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Conferences > UP > 2016 > UM2A > UM2A.6

Vibrational Coherence Spectroscopy of Biomimetic Molecular Switches

Moussa Gueye, Mounika Rapolu, Stefan Haacke, and Jérémie Léonard

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Abstract

C=C double-bond photoisomerization is investigated by impulsive vibrational spectroscopy using a 400-nm, 8-fs pump. A specific, very pronounced sub-100 cm−1 vibrational mode is observed only when the electronic population decay is faster than 300 fs.

© 2016 Optical Society of America

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