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Radiation and collisional energy transfer among the A 2Πi and X 2+ states of CN

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Abstract

Laser-photolysis–laser-induced-fluorescence methods are used to characterize the collisional energy transfer between CN (A 2Πi) and (X 2+) states and to measure radiative lifetimes of the (A 2Πi) v′ = 2–7 vibrational levels. In addition, use of the A 2ΠiX 2+ system for the laser-induced-fluorescence determination of (X 2+) populations is demonstrated and discussed.

© 1993 Optical Society of America

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