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Singlet Fission Mediating States in TIPS-Pentacene and its Aza-Derivatives Uncovered by Pump-Depletion-Probe Spectroscopy

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Abstract

Femtosecond pump-depletion-probe experiments were carried out in order to unveil the ultrafast excited singlet fission dynamics of TIPS-pentacene derivatives. The extremely short-lived intermediate 1TT state is revealed and the nitrogen-substitution leads to shorter dynamics.

© 2016 Optical Society of America

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