Hyperfine structure in the 253Es emission spectrum, III: Extension of the line list, levels of Es i and Es ii, nuclear magnetic-dipole and quadrupole moments
Earl F. Worden, R. W. Lougheed, R. G. Gutmacher, and John G. Conway
Earl F. Worden, R. W. Lougheed, R. G. Gutmacher, and John G. Conway, "Hyperfine structure in the 253Es emission spectrum, III: Extension of the line list, levels of Es i and Es ii, nuclear magnetic-dipole and quadrupole moments*," J. Opt. Soc. Am. 64, 77-85 (1974)
New observations of the einsteinium emission spectrum have increased the number of observed lines from 53 to 290 in the wavelength range 2600–6900 Å. Ten lines have been assigned as transitions to the 5f11 7s2 4I15/2° ground state of Es i on the basis of reversal and hyperfine structure. The next odd level is 4I13/2° at 8759.25 cm−1. The lowest even level is 6I15/2 of the 5f11 7s7p configuration at 17 802.89 cm−1. The lowest level of the 5f106d7s2 configuration is 6I17/2 at 19 367.93 cm−1. Fifteen lines are classified as The lowest level transitions between Es i levels. Twenty-three lines are assigned as transitions to the two known lowest of Es ii. The hyperfine constants a5f = 0.033±0.001 cm−1 and bf = 0.48±0.06 cm−1 have been derived by an analysis of the hyperfine structure of assigned Es ii lines. From these constants for 253Es, we obtained a nuclear magnetic dipole moment of +3.6±0.4μN and a quadrupole moment of +6.0±0.8 b.
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Einsteinium wavelengths. P = peculiar, R = reversed, S = sharp, W = wide, C = off-diagonal components present, E =estimated width, − = degraded to red or to lower wave number, width with no sign = degraded to violet or to higher wave numbers. The direction of degradation is not determined if W follows the intensity.
Predicted values from Ref. 3.
Widths are positive for normal and negative for inverted hfs splittings.
Table III
Hyperfine splittings determined from the reversed Es line at 3514 Å and the strong Es lines at 5204 and 5615 Å assigned as combinations with the 4I15/2° ground level of Es i. All splittings in mK (10−3 cm−1).
Widths are positive for normal and negative for inverted hfs splittings.
Lowest level of the 5f117p configuration predicted to be at 27 000±1000 cm−1 from Ref. 9.
Table VII
Hyperfine structure and hyperfine constants for the 5I8° and 3I7° levels of the 5f117s configuration in Es ii. Hyperfine level with lowest F is arbitrarily assigned 0-mK energy.
5I8°
3I7°
F
Level (mK)
Interval (mK)
F
Level (mK)
Interval (mK)
4.5
0
676±13
3.5
0
−279±11
5.5
676
788±37
4.5
−279
−345±4
6.5
1464
916±16
5.5
−624
−415±3
7.5
2376
1029±30
6.5
−1039
−498±2
8.5
3405
1124±10
7.5
−1537
−591±7
9.5
4529
1233±3
8.5
−2128
−674±2
10.5
5762
1324±5
9.5
−2802
−765±2
11.5
7086
10.5
−3567
A = 118.7±0.3 mK
A = −68.4±0.2 mK
B = −130±18 mK
B = −160±7 mK
Table VIII
Values of θ1, θ2, and θ3 for the 5I8° and 3I7° levels of Es ii.
Level
θ1
θ2
θ3
5I8
0.7090
0.06250
−0.3051
3I7
0.8020
−0.06207
−0.2979
Table IX
Values of the nuclear magnetic dipole moment of 253Es.
Einsteinium wavelengths. P = peculiar, R = reversed, S = sharp, W = wide, C = off-diagonal components present, E =estimated width, − = degraded to red or to lower wave number, width with no sign = degraded to violet or to higher wave numbers. The direction of degradation is not determined if W follows the intensity.
Predicted values from Ref. 3.
Widths are positive for normal and negative for inverted hfs splittings.
Table III
Hyperfine splittings determined from the reversed Es line at 3514 Å and the strong Es lines at 5204 and 5615 Å assigned as combinations with the 4I15/2° ground level of Es i. All splittings in mK (10−3 cm−1).
Widths are positive for normal and negative for inverted hfs splittings.
Lowest level of the 5f117p configuration predicted to be at 27 000±1000 cm−1 from Ref. 9.
Table VII
Hyperfine structure and hyperfine constants for the 5I8° and 3I7° levels of the 5f117s configuration in Es ii. Hyperfine level with lowest F is arbitrarily assigned 0-mK energy.
5I8°
3I7°
F
Level (mK)
Interval (mK)
F
Level (mK)
Interval (mK)
4.5
0
676±13
3.5
0
−279±11
5.5
676
788±37
4.5
−279
−345±4
6.5
1464
916±16
5.5
−624
−415±3
7.5
2376
1029±30
6.5
−1039
−498±2
8.5
3405
1124±10
7.5
−1537
−591±7
9.5
4529
1233±3
8.5
−2128
−674±2
10.5
5762
1324±5
9.5
−2802
−765±2
11.5
7086
10.5
−3567
A = 118.7±0.3 mK
A = −68.4±0.2 mK
B = −130±18 mK
B = −160±7 mK
Table VIII
Values of θ1, θ2, and θ3 for the 5I8° and 3I7° levels of Es ii.
Level
θ1
θ2
θ3
5I8
0.7090
0.06250
−0.3051
3I7
0.8020
−0.06207
−0.2979
Table IX
Values of the nuclear magnetic dipole moment of 253Es.