Spectra in the period between copper and bromine produced with the aid of a 4 GW laser

B. C. Fawcett; R. W. Hayes

doi:10.1364/JOSA.65.000623

Journal of the Optical Society of America
Vol. 65,
Issue 6,
pp. 623-627
(1975)
•https://doi.org/10.1364/JOSA.65.000623

Spectra in the period between copper and bromine produced with the aid of a 4 GW laser

B. C. Fawcett and R. W. Hayes

Not Accessible

Your library or personal account may give you access

Get PDF
Email
Share
Get Citation
Copy Citation Text
B. C. Fawcett and R. W. Hayes, "Spectra in the period between copper and bromine produced with the aid of a 4 GW laser," J. Opt. Soc. Am. 65, 623-627 (1975)

Export Citation
- BibTex
- Endnote (RIS)
- HTML
- Plain Text
Citation alert
Save article

Abstract

Spectroscopic observations of plasmas produced when the output of a 4 GW neodymium laser was focused onto solid targets of elements in the period between copper and molybdenum have led to line classifications of spectra of higher ionized atoms from copper through to bromine. Identifications include lines of ions up to the twenty-fifth stage of ionization. Information of astrophysical interest regarding the 3p ⁶ 3dⁿ⁻¹ 4f configurations is also reported.

Full Article | PDF Article

More Like This

Spectrum of doubly ionized yttrium (Y iii)

Gabriel L. Epstein and Joseph Reader
J. Opt. Soc. Am. 65(3) 310-314 (1975)

2p⁴, 4f, 5f, and 5g configurations of quadruply ionized aluminum (Al v)

Wan-Ü Lydia Brillet and Marie-Christine Artru
J. Opt. Soc. Am. 65(12) 1399-1403 (1975)

Absorption spectra of Zn i and Cd i in the 1300–1750 Å region

Charles M. Brown, S. G. Tilford, and Marshall L. Ginter
J. Opt. Soc. Am. 65(12) 1404-1409 (1975)

Cited By

You do not have subscription access to this journal. Cited by links are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access Optica Member Subscription

Tables (2)

You do not have subscription access to this journal. Article tables are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access Optica Member Subscription

Combination
3s–3p		Zn xx	Ga xxi	Ge xxii	As xxiii	Se xxiv	I^a
²S_1/2–²P_{1_1/2}	obs	256.41 Å	240.82	226.51	213.23		2
²S_1/2–²P_{1_1/2}	calc	256.41	240.83	226.49	213.24	200.95
²S_1/2–²P_1/2	obs	288.13			249.81		4
²S_1/2–²P_1/2	calc	288.14	274.19	261.46	249.81	239.10
3p–3d
²P_{1_1/2}–²D_{2_1/2}	obs	210.21	200.00	190.63	181.97	173.96	8
²P_{1_1/2}–²D_{2_1/2}	calc	210.22	200.00	190.62	181.97	173.96
²P_1/2–²D_{1_1/2}	obs	195.43	184.45	174.43	165.04	156.29	6
²P_1/2–²D_{1_1/2}	calc	195.45	184.49	174.38	165.02	156.31
3s²–3s3p		Cu xviii	Zn xix	Ga xx	Fe xxi	As xxii	Se xxiii	I
¹S₀–¹P₁	obs	234.24	220.60	208.11	196.57	185.87	175.92
¹S₀–¹P₁	calc	234.24	220.60	208.09	196.87	185.87	175.93	5
3s3p–3s3d
³P₂–³D₃	obs	196.40	186.38	177.21	168.90	161.21	154.04	5
³P₂–³D₃	calc	196.41	186.38	177.24	168.88	161.88	154.07
³P₁–³D₂	obs	188.20	177.67	167.97	159.14			3
³P₁–³D₂	calc	188.22	177.65	168.00	159.13	150.94	143.36
³P₀–³D₁	obs	185.58	175.02					1
³P₀–³D₁	calc	185.60	175.01	165.36	156.52	158.38	140.85
¹P₁–¹D₂	obs	204.06	193.42	183.65	174.78	166.52	158.86	5
¹P₁–¹D₂	calc	204.11	193.42	183.68	174.74	166.50	158.88
3s² 3p–3s² 3d		Cu xvii	Zn xviii	Ge xix	Fe xx	As xxi	Se xxii	I
²P_{1_1/2}–²D_{2_1/2}	obs	183.47	174.01	165.35	157.55	150.22		5
²P_{1_1/2}–²D_{2_1/2}	calc	183.51	174.00	165.37	157.49	150.25	143.57
²P_1/2–²D_{1_1/2}	obs	174.12	164.06	155.01^b	146.61	138.77		2
²P_1/2–²D_{1_1/2}	calc	174.16	164.13	154.97	146.56	138.80	131.61
3s² 3p–3s 3p²
²P_{1_1/2}–²P_{1_1/2}	obs	218.76	206.29	194.83	184.38	174.67	165.62	2
²P_{1_1/2}–²P_{1_1/2}	calc	218.76	206.28	194.86	184.36	174.65	165.64
3s² 3p²–3s² 3p 3d		Cu xvi	Zn xvii	Ga xviii	Ge xix	I
³P₂–³D₃	obs	168.80	159.48	150.86	143.04	3
³P₂–³D₃	calc	168.85	159.45	150.88	143.03
3s² 3p²–3s² 3p² 3d		Cu xv	Zn xvi	Ga xvii	I
²D_{2_1/2}–²F_{3_1/2}	obs	154.67	146.24	138.54	3
²D_{2_1/2}–²F_{3_1/2}	calc	154.70	146.21	138.55
⁴S_{1_1/2}–⁴P_{2_1/2}	obs	161.34	152.42	144.23	2
⁴S_{1_1/2}–⁴P_{2_1/2}	calc	161.38	152.39	144.24
3s² 3p⁵–3s² 3p⁴ 3d		Zn xiv	Zn xv	Ga xvi	I
³P₂–³D₃	obs	148.30^b	139.87	132.19	2
³P₂–³D₃	calc	148.30	139.85	132.20
¹D₂–¹F₃	obs	148.30^b	140.13	132.69	1
¹D₂–¹F₃	calc	148.32	140.10	132.70
3s² 3p⁵–3s² 3p⁴ 3d		Zn xiv	Ga xv	I
²P_{1_1/2}–²D_{2_1/2}	obs	134.80	127.48	3
²P_{1_1/2}–²D_{2_1/2}	calc	134.80	127.48
²P_1/2–²D_{1_1/2}	obs	135.64	128.31	2
²P_1/2–²D_{1_1/2}	calc	135.64	128.31
3s² 3p⁶–3s² 3p⁵ 3d		Ga xiv	Ge xv	I
¹S₀–¹P₁	obs	123.80	117.25	6
¹S₀–¹P₁	calc	123.81	117.24
3p⁶ 3d–3p⁵ 3d²		Ga xiii	Ge xiv	I
²D_{2_1/2}–²D_{2_1/2}	obs	120.37	113.93	7
²D_{2_1/2}–²D_{2_1/2}	calc	120.40	113.92
²D_{1_1/2}–²D_{1_1/2}	obs	119.49	112.96	6
²D_{1_1/2}–²D_{1_1/2}	calc	119.51	112.95
²D_{2_1/2}–²F_{3_1/2}	obs	130.18	122.82	5
²D_{2_1/2}–²F_{3_1/2}	calc	130.20	122.81
3p⁶ 3dⁿ–3p⁵ 3dⁿ⁺¹	Cu	Zn	Ga	Ge	As	Se	Br
Main range of groups	128–175	120–165	114–155	106–146	100–138	96–130	88–120

Combination	Zn xx		Ga xxi	Ge xxii	As xxiii	Se xxiv	Br xxv	I^a
3d–4f ²D_{2_1/2}–²F_{3_1/2}	42.924		39.033	35.637	32.687	30.068	27.781	9
²D_{1_1/2}–²F_{2_1/2}	42.828		38.924	35.531	32.586	29.960	27.678	9
3d–5f ²D_{2_1/2}–²F_{3_1/2}	30.142		27.27	24.963	22.892	21.07		6
²D_{1_1/2}–¹F_{2_1/2}	30.078		27.32	24.932	22.831			6
3d–6f ²D_{2_1/2}–²F_{3_1/2}	25.891		23.54	21.476	19.649			2
3p–4d ²P_{1_1/2}–²D_{2_1/2}	36.720		33.610	30.871	28.474	26.35	24.465	8
²P_1/2–²D_{1_1/2}	36.187		33.100	30.361	27.983	25.83	23.910	7
3p–5d ²P_{1_1/2}–²D_{2_1/2}	26.619		24.330	22.301	20.545	18.98		3
²P_1/2–²D_{1_1/2}	26.331		24.039	22.020	20.266			2
3p–6d ²P_{1_1/2}–²D_{2_1/2}	23.161							1
²P_1/2–²D_{1_1/2}	22.925							1
3s–4p ²S_1/2–²P_1/2	34.248		31.417	28.902	26.687	24.73	22.959	5
²S_1/2–²P_{1_1/2}	34.051		31.216	28.705	26.500	24.53	22.739	6
3s–5p ²S_1/2–²P_1/2	24.657		22.536	20.72	19.090			2
²S_1/2–²P_{1_1/2}	24.610							2
3p–4s ²P_{1_1/2}–²S_1/2	41.828		38.153	34.921	32.107	29.596		4
²P_1/2–²S_1/2	41.111		37.430	34.212	31.413	28.907		2
3d–4p ²D_{2_1/2}–²P_{1_1/2}	48.28		43.70	39.72				2
²D_{1_1/2}–²P_1/2	48.52		43.93	39.94
Cu xix²D_{2_1/2}–4p ²P_{1_1/2} 53.64 ²D_{1_1/2}–²P_1/2 53.90
	Zn xix		Ga xx	Ge xxi	As xxii	Se xxiii	Br xxiv	I
3s3d–3s4f ³D₃–³F₄	44.70		40.54	36.95	33.84	31.10	28.64	4
3s3d–3s5f ³D₃–F₄	31.80		28.83	26.22	23.95		20.21	1
3s3p–3s4d ³P₂–³D₃	37.448		34.250	31.451	28.972	26.76	24.816	3
³P₁–³D₂	37.085		33.894	31.188	28.699			2
³P₀–³D₁				31.055	28.601			1
3s3p–3s5d ³P₂–³D₃	27.510			23.002	21.142			1
3s3d–3s4f ¹D₂–¹F₃	46.383		41.983	38.182		32.01	29.486	2
3p²–3s4f ¹D₂–¹F₃	41.581		37.849	34.604	31.765	29.20		1
3s²–3s4p ¹S₀–¹P₁	35.423		32.417	29.739	27.432	25.36		1
3s3p–3s4d ¹P₁–¹D₂	39.135		35.700	32.727^b	30.084^b	27.75		2
3p3d–3p4f ³F₄–³G₅	44.166		40.100	36.560	33.445			4
³F₃–³G₄	44.341			36.741	33.519			2
3p3d–3p4f ¹F₃–¹G₄	46.18		41.798	37.994	34.732	31.85	29.355	2
3s3p–3s4p ²P₂–³D₃	34.831		31.797					2
3p² 3d–3p² 4f	Cu xv		Zn xvi	Ga xvii	Ge xviii			I
⁴F_{4_1/2}–⁴G_{5_1/2}	57.44		51.3^b	45.96^b	41.53			1
(¹D) ²G_{4_1/2}–²H_{5_1/2}	57.52		51.8^b	46.3^b	41.81			1
3p³ 3d–3p³ 4f^c	Cu xiv		Zn xv	Ga xvi	Ge xvii	As xviii	Se xix	I
⁵D₄–⁵F₅	61.08		54.40	43.69	43.88	39.7	36.2	1
(²D) ³G₅–³H₆	61.70		54.91	49.19	44.29
3p⁴ 3d–3p⁴ 4f^c	Cu xiii	Zn xiv	Ga xv	Ge xvi	As xvii	Se xviii	Br xix	I
(³P) ⁴F_{4_1/2}–⁴G_{5_1/2}	66.18	58.60	52.27	46.9	42.4^b	38.6	35.3	1
(³P) ⁴D_{3_1/2}–⁴F_{4_1/2}	65.24	57.74	51.57	46.25	46.84	37.9	34.7	1
3p⁴ 3d–3p⁵ 4f			Zn xiii	Ga xiv	Ge xv	As xvi		I
³F₄–³G₅			62.87	55.72	49.73	44.66		1
3p⁶ 3d–3p⁶ 4f				Ga xii	Ge xiii	As xv	Se xvi	I
²D_{2_1/2}–²F_{3_1/2}				60.171	53.378	47.711	42.91	3
²D_{1_1/2}–²F_{2_1/2}				59.975	53.165	47.514		2
3p⁶ 3d²–3p⁶ 3d4f^c			Ga xii	Ge xiv	As xiv	Se xv	Br xvi	I
³F–³G			64.69	56.93	50.68	45.56	40.91^b	3
3p⁶ 3d³–3p⁶ 3d² 4f	Cu ix		Zn x	Ga xi	Ge xii	As xiii	Se xiv	Br xv
Main range of group	95–101		81–86	70–75	61–85	54–57	48–50	43–45
3p⁶ 3d⁴–3p⁶ 3d³ 4f	Cu viii		Zn ix	Ga x	Ge xi	As xii	Se xiii	Br xiv
Main range of group	107–116		92–110	78–84	67–71	58–62	52–55	46–48.5

Combination
3s–3p		Zn xx	Ga xxi	Ge xxii	As xxiii	Se xxiv	I^a
²S_1/2–²P_{1_1/2}	obs	256.41 Å	240.82	226.51	213.23		2
²S_1/2–²P_{1_1/2}	calc	256.41	240.83	226.49	213.24	200.95
²S_1/2–²P_1/2	obs	288.13			249.81		4
²S_1/2–²P_1/2	calc	288.14	274.19	261.46	249.81	239.10
3p–3d
²P_{1_1/2}–²D_{2_1/2}	obs	210.21	200.00	190.63	181.97	173.96	8
²P_{1_1/2}–²D_{2_1/2}	calc	210.22	200.00	190.62	181.97	173.96
²P_1/2–²D_{1_1/2}	obs	195.43	184.45	174.43	165.04	156.29	6
²P_1/2–²D_{1_1/2}	calc	195.45	184.49	174.38	165.02	156.31
3s²–3s3p		Cu xviii	Zn xix	Ga xx	Fe xxi	As xxii	Se xxiii	I
¹S₀–¹P₁	obs	234.24	220.60	208.11	196.57	185.87	175.92
¹S₀–¹P₁	calc	234.24	220.60	208.09	196.87	185.87	175.93	5
3s3p–3s3d
³P₂–³D₃	obs	196.40	186.38	177.21	168.90	161.21	154.04	5
³P₂–³D₃	calc	196.41	186.38	177.24	168.88	161.88	154.07
³P₁–³D₂	obs	188.20	177.67	167.97	159.14			3
³P₁–³D₂	calc	188.22	177.65	168.00	159.13	150.94	143.36
³P₀–³D₁	obs	185.58	175.02					1
³P₀–³D₁	calc	185.60	175.01	165.36	156.52	158.38	140.85
¹P₁–¹D₂	obs	204.06	193.42	183.65	174.78	166.52	158.86	5
¹P₁–¹D₂	calc	204.11	193.42	183.68	174.74	166.50	158.88
3s² 3p–3s² 3d		Cu xvii	Zn xviii	Ge xix	Fe xx	As xxi	Se xxii	I
²P_{1_1/2}–²D_{2_1/2}	obs	183.47	174.01	165.35	157.55	150.22		5
²P_{1_1/2}–²D_{2_1/2}	calc	183.51	174.00	165.37	157.49	150.25	143.57
²P_1/2–²D_{1_1/2}	obs	174.12	164.06	155.01^b	146.61	138.77		2
²P_1/2–²D_{1_1/2}	calc	174.16	164.13	154.97	146.56	138.80	131.61
3s² 3p–3s 3p²
²P_{1_1/2}–²P_{1_1/2}	obs	218.76	206.29	194.83	184.38	174.67	165.62	2
²P_{1_1/2}–²P_{1_1/2}	calc	218.76	206.28	194.86	184.36	174.65	165.64
3s² 3p²–3s² 3p 3d		Cu xvi	Zn xvii	Ga xviii	Ge xix	I
³P₂–³D₃	obs	168.80	159.48	150.86	143.04	3
³P₂–³D₃	calc	168.85	159.45	150.88	143.03
3s² 3p²–3s² 3p² 3d		Cu xv	Zn xvi	Ga xvii	I
²D_{2_1/2}–²F_{3_1/2}	obs	154.67	146.24	138.54	3
²D_{2_1/2}–²F_{3_1/2}	calc	154.70	146.21	138.55
⁴S_{1_1/2}–⁴P_{2_1/2}	obs	161.34	152.42	144.23	2
⁴S_{1_1/2}–⁴P_{2_1/2}	calc	161.38	152.39	144.24
3s² 3p⁵–3s² 3p⁴ 3d		Zn xiv	Zn xv	Ga xvi	I
³P₂–³D₃	obs	148.30^b	139.87	132.19	2
³P₂–³D₃	calc	148.30	139.85	132.20
¹D₂–¹F₃	obs	148.30^b	140.13	132.69	1
¹D₂–¹F₃	calc	148.32	140.10	132.70
3s² 3p⁵–3s² 3p⁴ 3d		Zn xiv	Ga xv	I
²P_{1_1/2}–²D_{2_1/2}	obs	134.80	127.48	3
²P_{1_1/2}–²D_{2_1/2}	calc	134.80	127.48
²P_1/2–²D_{1_1/2}	obs	135.64	128.31	2
²P_1/2–²D_{1_1/2}	calc	135.64	128.31
3s² 3p⁶–3s² 3p⁵ 3d		Ga xiv	Ge xv	I
¹S₀–¹P₁	obs	123.80	117.25	6
¹S₀–¹P₁	calc	123.81	117.24
3p⁶ 3d–3p⁵ 3d²		Ga xiii	Ge xiv	I
²D_{2_1/2}–²D_{2_1/2}	obs	120.37	113.93	7
²D_{2_1/2}–²D_{2_1/2}	calc	120.40	113.92
²D_{1_1/2}–²D_{1_1/2}	obs	119.49	112.96	6
²D_{1_1/2}–²D_{1_1/2}	calc	119.51	112.95
²D_{2_1/2}–²F_{3_1/2}	obs	130.18	122.82	5
²D_{2_1/2}–²F_{3_1/2}	calc	130.20	122.81
3p⁶ 3dⁿ–3p⁵ 3dⁿ⁺¹	Cu	Zn	Ga	Ge	As	Se	Br
Main range of groups	128–175	120–165	114–155	106–146	100–138	96–130	88–120

Combination	Zn xx		Ga xxi	Ge xxii	As xxiii	Se xxiv	Br xxv	I^a
3d–4f ²D_{2_1/2}–²F_{3_1/2}	42.924		39.033	35.637	32.687	30.068	27.781	9
²D_{1_1/2}–²F_{2_1/2}	42.828		38.924	35.531	32.586	29.960	27.678	9
3d–5f ²D_{2_1/2}–²F_{3_1/2}	30.142		27.27	24.963	22.892	21.07		6
²D_{1_1/2}–¹F_{2_1/2}	30.078		27.32	24.932	22.831			6
3d–6f ²D_{2_1/2}–²F_{3_1/2}	25.891		23.54	21.476	19.649			2
3p–4d ²P_{1_1/2}–²D_{2_1/2}	36.720		33.610	30.871	28.474	26.35	24.465	8
²P_1/2–²D_{1_1/2}	36.187		33.100	30.361	27.983	25.83	23.910	7
3p–5d ²P_{1_1/2}–²D_{2_1/2}	26.619		24.330	22.301	20.545	18.98		3
²P_1/2–²D_{1_1/2}	26.331		24.039	22.020	20.266			2
3p–6d ²P_{1_1/2}–²D_{2_1/2}	23.161							1
²P_1/2–²D_{1_1/2}	22.925							1
3s–4p ²S_1/2–²P_1/2	34.248		31.417	28.902	26.687	24.73	22.959	5
²S_1/2–²P_{1_1/2}	34.051		31.216	28.705	26.500	24.53	22.739	6
3s–5p ²S_1/2–²P_1/2	24.657		22.536	20.72	19.090			2
²S_1/2–²P_{1_1/2}	24.610							2
3p–4s ²P_{1_1/2}–²S_1/2	41.828		38.153	34.921	32.107	29.596		4
²P_1/2–²S_1/2	41.111		37.430	34.212	31.413	28.907		2
3d–4p ²D_{2_1/2}–²P_{1_1/2}	48.28		43.70	39.72				2
²D_{1_1/2}–²P_1/2	48.52		43.93	39.94
Cu xix²D_{2_1/2}–4p ²P_{1_1/2} 53.64 ²D_{1_1/2}–²P_1/2 53.90
	Zn xix		Ga xx	Ge xxi	As xxii	Se xxiii	Br xxiv	I
3s3d–3s4f ³D₃–³F₄	44.70		40.54	36.95	33.84	31.10	28.64	4
3s3d–3s5f ³D₃–F₄	31.80		28.83	26.22	23.95		20.21	1
3s3p–3s4d ³P₂–³D₃	37.448		34.250	31.451	28.972	26.76	24.816	3
³P₁–³D₂	37.085		33.894	31.188	28.699			2
³P₀–³D₁				31.055	28.601			1
3s3p–3s5d ³P₂–³D₃	27.510			23.002	21.142			1
3s3d–3s4f ¹D₂–¹F₃	46.383		41.983	38.182		32.01	29.486	2
3p²–3s4f ¹D₂–¹F₃	41.581		37.849	34.604	31.765	29.20		1
3s²–3s4p ¹S₀–¹P₁	35.423		32.417	29.739	27.432	25.36		1
3s3p–3s4d ¹P₁–¹D₂	39.135		35.700	32.727^b	30.084^b	27.75		2
3p3d–3p4f ³F₄–³G₅	44.166		40.100	36.560	33.445			4
³F₃–³G₄	44.341			36.741	33.519			2
3p3d–3p4f ¹F₃–¹G₄	46.18		41.798	37.994	34.732	31.85	29.355	2
3s3p–3s4p ²P₂–³D₃	34.831		31.797					2
3p² 3d–3p² 4f	Cu xv		Zn xvi	Ga xvii	Ge xviii			I
⁴F_{4_1/2}–⁴G_{5_1/2}	57.44		51.3^b	45.96^b	41.53			1
(¹D) ²G_{4_1/2}–²H_{5_1/2}	57.52		51.8^b	46.3^b	41.81			1
3p³ 3d–3p³ 4f^c	Cu xiv		Zn xv	Ga xvi	Ge xvii	As xviii	Se xix	I
⁵D₄–⁵F₅	61.08		54.40	43.69	43.88	39.7	36.2	1
(²D) ³G₅–³H₆	61.70		54.91	49.19	44.29
3p⁴ 3d–3p⁴ 4f^c	Cu xiii	Zn xiv	Ga xv	Ge xvi	As xvii	Se xviii	Br xix	I
(³P) ⁴F_{4_1/2}–⁴G_{5_1/2}	66.18	58.60	52.27	46.9	42.4^b	38.6	35.3	1
(³P) ⁴D_{3_1/2}–⁴F_{4_1/2}	65.24	57.74	51.57	46.25	46.84	37.9	34.7	1
3p⁴ 3d–3p⁵ 4f			Zn xiii	Ga xiv	Ge xv	As xvi		I
³F₄–³G₅			62.87	55.72	49.73	44.66		1
3p⁶ 3d–3p⁶ 4f				Ga xii	Ge xiii	As xv	Se xvi	I
²D_{2_1/2}–²F_{3_1/2}				60.171	53.378	47.711	42.91	3
²D_{1_1/2}–²F_{2_1/2}				59.975	53.165	47.514		2
3p⁶ 3d²–3p⁶ 3d4f^c			Ga xii	Ge xiv	As xiv	Se xv	Br xvi	I
³F–³G			64.69	56.93	50.68	45.56	40.91^b	3
3p⁶ 3d³–3p⁶ 3d² 4f	Cu ix		Zn x	Ga xi	Ge xii	As xiii	Se xiv	Br xv
Main range of group	95–101		81–86	70–75	61–85	54–57	48–50	43–45
3p⁶ 3d⁴–3p⁶ 3d³ 4f	Cu viii		Zn ix	Ga x	Ge xi	As xii	Se xiii	Br xiv
Main range of group	107–116		92–110	78–84	67–71	58–62	52–55	46–48.5

Abstract

Cited By

Tables (2)

Journal of the Optical Society of America