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Predicted Term Splittings for the Li i, B i, Na i Sequences and Other Sequences with One-Electron Spectra

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Abstract

Screening parameters obtained by Froese [ Can. J. Phys. 41, 51 ( 1963)] from Hartree–Fock calculations are used in the usual one-electron term-interval formula to predict values of splitting that become more accurate as Z increases. The ratio of observed splitting to calculated splitting is studied to give information on the behavior of the observed values; some discrepancies are found, for example, in the n2D intervals of Na ix and Mg x in the Li i sequence. For other deviations, the possibility of configuration interactions is explored. Some possible coronal uv wavelengths arising from the B i sequence are also given: the Fe xxii line predicted near 844 Å may have been observed recently.

© 1971 Optical Society of America

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