Absorption Bands of Carbon Dioxide from 2.8–4.2 μ

Earle K. Plyler; Eugene D. Tidwell; W. S. Benedict

doi:10.1364/JOSA.52.001017

Journal of the Optical Society of America
Vol. 52,
Issue 9,
pp. 1017-1022
(1962)
•https://doi.org/10.1364/JOSA.52.001017

Absorption Bands of Carbon Dioxide from 2.8–4.2 μ

Earle K. Plyler, Eugene D. Tidwell, and W. S. Benedict

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Earle K. Plyler, Eugene D. Tidwell, and W. S. Benedict, "Absorption Bands of Carbon Dioxide from 2.8–4.2 μ," J. Opt. Soc. Am. 52, 1017-1022 (1962)

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Abstract

The high-resolution spectrum of CO₂ has been studied between 2.8 and 4.2 μ, by using up to 48 meter-atmospheres path to develop weak bands. Accurate band constants have been obtained for the transitions 13¹0–000, 05¹0–000, and 101–02⁰0, and fragments of new weak bands have been detected near 3500 cm⁻¹. Estimates of band intensities are given, including a discussion of the highly abnormal intensity distribution in the weak perpendicular bands.

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Band J″	05¹0–000				13¹0–000
Band J″	P calc	O-C	R calc	O-C	P calc	O-C	R calc	O-C
2	3179.89	⋯	3183.80	⋯	3337.78	⋯	3341.68	0.02
4	77.34	⋯	85.37	⋯	36.22	⋯	43.24	w
6	76.79	⋯	86.95	⋯	34.66	⋯	44.79	0.00
8	75.25	⋯	88.54	⋯	33.09	⋯	46.34	0.00
10	73.72	⋯	90.14	0.03	31.52	⋯	47.90	0.01
12	3172.19	⋯	3191.74	0.09^w	3329.95	0.04	3349.46	0.00
14	70.67	⋯	93.34	0.00	28.38	0.04	51.01	0.02
16	69.16	0.04	94.95	0.02	26.81	−0.03^w	52.55	0.00
18	67.65	0.07	96.57	0.01	25.24	−0.04	54.10	0.01
20	66.15	0.02	98.19	w	23.66	−0.01	55.64	w
22	3164.65	0.01	3199.82	w	3322.08	0.00	3357.18	−0.05^w
24	63.16	0.01	3201.46	−0.01	20.51	0.04	58.72	−0.04
26	61.68	−0.01	03.10	−0.01	18.93	−0.01	60.26	−0.02
28	60.20	−0.02	04.75	−0.01	17.36	−0.05	61.79	w
30	58.73	0.00	06.40	0.01	15.78	−0.01	63.33	0.01
32	3157.27	0.04	3208.06	−0.01	3314.19	−0.01	3364.86	0.00
34	55.81	0.03	09.72	w	12.61	0.01	66.39	0.03^w
36	54.35	0.01	11.38	0.04	11.03	0.01	67.92	0.00
38	52.91	0.01	13.05	0.03	09.44	0.00	69.45	0.01
40	51.47	−0.03^w	14.73	w	07.86	0.02	70.98	0.01
42	3150.03	0.02	3216.41	w	3306.27	−0.02	3372.50	0.00
44	48.60	0.02	18.09	0.00	04.69	0.00	74.02	0.00
46	47.17	⋯	19.78	⋯	03.10	0.01	75.54	0.01
48	45.75	⋯	21.47	⋯	01.51	0.00	77.05	0.00
50					3299.92	−0.06	78.57	0.02
52					3298.33	−0.03	3380.08	0.00
54					96.74	⋯	81.59	0.02
56					95.15	⋯	83.10	w
58					93.55	⋯	84.60	w
60					91.95	⋯	86.11	w

Constant	Band	101–02⁰0	05¹0–000	13¹0–000	21¹0–000	05³1–03³0
ν₀	obs	2429.36	3181.45	3339.34	3500.54	3528.25
	calc	2429.43	3181.35	3339.10	3500.46	3528.14
B″	calc	0.39047	0.39021	0.39021	0.39021	0.39237
B′	obs	⋯	0.39101	0.39002	⋯	0.38950
	calc	0.38706	0.39098	0.39003	0.39056	0.38960
D″	calc	15.2×10⁻⁸	13.5×10⁻⁸	13.5×10⁻⁸	13.5×10⁻⁸	13.5×10⁻⁸
D′	obs	⋯	⋯	13.5×10⁻⁸	⋯	⋯
	calc	11.7×10⁻⁸	15.6×10⁻⁸	13.7×10⁻⁸	11.0×10⁻⁸	11.7×10⁻⁸

A. Fully measured bands.
Band	ν₀ cm⁻¹	S_v(cm⁻²atm⁻¹)^a			S_r(cm⁻²atm⁻¹)			R_v_″^v^′	Est. unc. %
Band	ν₀ cm⁻¹	(1)	(2)	(3)		R30	P30	D	Est. unc. %
13¹0–000	3339.34	6.2×10⁻⁴	5.2×10⁻⁴	3.5×10⁻³	0.15	1.7×10⁻⁴	5.3×10⁻⁵	1.3×10⁻⁴	10
05¹0–000	3181.45	1.3×10⁻⁵	1.4×10⁻⁵	3.3×10⁻⁴	0.3	1.4×10⁻⁵	7.5×10⁻⁶	2.1×10⁻⁵	10
						R16	P16
04⁰1–000	3465.34			6.10⁻⁴		2.10⁻⁵	2.10⁻⁵	3.7×10⁻³	15
101–02⁰0	2429.36			1.7×10⁻³		6.0×10⁻⁵	5.5×10⁻⁵	5.9×10⁻³	10

B. Partially measured bands.
	Band	ν₀	Lines used	S_v	R_v_″^v^′	Est. unc. %
	02⁰1–000	3612.84	P72–74	30.	2.8×10⁻²	10
	03¹1–01¹0	3580.30	P46–62	2.8	3.1×10⁻²	10
C¹³	02⁰1–000	3527.71	R4–P64	0.21	2.6×10⁻²	10
O¹⁸	101–000	3587.51	P45–55	0.18	3.6×10⁻²	20
	04⁰1–02⁰0	3568.19	P42–54	0.28	6.3×10⁻²	20
	04²1–02²0	3552.82	P24–53	0.074	2.6×10⁻²	25
C¹³	03¹1–01¹0	3498.72	R36–P54	0.014	2.1×10⁻²	10
	05¹1–03¹0	3542.60	P11–35	0.016	5.9×10⁻²	50
?	21¹0–000	3500.54	R16–26	0.008	5.10⁻⁴	100?

J	ν_obs	ν_calc
16	3513.94	3513.91
18	bl	15.50
20	17.09^b	17.09
22	18.67	18.68
24	20.30^b	20.28
26	21.85	21.88

Abstract

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Journal of the Optical Society of America