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Infrared Spectroscopy at High Pressures: Polarized Spectra of Single Crystals of Acetonitrile

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Abstract

Single crystals of three polymorphs of acetonitrile and acetonitrile-d3 have been grown under pressure in a diamond anvil cell. While still under pressure polarized mid-infrared spectra of these three single crystals have been obtained. In addition, low temperature far-infrared spectra have been recorded for polycrystals of two of the polymorphs. These data have been used to predict likely crystal structures for the three crystalline phases.

© 1970 Optical Society of America

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