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Conferences > UP > 2020 > M4B > M4B.29

Gold Rush in Dynamics? Time-resolved Ion Spectroscopy Reveals Ultrafast Processes in Isomorphic, Ligated Ag/Au Coinage Metal Dimers

S. V. Kruppa, M. Schmitt, R. Israil, F. Bäppler, M. Grupe, L. Schüssler, R. Diller, W. Klopper, and C. Riehn

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Abstract

Ultrafast electronic dynamics and UV absorption of phosphine–ligated (L) coinage metal complexes [Ag2(L)2]2, [AgAu(L)2]2+ and [Au2(L)2]2+ reveal the influence of intermetallic interaction on electronic states. Isomorphic exchange by AuI presumably accelerates ISC rate.

© 2020 The Author(s)

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