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The Photoprotective Properties of Adenine: Time-resolved Photoelectron Spectroscopy at Different Excitation Wavelengths

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Abstract

Competing deactivation pathways in Adenine are identified using wavelength-dependent time-resolved photoelectron spectroscopy. Excited state lifetimes associated with ππ*→nπ*→ground state relaxation decrease with increasing excitation energies and an additional pathway is accessible around 6eV.

© 2010 Optical Society of America

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