Improved line parameters for ozone bands in the 10-μm spectral region

Jean-Marie Flaud; Claude Camy-Peyret; Curtis P. Rinsland; V. Malathy Devi; Mary Ann H. Smith; Aaron Goldman

doi:10.1364/AO.29.003667

Applied Optics
Vol. 29,
Issue 25,
pp. 3667-3671
(1990)
•https://doi.org/10.1364/AO.29.003667

Improved line parameters for ozone bands in the 10-μm spectral region

Jean-Marie Flaud, Claude Camy-Peyret, Curtis P. Rinsland, V. Malathy Devi, Mary Ann H. Smith, and Aaron Goldman

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Jean-Marie Flaud, Claude Camy-Peyret, Curtis P. Rinsland, V. Malathy Devi, Mary Ann H. Smith, and Aaron Goldman, "Improved line parameters for ozone bands in the 10-μm spectral region," Appl. Opt. 29, 3667-3671 (1990)

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Abstract

A complete update of spectroscopic line parameters for the 10-μm bands of ozone is reported. The listing contains calculated positions, intensities, lower state energies, and air- and self-broadened halfwidths of more than 53,000 lines. The results have been generated using improved spectroscopic parameters obtained in a number of recent high resolution laboratory studies. A total of eighteen bands of ¹⁶O₃ (sixteen hot bands plus the ν₁ and ν₃ fundamentals) are included along with the ν₁ and ν₃ fundamentals of both ¹⁶O¹⁶O¹⁸AO and ¹⁶O¹⁸AO¹⁶O. As shown by comparisons of line-by-line simulations with 0.003-cm⁻¹ resolution balloon-borne stratospheric solar spectra, the new parameters greatly improve the accuracy of atmospheric calculations in the 10-μm region, especially for the isotopic ¹⁶O¹⁶O¹⁸AO and ¹⁶O¹⁸AO¹⁶O lines.

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Vibrational States		Isotopea	Band Center (cm⁻¹)	Calculated Intensitiesb		Number of Lines

Upper	Lower			S_bandc	S_listd
012	110	666	929.8447	4.16×10⁻²³	3.29×10⁻²³	164
002	100	666	954.7535	3.33×10⁻²¹	3.27×10⁻²¹	951
111	110	666	988.9772	2.12×10⁻²¹	2.10×10⁻²¹	1342
012	011	666	999.5841	6.01×10⁻²¹	6.00×10⁻²¹	1603
101	100	666	1007.6470	6.25×10⁻²⁰	6.25×10⁻²⁰	2646
001	000	666	1008.4528	2.65×10⁻²⁰	2.65×10⁻²⁰	2095
021	020	666	1008.6618	1.50×10⁻²⁰	1.50×10⁻²⁰	1511
002	001	666	1015.8068	1.68×10⁻¹⁹	1.68×10⁻¹⁹	3137
011	010	666	1025.5914	4.64×10⁻¹⁹	4.64×10⁻¹⁹	3883
001	000	666	1028.1120	5.12×10⁻²⁰	5.12×10⁻²⁰	3827
001	000	666	1042.0840	1.41×10⁻¹⁷	1.41×10⁻¹⁷	7224
111	011	666	1058.7166	1.22×10⁻²²	6.38×10⁻²³	252
101	001	666	1068.7003	5.31×10⁻²¹	5.24×10⁻²¹	2558
100	000	686	1074.3076	4.54×10⁻²²	4.54×10⁻²²	888
120	020	666	1087.3041	2.72×10⁻²²	2.21×10⁻²²	820
210	110	666	1089.9162	8.85×10⁻²³	3.33×10⁻²³	177
100	000	668	1090.3541	4.07×10⁻²¹	4.07×10⁻²¹	4425
110	010	666	1095.3308	1.27×10⁻²⁰	1.27×10⁻²⁰	3885
200	100	666	1098.0179	3.37×10⁻²¹	3.30×10⁻²¹	2931
100	000	666	1103.1373	5.40×10⁻¹⁹	5.40×10⁻¹⁹	6766
200	001	666	1159.0712	8.42×10⁻²¹	8.34×10⁻²¹	2057
210	011	666	1159.6556	1.95×10⁻²²	1.65×10⁻²²	593

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Applied Optics