Zeeman Effect of Gold

J. B. Green; H. N. Maxwell

doi:10.1364/JOSA.45.000098

Journal of the Optical Society of America
Vol. 45,
Issue 2,
pp. 98-102
(1955)
•https://doi.org/10.1364/JOSA.45.000098

Zeeman Effect of Gold

J. B. Green and H. N. Maxwell

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J. B. Green and H. N. Maxwell, "Zeeman Effect of Gold," J. Opt. Soc. Am. 45, 98-102 (1955)

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Abstract

The Zeeman effects of Au i and Au ii have been investigated in the region of λλ 2400 A to 6500 A for a magnetic field strength of about 38 000 gauss. The work of Symons and Daley has been confirmed and somewhat extended for Au i. Unfortunately, most of the Au ii patterns were triplets and hence of little value. Some doubt is cast on existing classification of Au ii by the persistent appearance of the lines λλ 5354, 5380, and 5427 which come out as strong, well-resolved patterns on the plates, so that g and J values could be found. These lines are members of a multiplet, the transitions occurring between levels J=0, 1, 2 and the level J=1, g=1.78.

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Wavelength	Classification	Zeeman pattern			g₁	g₂
2427.978^a	6s²S_1/2–6p ²P_3/2	(0.351)	1.024	1.656	1.996	1.340
2641.491^b	6s″ ²D_5/2–6p″ ⁴P_3/2	(0)	1.009		1.199	1.422
2675.953^b	6s²S_1/2–6p ²P_1/2	(0.668)	1.330		1.998	0.662
2688.721^b,c	6s″ ²D_3/2–6p ²F_5/2	0.976	(0)	1.267	0.800	0.984
2700.903^b	6s″ ²D_5/2–6p″ ⁴F_5/2	(0.377)			1.190	1.018
2748.257^b	6s″ ²D_5/2–6p″ ⁴F_7/2	(0)	1.318		1.196	1.256
2963.755		(0)	2.210
3029.219^a	6s″ ²D_5/2–a(⁴P_5/2)	(0.135)	(0.488)	0.873	1.193	1.528
		1.360	1.691	2.030
3122.781^b	6s″ ²D_5/2–6p ²P_3/2	(0)	1.066		1.181	1.333
3586.70	7_1/2–6⁰_9/2	(0)	1.083
3897.885^b	a–6d″ ⁴D_7/2	(0)	1.274		1.537	1.419
4065.08^a	6p ²P_1/2–6d ²D_3/2	(0.067)	0.717	0.851	0.650	0.784
4084.139^b	6p″ ⁴F_5/2–6d″ ⁴D_3/2	(0)	1.073		1.005	0.913
4315.113^b	6p″ ⁴F_7/2–6d″ ⁴D_5/2	(0)	1.260		1.266	1.272
4437.277^a	6p″ ⁴F_5/2–6d″ ⁴D_5/2	(0.399)	0.625	0.885	1.010	1.272
		1.137	1.406	1.670
4488.256^a	6p″ ⁴F_7/2–6d″ ⁴_7/2	(0.091)	(0.261)	(0.422)	1.253	1.423
		(0.567)	0.823	0.987
		1.161	1.339	1.499
		1.700	1.854
4792.601^a	6p ²P_3/2–6d ²D_5/2	(0.070)	(0.203)	0.984	1.332	1.193
		1.129	1.256
4811.611^a	6p ²P_3/2–6d ²D_3/2	(0.795)	0.534		1.329	0.800
		1.065	1.592
4902.30	14_3/2–15⁰_5/2	(0)	0.900
5064.616^a	6s″ ²D_3/2–6p ²P_3/2	(0.249)	(0.800)	0.536	0.809	1.335
			1.082	1.591
5147.59	6p″ ²P_3/2–6d″ ⁴D_3/2	(0.235)	0.980		1.064	0.896
5261.76	6p″ ²D_5/2–6d″ ⁴D_3/2	(0.158)	(0.487)		1.218	0.906
		[0.750]	1.058
		1.374	1.703
5655.764^b	6p″ ⁴D_7/2–6d″ ¹D_5/2	(0)	1.502		1.387	1.272
5837.396^b	6p″ ²P_1/2–7s ²S_1/2	(0.664)	1.331		0.667	1.995
5862.943	6p″ ²D_5/2–6d″ ⁴D_5/2	(0.086)	1.245		1.226	1.265
5956.984	6p″ ⁴D_7/2–6d″ ⁴D_7/2	(0.221)	1.390		1.357	1.427
6278.179^a	6s″ ²D_3/2–6p ²P_1/2	(0.075)	0.736	0.871	0.804	0.665
	6s″=5d⁹6s²
	6p″=5d⁹6s6p
	6d″=5d⁹6s6d
	()=parallel polarization
	[ ]=mixed polarization
	1.080=strongest component.

Configuration	Term (S and D)^a	Term (S and P)^b	g (exp)	g (LS)
5d¹⁰6s	²S_1/2	²S_1/2	2.003	2.000
5d¹⁰6p	²P_3/2	²P_3/2	1.331	1.333
	²P_1/2	²P_1/2	0.665	0.667
5d¹⁰7s	²S_1/2	²S_1/2	1.995	2.000
5d¹⁰6d	²D_5/2	²D_5/2	1.193	1.200
	²D_3/2	²D_3/2	0.795	0.800
5d⁹6s²	²D_5/2	²D_5/2	1.198	1.200
	²D_3/2	²D_3/2	0.806	0.800
5d⁹6s6p	⁴F_7/2	2⁰	1.255	1.238
	⁴D_7/2	7⁰	1.353	1.429
	⁴F_5/2	4⁰	1.010	1.028
	²F_5/2	15⁰	0.984	0.857
	²D_5/2	10⁰	1.220	1.200
	a(⁴P_5/2)	1⁰	1.528	1.600
	⁴P_3/2	5⁰	1.422	1.733
	²P_3/2	8⁰	1.060	1.333
5d⁹6s6d	⁴D_7/2	1	1.425	1.429
(called 5d⁹6s7s by S and P)	⁴D_5/2	2	1.270	1.372
(called 5d⁹6s7s by S and P)	⁴D_3/2	3	0.903	1.200

	S and P class.	Zeeman pattern		g₁	g₂
2802.20	15₃–3₄⁰	(0)	1.07	(1.20)	1.15
2819.97^a	16₂–4₂⁰	(0)	1.03	0.94	(1.12)
2822.70^a	26₂–10₃⁰	(0)	1.01
2825.45^a	5₂–2₃⁰	(0)	1.08	1.00	(1.04)
2838.03^a	16₂–5₁⁰	(0)	0.93	0.97	(1.04)
2893.41^a	26₂–12₂⁰	(0)	0.94	Inconsistent pattern
2907.07^a	8₃–12₂⁰	(0)	1.01	(1.15)	1.29
2913.52^a	6₄–6₃⁰	(0)	1.17	1.13	(1.30)
2990.28^a	5₂–1₂⁰	(0.69)	1.26	1.07	1.45
2995.00^a	15₃–6₃⁰	(0)	1.25	1.20	(1.30)
3586.70^a arc.→		(0)	1.03
3614.05		(0)	0.94
3623.4^a		(0)	0.73
3623.7 arc?→		(0)	1.21
3633.25^a	10₂–11₁⁰	(0)	1.14	(1.09)	1.11
3635.13		(0)	0.96
3649.1		(0)	1.18
3653.5^a		(0)	0.94
3654.0^a arc?→		(0)	1.02
3821.9		(0)	1.07
3822.9		(0)	0.51
3825.7		(0)	1.07
3959.13		(0)	1.25
4016.12^a	7₂–5₁⁰	(0)	1.01	(1.02)	1.04
4052.78^a arc?	7₂–4₂⁰	(0)	1.07	1.02	(1.12)
4174.97		(0)	1.09
4310.33^b		(0)	1.11
4374.78^b		(0.72)	1.51
4382.12		(0.17)	0.94
4410.37^a		(0)	1.17
4420.64^a	8₃–6₃⁰	(0.47)	1.23	1.15	1.30
4475.57^b		(0.39)	1.33
4482.18^b,a		(0.25)	1.10
4492.35^a		(0)	1.03
4498.05^b		(0)	1.02
4541.49		(0.27)	1.04
4549.52^a arc? →		(0)	1.12
4559.05		(0)	1.01
4582.40		(0.64)	1.24
4583.99		(0)	0.95
4588.02		(0)	1.19
4627.94		(0)	0.85
4633.21^a		(0)	0.99
4673.24^a		(0)	1.04
4754.26^a		(0)	1.52
4760.17^a	8₃–4₂⁰	(0)	1.08	(1.15)	1.12
4828.27		(0)	0.94
4851.46^b		(0)	1.06
4902.30 arc.		(0)	0.90
4948.87		(0.18)	1.19
5041.72		(0)	1.57
5202.82		(0.22)	1.05
5230.31 arc.		(0)	1.10
5269.33		(0)	1.34
5279.51		(0)	1.07
5363.44		(0)	1.13
5394.49		(0)	0.59
5409.35		(0)	1.07
5413.19	10₂–7₂⁰	(0.63) 1.09	1.36	1.08	1.38
5424.66^b		(0)	0.95
5428.42		(0)	1.15
5462.78^b		(0)	1.15
5504.72^b		(0)	1.08
5511.78		(0)	1.18
5514.64^a		(0)	1.03
5544.89^b		(0)	1.30
5577.95^a		(0)	0.99
5585.70		(0)	1.00
5587.30^b,a		(0)	1.17
5588.74		(0)	0.89
5590.38		(0)	0.90
5594.43		(0)	1.15
5597.84^a		(0) (0.29)	1.01 —, —.	J=2	J=1
				g=1.304	g=1.595
5600.14		(0.64)
5611.73^b,a		(0)	1.30
5619.95		(0.58)
5650.67^a		(0.17)	0.88
5661.87^a		(0.11)	1.29
5670.94^b,a		(0)	0.98
5688.79		(0)	1.59
5691.71^b,a arc?	13₂–11₁⁰	(0)	1.32	1.26	(1.11)
5700.90^b,a		(0.13)	1.08
5706.17^b,a		(0.581) 1.04	1.35	J=2	J=2
				g=1.35	g=1.04
5719.20^a		(0) (0.44)	0.86	J=2	J=1
		1.31	1.73?	g=1.303	g=1.744
5721.39^a		(0)	1.48
5723.07^b,a		(0)	0.77
5726.97^a arc x→		(0) (0.46)	0.90	J=2	J=1
		1.34, —		g=1.352	g=1.805
5737.29^b,a		(0) (0.29), —, 1.26	1.55	J=2	J=1
				1.264	0.980
5741.41^a arc→		(0)	1.15
5759.38^a		(0)	1.08
5762.43^b		(0)	1.22
5775.10^b,a		(0)	0.81
5788.39^a		(0)	1.01
5798.91^b,a		(0)	1.06
5818.67^a		(0)	1.50
5826.31^b		(0)	1.09
5898.97^b,a		(0)	0.84
5900.78^b,a		(0)	1.13
5917.18^b,a		(0)	1.29
5919.66^b,a		(0)	1.18
5923.80^b		(0)	1.06
5932.88^a		(0.27)	1.20
5962.71^a		(0)	1.08
5988.75^b,a		(0.41)	1.05
6003.73^b,a		(0)	1.21
6013.75^b		(0)	1.19
6022.55^a		(0)	1.58
6061.66^a	7₂–2₃⁰	(0)	1.07	(1.02)	1.04
6102.62^b,a		(0)	1.14
6111.79^b		(0)	1.09
6140.64^b		(0)	1.29
6181.44^b		(0)	1.12
6190.85^b		(0)	1.16
6193.13^b		(0)	1.27
6213.65^b		(0.17)	1.25
6219.31^b		(0)	1.04
6224.79^b		(0)	1.05
6271.89^b,a		(0)	0.83
6281.53^b,a		(0)	1.06
6301.66^a		(0)	1.09
6311.66^a		(0.35)	1.26
6323.94^b		(0)	1.08
6330.35^b		(0)	1.18
6387.26^b,a		(0)	1.16
6428.20^a		(0)	1.05
6461.10		(0)	1.10
6487.93^b		(0)	1.30
6499.88^a		(0)	1.44
6523.14^b,a		(0.47)	0.93
6589.76^a	15₃–19₃⁰^c	(0) (0.54),—, 1.04	1.60	J=2	J=1
				g=1.044	g=0.494
6649.43^b		(0)	1.03
6794.57 arc→		(0)	1.10

Wavelength	Classification	Zeeman pattern			g₁	g₂
2427.978^a	6s²S_1/2–6p ²P_3/2	(0.351)	1.024	1.656	1.996	1.340
2641.491^b	6s″ ²D_5/2–6p″ ⁴P_3/2	(0)	1.009		1.199	1.422
2675.953^b	6s²S_1/2–6p ²P_1/2	(0.668)	1.330		1.998	0.662
2688.721^b,c	6s″ ²D_3/2–6p ²F_5/2	0.976	(0)	1.267	0.800	0.984
2700.903^b	6s″ ²D_5/2–6p″ ⁴F_5/2	(0.377)			1.190	1.018
2748.257^b	6s″ ²D_5/2–6p″ ⁴F_7/2	(0)	1.318		1.196	1.256
2963.755		(0)	2.210
3029.219^a	6s″ ²D_5/2–a(⁴P_5/2)	(0.135)	(0.488)	0.873	1.193	1.528
		1.360	1.691	2.030
3122.781^b	6s″ ²D_5/2–6p ²P_3/2	(0)	1.066		1.181	1.333
3586.70	7_1/2–6⁰_9/2	(0)	1.083
3897.885^b	a–6d″ ⁴D_7/2	(0)	1.274		1.537	1.419
4065.08^a	6p ²P_1/2–6d ²D_3/2	(0.067)	0.717	0.851	0.650	0.784
4084.139^b	6p″ ⁴F_5/2–6d″ ⁴D_3/2	(0)	1.073		1.005	0.913
4315.113^b	6p″ ⁴F_7/2–6d″ ⁴D_5/2	(0)	1.260		1.266	1.272
4437.277^a	6p″ ⁴F_5/2–6d″ ⁴D_5/2	(0.399)	0.625	0.885	1.010	1.272
		1.137	1.406	1.670
4488.256^a	6p″ ⁴F_7/2–6d″ ⁴_7/2	(0.091)	(0.261)	(0.422)	1.253	1.423
		(0.567)	0.823	0.987
		1.161	1.339	1.499
		1.700	1.854
4792.601^a	6p ²P_3/2–6d ²D_5/2	(0.070)	(0.203)	0.984	1.332	1.193
		1.129	1.256
4811.611^a	6p ²P_3/2–6d ²D_3/2	(0.795)	0.534		1.329	0.800
		1.065	1.592
4902.30	14_3/2–15⁰_5/2	(0)	0.900
5064.616^a	6s″ ²D_3/2–6p ²P_3/2	(0.249)	(0.800)	0.536	0.809	1.335
			1.082	1.591
5147.59	6p″ ²P_3/2–6d″ ⁴D_3/2	(0.235)	0.980		1.064	0.896
5261.76	6p″ ²D_5/2–6d″ ⁴D_3/2	(0.158)	(0.487)		1.218	0.906
		[0.750]	1.058
		1.374	1.703
5655.764^b	6p″ ⁴D_7/2–6d″ ¹D_5/2	(0)	1.502		1.387	1.272
5837.396^b	6p″ ²P_1/2–7s ²S_1/2	(0.664)	1.331		0.667	1.995
5862.943	6p″ ²D_5/2–6d″ ⁴D_5/2	(0.086)	1.245		1.226	1.265
5956.984	6p″ ⁴D_7/2–6d″ ⁴D_7/2	(0.221)	1.390		1.357	1.427
6278.179^a	6s″ ²D_3/2–6p ²P_1/2	(0.075)	0.736	0.871	0.804	0.665
	6s″=5d⁹6s²
	6p″=5d⁹6s6p
	6d″=5d⁹6s6d
	()=parallel polarization
	[ ]=mixed polarization
	1.080=strongest component.

Configuration	Term (S and D)^a	Term (S and P)^b	g (exp)	g (LS)
5d¹⁰6s	²S_1/2	²S_1/2	2.003	2.000
5d¹⁰6p	²P_3/2	²P_3/2	1.331	1.333
	²P_1/2	²P_1/2	0.665	0.667
5d¹⁰7s	²S_1/2	²S_1/2	1.995	2.000
5d¹⁰6d	²D_5/2	²D_5/2	1.193	1.200
	²D_3/2	²D_3/2	0.795	0.800
5d⁹6s²	²D_5/2	²D_5/2	1.198	1.200
	²D_3/2	²D_3/2	0.806	0.800
5d⁹6s6p	⁴F_7/2	2⁰	1.255	1.238
	⁴D_7/2	7⁰	1.353	1.429
	⁴F_5/2	4⁰	1.010	1.028
	²F_5/2	15⁰	0.984	0.857
	²D_5/2	10⁰	1.220	1.200
	a(⁴P_5/2)	1⁰	1.528	1.600
	⁴P_3/2	5⁰	1.422	1.733
	²P_3/2	8⁰	1.060	1.333
5d⁹6s6d	⁴D_7/2	1	1.425	1.429
(called 5d⁹6s7s by S and P)	⁴D_5/2	2	1.270	1.372
(called 5d⁹6s7s by S and P)	⁴D_3/2	3	0.903	1.200

Abstract

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Figures (1)

Tables (3)

Journal of the Optical Society of America