Spectra of P xii and P xiii in the extreme vacuum ultraviolet

S. Goldsmith; L. Oren (Katz); Leonard Cohen

doi:10.1364/JOSA.63.000352

Spectra of P xii and P xiii in the extreme vacuum ultraviolet

S. Goldsmith, L. Oren (Katz), and Leonard Cohen

Journal of the Optical Society of America
Vol. 63,
Issue 3,
pp. 352-358
(1973)
•https://doi.org/10.1364/JOSA.63.000352

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S. Goldsmith, L. Oren (Katz), and Leonard Cohen, "Spectra of P xii and P xiii in the extreme vacuum ultraviolet," J. Opt. Soc. Am. 63, 352-358 (1973)

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History
- Original Manuscript: August 4, 1972
- Published: March 1, 1973

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Abstract

We present here a new study of the spectra P xii and P xiii in the wavelength region between 23–44 Å. The previous analyses of the energy levels have been much extended and revised. The extrapolation procedures used to calculate these spectra are presented in detail.

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Ion	(³P₁°–³P₀°)		(³P₂°–³P₁)
Ion	Expt^a	Calc	Expt^a	Calc
B ii	6.4	8	16.4	15
C iii	24.7	27	56.4	55
N iv	63	70	144	140
O v	136	148	307	289
F vi	260	279	576	563
Ne vii	455	479	994	972
Na viii	730	770	1604	1572
Mg ix	1162	1175	2472	2416
Al x	1690	1716	3660	3564
Si xi	2420	2422	5250	5182
P xii	3256	3316	7137	7051

Ion	ζ₂_p(2s2p)		ζ₂_p(2p²)
Ion	Expt	Calc	Expt	Calc
B ii	15.2	15.3	16.7	16.5
C iii	53.9	54.3	58.2	57.8
N iv	138.1	139.5	142.7	144.1
O v	295.3	297.3	303.2	302.4
F vi	557.3	559.8	565.6	564.9
Ne vii	962.0	965.5		969.5
Na viii	1556.0	1558.4	1537.4	1560.1
Mg ix	2422.7	2388.8	2358.3	2386.9

Ion	³P₁–³P₀^a	³P₁–³P₀^b	³P₂–³P₁^a	³P₂–³P₁^b	¹D₂–³P₂^a	¹D₂–³P₂^b
Ne vii	511	512	883	952		26 853
Na viii	827	839	1405	1521	31 147^c	31 262
Mg ix	1299	1315	2157	2306	35 094^c	35 578
Al x	1970	1982	3190	3451	39 132^c	39 806
Si xi	2816	2902	4480	4695	43 967^c	43 954
P xii	4010	4144	6070	6378		48 056
S xiii	5535	5793	8104	8432		52 155
Cl xiv	7506	7954	10420	10978		56 333

Ion	3s–3p		3p–3d
Ion	Observed^a	Calculated	Observed^a	Calculated
Li i	3 719	3 984	358	−221
B ii	8 265	8 378	1 555	1 532
B iii	12 748	12 772	3 109	3 287
C iv	17 200	17 166	4 800	5 041
N v	21 643	21 561	6 552	6 796
O vi	26 074	25 955	8 356	8 550
F vii	30 511	30 349	10 214	10 304
Ne viii		34 743		12 059
Na ix	39 424	39 137	13 850	13 813
Mg x	43 871	43 532	15 578	15 568
Al xi	48 310	47 926	17 460	17 322
Si xii	51 320	52 320	19 240	19 076
P xiii	49 490	56 714	20 110	20 831
S xiv		61 108		22 585
Cl xv		65 502		24 340

Ion	4d ^a	4d ^b	5d ^a	5d ^b
Li i	36 983	36 623	39 454	39 094
B ii	119 419	119 422	129 308	129 311
B iii	244 135	244 137	266 388	266 416
C iv	410 317	410 334	449 875	449 885
N v	617 878	617 905	679 688	679 725
O vi	866 825	866 880	955 833	955 856
F vii	1 157 198	1 157 223	1 278 355	1 278 404
Ne viii	1 489 062		1 646 322
Na ix	1 862 494	1 862 222	2 062 815	2 062 835
Mg x	2 277 580	2 277 182	2 524 927	2 524 300
Al xi	2 734 422	2 734 000	3 033 764	3 033 500
Si xii	3 233 130	3 233 250	3 589 445	3 588 800
P xiii	3 773 824	3 776 703	4 192 095	4 190 656
S xiv	4 356 635	4 361 476	4 841 853	4 828 725
Cl xv	4 981 702		5 538 869

Transition	Int.	λ(Å) Extrapolated	λ(Å)	1/λ(cm⁻¹)	Remarks^a
2s^{2 1}S₀ –2s5p ¹P₁°	0	25.81	25.788	3 878 000
2s2p ³P₁°–2s5d ³D₂	1	27.04	27.049	3 697 000
³P₂°– ³D₃	1	27.11	27.101	3 689 800	27.06 F
2p^{2 3}P₂–2p5d ³P₂°		27.70
	0		27.677	3 613 000	27.66 F
³P₂ – ³D₃°		27.68
2p^{2 1}D₂ –2p5d ¹F₃°	1	28.01	28.017	3 569 200
2s2p ³P₂°–2p4p ³P₂	3	28.33	28.304	3 533 000	wide
2s^{2 1}S₀ –2s4p ¹P₁°	1	28.54	28.549	3 502 800
2s2p ¹P₁°–2p4p ¹D₂	1	29.63	29.622	3 376 000
³P₀°–2s4d ³D₁	1	29.98	29.970	3 336 600
³P₁°– ³D₂	4	30.01	29.996	3 333 800
³P₂°– ³D₃	6	30.07	30.060	3 326 700
2p^{2 3}P₁ –2p4d ³P₂°	0	30.69	30.667	3 261 000
³P₂ – ³P₂°	4	30.74	30.722	3 255 000	30.72 F
³P₂ – ³D₃°	4	30.76	30.749	3 252 100
¹D₂ – ¹F₃°	4	31.08	31.090	3 216 500
¹D₂ – ¹D₂°	1	31.33	31.327	3 192 200
2s2p ¹P₁° –2s4d ¹D₂°	3	31.53	31.527	3 171 800
2p^{2 1}S₀ –2p4d ¹P₁°	0	32.30	32.304	3 095 600
2s2p ³P₁°–2p3p ³P₂		36.53
	3		36.520	2 738 200
³P₀°– ³P₁		36.53
³P₁°– ³P₁	5	36.57	56.562	2 735 100
³P₂°– ³P₂	8	36.61	36.613	2 731 300
³P₂°– ³P₁		36.66
	6		36.655	2 728 100
³P₀°– ³S₁		36.67
³P₁°– ³S₁	4	36.72	36.697	2 725 000
³P₂°– ³S₁	7	36.80	37.792	2 718 000
³P₂°– ³D₃	10	36.97	36.975	2 704 600	36.978 M
³P₁°– ³D₁	1	37.02	37.041	2 699 700
³P₂°– ³D₂	1	37.07	37.074	2 697 300
2s^{2 1}S₀ –2s3p ¹P₁°	15	37.36	37.347	2 677 600	37.345 M
2s2p ¹P₁°–2p3p ¹D₂	9	38.64	38.629	2 588 700	38.626 M
³P₀°–2s3d ³D₁	12	39.32	39.310	2 544 000	39.316 M
³P₁°– ³D₂	30	39.36	39.354	2 541 000	39.358 M
³P₂°– ³D₃	50	39.45	39.456	2 534 400	39.450 M
2s2p ¹P₁°–2p3p ¹P₁	4	39.66	39.664	2 521 200
2p^{2 3}P₁ –2p3d ³P₁°	1	40.15	40.157	2 490 300
³P₁ – ³P₂°	3	40.18	40.171	2 489 300	?
³P₂ – ³P₂°	20	40.30	40.301	2 481 300
³P₀ – ³D₁°	5	40.36	40.348	2 478 400
³P₁ – ³D₂°	12	40.38	40.388	2 476 000
³P₂ – ³D₃°	15	40.43	40.429	2 473 500	40.431 M
³P₂ – ³D₂°		40.47
	2		40.478	2 470 500
¹D₂ – ¹P₁°		40.48
¹D₂ – ¹F₃°	12	40.61	40.613	2 462 300	40.617 M
2s2p ³P₀°–2s3s ³S₁	5	41.50	41.471	2 411 300	Blended?
³P₁°– ³S₁	6	41.55	41.518	2 408 600	41.524 M Blended?
³P₂°– ³S₁		41.65
	12		41.634	2 401 860	41.638 M
¹P₁°–2s3d ¹D₂		41.64
2p^{2 1}D₂ –2p3d ¹D₂°	7	41.69	41.700	2 398 100	41.702 M
2p^{2 3}P₁ –2p3s ³P₂°	2	42.55	42.553	2 350 000
³P₂ – ³P₂°	4	42.65	42.647	2 344 800
³P₁ – ³P₁°	2	42.67	42.679	2 343 100
¹D₂ – ¹P₁°	14	42.76	42.763	2 338 500	Blended?
³P₂ – ³P₁°	2	42.77	42.779	2 337 600
2s2p ¹P₁°–2s3s ¹S₀	1	44.05	44.044	2 270 500	44.045 M

	Designation	Level (cm⁻¹)
2s²	¹S₀	0
2s2p	³P₀°	184 690+x
	³P₁°	187 940+x
	³P₂°	195 090+x
	¹P₁°	359 360
2p²	³P₀	483 440+x
	³P₁	487 450+x
	³P₂	493 520+x
	¹D₂	541 720
	¹S₀	666 100+y
2s3s	3S₁	2 596 900+x
	¹S₀	2 629 900
2s3p	¹P₁°	2 677 600
2s3d	³D₁	2 728 700+x
	³D₂	2 728 900+x
	³D₃	2 729 500+x
2s3d	¹D₂	2 761 200
2p3s	³P₀°	2 827 700+x
	³P₁°	2 830 600+x
	³P₂°	2 838 300+x
2p3s	¹P₁°	2 880 200
2p3p	¹P₁	2 880 600
2p3p	³D₁	2 887 600+x
	³D₂	2 892 400+x
	³D₃	2 899 700+x
2p3p	³S₁	2 913 000+x
2p3p	³P₁	2 923 000+x
	³P₂	2 926 400+x
2p3d	¹D₂°	2 939 800
2p3p	¹D₂	2 948 100
2p3d	³D₁°	2 961 800+x
	³D₂°	2 963 500+x
	³D₃°	2 967 000+x
2p3d	³P₂°	2 974 800+x
	³P₁°	2 977 800+x
2p3d	¹F₃°	3 004 300
2p3d	¹P₁°	3 012 200
2s4p	¹P₁°	3 502 800
2s4d	³D₁	3 521 300+x
	³D₂	3 521 700+x
	³D₃	3 521 800+x
2s4d	¹D₂	3 531 200
2p4p	³P₂	3 728 100+x
2p4d	¹D₂°	3 733 900
2p4d	¹D₂	3 735 400
2p4d	³P₂°	3 748 500+x
2p4d	¹F₃°	3 758 300
2p4d	¹P₁°	3 761 700+y
2s5d	¹P₁°	3 878 000
2s5d	³D₃	3 884 900+x
2p5d	³P₂°	4 106 500+x
2p5d	¹F₃°	4 110 900

Transition	Int.	λ (Å) Extrapolated	λ (Å)	1/λ (cm⁻¹)	Remarks^a
2p ²P_1/2°–6d ²D_3/2		23.75			23 84 F
²P_3/2°– ²D_5/2	1	23.81	23.810	4 199 640	23 84 F
2p ²P_1/2°–5d ²D_3/2	2	25.10	25.103	3 983 600	25.18 F
²P_3/2°– ²D_5/2	2	25.17	25.169	3 973 200	25.18 F
2s ²S_1/2 –4p ²P_3/2°	1	26.60	26.608	3 758 280	26.60 F
2p ²P_1/2°–4d ²D_3/2	5	28.04	28.044	3 565 800	28.11 F
²P_3/2°– ²D_5/2	7	28.13	28.128	3 555 200	28.11 F
2s ²S_1/2 –3p ²P_3/2°	15	35.10	35.095	2 849 400	35.086 M
²S_1/2 – ²P_1/2°	10	35.14	35.136	2 846 100	35.157 M
2p ²P_1/2°–3d ²D_3/2	15	37.56	37.561	2 662 300
²P_3/2°– ²D_5/2	20	37.70	37.706	2 652 100
²P_3/2°– ²D_3/2	2	37.72	37.723	2 650 930
2p ²P_1/2°–3s ²S_1/2	3	38.74	38.754	2 580 350	38.652 M
²P_3/2°– ²S_1/2	5	38.91	38.921	2 569 290	38.825 M

Designation	Level (cm⁻¹)	Interval
2s ²S_1/2	0
2p ²P_1/2°	208 150	11 250
²P_3/2°	219 400	11 250
3s ²S_1/2	2 788 600
3p ²P_1/2°	2 846 100	3 300
²P_3/2°	2 849 400	3 300
3d ²D_3/2	2 870 500
²D_5/2	2 871 500	1000
4p ²P_3/2°	3 758 300	1000
4d ²D_3/2°	3 774 000	600
²D_5/2	3 774 600	600
5d ²D_3/2	4 191 800	500
²D_5/2	4 192 300	500
6d ²D_5/2	4 419 000

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Equations (10)

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