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Hyperfine structure in the 253Es emission spectrum, III: Extension of the line list, levels of Es i and Es ii, nuclear magnetic-dipole and quadrupole moments

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Abstract

New observations of the einsteinium emission spectrum have increased the number of observed lines from 53 to 290 in the wavelength range 2600–6900 Å. Ten lines have been assigned as transitions to the 5f11 7s2 4I15/2° ground state of Es i on the basis of reversal and hyperfine structure. The next odd level is 4I13/2° at 8759.25 cm−1. The lowest even level is 6I15/2 of the 5f11 7s7p configuration at 17 802.89 cm−1. The lowest level of the 5f106d7s2 configuration is 6I17/2 at 19 367.93 cm−1. Fifteen lines are classified as The lowest level transitions between Es i levels. Twenty-three lines are assigned as transitions to the two known lowest of Es ii. The hyperfine constants a5f = 0.033±0.001 cm−1 and bf = 0.48±0.06 cm−1 have been derived by an analysis of the hyperfine structure of assigned Es ii lines. From these constants for 253Es, we obtained a nuclear magnetic dipole moment of +3.6±0.4μN and a quadrupole moment of +6.0±0.8 b.

© 1974 Optical Society of America

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