Samuel Goldsmith and John G. Conway, "Analysis of the configurations 5d86s2 in Pt i through Hg iii and 5d96p in Pt i through Bi vi*," J. Opt. Soc. Am. 65, 1371-1375 (1975)
The levels of the configurations 5d86s2 in Pt i through Hg iii and 5d96p in Pt i through Bi vi were calculated and compared with experiment. The experimental levels of 5d96p in Pt i and 5d86s2 in Au ii do not agree with the calculated values. Some minor corrections are suggested for the other ions. The published g factors of Au ii are shown to be rather doubtful.
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Comparison between observed and calculated Zeeman pattern in Au ii. (Calculated center of gravity of π and σ components with respect to the place of the unsplit line.)
Observed Zeeman pattern
Calculated Zeeman pattern
Transition
π
σ
π
σ
0
1.07
0
1.13
0
1.03
0
1.10
0
1.01
0
1.07
0
1.08
0
1.13
0
0.93
0
1.02
0
0.94
0
1.08
0
1.01
0
1.08
0
1.17
0
1.22
0.69
1.26
0.56
1.23
0
1.25
0.21
1.29
0
1.14
0
1.15
0
1.01
0
1.06
0
1.07
0
1.11
0.47
1.23
0.43
1.17
0
1.08
0
1.08
0.63
1.36
0.54
0.93
0
1.32
0
0.98
0
1.07
0
1.10
Tables (5)
TABLE I
Parameters of the configuration 5d86s2 in Pt i, Hg iii (in cm−1).
Comparison between observed and calculated Zeeman pattern in Au ii. (Calculated center of gravity of π and σ components with respect to the place of the unsplit line.)