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Impact of RNA Melting on Hydrating Water Structure Mapped by Femtosecond 2D-IR Spectroscopy

Benjamin P. Fingerhut, Achintya Kundu, Jakob Schauss, and Thomas Elsaesser

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Abstract

We discern hydration geometries around the sugar-phosphate-backbone of an RNA double helix at the molecular level. RNA disordering upon melting is connected with a transition from ordered water structures towards local phosphate group hydration shells.

© 2020 The Author(s)

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