Spectrum of Rb iii observed with a pulsed-rf light source

Joseph Reader

doi:10.1364/JOSA.65.000988

Journal of the Optical Society of America
Vol. 65,
Issue 9,
pp. 988-990
(1975)
•https://doi.org/10.1364/JOSA.65.000988

Spectrum of Rb iii observed with a pulsed-rf light source

Joseph Reader

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Joseph Reader, "Spectrum of Rb iii observed with a pulsed-rf light source," J. Opt. Soc. Am. 65, 988-990 (1975)

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Abstract

The spectrum of doubly ionized rubidium, Rb iii, was observed with a pulsed-rf light source on two 10.7 m normal-incidence spectrographs at NBS. Wavelengths and classifications were obtained for 103 Rb iii lines, 90 of which were newly observed. The three missing levels of the 4p⁴ 4d configuration, (³P)⁴F_9/2 and (¹D)²G_7/2,9/2, and the one missing level of the 4p⁴ 5p configuration, (¹S₀)[1]_1/2, were located. The 4p⁴(¹D)5d ²G_9/2 level was also located. Improved values were determined for 13 excited levels.

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λ (Å)	Int.	σ (cm⁻¹)	Classification
1917.310	20	52 156.40	$({}^{3}P) 4 d {{}^{4}D}_{7 / 2} - ({{}^{3}P}_{1}) 5 p {[2]}_{5 / 2}^{°}$
1923.062	1	52 000.39	$({}^{3}P) 4 d {{}^{4}D}_{5 / 2} - ({{}^{3}P}_{1}) 5 p {[2]}_{5 / 2}^{°}$
1967.869	1	50 816.40	$({}^{3}P) 4 d {{}^{4}D}_{3 / 2} - ({{}^{3}P}_{0}) 5 p {[1]}_{1 / 2}^{°}$
2008.860	4	49 779.48	$({}^{3}P) 4 d {{}^{4}D}_{5 / 2} - ({{}^{3}P}_{2}) 5 p {[2]}_{3 / 2}^{°}$
2060.259	3	48 537.58	$({}^{3}P) 4 d {{}^{4}D}_{1 / 2} - ({{}^{3}P}_{1}) 5 p {[0]}_{1 / 2}^{°}$
2070.937	1	48 287.32	$({}^{1}D) 4 d {{}^{2}D}_{3 / 2} - ({{}^{1}D}_{2}) 5 p {[1]}_{3 / 2}^{°}$
2151.939	1	46 469.73	$({}^{1}D) 4 d {{}^{2}D}_{5 / 2} - ({{}^{1}D}_{2}) 5 p {[2]}_{5 / 2}^{°}$
2153.891	100	46 427.61	$({}^{3}P) 4 d {{}^{4}D}_{7 / 2} - ({{}^{3}P}_{2}) 5 p {[3]}_{5 / 2}^{°}$
2161.153	7	46 271.60	$({}^{3}P) 4 d {{}^{4}D}_{5 / 2} - ({{}^{3}P}_{2}) 5 p {[3]}_{5 / 2}^{°}$
2165.199	3u	46 185.12	$5 s {({{}^{3}P}_{2}, \frac{1}{2})}_{3 / 2} - ({{}^{1}D}_{2}) 5 p {[1]}_{3 / 2}^{°}$
2165.269	250	46 183.63	$({}^{3}P) 4 d {{}^{4}D}_{7 / 2} - ({{}^{3}P}_{2}) 5 p {[3]}_{7 / 2}^{°}$
2172.609	50	46 027.61	$({}^{3}P) 4 d {{}^{4}D}_{5 / 2} - ({{}^{3}P}_{2}) 5 p {[3]}_{7 / 2}^{°}$
2181.321	2w	45 843.78	$5 s {({{}^{3}P}_{1}, \frac{1}{2})}_{3 / 2} - ({{}^{1}D}_{2}) 5 p {[1]}_{1 / 2}^{°}$
2181.321	2w	45 843.78	$({{}^{3}P}_{2}) 5 p {[1]}_{1 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}P}_{3 / 2}$
2182.851	25	45 811.65	$({}^{1}D) 4 d {{}^{2}D}_{3 / 2} - ({{}^{1}D}_{2}) 5 p {[3]}_{5 / 2}^{°}$
2206.448	1	45 321.72	$({{}^{3}P}_{2}) 5 p {[3]}_{5 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}P}_{5 / 2}$
2218.467	2	45 076.17	$({}^{3}P) 4 d {{}^{2}F}_{7 / 2} - ({{}^{1}D}_{2}) 5 p {[3]}_{5 / 2}^{°}$
2226.814	75	44 907.21	$({}^{3}P) 4 d {{}^{4}D}_{3 / 2} - ({{}^{3}P}_{2}) 5 p {[1]}_{1 / 2}^{°}$
2243.281	1	44 577.57	$({{}^{3}P}_{2}) 5 p {[1]}_{1 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}P}_{1 / 2}$
2247.107	10	44 501.67	$({{}^{1}D}_{2}) 5 p {[3]}_{7 / 2}^{°} - ({}^{1}D) 5 d {{}^{2}F}_{7 / 2}$
2249.654	15	44 451.28	$({{}^{3}P}_{2}) {[1]}_{3 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}D}_{1 / 2}$
2262.767	2	44 193.69	$({}^{1}D) 4 d {{}^{2}P}_{3 / 2} - ({{}^{1}D}_{2}) 5 p {[3]}_{5 / 2}^{°}$
2268.698	100	44 078.15	$({}^{3}P) 4 d {{}^{4}D}_{1 / 2} - ({{}^{3}P}_{2}) 5 p {[1]}_{1 / 2}^{°}$
2273.670	1	43 981.76	$({}^{3}P) 4 d {{}^{2}F}_{5 / 2} - ({{}^{1}D}_{2}) 5 p {[2]}_{5 / 2}^{°}$
2276.275	5	43 931.43	$({{}^{3}P}_{2}) 5 p {[2]}_{5 / 2}^{°} - ({}^{3}P) 6 s {{}^{2}P}_{3 / 2}$
2283.411	1	43 794.14	$({}^{3}P) 4 d {{}^{2}F}_{5 / 2} - ({{}^{1}D}_{2}) 5 p {[2]}_{3 / 2}^{°}$
2287.641	3	43 713.16	$({{}^{3}P}_{0}) 5 p {[1]}_{3 / 2}^{°} - ({}^{3}P) 5 d {{}^{2}D}_{5 / 2}$
2287.827	1	43 709.61	$5 s {({{}^{3}P}_{2}, \frac{1}{2})}_{3 / 2} - ({{}^{1}D}_{2}) 5 p {[3]}_{5 / 2}^{°}$
2288.350	50	43 699.60	$({{}^{3}P}_{2}) 5 p {[1]}_{3 / 2}^{°} - ({}^{3}P) 6 s {{}^{2}P}_{3 / 2}$
2290.624	1	43 656.22	$({{}^{3}P}_{1}) 5 p {[2]}_{3 / 2}^{°} - ({}^{3}P) 5 d {{}^{2}D}_{3 / 2}$
2295.678	50	43 560.12	$({{}^{3}P}_{2}) 5 p {[2]}_{5 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}D}_{5 / 2}$
2300.833	150	43 462.52	$({}^{3}P) 4 d {{}^{4}D}_{5 / 2} - ({{}^{3}P}_{2}) 5 p {[1]}_{3 / 2}^{°}$
2304.853	500	43 386.72	$({}^{3}P) 4 d {{}^{4}D}_{7 / 2} - ({{}^{3}P}_{2}) 5 p {[2]}_{5 / 2}^{°}$
2305.155	150	43 381.03	$({{}^{3}P}_{2}) 5 p {[2]}_{5 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}D}_{7 / 2}$
2307.958	60	43 328.34	$({{}^{3}P}_{2}) 5 p {[1]}_{3 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}D}_{5 / 2}$
2309.131	1	43 306.33	$({{}^{3}P}_{1}) 5 p {[1]}_{1 / 2}^{°} - ({}^{3}P) 5 d {{}^{2}P}_{3 / 2}$
2310.165	3	43 286.96	$({{}^{3}P}_{1}) 5 p {[2]}_{5 / 2}^{°} - ({}^{3}P) 5 d {{}^{2}F}_{5 / 2}$
2313.167	250	43 230.78	$({}^{3}P) 4 d {{}^{4}D}_{5 / 2} - ({{}^{3}P}_{2}) 5 p {[2]}_{5 / 2}^{°}$
2314.515	15h	43 205.60	$5 s {({{}^{3}P}_{1}, \frac{1}{2})}_{1 / 2} - ({{}^{1}D}_{2}) 5 p {[1]}_{1 / 2}^{°}$
2315.278	75	43 191.35	$({{}^{1}D}_{2}) 5 p {[3]}_{5 / 2}^{°} - ({}^{1}D) 5 d {{}^{2}G}_{7 / 2}$
2324.091	1	43 027.58	$({}^{1}D) 4 d {{}^{2}P}_{1 / 2} - ({{}^{3}P}_{0}) 5 p {[1]}_{3 / 2}^{°}$
2324.456	75	43 020.81	$({{}^{3}P}_{2}) 5 p {[2]}_{5 / 2}^{°} - ({}^{3}P) 6 s {{}^{4}P}_{5 / 2}$
2334.515	20	42 835.45	$({{}^{3}P}_{0}) 5 p {[1]}_{1 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}F}_{3 / 2}$
2336.137	15	42 805.70	$({{}^{3}P}_{1}) 5 p {[2]}_{3 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}F}_{5 / 2}$
2337.049	10	42 789.01	$({{}^{3}P}_{2}) 5 p {[1]}_{3 / 2}^{°} - ({}^{3}P) 6 s {{}^{4}P}_{5 / 2}$
2337.670	1	42 777.64	$({{}^{3}P}_{1}) 5 p {[0]}_{1 / 2}^{°} - ({}^{3}P) 6 s {{}^{4}P}_{3 / 2}$
2337.787	200	42 775.50	$({}^{3}P) 4 d {{}^{4}D}_{3 / 2} - ({{}^{3}P}_{2}) 5 p {[1]}_{3 / 2}^{°}$
2342.617	100	42 687.30	$({}^{1}D) 4 d {{}^{2}D}_{5 / 2} - ({{}^{1}D}_{2}) 5 p {[3]}_{7 / 2}^{°}$
2346.089	200	42 624.13	$({{}^{3}P}_{2}) 5 p {[3]}_{5 / 2}^{°} - ({}^{3}P) 5 d {{}^{2}F}_{7 / 2}$
2350.526	100	42 543.67	$({}^{3}P) 4 d {{}^{4}D}_{3 / 2} - ({{}^{3}P}_{2}) 5 p {[2]}_{5 / 2}^{°}$
2352.203	1	42 513.34	$({{}^{1}D}_{2}) 5 p {[1]}_{3 / 2}^{°} - ({}^{1}D) 5 d {{}^{2}F}_{5 / 2}$
2362.976	3	42 319.51	$({{}^{3}P}_{2}) 5 p {[1]}_{1 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}D}_{1 / 2}$
2365.795	65	42 269.09	$({{}^{1}D}_{2}) 5 p {[3]}_{7 / 2}^{°} - ({}^{1}D) 5 d {{}^{2}G}_{9 / 2}$
2366.697	50	42 252.99	$5 s {({{}^{3}P}_{1}, \frac{1}{2})}_{3 / 2} - ({{}^{1}D}_{2}) 5 p {[1]}_{3 / 2}^{°}$
2381.166	150	41 996.24	$({{}^{3}P}_{2}) 5 p {[3]}_{7 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}F}_{9 / 2} ?$
2381.166	150	41 996.24	$({{}^{3}P}_{1}) 5 p {[2]}_{5 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}F}_{7 / 2} ?$
2382.014	100	41 981.28	$({{}^{3}P}_{2}) 5 p {[3]}_{7 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}F}_{9 / 2} ?$
2382.014	100	41 981.28	$({{}^{3}P}_{1}) 5 p {[2]}_{5 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}F}_{7 / 2} ?$
2383.999	65	41 946.33	$({}^{3}P) 4 d {{}^{4}D}_{1 / 2} - ({{}^{3}P}_{2}) 5 p {[1]}_{3 / 2}^{°}$
2391.000	2	41 823.50	$({{}^{3}P}_{2}) 5 p {[1]}_{1 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}D}_{3 / 2}$
2391.553	15	41 813.84	$({{}^{3}P}_{2}) 5 p {[2]}_{3 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}P}_{5 / 2}$
2400.363	2	41 660.37	$({}^{1}D) 4 d {{}^{2}D}_{5 / 2} - ({{}^{1}D}_{2}) 5 p {[3]}_{5 / 2}^{°}$
2401.062	1	41 648.24	$({}^{3}P) 4 d {{}^{2}F}_{5 / 2} - ({{}^{1}D}_{2}) 5 p {[1]}_{3 / 2}^{°}$
2407.573	1	41 535.60	$({{}^{1}D}_{2}) 5 p {[3]}_{7 / 2}^{°} - ({}^{1}D) 6 s {{}^{2}D}_{5 / 2}$
2419.198	150	41 336.02	$({}^{3}P) 4 d {{}^{4}F}_{7 / 2} - ({{}^{3}P}_{1}) 5 p {[2]}_{5 / 2}^{°}$
2421.538	1	41 296.07	$({}^{3}P) 4 d {{}^{4}F}_{5 / 2} - ({{}^{3}P}_{0}) 5 p {[1]}_{3 / 2}^{°}$
2424.644	1	41 243.16	$({{}^{3}P}_{1}) 5 p {[2]}_{3 / 2}^{°} - ({}^{3}P) 6 s {{}^{4}P}_{3 / 2}$
2430.363	10	41 146.12	$({{}^{3}P}_{2}) 5 p {[3]}_{5 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}D}_{3 / 2}$
2437.224	1	41 030.28	$({}^{3}P) 4 d {{}^{4}P}_{3 / 2} - ({{}^{3}P}_{0}) 5 p {[1]}_{3 / 2}^{°}$
2448.741	30	40 837.31	$({{}^{3}P}_{1}) 5 p {[1]}_{3 / 2}^{°} - ({}^{3}P) 5 d {{}^{2}F}_{5 / 2}$
2449.112	15	40 831.13	$({{}^{3}P}_{1}) 5 p {[2]}_{5 / 2}^{°} - ({}^{3}P) 6 s {{}^{4}P}_{3 / 2}$
2453.189	20	40 763.27	$({{}^{3}P}_{2}) 5 p {[3]}_{7 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}D}_{5 / 2}$
2455.827	65	40 719.48	$({{}^{1}D}_{2}) 5 p {[2]}_{5 / 2}^{°} - ({}^{1}D) 5 d {{}^{2}F}_{7 / 2}$
2459.065	2	40 665.86	$({}^{3}P) 4 d {{}^{4}P}_{1 / 2} - ({{}^{3}P}_{0}) 5 p {[1]}_{3 / 2}^{°}$
2464.015	90	40 584.17	$({{}^{3}P}_{2}) 5 p {[3]}_{7 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}D}_{7 / 2}$
2476.650	5	40 377.12	$({}^{1}D) 4 d {{}^{2}P}_{1 / 2} - ({{}^{3}P}_{1}) 5 p {[2]}_{3 / 2}^{°}$
2477.242	3	40 367.47	$({{}^{1}D}_{2}) 5 p {[2]}_{3 / 2}^{°} - ({}^{1}D) 5 d {{}^{2}F}_{5 / 2}$
2478.923	4	40 340.10	$({{}^{3}P}_{2}) 5 p {[3]}_{5 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}D}_{7 / 2}$
2486.085	65	40 223.89	$({{}^{3}P}_{2}) 5 p {[3]}_{7 / 2}^{°} - ({}^{3}P) 6 s {{}^{4}P}_{5 / 2}$
2487.591	70	40 199.54	$({}^{3}P) 4 d {{}^{2}F}_{5 / 2} - ({{}^{1}D}_{2}) 5 p {[3]}_{7 / 2}^{°}$
2488.819	1w	40 179.70	$({{}^{1}D}_{2}) 5 p {[2]}_{5 / 2}^{°} - ({}^{1}D) 5 d {{}^{2}F}_{5 / 2}$
2490.329	4	40 155.34	$({{}^{3}P}_{0}) 5 p {[1]}_{3 / 2}^{°} - ({}^{1}D) 5 d {{}^{4}F}_{5 / 2}$
2503.506	1	39 943.99	$({{}^{3}P}_{1}) 5 p {[1]}_{3 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}F}_{5 / 2}$
2513.105	2	39 791.41	$5 s {({{}^{3}P}_{2}, \frac{1}{2})}_{5 / 2} - ({{}^{3}P}_{1}) 5 p {[2]}_{5 / 2}^{°}$
2524.287	5	39 615.14	$5 s {({{}^{3}P}_{1}, \frac{1}{2})}_{1 / 2} - ({{}^{1}D}_{2}) 5 p {[1]}_{3 / 2}^{°}$
2560.307	65	39 057.81	$({}^{3}P) 4 d {{}^{2}F}_{5 / 2} - ({{}^{3}P}_{1}) 5 p {[2]}_{5 / 2}^{°}$
2562.631	300	39 022.40	$({}^{1}D) 4 d {{}^{2}G}_{9 / 2} - ({{}^{1}D}_{2}) 5 p {[3]}_{7 / 2}^{°}$
2568.061	35	38 939.89	$({}^{1}D) 4 d {{}^{2}G}_{7 / 2} - ({{}^{1}D}_{2}) 5 p {[3]}_{7 / 2}^{°}$
2574.482	100	38 842.76	$({}^{1}D) 4 d {{}^{2}P}_{1 / 2} - ({{}^{3}P}_{1}) 5 p {[0]}_{1 / 2}^{°}$
2577.843	100	38 792.11	$({}^{3}P) 4 d {{}^{4}P}_{3 / 2} - ({{}^{3}P}_{1}) 5 p {[2]}_{5 / 2}^{°}$
2584.519	2	38 691.92	$({}^{1}D) 4 d {{}^{2}D}_{3 / 2} - ({{}^{3}P}_{0}) 5 p {[1]}_{3 / 2}^{°}$
2587.607	200	38 645.74	$({}^{3}P) 4 d {{}^{4}F}_{5 / 2} - ({{}^{3}P}_{1}) 5 p {[2]}_{3 / 2}^{°}$
2605.424	1	38 381.47	$({{}^{3}P}_{1}) 5 p {[1]}_{3 / 2}^{°} - ({}^{3}P) 6 s {{}^{4}P}_{3 / 2}$
2622.833	10	38 126.72	$({}^{3}P) 4 d {{}^{4}F}_{3 / 2} - ({{}^{3}P}_{1}) 5 p {[2]}_{5 / 2}^{°}$
2630.308	2s	38 018.36	$({}^{1}S) 4 d {{}^{2}D}_{3 / 2} - ({{}^{1}S}_{0}) 5 p {[1]}_{1 / 2}^{°}$
2632.537	1000	37 986.17	$({}^{3}P) 4 d {{}^{4}F}_{9 / 2} - ({{}^{3}P}_{2}) 5 p {[3]}_{7 / 2}^{°}$
2636.387	5	37 930.70	$({}^{3}P) 4 d {{}^{4}P}_{1 / 2} - ({{}^{3}P}_{0}) 5 p {[1]}_{1 / 2}^{°}$
2637.616	350	37 913.02	$({}^{1}D) 4 d {{}^{2}G}_{7 / 2} - ({{}^{1}D}_{2}) 5 p {[3]}_{5 / 2}^{°}$
2651.493	20	37 714.60	$({}^{3}P) 4 d {{}^{4}F}_{3 / 2} - ({{}^{3}P}_{1}) 5 p {[2]}_{3 / 2}^{°}$
2654.268	7	37 675.17	$({}^{1}D) 4 d {{}^{2}P}_{3 / 2} - ({{}^{3}P}_{1}) 5 p {[1]}_{1 / 2}^{°}$
2656.866	1	37 638.34	$({{}^{3}P}_{2}) 5 p {[2]}_{3 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}D}_{3 / 2}$
2657.468	100	37 629.80	$({}^{3}P) 4 d {{}^{4}F}_{3 / 2} - ({{}^{3}P}_{0}) 5 p {[1]}_{1 / 2}^{°}$
2661.663	5	37 570.50	$5 s {({{}^{3}P}_{2}, \frac{1}{2})}_{5 / 2} - ({{}^{3}P}_{2}) 5 p {[2]}_{3 / 2}^{°}$
2845.444^a	100	35 133.57	$5 s {({{}^{1}D}_{2}, \frac{1}{2})}_{3 / 2} - ({{}^{1}D}_{2}) 5 p {[1]}_{1 / 2}^{°}$
2872.920^a	25s	34 797.58	$5 s {({{}^{1}S}_{0}, \frac{1}{2})}_{1 / 2} - ({{}^{1}S}_{0}) 5 p {[1]}_{1 / 2}^{°}$
3094.841^a,b	10p	32 302.46^a	$({}^{1}D) 4 d {{}^{2}D}_{5 / 2} - ({{}^{3}P}_{1}) 5 p {[2]}_{5 / 2}^{°}$
3198.697^a	25	31 253.69	$5 s {({{}^{3}P}_{2}, \frac{1}{2})}_{5 / 2} - ({{}^{3}P}_{2}) 5 p {[1]}_{3 / 2}^{°}$
4443.203^c	1w	22 499.97	$5 s {({{}^{1}D}_{2}, \frac{1}{2})}_{5 / 2} - ({{}^{3}P}_{0}) 5 p {[1]}_{3 / 2}^{°}$
4617.663^c	1h	21 649.91	$5 s {({{}^{3}P}_{1}, \frac{1}{2})}_{3 / 2} - ({{}^{3}P}_{2}) 5 p {[2]}_{5 / 2}^{°}$
4676.922^c	1	21 375.60	$5 s {({{}^{3}P}_{1}, \frac{1}{2})}_{1 / 2} - ({{}^{3}P}_{2}) 5 p {[1]}_{1 / 2}^{°}$

λ (Å)	Zeeman type	Zeeman components	J₁(g₁) − J₂(g₂)
2562.631^a	7	(0)1055	[9/2](1.12)–[7/2][1.14]
2632.537^a	4u	(0)1049	[9/2](1.33)–[7/2][1.41]
2637.616^a	7	(0)999	[7/2](0.92)–[5/2][0.89]
2845.444^b	5u	(0)884	[3/2][0.81]–[1/2](0.66)
2872.920^b	6	1305	[1/2][1.94]–[1/2](0.67)
3198.697^b	7	(0)1532	[5/2][1.58]–[3/2](1.61)

	Previous value (cm⁻¹)
Designation	Reader and Epstein, Ref. 1	Hansert, Persson, and Valind, Ref. 2	New value (cm⁻¹)
(³P)4d ⁴D_7/2		154 722	154 721.27
(³P)4d ⁴D_1/2	156 393.3	156 394	156 393.46
(³P)4d ⁴F_9/2			162 918.68
(¹D)4d ²G_9/2			178 239.98
(¹D)4d ²G_7/2			178 322.45
$5 s {({{}^{1}D}_{2}, \frac{1}{2})}_{5 / 2}$	186 616.3	186 616	186 615.76
$5 s {({{}^{1}D}_{2}, \frac{1}{2})}_{3 / 2}$	187 168.4	187 168	187 167.80
(¹D)4d ²F_5/2	187 393.6	187 392	187 392.77
(¹D)4d ²F_7/2	188 488.9		188 488.28
$({{}^{1}D}_{2}) 5 p {[3]}_{5 / 2}^{°}$	216 236.0	216 236	216 235.44
$({{}^{1}D}_{2}) 5 p {[3]}_{7 / 2}^{°}$	217 263.1	217 263	217 262.38
$({{}^{1}D}_{2}) 5 p {[1]}_{3 / 2}^{°}$	218 711.6	218 712	218 711.04
$({{}^{1}D}_{2}) 5 p {[2]}_{3 / 2}^{°}$	220 857.6	220 857	220 856.92
$({{}^{1}D}_{2}) 5 p {[2]}_{5 / 2}^{°}$	221 045.2	221 045	221 044.60
$({{}^{1}D}_{2}) 5 p {[1]}_{1 / 2}^{°}$		222 302	222 301.41
$({{}^{1}S}_{0}) 5 p {[1]}_{1 / 2}^{°}$			238 894.2
(³P)5d ⁴F_9/2			242 886.13?
(³P)5d ⁴F_9/2			242 901.09?
(³P)5d ⁴F_7/2			248 858.80?
(³P)5d ⁴F_7/2			248 873.76?
(¹D)5d ²G_9/2			259 431.37

λ (Å)	Int.	σ (cm⁻¹)	Classification
1917.310	20	52 156.40	$({}^{3}P) 4 d {{}^{4}D}_{7 / 2} - ({{}^{3}P}_{1}) 5 p {[2]}_{5 / 2}^{°}$
1923.062	1	52 000.39	$({}^{3}P) 4 d {{}^{4}D}_{5 / 2} - ({{}^{3}P}_{1}) 5 p {[2]}_{5 / 2}^{°}$
1967.869	1	50 816.40	$({}^{3}P) 4 d {{}^{4}D}_{3 / 2} - ({{}^{3}P}_{0}) 5 p {[1]}_{1 / 2}^{°}$
2008.860	4	49 779.48	$({}^{3}P) 4 d {{}^{4}D}_{5 / 2} - ({{}^{3}P}_{2}) 5 p {[2]}_{3 / 2}^{°}$
2060.259	3	48 537.58	$({}^{3}P) 4 d {{}^{4}D}_{1 / 2} - ({{}^{3}P}_{1}) 5 p {[0]}_{1 / 2}^{°}$
2070.937	1	48 287.32	$({}^{1}D) 4 d {{}^{2}D}_{3 / 2} - ({{}^{1}D}_{2}) 5 p {[1]}_{3 / 2}^{°}$
2151.939	1	46 469.73	$({}^{1}D) 4 d {{}^{2}D}_{5 / 2} - ({{}^{1}D}_{2}) 5 p {[2]}_{5 / 2}^{°}$
2153.891	100	46 427.61	$({}^{3}P) 4 d {{}^{4}D}_{7 / 2} - ({{}^{3}P}_{2}) 5 p {[3]}_{5 / 2}^{°}$
2161.153	7	46 271.60	$({}^{3}P) 4 d {{}^{4}D}_{5 / 2} - ({{}^{3}P}_{2}) 5 p {[3]}_{5 / 2}^{°}$
2165.199	3u	46 185.12	$5 s {({{}^{3}P}_{2}, \frac{1}{2})}_{3 / 2} - ({{}^{1}D}_{2}) 5 p {[1]}_{3 / 2}^{°}$
2165.269	250	46 183.63	$({}^{3}P) 4 d {{}^{4}D}_{7 / 2} - ({{}^{3}P}_{2}) 5 p {[3]}_{7 / 2}^{°}$
2172.609	50	46 027.61	$({}^{3}P) 4 d {{}^{4}D}_{5 / 2} - ({{}^{3}P}_{2}) 5 p {[3]}_{7 / 2}^{°}$
2181.321	2w	45 843.78	$5 s {({{}^{3}P}_{1}, \frac{1}{2})}_{3 / 2} - ({{}^{1}D}_{2}) 5 p {[1]}_{1 / 2}^{°}$
2181.321	2w	45 843.78	$({{}^{3}P}_{2}) 5 p {[1]}_{1 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}P}_{3 / 2}$
2182.851	25	45 811.65	$({}^{1}D) 4 d {{}^{2}D}_{3 / 2} - ({{}^{1}D}_{2}) 5 p {[3]}_{5 / 2}^{°}$
2206.448	1	45 321.72	$({{}^{3}P}_{2}) 5 p {[3]}_{5 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}P}_{5 / 2}$
2218.467	2	45 076.17	$({}^{3}P) 4 d {{}^{2}F}_{7 / 2} - ({{}^{1}D}_{2}) 5 p {[3]}_{5 / 2}^{°}$
2226.814	75	44 907.21	$({}^{3}P) 4 d {{}^{4}D}_{3 / 2} - ({{}^{3}P}_{2}) 5 p {[1]}_{1 / 2}^{°}$
2243.281	1	44 577.57	$({{}^{3}P}_{2}) 5 p {[1]}_{1 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}P}_{1 / 2}$
2247.107	10	44 501.67	$({{}^{1}D}_{2}) 5 p {[3]}_{7 / 2}^{°} - ({}^{1}D) 5 d {{}^{2}F}_{7 / 2}$
2249.654	15	44 451.28	$({{}^{3}P}_{2}) {[1]}_{3 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}D}_{1 / 2}$
2262.767	2	44 193.69	$({}^{1}D) 4 d {{}^{2}P}_{3 / 2} - ({{}^{1}D}_{2}) 5 p {[3]}_{5 / 2}^{°}$
2268.698	100	44 078.15	$({}^{3}P) 4 d {{}^{4}D}_{1 / 2} - ({{}^{3}P}_{2}) 5 p {[1]}_{1 / 2}^{°}$
2273.670	1	43 981.76	$({}^{3}P) 4 d {{}^{2}F}_{5 / 2} - ({{}^{1}D}_{2}) 5 p {[2]}_{5 / 2}^{°}$
2276.275	5	43 931.43	$({{}^{3}P}_{2}) 5 p {[2]}_{5 / 2}^{°} - ({}^{3}P) 6 s {{}^{2}P}_{3 / 2}$
2283.411	1	43 794.14	$({}^{3}P) 4 d {{}^{2}F}_{5 / 2} - ({{}^{1}D}_{2}) 5 p {[2]}_{3 / 2}^{°}$
2287.641	3	43 713.16	$({{}^{3}P}_{0}) 5 p {[1]}_{3 / 2}^{°} - ({}^{3}P) 5 d {{}^{2}D}_{5 / 2}$
2287.827	1	43 709.61	$5 s {({{}^{3}P}_{2}, \frac{1}{2})}_{3 / 2} - ({{}^{1}D}_{2}) 5 p {[3]}_{5 / 2}^{°}$
2288.350	50	43 699.60	$({{}^{3}P}_{2}) 5 p {[1]}_{3 / 2}^{°} - ({}^{3}P) 6 s {{}^{2}P}_{3 / 2}$
2290.624	1	43 656.22	$({{}^{3}P}_{1}) 5 p {[2]}_{3 / 2}^{°} - ({}^{3}P) 5 d {{}^{2}D}_{3 / 2}$
2295.678	50	43 560.12	$({{}^{3}P}_{2}) 5 p {[2]}_{5 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}D}_{5 / 2}$
2300.833	150	43 462.52	$({}^{3}P) 4 d {{}^{4}D}_{5 / 2} - ({{}^{3}P}_{2}) 5 p {[1]}_{3 / 2}^{°}$
2304.853	500	43 386.72	$({}^{3}P) 4 d {{}^{4}D}_{7 / 2} - ({{}^{3}P}_{2}) 5 p {[2]}_{5 / 2}^{°}$
2305.155	150	43 381.03	$({{}^{3}P}_{2}) 5 p {[2]}_{5 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}D}_{7 / 2}$
2307.958	60	43 328.34	$({{}^{3}P}_{2}) 5 p {[1]}_{3 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}D}_{5 / 2}$
2309.131	1	43 306.33	$({{}^{3}P}_{1}) 5 p {[1]}_{1 / 2}^{°} - ({}^{3}P) 5 d {{}^{2}P}_{3 / 2}$
2310.165	3	43 286.96	$({{}^{3}P}_{1}) 5 p {[2]}_{5 / 2}^{°} - ({}^{3}P) 5 d {{}^{2}F}_{5 / 2}$
2313.167	250	43 230.78	$({}^{3}P) 4 d {{}^{4}D}_{5 / 2} - ({{}^{3}P}_{2}) 5 p {[2]}_{5 / 2}^{°}$
2314.515	15h	43 205.60	$5 s {({{}^{3}P}_{1}, \frac{1}{2})}_{1 / 2} - ({{}^{1}D}_{2}) 5 p {[1]}_{1 / 2}^{°}$
2315.278	75	43 191.35	$({{}^{1}D}_{2}) 5 p {[3]}_{5 / 2}^{°} - ({}^{1}D) 5 d {{}^{2}G}_{7 / 2}$
2324.091	1	43 027.58	$({}^{1}D) 4 d {{}^{2}P}_{1 / 2} - ({{}^{3}P}_{0}) 5 p {[1]}_{3 / 2}^{°}$
2324.456	75	43 020.81	$({{}^{3}P}_{2}) 5 p {[2]}_{5 / 2}^{°} - ({}^{3}P) 6 s {{}^{4}P}_{5 / 2}$
2334.515	20	42 835.45	$({{}^{3}P}_{0}) 5 p {[1]}_{1 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}F}_{3 / 2}$
2336.137	15	42 805.70	$({{}^{3}P}_{1}) 5 p {[2]}_{3 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}F}_{5 / 2}$
2337.049	10	42 789.01	$({{}^{3}P}_{2}) 5 p {[1]}_{3 / 2}^{°} - ({}^{3}P) 6 s {{}^{4}P}_{5 / 2}$
2337.670	1	42 777.64	$({{}^{3}P}_{1}) 5 p {[0]}_{1 / 2}^{°} - ({}^{3}P) 6 s {{}^{4}P}_{3 / 2}$
2337.787	200	42 775.50	$({}^{3}P) 4 d {{}^{4}D}_{3 / 2} - ({{}^{3}P}_{2}) 5 p {[1]}_{3 / 2}^{°}$
2342.617	100	42 687.30	$({}^{1}D) 4 d {{}^{2}D}_{5 / 2} - ({{}^{1}D}_{2}) 5 p {[3]}_{7 / 2}^{°}$
2346.089	200	42 624.13	$({{}^{3}P}_{2}) 5 p {[3]}_{5 / 2}^{°} - ({}^{3}P) 5 d {{}^{2}F}_{7 / 2}$
2350.526	100	42 543.67	$({}^{3}P) 4 d {{}^{4}D}_{3 / 2} - ({{}^{3}P}_{2}) 5 p {[2]}_{5 / 2}^{°}$
2352.203	1	42 513.34	$({{}^{1}D}_{2}) 5 p {[1]}_{3 / 2}^{°} - ({}^{1}D) 5 d {{}^{2}F}_{5 / 2}$
2362.976	3	42 319.51	$({{}^{3}P}_{2}) 5 p {[1]}_{1 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}D}_{1 / 2}$
2365.795	65	42 269.09	$({{}^{1}D}_{2}) 5 p {[3]}_{7 / 2}^{°} - ({}^{1}D) 5 d {{}^{2}G}_{9 / 2}$
2366.697	50	42 252.99	$5 s {({{}^{3}P}_{1}, \frac{1}{2})}_{3 / 2} - ({{}^{1}D}_{2}) 5 p {[1]}_{3 / 2}^{°}$
2381.166	150	41 996.24	$({{}^{3}P}_{2}) 5 p {[3]}_{7 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}F}_{9 / 2} ?$
2381.166	150	41 996.24	$({{}^{3}P}_{1}) 5 p {[2]}_{5 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}F}_{7 / 2} ?$
2382.014	100	41 981.28	$({{}^{3}P}_{2}) 5 p {[3]}_{7 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}F}_{9 / 2} ?$
2382.014	100	41 981.28	$({{}^{3}P}_{1}) 5 p {[2]}_{5 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}F}_{7 / 2} ?$
2383.999	65	41 946.33	$({}^{3}P) 4 d {{}^{4}D}_{1 / 2} - ({{}^{3}P}_{2}) 5 p {[1]}_{3 / 2}^{°}$
2391.000	2	41 823.50	$({{}^{3}P}_{2}) 5 p {[1]}_{1 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}D}_{3 / 2}$
2391.553	15	41 813.84	$({{}^{3}P}_{2}) 5 p {[2]}_{3 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}P}_{5 / 2}$
2400.363	2	41 660.37	$({}^{1}D) 4 d {{}^{2}D}_{5 / 2} - ({{}^{1}D}_{2}) 5 p {[3]}_{5 / 2}^{°}$
2401.062	1	41 648.24	$({}^{3}P) 4 d {{}^{2}F}_{5 / 2} - ({{}^{1}D}_{2}) 5 p {[1]}_{3 / 2}^{°}$
2407.573	1	41 535.60	$({{}^{1}D}_{2}) 5 p {[3]}_{7 / 2}^{°} - ({}^{1}D) 6 s {{}^{2}D}_{5 / 2}$
2419.198	150	41 336.02	$({}^{3}P) 4 d {{}^{4}F}_{7 / 2} - ({{}^{3}P}_{1}) 5 p {[2]}_{5 / 2}^{°}$
2421.538	1	41 296.07	$({}^{3}P) 4 d {{}^{4}F}_{5 / 2} - ({{}^{3}P}_{0}) 5 p {[1]}_{3 / 2}^{°}$
2424.644	1	41 243.16	$({{}^{3}P}_{1}) 5 p {[2]}_{3 / 2}^{°} - ({}^{3}P) 6 s {{}^{4}P}_{3 / 2}$
2430.363	10	41 146.12	$({{}^{3}P}_{2}) 5 p {[3]}_{5 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}D}_{3 / 2}$
2437.224	1	41 030.28	$({}^{3}P) 4 d {{}^{4}P}_{3 / 2} - ({{}^{3}P}_{0}) 5 p {[1]}_{3 / 2}^{°}$
2448.741	30	40 837.31	$({{}^{3}P}_{1}) 5 p {[1]}_{3 / 2}^{°} - ({}^{3}P) 5 d {{}^{2}F}_{5 / 2}$
2449.112	15	40 831.13	$({{}^{3}P}_{1}) 5 p {[2]}_{5 / 2}^{°} - ({}^{3}P) 6 s {{}^{4}P}_{3 / 2}$
2453.189	20	40 763.27	$({{}^{3}P}_{2}) 5 p {[3]}_{7 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}D}_{5 / 2}$
2455.827	65	40 719.48	$({{}^{1}D}_{2}) 5 p {[2]}_{5 / 2}^{°} - ({}^{1}D) 5 d {{}^{2}F}_{7 / 2}$
2459.065	2	40 665.86	$({}^{3}P) 4 d {{}^{4}P}_{1 / 2} - ({{}^{3}P}_{0}) 5 p {[1]}_{3 / 2}^{°}$
2464.015	90	40 584.17	$({{}^{3}P}_{2}) 5 p {[3]}_{7 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}D}_{7 / 2}$
2476.650	5	40 377.12	$({}^{1}D) 4 d {{}^{2}P}_{1 / 2} - ({{}^{3}P}_{1}) 5 p {[2]}_{3 / 2}^{°}$
2477.242	3	40 367.47	$({{}^{1}D}_{2}) 5 p {[2]}_{3 / 2}^{°} - ({}^{1}D) 5 d {{}^{2}F}_{5 / 2}$
2478.923	4	40 340.10	$({{}^{3}P}_{2}) 5 p {[3]}_{5 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}D}_{7 / 2}$
2486.085	65	40 223.89	$({{}^{3}P}_{2}) 5 p {[3]}_{7 / 2}^{°} - ({}^{3}P) 6 s {{}^{4}P}_{5 / 2}$
2487.591	70	40 199.54	$({}^{3}P) 4 d {{}^{2}F}_{5 / 2} - ({{}^{1}D}_{2}) 5 p {[3]}_{7 / 2}^{°}$
2488.819	1w	40 179.70	$({{}^{1}D}_{2}) 5 p {[2]}_{5 / 2}^{°} - ({}^{1}D) 5 d {{}^{2}F}_{5 / 2}$
2490.329	4	40 155.34	$({{}^{3}P}_{0}) 5 p {[1]}_{3 / 2}^{°} - ({}^{1}D) 5 d {{}^{4}F}_{5 / 2}$
2503.506	1	39 943.99	$({{}^{3}P}_{1}) 5 p {[1]}_{3 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}F}_{5 / 2}$
2513.105	2	39 791.41	$5 s {({{}^{3}P}_{2}, \frac{1}{2})}_{5 / 2} - ({{}^{3}P}_{1}) 5 p {[2]}_{5 / 2}^{°}$
2524.287	5	39 615.14	$5 s {({{}^{3}P}_{1}, \frac{1}{2})}_{1 / 2} - ({{}^{1}D}_{2}) 5 p {[1]}_{3 / 2}^{°}$
2560.307	65	39 057.81	$({}^{3}P) 4 d {{}^{2}F}_{5 / 2} - ({{}^{3}P}_{1}) 5 p {[2]}_{5 / 2}^{°}$
2562.631	300	39 022.40	$({}^{1}D) 4 d {{}^{2}G}_{9 / 2} - ({{}^{1}D}_{2}) 5 p {[3]}_{7 / 2}^{°}$
2568.061	35	38 939.89	$({}^{1}D) 4 d {{}^{2}G}_{7 / 2} - ({{}^{1}D}_{2}) 5 p {[3]}_{7 / 2}^{°}$
2574.482	100	38 842.76	$({}^{1}D) 4 d {{}^{2}P}_{1 / 2} - ({{}^{3}P}_{1}) 5 p {[0]}_{1 / 2}^{°}$
2577.843	100	38 792.11	$({}^{3}P) 4 d {{}^{4}P}_{3 / 2} - ({{}^{3}P}_{1}) 5 p {[2]}_{5 / 2}^{°}$
2584.519	2	38 691.92	$({}^{1}D) 4 d {{}^{2}D}_{3 / 2} - ({{}^{3}P}_{0}) 5 p {[1]}_{3 / 2}^{°}$
2587.607	200	38 645.74	$({}^{3}P) 4 d {{}^{4}F}_{5 / 2} - ({{}^{3}P}_{1}) 5 p {[2]}_{3 / 2}^{°}$
2605.424	1	38 381.47	$({{}^{3}P}_{1}) 5 p {[1]}_{3 / 2}^{°} - ({}^{3}P) 6 s {{}^{4}P}_{3 / 2}$
2622.833	10	38 126.72	$({}^{3}P) 4 d {{}^{4}F}_{3 / 2} - ({{}^{3}P}_{1}) 5 p {[2]}_{5 / 2}^{°}$
2630.308	2s	38 018.36	$({}^{1}S) 4 d {{}^{2}D}_{3 / 2} - ({{}^{1}S}_{0}) 5 p {[1]}_{1 / 2}^{°}$
2632.537	1000	37 986.17	$({}^{3}P) 4 d {{}^{4}F}_{9 / 2} - ({{}^{3}P}_{2}) 5 p {[3]}_{7 / 2}^{°}$
2636.387	5	37 930.70	$({}^{3}P) 4 d {{}^{4}P}_{1 / 2} - ({{}^{3}P}_{0}) 5 p {[1]}_{1 / 2}^{°}$
2637.616	350	37 913.02	$({}^{1}D) 4 d {{}^{2}G}_{7 / 2} - ({{}^{1}D}_{2}) 5 p {[3]}_{5 / 2}^{°}$
2651.493	20	37 714.60	$({}^{3}P) 4 d {{}^{4}F}_{3 / 2} - ({{}^{3}P}_{1}) 5 p {[2]}_{3 / 2}^{°}$
2654.268	7	37 675.17	$({}^{1}D) 4 d {{}^{2}P}_{3 / 2} - ({{}^{3}P}_{1}) 5 p {[1]}_{1 / 2}^{°}$
2656.866	1	37 638.34	$({{}^{3}P}_{2}) 5 p {[2]}_{3 / 2}^{°} - ({}^{3}P) 5 d {{}^{4}D}_{3 / 2}$
2657.468	100	37 629.80	$({}^{3}P) 4 d {{}^{4}F}_{3 / 2} - ({{}^{3}P}_{0}) 5 p {[1]}_{1 / 2}^{°}$
2661.663	5	37 570.50	$5 s {({{}^{3}P}_{2}, \frac{1}{2})}_{5 / 2} - ({{}^{3}P}_{2}) 5 p {[2]}_{3 / 2}^{°}$
2845.444^a	100	35 133.57	$5 s {({{}^{1}D}_{2}, \frac{1}{2})}_{3 / 2} - ({{}^{1}D}_{2}) 5 p {[1]}_{1 / 2}^{°}$
2872.920^a	25s	34 797.58	$5 s {({{}^{1}S}_{0}, \frac{1}{2})}_{1 / 2} - ({{}^{1}S}_{0}) 5 p {[1]}_{1 / 2}^{°}$
3094.841^a,b	10p	32 302.46^a	$({}^{1}D) 4 d {{}^{2}D}_{5 / 2} - ({{}^{3}P}_{1}) 5 p {[2]}_{5 / 2}^{°}$
3198.697^a	25	31 253.69	$5 s {({{}^{3}P}_{2}, \frac{1}{2})}_{5 / 2} - ({{}^{3}P}_{2}) 5 p {[1]}_{3 / 2}^{°}$
4443.203^c	1w	22 499.97	$5 s {({{}^{1}D}_{2}, \frac{1}{2})}_{5 / 2} - ({{}^{3}P}_{0}) 5 p {[1]}_{3 / 2}^{°}$
4617.663^c	1h	21 649.91	$5 s {({{}^{3}P}_{1}, \frac{1}{2})}_{3 / 2} - ({{}^{3}P}_{2}) 5 p {[2]}_{5 / 2}^{°}$
4676.922^c	1	21 375.60	$5 s {({{}^{3}P}_{1}, \frac{1}{2})}_{1 / 2} - ({{}^{3}P}_{2}) 5 p {[1]}_{1 / 2}^{°}$

λ (Å)	Zeeman type	Zeeman components	J₁(g₁) − J₂(g₂)
2562.631^a	7	(0)1055	[9/2](1.12)–[7/2][1.14]
2632.537^a	4u	(0)1049	[9/2](1.33)–[7/2][1.41]
2637.616^a	7	(0)999	[7/2](0.92)–[5/2][0.89]
2845.444^b	5u	(0)884	[3/2][0.81]–[1/2](0.66)
2872.920^b	6	1305	[1/2][1.94]–[1/2](0.67)
3198.697^b	7	(0)1532	[5/2][1.58]–[3/2](1.61)

Abstract

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Tables (3)

Journal of the Optical Society of America