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Solvated Electron Scavenging by Metal Cations: A Microscopic Picture Derived from the Transient Effect

Uli Schmidhammer, Pascal Pernot, Pierre Jeunesse, Shigeo Murata, and Mehran Mostafavi

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Abstract

The decay of the solvated electron generated by picosecond electron radiolysis is measured for highly concentrated oxidizers in a viscous solvent. Analyzing the non-exponential kinetics reveals molecular parameters of the reaction, particularly its distance distribution.

© 2010 Optical Society of America

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