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Long-Lived Vibronic Coherence in Pentafluorobenzene in the ππ* Excited State

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Abstract

We report on a long-lived vibronic coherence by coupling of the lowest ππ* and πσ* electronic states of pentafluorobenzene observed by femtosecond mass spectrometry, photoelectron imaging and high-level ab initio quantum dynamics calculations.

© 2016 Optical Society of America

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