ²S_1/2–5p	²P_1/2
20	4200.322	0.314	23 800.99	²S_1/2–	²P_3/2
1	3989.471	0.462	25 058. 89	4d ²D_5/2–3p⁵3d²(¹G)	²F_5/2
5	3966.598	0.607	25 203.39	²D_3/2–(¹G)	²F_5/2
12b	3476.36	0.449	26 685.0	²D_5/2–(¹G)	²F_7/2
4	3648.724	0.725	27 399.03	7s ²S_1/2–6p	²P_3/2
8	3642.887	0.874	27 442. 94	5d ²D_3/2–6p	²P_1/2
15	3617.966	0.961	27 631.96	²D_5/2–	²P_3/2
2h	3615.039	0.001	27 654.33	7s ²S_1/2–6p	²P_1/2
2	3609.269	0.259	27 698.54	5d ²D_3/2–6p	²P_3/2
1	3371.089	0.098	29 655.48	5d ²D_5/2–5f	²F_5/2
6	3363.517	0.541	29 722.24	²D_3/2–	²F_5/2
10	3316.470	0.480	30 143.86	²D_5/2–	²F_7/2
8b	3139.94	0.018	31 838.5	6g ²G_9/2–5f	²F_7/2
4	3092.641	0.641	32 325.44	²G_7/2–	²F_5/2
8w	2950.134		33 886. 87	5g ²G G–6h	²H
3	2780.959^c	0.966	35 958.82	5d ²D_3/2–5p	²P_3/2
15	2775.816^c	0.823	36 025.44	²D_5/2–	²P_3/2
10	2741.480^c	0.487	36 476.65	²D_3/2–	²P_1/2
10	2610.881^c	0.864	38 301.25	5d ²D_3/2–4f	²F_5/2
4h	2606.30^c	0.330	38 368.6	²D_5/2–	²F_5/2
20	2577.899^c	0.898	38 791.27	²D_5/2–	²F_7/2
1	2374. 183^c		42 119.75	6g ²G_7/2– 9f	²F_5/2
3	2370. 984^c		42 176.59	²G_9/2–	²F_7/2
6	2327. 463^c	0.457	42 965.23	4d ²D_5/2–3p⁵3d²(¹D)	²F_5/2
20b	2319.66^c	0.662	43 109.7	²D_3/2–(¹D)	²F_5/2
1	1962.154	0.151	50 964.41	5d ²D_3/2–3p⁵3d²(¹D)	²F_5/2
9	1929.138	0.132	51 836.63	6s ²S_1/2–5p	²P_3/2
1	1921.915	0.911	52 031.43	6g ²G_9/2–3p⁵3d²(³F)	²F_7/2
1	1917.686	0.682	52 146.17	7g ²G_9/2–5f	²F_7/2
4	1910.062	0.052	52 354.33	6s ²S_1/2–5p	²P_1/2
30	1811.425	0.425	55 205.15	4d ²D_5/2–4f	²F_7/2
6	1797.646	0.645	55 628.31	²D_5/2–	²F_5/2
25	1792.992	0.992	55 772.71	²D_3/2–	²F_5/2
10	1736.182	0.182	57 597.66	4d ²D_3/2–5p	²P_1/2
15	1724.994	0.998	57 971.23	²D_5/2–	²P_3/2
4	1720.712	0.712	58 115.48	²D_3/2–	²P_3/2
50	1716.725	0.727	58 250.43	4s ²S_1/2–4p	²P_1/2
100	1680.204	0.202	59 516.56	²S_1/2–	²P_3/2
10	1499.596	0.594	66 684.63	5g ²G_7/2–4f	²F_5/2
20	1490.107	0.105	67 109.29	²G_9/2–	²F_7/2
1	1260.278	0.276	79 347.57	5g ²G_7/2–3p⁵3d²(¹D)	²F_5/2
6	1159.516	0.516	86 242.87	4d ²D_3/2–4p	²P_3/2
25	1157.575	0.578	86 387.48	²D_5/2–	²P_3/2
1	1143.395	0.401	87 458. 84	5s ²S_1/2–6p	²P_3/2
15	1142.737	0.738	87 509.18	4d ²D_3/2–4p	²P_1/2
2	1098.222	0.221	91 056.27	7s ²S_1/2–5p	²P_3/2
1h	1092.00	0.011	91 575.0	²S_1/2–	²P_1/2
2	1045.711	0.7113	95 628.71	5g²G_7/2–3p⁵3d²(¹G)	²F_7/2
5	996.521	0.5224	100 349.1	6g ²G_7/2–4f	²F_5/2
10	992.330	0.3313	100 773.0	²G_9/2–	²F_7/2
1	979.547	0.5471	102 088. 1	4d ²D_5/2–3p⁵3d²(³F)	²F_5/2
10	978.166	0.1637	102 232.2	²D_3/2–(³F)	²F_5/2
15	962.031	0.0341	103 946.7	3p⁶ ²D_5/2–(³F)	²F_7/2
2	897. 124		111 467.3	7d ²D_5/2–4f	²F_7/2
30	829.483	0.4811	120 557.0	5s ²S_1/2–4p	²P_3/2
1	828.791	0.7903	120 657.7	7g ²G_7/2–4f	²F_5/2
2	825. 891	0.8910	121 081.3	²G_9/2–	²F_7/2
3	822.927	0.9285	121 517.4	4d ²D_3/2–6p	²P_1/2
1	822.668	0.6695	121 555.7	5s ²S_1/2–7p	²P_3/2
6	822.176	0.1761	121 628.5	4d ²D_5/2–6p	²P_3/2
1	821.202	0.2012	121 772.7	²D_3/2–	²P_3/2
20	820.859	0.8591	121 823.5	5s ²S_1/2–4p	²P_1/2
1	643.603	0.6032	155 375.3	4d ²D_5/2–6f	²F_7/2
2	509.697	0.6967	196 195.1	6s ²S_1/2–4p	²P_3/2
1	506.429	0.4281	197 461.0	²S_1/2–	²P_1/2
2	491.746	0.7457	203 357.2	4s ²S_1/2–5p	²P_1/2
4	490.496	0.4966	203 875.1	²S_1/2–	²P_3/2
25	484.510		206 393.74	3d ²D_3/2–4p	²P_1/2
35	483.009		207 035. 13	²D_5/2–	²P_3/2
8	481.556		207 660.00	²D_3/2–	²P_3/2
1	424. 782	0.7823	235 415.1	7s ²S_1/2–4p	²P_3/2
10	313.993	0. 9902	318 478	3d ²D_5/2–3p⁵4d²(¹G)	²F_5/2
14	313.376	0.3753	319 105	²D_3/2–(¹G) (¹G)	²F_5/2
17	312.394	0.3958	320 109	²D_5/2–(¹G) (¹G)	²F_7/2
10b	301.604		331 561	3d ²D_5/2–3p⁵3d²(¹D)	²F_7/2
2	297.276	0.2760	336 387.3	²D_5/2–(¹D)	²F_5/2
5	296.724	0.7248	337 013.6	²D_3/2–(¹D)	²F_5/2
20	286. 839	0.8391	348 627.0	3d ²D_5/2–4f	²F_7/2
5	286.490	0.4913	349 052.6	²D_5/2–	²F_5/2
18	285.979	0.9794	349 676. 0	²D_3/2–	²F_5/2
11	284.581	0.5813	351 393.4	3d ²D_5/2–5p	²P_3/2
8	284.494	0.4946	351 500.8	²D_3/2–	²P_1/2
2	284.075	0.0761	352 019.8	²D_3/2–	²P_3/2
8	252. 838	0.8379	395 509.7	3d ²D_5/2–3p⁵3d²(³F)	²F_5/2
18	252.440	0.4390	396 133.2	²D_3/2–(³F)	²F_5/2
20	251.655	0.6554	397 369.4	²D_5/2–(³F)	²F_7/2
7	240.933	0. 9343	415 052. 8	3d ²D_5/2–6p	²P_3/2
4	240.719	0.7202	415 422.5	²D_3/2–	²P_1/2
1	240.572	0.5722	415 676.2	²D_3/2–	²P_3/2
7	239.765	0.7655	417 075.7	3d ²D_5/2–5f	²F_5/2
19	239.485	0.4850	417 562.2	²D_5/2–5f	²F_7/2
16	239.407	0.4068	417 698.1	²D_3/2–	²F_5/2
14	228.301		438 018.3	3p ²D_3/2–3p⁵3d²(³P)	²F_1/2
17	227.885		438 817.2	²D_5/2–(³P)	²F_3/2
10	227.561		439 443.4	²D_3/2–(³P)	²F_3/2
20	225.465		443 527.6	3d ²D_5/2–3p⁵3d²(³F)	²F_5/2
13	225.225		444 000.5	²D_5/2–(³F)	²F_3/2
13	225.146		444 154. 8	²D_3/2–(³F)	²F_5/2
18	224.913		444 616.3	²D_3/2–(³F)	²F_3/2
3	222.842	0. 8432	448 748.0	3d ²D_5/2–6f	²F_5/2
13	222.818	0.8176	448 796.8	²D_5/2–	²F_7/2
10	222.533	0.5334	449 371.1	²D_3/2–	²F_5/2
9	213.178		469 092	3d ²D_5/2–7f	²F_7/2
7	212.901		469 702	²D_3/2–	²F_5/2
12	210.568		474 906	3d ²D_5/2–3p⁵3d(³F)4s	²F_7/2
1	209.230		477 942	²D_5/2–(³F)	²F_5/2
10	208.958		478 565	²D_3/2–(³F)	²F_5/2
6	207.291		482 414	3d ²D_5/2– 8f	²F_7/2
4	207.031		483 019	²D_3/2–	²F_5/2
5	203.428		491 574	3d ²D_5/2– 9f	²F_7/2
2	203. 194		492 141	²D_3/2–	²F_5/2
2	201.746		495 673	3d ²D_5/2–3p⁵3d(¹F)4s	²F_5/2
1	201.493		496 295	²D_3/2–(¹F)	²F_5/2
4	201.235		496 931	²D_5/2–(¹F)	²F_7/2
1	200.202		499 495	3d ²D_5/2–3p⁵3d(³D)4s	²D_5/2
5	200.050		499 876	²D_5/2–(³D)	²D_3/2
5	199.955		500 113	²D_3/2–(³D)	²D_5/2
1	199.799		500 503	²D_3/2–(³D)	²D_3/2

Designation	Energy (cm⁻¹)	Interval (cm⁻¹)	n*	10⁶ Δn*
3p⁶4s ²S_1/2	148 143.35		2.692624
5s ²S_1/2	328 217.30		3.719353
6s ²S_1/2	403.855.12		4. 728937
7s ²S_1/2	443 074.72		5.733406
8s ²S_1/2	466 065.79^a		6.735789
9s ²S_1/2	(480 704.7)^b
$4 p {² P}_{1 / 2}^{0}$	206 393.72		2.927359
${² P}_{3 / 2}^{0}$	207 660.00	1266.28	2.933166	5806
$5 p {² P}_{1 / 2}^{0}$	351 500.51		3.959011
${² P}_{3 / 2}^{0}$	352 018.34	517.83	3.964881	5869
$6 p {² P}_{1 / 2}^{0}$	415 420.10		4.968949
${² P}_{3 / 2}^{0}$	415 675.69	255.59	4.974674	5724
$7 p {² P}_{1 / 2}^{0}$	449 586.71^a		5.971093
${² P}_{3 / 2}^{0}$	449 772.79^a	186.08	5.978326	7233
3d ²D_3/2	0.00		2. 282614
²D_5/2	624.87	624.87	2.283969	1355
4d ²D_3/2	293 902.86		3.434099
²D_5/2	294 047.24	144.38	3.435165	1066
5d ²D_3/2	387 977.07		4.449732
²D_5/2	388 043.69	66.62	4.450802	1070
6d ²D_3/2	434 303.77		5. 453972
²D_5/2	434 340.92	37.15	5.455071	1098
7d ²D_3/2	(460 696.8)^b
²D_5/2	460 719.7^a	(22.9)	6.456413
$4 f {² F}_{5 / 2}^{0}$	349 675.57		3.938532
${² F}_{7 / 2}^{0}$	349 252.40	−423.17	3.933829	−4703
$5 f {² F}_{5 / 2}^{0}$	417 699.10		5.020705
${² F}_{7 / 2}^{0}$	418 187.47	488.37	5.032008	11302
$6 f {² F}_{5 / 2}^{0}$	449 370.81		5.962733
${² F}_{7 / 2}^{0}$	449 422.47	51.66	5.964730	1997
$7 f {² F}_{5 / 2}^{0}$	469 706.4		6.948208
${² F}_{7 / 2}^{0}$	469 721	15	6.949101	892
$8 f {² F}_{5 / 2}^{0}$	483 019		7. 940271
${² F}_{7 / 2}^{0}$	483 039	20	7.942096	1825
$9 f {² F}_{5 / 2}^{0}$	492 144.3		8.931886
${² F}_{7 / 2}^{0}$	492 201.8	57.5	8.939363	7476
5g ²G_7/2	416 360.29		4.990106
²G_9/2	416 361.78	1.49	4.990140	33
6g ²G_7/2	450 024.54		5.988154
²G_9/2	450 025.20	0.66	5.988179	25
7g ²G_7/2	470 333.35		6.986857
²G_9/2	470 333.75	0.40	6.986882	24
8g ²G	(483 515.7)^b
6h ²H⁰	450 247.99		5.996917
7h ²H⁰	470 488.77		6.996 539
8h ²H⁰	(483 626.4)^b
7i ²I	470 524.11		6.998746
8i ²I	483 650.82^a		7.998554
9i ²I	(492 651.5)^b
Limit 3p⁶ ¹S₀	526 532.0
$3 p^{5} 3 d^{2} (^{1} G) {² F}_{5 / 2}^{0}$	319 106.19
${² F}_{7 / 2}^{0}$	320 731.60	1625.41
$(^{1} D) {² F}_{5 / 2}^{0}$	337 012.59
${² F}_{7 / 2}^{0}$	332.198.1	−4814.5
$(^{3} F) {² F}_{5 / 2}^{0}$	396 135.24
$² F_{7 / 2}^{0}$	397 993.66	1858.42
$(^{3} P) {² P}_{1 / 2}^{0}$	438 018.3
${² P}_{3 / 2}^{0}$	439 442.7	1424.4
$(^{3} F) {² D}_{3 / 2}^{0}$	444 620.8
${² D}_{5 / 2}^{0}$	444 153.7	−467.1
$3 p^{5} 3 d (^{3} F) 4 s {² F}_{5 / 2}^{0}$	478 566
${² F}_{7 / 2}^{0}$	475 531	−3035
$(^{1} F) 4 s {² F}_{5 / 2}^{0}$	496 296
${² F}_{7 / 2}^{0}$	497 556	1260
$(^{3} D) 4 s {² D}_{3 / 2}^{0}$	500 502^a
${² D}_{5 / 2}^{0}$	500 117^a	−385

Abstract

Corrections

Cited By

Figures (2)

Tables (3)

Equations (41)

Journal of the Optical Society of America