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Towards a Molecular Movie: Real Time Observation of Hydrogen Bond Breaking by Transient 2D-IR Spectroscopy in a Cyclic Peptide

Christoph Kolano, Jan Helbing, Peter Hamm, and Wolfram Sander

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Abstract

Transient two-dimensional infrared spectroscopy (T2D–IR) has been used to observe in real time the non-equilibrium structural dynamics of intramolecular hydrogen bond breaking in a small cyclic disulfide-bridged peptide.

© 2006 Optical Society of America

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